light emission may cease immediately upon cessation of the exposure, or it
may continue for an indefinite period. The property of continuing to emit light after the energizing source has been removed is known as phosphores- cence. Certain of the alkaline earth sulphides exhibit this property for a significant period of time after the activating exposure ceases and for this reason are classed as phosphorescent materials. Phosphorescent materials are activated not only by ultraviolet energy but also by light. (Most fluorescent materials respond also to light wave- lengths, but because of the masking effect of the reflected light the relatively small fluorescent brightness component is not noticed.) Many alkaline earth sulphides not only emit light when exposed to ultraviolet or light energy, but also exhibit this property under bombardment by alpha rays from radium. Thus, by compounding a mixture of such a radioluminescent material and a small amount of radium compound, a self-luminous mixture can be produced. Such a radium-luminous compound will continue to emit light without the help of external activation of any type for periods as long as six months to a year in practical applications. Fluorescent materials. Most fluorescent materials now available com- mercially depend upon organic dyes as the source of their fluorescence. Used in night clubs, theaters, ice shows, and other places of entertainment, these materials form spectacular displays when excited by ultraviolet energy in a darkened area. Practically all of the fluorescent materials used commercially today are activated by ultraviolet energy of the 0.3650- micron wavelength. This wavelength is emitted by mercury-vapor lamps filtered with a type of glass that absorbs the greater part of visible light but permits the relatively invisible ultraviolet radiation to pass through. The 360 BL fluorescent lamp has a high percentage of its output in the 0.3650-micron region and can be used in combination with the proper filter for exciting fluorescent materials. However, this source is not as con- centrated as the mercury-vapor-discharge lamp, and where more precise control of the radiation is necessary, the mercury lamp is preferred. Argon- glow lamps furnish ultraviolet energy of the proper wavelength for exciting- fluorescence, but in small quantities. Incandescent-filament lamps, though they emit a small amount of near-visible ultraviolet, are quite inefficient sources. In order to transmit a useful amount of ultraviolet, any filter used with filament lamps must pass a large amount of light also. This masks the fluorescent effect. Fluorescent paint, ink, and dyed fabrics are available in many colors, including red, orange, green, blue, yellow, and a white that appears blue under ultraviolet. Because these materials transform ultraviolet energy into light, as well as reflect incident light, their brightness under daylight is striking. This is true because of the ultraviolet energy in daylight, which, after striking the material, returns to the eye as light in addition to the daylight reflected by the material and gives some fluorescent materials an apparent reflectance (under daylight) as great as 110 per cent, that is, the}' send back more visible light than strikes them. This quality is especially useful in signal flags and signal panels that can be seen at greater distances
Handbook of Fluorescent Gems and Minerals - An Exposition and Catalog of the Fluorescent and Phosphorescent Gems and Minerals, Including the Use of Ultraviolet Light in the Earth Sciences