2-138

PHYSICAL AND CHEMICAL DATA

CRITICAL CONSTANTS
ADDITIONAL REFERENCES
Other data and estimation techniques for the elements are contained
in Gates and Thodos, Am. Inst. Chem. Eng. J., 6 (1960):5054; and
Ohse and von Tippelskirch, High TemperaturesHigh Pressures, 9
(1977):367385. For inorganic substances see Mathews, Chem. Rev.,
TABLE 2-141

72 (1972):71100; for organics see Kudchaker, Alani, and Zwolinski,

Chem. Rev., 68 (1968):659735; and for fluorocarbons see Advances
in Fluorine Chemistry, App. B, Butterworth. Washington, 1963, pp.
173175. Pages 649 and 650 of the 84th edition of the Handbook of
Chemistry and Physics provide an excellent list of references for critical
properties.

Critical Constants and Acentric Factors of Inorganic and Organic Compounds

Vc,

Cmpd.

no.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64

Name
Acetaldehyde
Acetamide
Acetic acid
Acetic anhydride
Acetone
Acetonitrile
Acetylene
Acrolein
Acrylic acid
Acrylonitrile
Air
Ammonia
Anisole
Argon
Benzamide
Benzene
Benzenethiol
Benzoic acid
Benzonitrile
Benzophenone
Benzyl alcohol
Benzyl ethyl ether
Benzyl mercaptan
Biphenyl
Bromine
Bromobenzene
Bromoethane
Bromomethane
1,2-Butadiene
1,3-Butadiene
Butane
1,2-Butanediol
1,3-Butanediol
1-Butanol
2-Butanol
1-Butene
cis-2-Butene
trans-2-Butene
Butyl acetate
Butylbenzene
Butyl mercaptan
sec-Butyl mercaptan
1-Butyne
Butyraldehyde
Butyric acid
Butyronitrile
Carbon dioxide
Carbon disulfide
Carbon monoxide
Carbon tetrachloride
Carbon tetrafluoride
Chlorine
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1-Chloropropane
2-Chloropropane
m-Cresol
o-Cresol
p-Cresol
Cumene
Cyanogen
Cyclobutane

Formula
C2H4O
C2H5NO
C2H4O2
C4H6O3
C3H6O
C2H3N
C2H2
C3H4O
C3H4O2
C3H3N
Mixture
H3N
C7H8O
Ar
C7H7NO
C6H6
C6H6S
C7H6O2
C7H5N
C13H10O
C7H8O
C9H12O
C7H8S
C12H10
Br2
C6H5Br
C2H5Br
CH3Br
C4H6
C4H6
C4H10
C4H10O2
C4H10O2
C4H10O
C4H10O
C4H8
C4H8
C4H8
C6H12O2
C10H14
C4H10S
C4H10S
C4H6
C4H8O
C4H8O2
C4H7N
CO2
CS2
CO
CCl4
CF4
Cl2
C6H5Cl
C2H5Cl
CHCl3
CH3Cl
C3H7Cl
C3H7Cl
C7H8O
C7H8O
C7H8O
C9H12
C2N2
C4H8

Acentric

CAS no.

Mol. wt.

Tc, K

Pc, MPa

m3/kmol

Zc

factor

75-07-0
60-35-5
64-19-7
108-24-7
67-64-1
75-05-8
74-86-2
107-02-8
79-10-7
107-13-1
132259-10-0
7664-41-7
100-66-3
7440-37-1
55-21-0
71-43-2
108-98-5
65-85-0
100-47-0
119-61-9
100-51-6
539-30-0
100-53-8
92-52-4
7726-95-6
108-86-1
74-96-4
74-83-9
590-19-2
106-99-0
106-97-8
584-03-2
107-88-0
71-36-3
78-92-2
106-98-9
590-18-1
624-64-6
123-86-4
104-51-8
109-79-5
513-53-1
107-00-6
123-72-8
107-92-6
109-74-0
124-38-9
75-15-0
630-08-0
56-23-5
75-73-0
7782-50-5
108-90-7
75-00-3
67-66-3
74-87-3
540-54-5
75-29-6
108-39-4
95-48-7
106-44-5
98-82-8
460-19-5
287-23-0

44.053
59.067
60.052
102.089
58.079
41.052
26.037
56.063
72.063
53.063
28.960
17.031
108.138
39.948
121.137
78.112
110.177
122.121
103.121
182.218
108.138
136.191
124.203
154.208
159.808
157.008
108.965
94.939
54.090
54.090
58.122
90.121
90.121
74.122
74.122
56.106
56.106
56.106
116.158
134.218
90.187
90.187
54.090
72.106
88.105
69.105
44.010
76.141
28.010
153.823
88.004
70.906
112.557
64.514
119.378
50.488
78.541
78.541
108.138
108.138
108.138
120.192
52.035
56.106

466
761
591.95
606
508.2
545.5
308.3
506
615
535
132.45
405.65
645.6
150.86
824
562.05
689
751
699.35
830
720.15
662
718
773
584.15
670.15
503.8
467
452
425
425.12
680
676
563.1
535.9
419.5
435.5
428.6
575.4
660.5
570.1
554
440
537.2
615.7
582.25
304.21
552
132.92
556.35
227.51
417.15
632.35
460.35
536.4
416.25
503.15
489
705.85
697.55
704.65
631
400.15
459.93

5.55
6.6
5.786
4
4.701
4.83
6.138
5
5.66
4.48
3.774
11.28
4.25
4.898
5.05
4.895
4.74
4.47
4.215
3.352
4.374
3.11
4.06
3.38
10.3
4.519
6.23
8
4.36
4.32
3.796
5.21
4.02
4.414
4.188
4.02
4.21
4.1
3.09
2.89
3.97
4.06
4.6
4.32
4.06
3.79
7.383
7.9
3.499
4.56
3.745
7.71
4.519
5.27
5.472
6.68
4.58
4.54
4.56
5.01
5.15
3.209
5.98
4.98

0.154
0.215
0.177
0.29
0.209
0.173
0.112
0.197
0.208
0.212
0.09147
0.07247
0.337
0.07459
0.346
0.256
0.315
0.344
0.3132
0.5677
0.382
0.442
0.367
0.497
0.135
0.324
0.215
0.156
0.22
0.221
0.255
0.303
0.305
0.273
0.27
0.241
0.234
0.238
0.389
0.497
0.307
0.307
0.208
0.258
0.293
0.278
0.094
0.16
0.0944
0.276
0.143
0.124
0.308
0.2
0.239
0.143
0.247
0.247
0.312
0.282
0.277
0.434
0.195
0.21

0.221
0.224
0.208
0.23
0.233
0.184
0.268
0.234
0.23
0.214
0.313
0.242
0.267
0.291
0.255
0.268
0.261
0.246
0.227
0.276
0.279
0.25
0.25
0.261
0.286
0.263
0.32
0.321
0.255
0.27
0.274
0.279
0.218
0.258
0.254
0.278
0.272
0.274
0.251
0.262
0.257
0.271
0.262
0.25
0.232
0.218
0.274
0.275
0.299
0.272
0.283
0.276
0.265
0.275
0.293
0.276
0.27
0.276
0.242
0.244
0.244
0.265
0.351
0.273

0.2907
0.4210
0.4665
0.4535
0.3065
0.3379
0.1912
0.3198
0.5383
0.3498
0.2526
0.3502
0.0000
0.5585
0.2103
0.2628
0.6028
0.3662
0.5019
0.3631
0.4332
0.3126
0.4029
0.1290
0.2506
0.2548
0.1922
0.1659
0.1950
0.2002
0.6305
0.7043
0.5883
0.5692
0.1845
0.2019
0.2176
0.4394
0.3941
0.2714
0.2506
0.2470
0.2774
0.6805
0.3714
0.2236
0.1107
0.0482
0.1926
0.1790
0.0688
0.2499
0.1902
0.2219
0.1531
0.2277
0.1986
0.4480
0.4339
0.5072
0.3274
0.2790
0.1847

CRITICAL CONSTANTS
TABLE 2-141

Critical Constants and Acentric Factors of Inorganic and Organic Compounds (Continued)
Vc,

Cmpd.

no.
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140

2-139

Acentric

Name

Formula

CAS no.

Mol. wt.

Tc, K

Pc, MPa

m3/kmol

Zc

factor

Cyclohexane
Cyclohexanol
Cyclohexanone
Cyclohexene
Cyclopentane
Cyclopentene
Cyclopropane
Cyclohexyl mercaptan
Decanal
Decane
Decanoic acid
1-Decanol
1-Decene
Decyl mercaptan
1-Decyne
Deuterium
1,1-Dibromoethane
1,2-Dibromoethane
Dibromomethane
Dibutyl ether
m-Dichlorobenzene
o-Dichlorobenzene
p-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
Dichloromethane
1,1-Dichloropropane
1,2-Dichloropropane
Diethanol amine
Diethyl amine
Diethyl ether
Diethyl sulfide
1,1-Difluoroethane
1,2-Difluoroethane
Difluoromethane
Di-isopropyl amine
Di-isopropyl ether
Di-isopropyl ketone
1,1-Dimethoxyethane
1,2-Dimethoxypropane
Dimethyl acetylene
Dimethyl amine
2,3-Dimethylbutane
1,1-Dimethylcyclohexane
cis-1,2-Dimethylcyclohexane
trans-1,2-Dimethylcyclohexane
Dimethyl disulfide
Dimethyl ether
N,N-Dimethyl formamide
2,3-Dimethylpentane
Dimethyl phthalate
Dimethylsilane
Dimethyl sulfide
Dimethyl sulfoxide
Dimethyl terephthalate
1,4-Dioxane
Diphenyl ether
Dipropyl amine
Dodecane
Eicosane
Ethane
Ethanol
Ethyl acetate
Ethyl amine
Ethylbenzene
Ethyl benzoate
2-Ethyl butanoic acid
Ethyl butyrate
Ethylcyclohexane
Ethylcyclopentane
Ethylene
Ethylenediamine
Ethylene glycol
Ethyleneimine
Ethylene oxide
Ethyl formate

C6H12
C6H12O
C6H10O
C6H10
C5H10
C5H8
C3H6
C6H12S
C10H20O
C10H22
C10H20O2
C10H22O
C10H20
C10H22S
C10H18
D2
C2H4Br2
C2H4Br2
CH2Br2
C8H18O
C6H4Cl2
C6H4Cl2
C6H4Cl2
C2H4Cl2
C2H4Cl2
CH2Cl2
C3H6Cl2
C3H6Cl2
C4H11NO2
C4H11N
C4H10O
C4H10S
C2H4F2
C2H4F2
CH2F2
C6H15N
C6H14O
C7H14O
C4H10O2
C5H12O2
C4H6
C2H7N
C6H14
C8H16
C8H16
C8H16
C2H6S2
C2H6O
C3H7NO
C7H16
C10H10O4
C2H8Si
C2H6S
C2H6OS
C10H10O4
C4H8O2
C12H10O
C6H15N
C12H26
C20H42
C2H6
C2H6O
C4H8O2
C2H7N
C8H10
C9H10O2
C6H12O2
C6H12O2
C8H16
C7H14
C2H4
C2H8N2
C2H6O2
C2H5N
C2H4O
C3H6O2

110-82-7
108-93-0
108-94-1
110-83-8
287-92-3
142-29-0
75-19-4
1569-69-3
112-31-2
124-18-5
334-48-5
112-30-1
872-05-9
143-10-2
764-93-2
7782-39-0
557-91-5
106-93-4
74-95-3
142-96-1
541-73-1
95-50-1
106-46-7
75-34-3
107-06-2
75-09-2
78-99-9
78-87-5
111-42-2
109-89-7
60-29-7
352-93-2
75-37-6
624-72-6
75-10-5
108-18-9
108-20-3
565-80-0
534-15-6
7778-85-0
503-17-3
124-40-3
79-29-8
590-66-9
2207-01-4
6876-23-9
624-92-0
115-10-6
68-12-2
565-59-3
131-11-3
1111-74-6
75-18-3
67-68-5
120-61-6
123-91-1
101-84-8
142-84-7
112-40-3
112-95-8
74-84-0
64-17-5
141-78-6
75-04-7
100-41-4
93-89-0
88-09-5
105-54-4
1678-91-7
1640-89-7
74-85-1
107-15-3
107-21-1
151-56-4
75-21-8
109-94-4

84.159
100.159
98.143
82.144
70.133
68.117
42.080
116.224
156.265
142.282
172.265
158.281
140.266
174.347
138.250
4.032
187.861
187.861
173.835
130.228
147.002
147.002
147.002
98.959
98.959
84.933
112.986
112.986
105.136
73.137
74.122
90.187
66.050
66.050
52.023
101.190
102.175
114.185
90.121
104.148
54.090
45.084
86.175
112.213
112.213
112.213
94.199
46.068
73.094
100.202
194.184
60.170
62.134
78.133
194.184
88.105
170.207
101.190
170.335
282.547
30.069
46.068
88.105
45.084
106.165
150.175
116.158
116.158
112.213
98.186
28.053
60.098
62.068
43.068
44.053
74.079

553.8
650.1
653
560.4
511.7
507
398
664
674.2
617.7
722.1
688
616.6
696
619.85
38.35
628
650.15
611
584.1
683.95
705
684.75
523
561.6
510
560
572
736.6
496.6
466.7
557.15
386.44
445
351.255
523.1
500.05
576
507.8
543
473.2
437.2
500
591.15
606.15
596.15
615
400.1
649.6
537.3
766
402
503.04
729
772
587
766.8
550
658
768
305.32
514
523.3
456.15
617.15
698
655
571
609.15
569.5
282.34
593
720
537
469.15
508.4

4.08
4.26
4
4.35
4.51
4.8
5.54
3.97
2.6
2.11
2.28
2.308
2.223
2.13
2.37
1.6617
6.03
5.477
7.17
2.46
4.07
4.07
4.07
5.07
5.37
6.08
4.24
4.24
4.27
3.71
3.64
3.96
4.52
4.34
5.784
3.2
2.88
3.02
3.773
3.446
4.87
5.34
3.15
2.938
2.938
2.938
5.36
5.37
4.42
2.91
2.78
3.56
5.53
5.65
2.78
5.208
3.08
3.14
1.82
1.16
4.872
6.137
3.88
5.62
3.609
3.18
3.41
2.95
3.04
3.4
5.041
6.29
8.2
6.85
7.19
4.74

0.308
0.322
0.311
0.291
0.26
0.245
0.162
0.355
0.58
0.617
0.639
0.645
0.584
0.624
0.552
0.060263
0.276
0.2616
0.223
0.487
0.351
0.351
0.351
0.24
0.22
0.185
0.291
0.291
0.349
0.301
0.28
0.318
0.179
0.195
0.123
0.418
0.386
0.416
0.297
0.35
0.221
0.18
0.361
0.45
0.46
0.46
0.252
0.17
0.26199
0.393
0.53
0.258
0.201
0.227
0.529
0.238
0.503
0.402
0.755
1.34
0.1455
0.168
0.286
0.207
0.374
0.489
0.389
0.403
0.43
0.375
0.131
0.264
0.191
0.173
0.140296
0.229

0.273
0.254
0.229
0.272
0.276
0.279
0.271
0.255
0.269
0.254
0.243
0.26
0.253
0.23
0.254
0.314
0.319
0.265
0.315
0.247
0.251
0.244
0.251
0.28
0.253
0.265
0.265
0.259
0.243
0.27
0.263
0.272
0.252
0.229
0.244
0.308
0.267
0.262
0.265
0.267
0.274
0.264
0.274
0.269
0.268
0.273
0.264
0.2744
0.214
0.256
0.231
0.275
0.266
0.212
0.229
0.254
0.243
0.276
0.251
0.243
0.279
0.241
0.255
0.307
0.263
0.268
0.244
0.25
0.258
0.269
0.281
0.337
0.262
0.265
0.25876
0.257

0.2081
0.3690
0.2990
0.2123
0.1949
0.1961
0.1278
0.2641
0.5820
0.4923
0.8126
0.6070
0.4805
0.5874
0.5178
0.1449
0.1250
0.2067
0.2095
0.4476
0.2790
0.2192
0.2846
0.2339
0.2866
0.1986
0.2529
0.2564
0.9529
0.3039
0.2811
0.2900
0.2751
0.2224
0.2771
0.3883
0.3387
0.4044
0.3277
0.3522
0.2385
0.2999
0.2493
0.2326
0.2324
0.2379
0.2059
0.2002
0.3177
0.2964
0.6568
0.1300
0.1943
0.2806
0.6371
0.2793
0.4389
0.4497
0.5764
0.9069
0.0995
0.6436
0.3664
0.2848
0.3035
0.4771
0.6326
0.4011
0.2455
0.2701
0.0862
0.4724
0.5068
0.2007
0.1974
0.2847

2-140

PHYSICAL AND CHEMICAL DATA

TABLE 2-141

Critical Constants and Acentric Factors of Inorganic and Organic Compounds (Continued)
Vc,

Cmpd.

no.
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216

Acentric

Name

Formula

CAS no.

Mol. wt.

Tc, K

Pc, MPa

m3/kmol

Zc

factor

2-Ethyl hexanoic acid

Ethylhexyl ether
Ethylisopropyl ether
Ethylisopropyl ketone
Ethyl mercaptan
Ethyl propionate
Ethylpropyl ether
Ethyltrichlorosilane
Fluorine
Fluorobenzene
Fluoroethane
Fluoromethane
Formaldehyde
Formamide
Formic acid
Furan
Helium-4
Heptadecane
Heptanal
Heptane
Heptanoic acid
1-Heptanol
2-Heptanol
3-Heptanone
2-Heptanone
1-Heptene
Heptyl mercaptan
1-Heptyne
Hexadecane
Hexanal
Hexane
Hexanoic acid
1-Hexanol
2-Hexanol
2-Hexanone
3-Hexanone
1-Hexene
3-Hexyne
Hexyl mercaptan
1-Hexyne
2-Hexyne
Hydrazine
Hydrogen
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide
Hydrogen fluoride
Hydrogen sulfide
Isobutyric acid
Isopropyl amine
Malonic acid
Methacrylic acid
Methane
Methanol
N-Methyl acetamide
Methyl acetate
Methyl acetylene
Methyl acrylate
Methyl amine
Methyl benzoate
3-Methyl-1,2-butadiene
2-Methylbutane
2-Methylbutanoic acid
3-Methyl-1-butanol
2-Methyl-1-butene
2-Methyl-2-butene
2-Methyl-1-butene-3-yne
Methylbutyl ether
Methylbutyl sulfide
3-Methyl-1-butyne
Methyl butyrate
Methylchlorosilane
Methylcyclohexane
1-Methylcyclohexanol
cis-2-Methylcyclohexanol
trans-2-Methylcyclohexanol

C8H16O2
C8H18O
C5H12O
C6H12O
C2H6S
C5H10O2
C5H12O
C2H5Cl3Si
F2
C6H5F
C2H5F
CH3F
CH2O
CH3NO
CH2O2
C4H4O
He
C17H36
C7H14O
C7H16
C7H14O2
C7H16O
C7H16O
C7H14O
C7H14O
C7H14
C7H16S
C7H12
C16H34
C6H12O
C6H14
C6H12O2
C6H14O
C6H14O
C6H12O
C6H12O
C6H12
C6H10
C6H14S
C6H10
C6H10
H4N2
H2
HBr
HCl
CHN
HF
H2S
C4H8O2
C3H9N
C3H4O4
C4H6O2
CH4
CH4O
C3H7NO
C3H6O2
C3H4
C4H6O2
CH5N
C8H8O2
C5H8
C5H12
C5H10O2
C5H12O
C5H10
C5H10
C5H6
C5H12O
C5H12S
C5H8
C5H10O2
CH5ClSi
C7H14
C7H14O
C7H14O
C7H14O

149-57-5
5756-43-4
625-54-7
565-69-5
75-08-1
105-37-3
628-32-0
115-21-9
7782-41-4
462-06-6
353-36-6
593-53-3
50-00-0
75-12-7
64-18-6
110-00-9
7440-59-7
629-78-7
111-71-7
142-82-5
111-14-8
111-70-6
543-49-7
106-35-4
110-43-0
592-76-7
1639-09-4
628-71-7
544-76-3
66-25-1
110-54-3
142-62-1
111-27-3
626-93-7
591-78-6
589-38-8
592-41-6
928-49-4
111-31-9
693-02-7
764-35-2
302-01-2
1333-74-0
10035-10-6
7647-01-0
74-90-8
7664-39-3
7783-06-4
79-31-2
75-31-0
141-82-2
79-41-4
74-82-8
67-56-1
79-16-3
79-20-9
74-99-7
96-33-3
74-89-5
93-58-3
598-25-4
78-78-4
116-53-0
123-51-3
563-46-2
513-35-9
78-80-8
628-28-4
628-29-5
598-23-2
623-42-7
993-00-0
108-87-2
590-67-0
7443-70-1
7443-52-9

144.211
130.228
88.148
100.159
62.134
102.132
88.148
163.506
37.997
96.102
48.060
34.033
30.026
45.041
46.026
68.074
4.003
240.468
114.185
100.202
130.185
116.201
116.201
114.185
114.185
98.186
132.267
96.170
226.441
100.159
86.175
116.158
102.175
102.175
100.159
100.159
84.159
82.144
118.240
82.144
82.144
32.045
2.016
80.912
36.461
27.025
20.006
34.081
88.105
59.110
104.061
86.089
16.042
32.042
73.094
74.079
40.064
86.089
31.057
136.148
68.117
72.149
102.132
88.148
70.133
70.133
66.101
88.148
104.214
68.117
102.132
80.589
98.186
114.185
114.185
114.185

674.6
583
489
567
499.15
546
500.23
559.95
144.12
560.09
375.31
317.42
408
771
588
490.15
5.2
736
616.8
540.2
677.3
632.3
608.3
606.6
611.4
537.4
645
547
723
591
507.6
660.2
611.3
585.3
587.61
582.82
504
544
623
516.2
549
653.15
33.19
363.15
324.65
456.65
461.15
373.53
605
471.85
805
662
190.564
512.5
718
506.55
402.4
536
430.05
693
490
460.4
643
577.2
465
470
492
512.74
593
463.2
554.5
442
572.1
686
614
617

2.778
2.46
3.41
3.32
5.49
3.362
3.37
3.33
5.172
4.551
5.028
5.875
6.59
7.8
5.81
5.5
0.2275
1.34
3.16
2.74
3.043
3.085
3.001
2.92
2.94
2.92
2.77
3.21
1.4
3.46
3.025
3.308
3.446
3.311
3.287
3.32
3.21
3.53
3.08
3.62
3.53
14.7
1.313
8.552
8.31
5.39
6.48
8.963
3.7
4.54
5.64
4.79
4.599
8.084
4.98
4.75
5.63
4.25
7.46
3.59
3.83
3.38
3.89
3.93
3.447
3.42
4.38
3.371
3.47
4.2
3.473
4.17
3.48
4
3.79
3.79

0.528
0.487
0.329
0.369
0.207
0.345
0.339
0.414
0.066547
0.269
0.164
0.113
0.115
0.163
0.125
0.218
0.0573
1.11
0.434
0.428
0.466
0.444
0.447
0.433
0.434
0.402
0.465
0.387
1.04
0.369
0.371
0.408
0.382
0.385
0.378
0.378
0.348
0.331
0.412
0.322
0.331
0.158
0.064147
0.1
0.081
0.139
0.069
0.0985
0.292
0.221
0.258
0.28
0.0986
0.117
0.267
0.228
0.164
0.27
0.154
0.436
0.291
0.306
0.347
0.329
0.292
0.292
0.248
0.329
0.36
0.275
0.34
0.246
0.369
0.374
0.374
0.374

0.262
0.247
0.276
0.26
0.274
0.256
0.275
0.296
0.287
0.263
0.264
0.252
0.223
0.198
0.149
0.294
0.302
0.244
0.267
0.261
0.252
0.261
0.265
0.251
0.251
0.263
0.24
0.273
0.243
0.26
0.266
0.246
0.259
0.262
0.254
0.259
0.267
0.258
0.245
0.272
0.256
0.428
0.305
0.283
0.249
0.197
0.117
0.284
0.215
0.256
0.217
0.244
0.286
0.222
0.223
0.257
0.276
0.258
0.321
0.272
0.274
0.27
0.252
0.269
0.26
0.256
0.266
0.26
0.253
0.3
0.256
0.279
0.27
0.262
0.278
0.276

0.8067
0.4944
0.3056
0.3891
0.1878
0.3944
0.3473
0.2691
0.0530
0.2472
0.2200
0.1980
0.2818
0.4124
0.3173
0.2015
0.3900
0.7697
0.4279
0.3495
0.7564
0.5621
0.5628
0.4076
0.4190
0.3432
0.4226
0.3778
0.7174
0.3872
0.3013
0.7299
0.5586
0.5574
0.3846
0.3801
0.2888
0.2183
0.3681
0.3327
0.2214
0.3143
0.2160
0.0734
0.1315
0.4099
0.3823
0.0942
0.6141
0.2759
0.9418
0.3318
0.0115
0.5658
0.4351
0.3313
0.2115
0.3423
0.2814
0.4205
0.1874
0.2279
0.5894
0.5939
0.2341
0.2870
0.1370
0.3130
0.3229
0.3081
0.3775
0.2252
0.2361
0.2213
0.6805
0.6790

CRITICAL CONSTANTS
TABLE 2-141

Critical Constants and Acentric Factors of Inorganic and Organic Compounds (Continued)
Vc,

Cmpd.

no.
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
234
235
236
237
238
239
240
241
242
243
244
245
246
247
248
249
250
251
252
253
254
255
256
257
258
259
260
261
262
263
264
265
266
267
268
269
270
271
272
273
274
275
276
277
278
279
280
281
282
283
284
285
286
287
288
289
290
291
292

2-141

Acentric

Name

Formula

CAS no.

Mol. wt.

Tc, K

Pc, MPa

m3/kmol

Zc

factor

Methylcyclopentane
1-Methylcyclopentene
3-Methylcyclopentene
Methyldichlorosilane
Methylethyl ether
Methylethyl ketone
Methylethyl sulfide
Methyl formate
Methylisobutyl ether
Methylisobutyl ketone
Methyl Isocyanate
Methylisopropyl ether
Methylisopropyl ketone
Methylisopropyl sulfide
Methyl mercaptan
Methyl methacrylate
2-Methyloctanoic acid
2-Methylpentane
Methyl pentyl ether
2-Methylpropane
2-Methyl-2-propanol
2-Methyl propene
Methyl propionate
Methylpropyl ether
Methylpropyl sulfide
Methylsilane
alpha-Methyl styrene
Methyl tert-butyl ether
Methyl vinyl ether
Naphthalene
Neon
Nitroethane
Nitrogen
Nitrogen trifluoride
Nitromethane
Nitrous oxide
Nitric oxide
Nonadecane
Nonanal
Nonane
Nonanoic acid
1-Nonanol
2-Nonanol
1-Nonene
Nonyl mercaptan
1-Nonyne
Octadecane
Octanal
Octane
Octanoic acid
1-Octanol
2-Octanol
2-Octanone
3-Octanone
1-Octene
Octyl mercaptan
1-Octyne
Oxalic acid
Oxygen
Ozone
Pentadecane
Pentanal
Pentane
Pentanoic acid
1-Pentanol
2-Pentanol
2-Pentanone
3-Pentanone
1-Pentene
2-Pentyl mercaptan
Pentyl mercaptan
1-Pentyne
2-Pentyne
Phenanthrene
Phenol
Phenyl isocyanate

C6H12
C6H10
C6H10
CH4Cl2Si
C3H8O
C4H8O
C3H8S
C2H4O2
C5H12O
C6H12O
C2H3NO
C4H10O
C5H10O
C4H10S
CH4S
C5H8O2
C9H18O2
C6H14
C6H14O
C4H10
C4H10O
C4H8
C4H8O2
C4H10O
C4H10S
CH6Si
C9H10
C5H12O
C3H6O
C10H8
Ne
C2H5NO2
N2
F3N
CH3NO2
N2O
NO
C19H40
C9H18O
C9H20
C9H18O2
C9H20O
C9H20O
C9H18
C9H20S
C9H16
C18H38
C8H16O
C8H18
C8H16O2
C8H18O
C8H18O
C8H16O
C8H16O
C8H16
C8H18S
C8H14
C2H2O4
O2
O3
C15H32
C5H10O
C5H12
C5H10O2
C5H12O
C5H12O
C5H10O
C5H10O
C5H10
C5H12S
C5H12S
C5H8
C5H8
C14H10
C6H6O
C7H5NO

96-37-7
693-89-0
1120-62-3
75-54-7
540-67-0
78-93-3
624-89-5
107-31-3
625-44-5
108-10-1
624-83-9
598-53-8
563-80-4
1551-21-9
74-93-1
80-62-6
3004-93-1
107-83-5
628-80-8
75-28-5
75-65-0
115-11-7
554-12-1
557-17-5
3877-15-4
992-94-9
98-83-9
1634-04-4
107-25-5
91-20-3
7440-01-9
79-24-3
7727-37-9
7783-54-2
75-52-5
10024-97-2
10102-43-9
629-92-5
124-19-6
111-84-2
112-05-0
143-08-8
628-99-9
124-11-8
1455-21-6
3452-09-3
593-45-3
124-13-0
111-65-9
124-07-2
111-87-5
123-96-6
111-13-7
106-68-3
111-66-0
111-88-6
629-05-0
144-62-7
7782-44-7
10028-15-6
629-62-9
110-62-3
109-66-0
109-52-4
71-41-0
6032-29-7
107-87-9
96-22-0
109-67-1
2084-19-7
110-66-7
627-19-0
627-21-4
85-01-8
108-95-2
103-71-9

84.159
82.144
82.144
115.034
60.095
72.106
76.161
60.052
88.148
100.159
57.051
74.122
86.132
90.187
48.107
100.116
158.238
86.175
102.175
58.122
74.122
56.106
88.105
74.122
90.187
46.144
118.176
88.148
58.079
128.171
20.180
75.067
28.013
71.002
61.040
44.013
30.006
268.521
142.239
128.255
158.238
144.255
144.255
126.239
160.320
124.223
254.494
128.212
114.229
144.211
130.228
130.228
128.212
128.212
112.213
146.294
110.197
90.035
31.999
47.998
212.415
86.132
72.149
102.132
88.148
88.148
86.132
86.132
70.133
104.214
104.214
68.117
68.117
178.229
94.111
119.121

532.7
542
526
483
437.8
535.5
533
487.2
497
574.6
488
464.48
553.4
553.1
469.95
566
694
497.7
546.49
407.8
506.2
417.9
530.6
476.25
565
352.5
654
497.1
437
748.4
44.4
593
126.2
234
588.15
309.57
180.15
758
658
594.6
710.7
670.9
649.5
593.1
681
598.05
747
638.9
568.7
694.26
652.3
629.8
632.7
627.7
566.9
667.3
574
804
154.58
261
708
566.1
469.7
639.16
588.1
561
561.08
560.95
464.8
584.3
598
481.2
519
869
694.25
653

3.79
4.13
4.13
3.95
4.4
4.15
4.26
6
3.41
3.27
5.48
3.762
3.8
4.021
7.23
3.68
2.54
3.04
3.042
3.64
3.972
4
4.004
3.801
3.97
4.7
3.36
3.287
4.67
4.05
2.653
5.16
3.4
4.461
6.31
7.245
6.48
1.21
2.73
2.29
2.514
2.527
2.541
2.428
2.31
2.61
1.27
2.96
2.49
2.779
2.783
2.749
2.64
2.704
2.663
2.52
2.88
7.02
5.043
5.57
1.48
3.97
3.37
3.63
3.897
3.7
3.694
3.74
3.56
3.536
3.47
4.17
4.03
2.9
6.13
4.06

0.319
0.303
0.303
0.289
0.221
0.267
0.254
0.172
0.329
0.369
0.202
0.276
0.31
0.328
0.145
0.323
0.572
0.368
0.38
0.259
0.275
0.239
0.282
0.276
0.307
0.205
0.399
0.314
0.21
0.407
0.0417
0.236
0.08921
0.11875
0.173
0.0974
0.058
1.26
0.527
0.551
0.584
0.576
0.577
0.524
0.571
0.497
1.19
0.488
0.486
0.523
0.509
0.512
0.497
0.497
0.464
0.518
0.442
0.205
0.0734
0.089
0.969
0.313
0.313
0.35
0.326
0.326
0.301
0.336
0.293
0.385
0.359
0.277
0.276
0.554
0.229
0.37

0.273
0.278
0.286
0.284
0.267
0.249
0.244
0.255
0.272
0.253
0.273
0.269
0.256
0.28718
0.268
0.253
0.252
0.27
0.254
0.278
0.26
0.275
0.256
0.265
0.259
0.329
0.247
0.25
0.27
0.265
0.3
0.247
0.289
0.272
0.223
0.274
0.251
0.242
0.263
0.255
0.248
0.261
0.271
0.258
0.233
0.261
0.243
0.272
0.256
0.252
0.261
0.269
0.249
0.257
0.262
0.235
0.267
0.215
0.288
0.228
0.244
0.264
0.27
0.239
0.258
0.259
0.238
0.269
0.27
0.28
0.251
0.289
0.258
0.222
0.243
0.277

0.2288
0.2318
0.2296
0.2758
0.2314
0.3234
0.2091
0.2556
0.3078
0.3557
0.3007
0.2656
0.3208
0.2461
0.1582
0.2802
0.7913
0.2791
0.3442
0.1835
0.6152
0.1948
0.3466
0.2770
0.2737
0.1314
0.3230
0.2466
0.2416
0.3020
0.0396
0.3803
0.0377
0.1200
0.3480
0.1409
0.5829
0.8522
0.5117
0.4435
0.7724
0.5841
0.5911
0.4367
0.5260
0.4710
0.8114
0.4636
0.3996
0.7706
0.5697
0.5807
0.4549
0.4406
0.3921
0.4497
0.4233
0.9176
0.0222
0.2119
0.6863
0.3472
0.2515
0.7052
0.5748
0.5549
0.3433
0.3448
0.2372
0.2685
0.3207
0.2899
0.1752
0.4707
0.4435
0.4123

2-142

PHYSICAL AND CHEMICAL DATA

TABLE 2-141

Critical Constants and Acentric Factors of Inorganic and Organic Compounds (Concluded)
Vc,

Cmpd.

no.
293
294
295
296
297
298
299
300
301
302
303
304
305
306
307
308
309
310
311
312
313
314
315
316
317
318
319
320
321
322
323
324
325
326
327
328
329
330
331
332
333
334
335
336
337
338
339
340
341
342
343
344
345

Acentric

Name

Formula

CAS no.

Mol. wt.

Tc, K

Pc, MPa

m3/kmol

Zc

factor

Phthalic anhydride
Propadiene
Propane
1-Propanol
2-Propanol
Propenylcyclohexene
Propionaldehyde
Propionic acid
Propionitrile
Propyl acetate
Propyl amine
Propylbenzene
Propylene
Propyl formate
2-Propyl mercaptan
Propyl mercaptan
1,2-Propylene glycol
Quinone
Silicon tetrafluoride
Styrene
Succinic acid
Sulfur dioxide
Sulfur hexafluoride
Sulfur trioxide
Terephthalic acid
o-Terphenyl
Tetradecane
Tetrahydrofuran
1,2,3,4-Tetrahydronaphthalene
Tetrahydrothiophene
2,2,3,3-Tetramethylbutane
Thiophene
Toluene
1,1,2-Trichloroethane
Tridecane
Triethyl amine
Trimethyl amine
1,2,3-Trimethylbenzene
1,2,4-Trimethylbenzene
2,2,4-Trimethylpentane
2,3,3-Trimethylpentane
1,3,5-Trinitrobenzene
2,4,6-Trinitrotoluene
Undecane
1-Undecanol
Vinyl acetate
Vinyl acetylene
Vinyl chloride
Vinyl trichlorosilane
Water
m-Xylene
o-Xylene
p-Xylene

C8H4O3
C3H4
C3H8
C3H8O
C3H8O
C3H14
C3H6O
C3H6O2
C3H5N
C5H10O2
C3H9N
C9H12
C3H6
C4H8O2
C3H8S
C3H8S
C3H8O2
C6H4O2
F4Si
C8H8
C4H6O4
O2S
F6S
O3S
C8H6O4
C18H14
C14H30
C4H8O
C10H12
C4H8S
C8H18
C4H4S
C7H8
C2H3Cl3
C13H28
C6H15N
C3H9N
C9H12
C9H12
C8H18
C8H18
C6H3N3O6
C7H5N3O6
C11H24
C11H24O
C4H6O2
C4H4
C2H3Cl
C2H3Cl3Si
H2O
C8H10
C8H10
C8H10

85-44-9
463-49-0
74-98-6
71-23-8
67-63-0
13511-13-2
123-38-6
79-09-4
107-12-0
109-60-4
107-10-8
103-65-1
115-07-1
110-74-7
75-33-2
107-03-9
57-55-6
106-51-4
7783-61-1
100-42-5
110-15-6
7446-09-5
2551-62-4
7446-11-9
100-21-0
84-15-1
629-59-4
109-99-9
119-64-2
110-01-0
594-82-1
110-02-1
108-88-3
79-00-5
629-50-5
121-44-8
75-50-3
526-73-8
95-63-6
540-84-1
560-21-4
99-35-4
118-96-7
1120-21-4
112-42-5
108-05-4
689-97-4
75-01-4
75-94-5
7732-18-5
108-38-3
95-47-6
106-42-3

148.116
40.064
44.096
60.095
60.095
122.207
58.079
74.079
55.079
102.132
59.110
120.192
42.080
88.105
76.161
76.161
76.094
108.095
104.079
104.149
118.088
64.064
146.055
80.063
166.131
230.304
198.388
72.106
132.202
88.171
114.229
84.140
92.138
133.404
184.361
101.190
59.110
120.192
120.192
114.229
114.229
213.105
227.131
156.308
172.308
86.089
52.075
62.498
161.490
18.015
106.165
106.165
106.165

791
394
369.83
536.8
508.3
636
504.4
600.81
564.4
549.73
496.95
638.35
364.85
538
517
536.6
626
683
259
636
806
430.75
318.69
490.85
1113
857
693
540.15
720
631.95
568
579.35
591.75
602
675
535.15
433.25
664.5
649.1
543.8
573.5
846
828
639
703.9
519.13
454
432
543.15
647.096
617
630.3
616.2

4.72
5.25
4.248
5.169
4.765
3.12
4.92
4.668
4.18
3.36
4.74
3.2
4.6
4.02
4.75
4.63
6.1
5.96
3.72
3.84
4.71
7.884
3.76
8.21
3.95
2.99
1.57
5.19
3.65
5.16
2.87
5.69
4.108
4.48
1.68
3.04
4.07
3.454
3.232
2.57
2.82
3.39
3.04
1.95
2.119
3.958
4.86
5.67
3.06
22.064
3.541
3.732
3.511

0.421
0.165
0.2
0.219
0.222
0.437
0.204
0.235
0.229
0.345
0.26
0.44
0.185
0.285
0.254
0.254
0.239
0.291
0.202
0.352
0.317
0.122
0.19852
0.127
0.424
0.731
0.897
0.224
0.408
0.249
0.461
0.219
0.316
0.281
0.826
0.39
0.254
0.414
0.43
0.468
0.455
0.479
0.572
0.685
0.715
0.27
0.205
0.179
0.408
0.0559472
0.375
0.37
0.378

0.302
0.264
0.276
0.254
0.25
0.258
0.239
0.22
0.204
0.254
0.298
0.265
0.281
0.256
0.281
0.264
0.28
0.305
0.349
0.256
0.223
0.269
0.282
0.255
0.181
0.307
0.244
0.259
0.249
0.245
0.28
0.259
0.264
0.252
0.247
0.266
0.287
0.259
0.258
0.266
0.269
0.231
0.253
0.252
0.259
0.248
0.264
0.283
0.276
0.229
0.259
0.264
0.259

0.7025
0.1041
0.1523
0.6209
0.6544
0.3420
0.2559
0.5796
0.3243
0.3889
0.2798
0.3444
0.1376
0.3088
0.2138
0.2318
1.1065
0.4945
0.3858
0.2971
0.9922
0.2454
0.2151
0.4240
1.0591
0.5513
0.6430
0.2254
0.3353
0.1996
0.2450
0.1970
0.2640
0.2591
0.6174
0.3162
0.2062
0.3666
0.3787
0.3035
0.2903
0.8623
0.8972
0.5303
0.6236
0.3513
0.1069
0.1001
0.2815
0.3449
0.3265
0.3101
0.3218

All substances are listed by chemical family in Table 2-6 and by formula in Table 2-7.
Values in this table were taken from the Design Institute for Physical Properties (DIPPR) of the American Institute of Chemical Engineers (AIChE), copyright 2007
AIChE and reproduced with permission of AICHE and of the DIPPR Evaluated Process Design Data Project Steering Committee. Their source should be cited as R. L.
Rowley, W. V. Wilding, J. L. Oscarson, Y. Yang, N. A. Zundel, T. E. Daubert, R. P. Danner, DIPPR Data Compilation of Pure Chemical Properties, Design Institute for
Physical Properties, AIChE, New York (2007).
The number of digits provided for the acentric factor was chosen for uniformity of appearance and formatting; these do not represent the uncertainties of the physical
quantities, but are the result of calculations from the standard thermophysical property formulations within a fixed format.