233/1

CHEMISTRY
PAPER 1
THEORY
GUCHA SAMETA JOINT EVALUATION TEST 2014
MARKING SCHEME
1. (a) The almost colourless region contains unburnt gases.
1

(b) When the air hole is full / completely opened
(c) Blue flame
1
2 , very hot flame
1
2 / Noisy flame produce little or no soot
1
2
1 mk for any 2 correct characteristics
2. (a) B
1

(b) The atomic radius of K is smaller than that of F
1
. This is due to the more
number of protons in an atom of K and hence it has a stronger nuclear attraction
than F.
1

3. (a) Cation -
3
Al
+
or
2
( ) aq
Mg
+
ions
Anion -
2
4( ) aq
SO

ions
(b)
2 2
( ) ( ) 4( ) aq aq s
Ba SO BaSO
+
+
B.E
1
2 S.S
1
2 JL = O
(c)
2 2
( ) 3( ) 3( ) aq aq s
Mg CO MgCO
+
+
B.E
1
2 S.S
1
2 JL = 0
4. (a) Sacrificial protection
1
/ cathodic protection
1

(b) During rusting iron reacts with oxygen and water to form rust. But when the
Mg is connected to the Iron piple; it does not rust. This is because Mg is more
reactive / higher in the reactivity series than Iron. Therefore Mg reacts with
oxygen and water (corrodes) in place of Iron.
5. (a) Chloric I oxide;
(b) MgO is an ionic compound in which the ions are held by strong ionic
1
2 or
electrovalent
1
2 bonds giving rise to a giant ionic structure.
1
2 SO
2
molecular are held
together by very weak Vander Waals
1
2 forces resulting in a simple molecular
structure
1
2
6. (a) (i) X
1
2 (ii) W
1
2
2
(b) Litmus turns blue in Y since it is basic
1
. The mixture turns Red / Pink on
adding X since X is acidic
1

7. Heat
1
2
Copper metal strongly in air / oxygen to form CuO. Add the CuO so
formed to a certain volume of warm dilute HNO
3
1
2
acid while stirring till in
excess. Filter excess CuO or unreacted CuO to obtain a filtrate of Cu(NO
3
)
2

solution. To the filtrate add Na
2
CO
3
1
2
/K
2
CO
3
1
2
/ (NH4)
2
CO
3(aq)

1
2

solution.
Filter
1
2
to obtain CuCO
3(s)

1
2

precipitate as a residue. Wash it with distilled
water and dry
1
2
it between the filter papers.
8. Mass of salt = 25.7 21.5g = 4.2g
1
2

Mass of water = 37.7 25.7 = 12g
1
2

If 12g of water dissolve 4.2g of salt
100g of water will dissolve?

1 1
2 2
100 4.2
3.5
12
g

=
solubility of the salt = 35g of salt / 100g of water
1

9. (a)(i) Yellow deposit (of sulphur) seen, bromine water changes from orange /
yellow to colourless (due to formation of HBr).
(ii)
2 ( ) 2( ) ( ) ( )
2
g aq aq s
H S Br HBr S + +
Colourless yellow / orange colourless yellow
B.E
1
2 S.S
1
2 JL = 0
(b) H
2
S turns a filter paper soaked in Lead II ethenoate (acetate) black (accept
any other correct test)
1

10. (a) Increasing concentration of electrolyte
1

- Increasing the voltage
1

(b) (i) Cathode Hydrogen
1
2 gas (H
2
)
Anode Oxygen gas
1
2 (O
2
)
11. (a) (i) Anode
2
2( )
2 4
g
O O e

+
1

OR
2
2( )
6 3 12
g
O O e

+
1

(ii) Cathode
3
( ) ( )
3
l l
Al e Al
+
+
1

OR
3
( ) ( )
4 12 4
l l
Al e A
+
+
1

3
(b) Add concentrated NaOH
1
2 solution. Al
2
O
3
and SiO
2
dissolves but Fe
2
O
3

does not.
1
2 Filter
1
2 the mixture to remove insoluble Fe
2
O
3
as residue. Filtrate
contains Na
2
SiO
3
and NaAl(OH)
4(aq)

1
2
12.

(b) No of Neutrons = Mass No At. No.
= 40 18 = 22 Neutrons
1

13. If 1.785g of R requires 5790C then 119g of R will require??

1
2
1
119 5790
386000
1.785
C

=
But 96500C = 1Faraday

1
386000 1
386000
96500
C

=
= 4F
1
2
14. (a) Solvent front
1
2
(b) It is more soluble and less
1
2 sticky
(c) It is less soluble and more
1
2 sticky

15. (a) concentrated sulphuric (VI) acid
1

4
(b)
2 4
.
3 5 ( ) 3 6( ) 2 ( )
conc
l g l H SO
C H OH C H H O +
1

16. HCI would react with H
2
S
1
2 thereby reducing its concentration.
1
2 The
equilibrium would shift to the right.
1
2

17. (i)

(ii)

( ) ( ) ( )
1
2
2 394 3 286 1560
f
H A = +
= - 788 858 + 1560
1
2

= - 86 kj/mol
1
2

NB: Accept alternative
18. Element : Cu O
Moles :
6.4
64

1.6
16

0.1
1
2
0.1
1
2

Ratio 1 : 1
1
2

EF = CuO
1
2

MF = (EF)n

80
80
n =
1
2

MF = CuO
1
2

19. (i)
2 2
( ) ( ) ( ) ( ) s aq aq s
Mg Zn Mg Zn
+ +
+ +
1

(ii)
. .
Ped OX
E M F E E
u u
=

5
= - 0.76 + 2.37

1
2

= + 1.61V
1
2

20. (i)

(ii) Addition polymerization
1

(iii) Manufacture of car windscreens
1

21. (a) (i) 2.8
1
2
(ii) 2.8.4
1
2

(b) Atoms are covalently bonded together
1
2
to form a giant atomic
1
2
structure.
Atoms of V are bonded covalently to form
1
2
molecules. The molecules are then
hold together by weak Van der Waals to form a simple molecular
1
2
structure.

22. (i) Hydrogen gas
1

(ii) They increase the surface area
1
2
over which the gas dissolve in water.
(iii) Treatment of water at the water works
1

-
Sewerage treatment
1

-
Manufacture of dyes
1

-
To clean metal surfaces to remove
1
dust

Any 1 Award (1 mark) to a max. of 1 mk

23. (i)
( ) 2 ( ) 2 3 2( )
2 6 2 6
s g g
Fe H O Fe O H + +
1

(ii) Industrial manufacture of HCL
-
Industrial manufacture of Ammonia

-
Used in weather balloons

-
Hardening of oils

Any 2 award 2 marks to a max. 2 marks

24. (i) Residue yellow when hot
1
2
reddish brown
1
2
cold formation of a white ppt
in lime water
1

6
(ii) No formation of a white ppt
1
2
, Na
2
CO
3
does not decompose on heating
1
2

25. (i)
222 218 4
84 82 2
Ra Pb He +
1

(ii) 1 1 1
2 2 2
100 50 12.5 6.25
t t t

1
2

1
2
4 15 t =

1
2

1
2
15
4
t =

1
2

= 3.75 days
1
2

NB: Accept alternative method

26. (a) (i) black solid turns brown
1
2

(ii) Grey solid turns black
1
2

(b)
( ) 2 ( ) 2 3( ) 2( )
4 6 2 6
s g s g
Fe H O Fe O H + +
1

27. (a) When gases react, they do so in giving products that bear simple ratio with the
products formed.
1

(b)
2 4 2 2 2
3 2 2 C H O CO H O + +
25 75 50
1

From mole ratio
Volume of O
2
remaining = 15 cm
3
1
2
(90 75)
Volume of CO
2
= 50 cm
3
1
2