1 - HempelPackage 8783

Hempel helps Mlheim provide a smooth flow
Its a long journey by pipeline from Russia to Western Europe, so anything to make the natural gas
flow more smoothly is welcomed. HEMPELS HS GAS PIPE COATING 87830 specialises in doing
just that. It is applied as a one-coat lining for natural gas transport pipes.
HEMPELS HS GAS PIPE COATING 87830 is designed to reduce drag resistance by making the
inside pipe walls smoother, explains Gregor Schiffer, Hempel Germanys salesperson serving
pipeline customers. We call it flow coat. When the gas flows faster, fewer pumping stations are
needed to keep the gas flowing.
Hempel Germany has been supplying HEMPELS HS GAS PIPE COATING 87830 to Mlheim
Pipecoatings GmbH, a supplier of pipes for, among other projects, the Nord Stream I offshore
pipeline taking form along the bottom of the Baltic Sea from Vyborg, Russia to Greifswald, Germany.
At 1,222 km, this will be the worlds longest subsea pipeline. It is to be completed during 2011.
Mlheim is providing 75% (860,000 tonnes) of the pipes for Nord Stream I. It also has signed
a contract to provide coated pipes for Nord Stream II, a second pipeline to run parallel to the
first. Construction of the second is to begin in spring 2011 and be completed in 2012.
PIPE COATING 87830 is a two-component epoxy polyamine cured coating formulated in
accordance with the American Petroleum Institutes standard RP5L2 (Internal Coating of Line
Pipe for Non-corrosive Gas Transmission Service). It features very low VOCs (130 g/l), high solids
(81%), and fast drying.
Mlheim Pipecoatings application technology takes full advantage of PIPE COATING 87830s
excellent qualities. The two-component product is applied by airless spray and mixed at the nozzle.
The paint is warmed to 40 C, which reduces the viscosity to provide a more even paint flow and
coverage.
The guys working close to the nozzle of the spray gun say it is easier to handle this product, Mr.
Schiffer reports. Relative to competing products, Mlheim experience has shown 87830 to have
less odour, less wear on the spray nozzles, and allows easier cleaning of the spray equipment.
There is no contamination in the dry film and the paint film is very uniform and with a lower
roughness profile.
Very importantly, Mr. Christian Balkenohl, Production Manager at Mlheim Pipecoatings,
reports that its customer is satisfied with the performance of PIPE COATING 87830 and the
finished pipes.
Hempels dedication has led to a very good project realization up to now, Mr. Balkenohl notes.
We are sure it will continue in the same way through the coating phase for the Nord Stream
Pipeline Project and that it will open a new horizon for future cooperation on gas pipeline projects
requiring flow coat.
Based upon the experience with HEMPELS HS GAS PIPE COATING 87830, Hempel has made
adjustments to the product to extend the shelf life, which is a challenge for high solids paints applied
with low dry film thickness. This new product is named HEMPELS HS GAS PIPE COATING 87831.
It has passed all relevant tests according to the standards DIN EN 10 201:2003, ISO 15741:2001
and TRANSCO CM2.

HEMPELS HS GAS PIPE COATING 87830
Case Stories
HE MP E L C A S E S T ORI E S 1
Hempel works with Bredero Shaw to lower VOCs and save costs
Engineers and transport companies designing and constructing natural gas pipelines aim
to build pipelines through which gas can flow faster and at lower cost. Bredero Shaw is
supplying its customer pipes to meet those demands for building the 940 km QSN3 gas
pipeline from South Australias Moomba Gas Fields to South West Queensland. It has chosen
HEMPELS HS GAS PIPE COATING 87830 for coating half of the project.
Texas-based Bredero Shaw bills itself as the global leader in pipe coating solutions, so its coating
systems simply must be the best available. The companys cooperation with Hempel began about
5 years ago, explains Chris Francis, Manager Container & Pipelines at Hempel (Australia). The
QSN3 is owned by Epic Energy, and it has contracted with Netherlands-based Nacap to do the
construction.
We introduced HEMPELS HS GAS PIPE COATING 87830 to them a short time later, Mr. Francis
explains, when the QSN3 project was in front-end engineering design. We offered the advantages
of higher solids volume (81% compared to 48% offered by the competing supplier) that also better
fit the clients production system, a smoother and glossier finish, cost-savings via a massive 40%
lower paint consumption, as well as better work place safety and lower VOCs.
HEMPELS HS GAS PIPE COATING 87830 is a two-component epoxy polyamine cured coating
formulated in accordance with the American Petroleum Institutes standard RP5L2 (Internal
Coating of Line Pipe for Non-corrosive Gas Transmission Service). In addition to its very low VOCs
(130 g/l) and high solids (81%), it is also fast drying and has good application properties.
At the end of the day, Mr. Francis explains, our success was due to the fact that, by using
HEMPELS HS GAS PIPE COATING 87830, our customer was able to offer significant savings
while providing a quality finish.
An internally lined gas pipe reduces friction, Mr. Francis adds, thus providing greater flow
capacity, or allowing smaller gauge pipes to deliver equivalent gas flow. The pipes are easier to
pig and clean while the coating also provides corrosion protection.
(A final note: Based upon the experience with HEMPELS HS GAS PIPE COATING 87830,
Hempel has made adjustments to the product to extend the shelf life, which is a challenge
for high solids paints applied with low dry film thickness. This new product is named
HEMPELS HS GAS PIPE COATING 87831. It has passed all relevant tests according to the
standards DIN EN 10 201:2003, ISO 15741:2001, TRANSCO CM2, and API RP5L2.)
HEMPEL (UK) LTD.
Llantarnam Industrial Park
Gwent NP44 3XF Cwmbran
Tel.: +44 (01633) 874024
Fax: +44 (01633) 489089
E-mail: sales.uk@hempel.com
www.hempel.co.uk
Case Stories
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HE MP E L C A S E S T ORI E S 2
4Typical use
HEMPELS HS GAS PIPE COATING 87831 is used as a one-coat system for internal protection
of gas pipes designed for carrying of dry, sweet gas. The coating is designed to reduce the drag
resistance in the pipeline by making the pipe walls smoother.
Improve gas flow
Reduced pumping costs - increased pipeline life
Long term corrosion protection and chemical resistance
Easier and faster inspection of pipeline
More effective pigging/scraping
Improved product purity
Diverse pipeline use easier product switch
Environment protection
4Product description
HEMPELS HS GAS PIPE COATING 87831 is a two-component epoxy polyamine cured
coating. Formulated according to the requirements in AMERICAN PETROLEUM INSTITUTES
STANDARD RP 5L2.
FEATURES BENEFITS
Glossy and smooth appearance Easy to clean
Fast drying and good film forming
properties
High application productivity and absence of pores
Meet requirements of API, ISO, EN
standards
Well proven product performance all over the world
Service temperatures up to 140C Wide range of service temperatures
VOC compliant coating
High volume solid paint without increased coating
thickness or loss of performance
4Physical constants
Colour: Reddish brown/50890
Volume solids, %: 82 1
Theoretical spreading rate:
11,6 m
2
/litre 70 micron
464 sq.ft./US gallon - 2.8 mils
Flash point: 28C/82F
Specific gravity: 1.4 kg/litre 11.4 lbs/US gallon
Dry to touch: 4 hours at 20C/68F
Fully cured: 7 days at 20C/68F
V.O.C.: 155 g/litre 1.4 lbs/US gallon
Recoating:
Recoating will normally only apply in connection
with touch-up of too low dry film thickness
Recoat interval, min: 5 hours (20C/68F)
Recoat interval, max: 8 days (20C/68F)
Product Information
1 HE MP E L P RODU C T I NF ORMAT I ON
Please consult Product Data Sheet for further details.
HEMPEL (UK) LTD.
Tel.: +44 (01633) 874024
Fax: +44 (01633) 489089
www.hempel.co.uk
4Typical Specification
The flow coats are usually specified with thickness from 60-70 to 100 micron depending on speci-
fication of the owners. A specification can be adjusted to suit local regulations, local working condi-
tions or specific demands from designers or pipe coating manufacturers.
One coat application
1 x HEMPELS HS GAS PIPE COATING 87831 70 Micron
70 Micron
One coat application
1 x HEMPELS HS GAS PIPE COATING 87831 90 Micron
90 Micron
2 HE MP E L P RODU C T I NF ORMAT I ON
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Other custom-built specifications are possible - please contact your local Hempel office.

This product should not be used without reference to relevant Product Data sheet and
Material Safety Data sheet, copies of which are available from Hempel upon request.
4More information available upon request
4Test reports
API RP 5L2:2002
Recommended Practice for Internal Coating for Non-Corrosive Gas Transmission Service according
to API RP 5L2:2002 issued by Institut fr Lackprfung
DIN EN 10 301:2004
Steel tubes and fittings for on and offshore pipelines Internal coatings for the reduction of friction
for conveyance of non corrosive gas according to DIN EN 10 301:2004 issued by Institut fr
Lackprfung
ISO 15 741:2001
Paints and varnishes Friction-reduction coatings for the interior of on- and offshore steel pipelines
for non-corrosive gases according to ISO 15 741:2001 issued by Institut fr Lackprfung
TRANSCO CM2
Technical Specification for Internal Coating Materials for Steel Line Pipe and Fittings according
to TRANSCO CM2, Edition March 2003 issued by Institut fr Lackprfung
Gazprom VNIIGAZ
Internal flow coating meets STO Gazprom 2-2.2-180-2007 Internal flow pipe coating specifications
standard requirements
PROJECT NAME DATE DESCRIPTION
DOLPHIN GAS PIPELINE U.A.E. 2008 Pipeline connection from Qatar to U.A.E.
NORTH-SOUTH PROJECT 2009
The pipeline connection from north east
to south Netherlands by N.V.
Nederlandse Gasunie.
NORD-STREAM BALTIC-SEA PIPELINE
/ GAZPROM
20082011
Nord Stream is a gas pipeline that links
Russia to Europe via the Baltic Sea, carrying
a natural gas supply for both business and
household use. The new pipeline is an im-
portant factor of energy security in Europe.
Nord Stream will transport up to 55 billion
cubic metres of gas each year, enough
to supply more than 26 million households.
NORD-STREAM LINE 2 20102011
Nord Stream Line 2 is 1,224 kilometres
long and consists of two parallel lines. The
second line is due to be completed in 2012,
doubling annual capacity to around 55
billion cubic metres.
WINGAS - OPAL (OSTSEE-PIPELINE-
-ANBINDUNGS-LEITUNG BALTIC SEA
PIPELINE LINK)
20082011
OPAL connects Germany and Europe to
major natural gas reserves in Siberia via the
Nord-Stream Pipeline. The OPAL will pick up
natural gas in Lubmin near Greifswald from
the Nord Stream pipeline and transport it
470 kilometres south to Olbernhau on the
Czech border.
NEL (NORDDEUTSCHE
ERDGASLEITUNG)
20102011
North European Gas Pipeline (NEL) is
440 km long, used to transport Russian
natural gas from the Nord Stream Baltic Sea
pipeline landing point in Lubmin near Gre-
ifswald towards Rehden in Lower Saxony.
QSN3 GAS PIPELINE 20102011
The QSN3 pipeline stretches 945 km from
South Australias Moomba Gas Fields,
through to S/W Queensland.
HE MP E L L I S T OF A P P L I C AT I ONS
List of applications
HE MP E L L I S T OF A P P L I C AT I ONS
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HEMPEL (UK) LTD.
Tel.: +44 (01633) 874024
Fax: +44 (01633) 489089
www.hempel.co.uk
*HEMPELS HS GAS PIPE COATING 87830 has been applied to all the projects mentioned above. Currently there is available
HEMPELS HS GAS PIPE COATING 87831 which is an improved version of HEMPELS HS GAS PIPE COATING 87830 to have extended
anti-settlement property. Extended anti-settlement properties, which is a huge challenge for high solids paints applied with low dry
film thickness, enable our customers to have the application process easier.
Product Data
Product Data
Product Data Sheet
HEMPEL

Issued: December 2010 Page 1 of 2
BASE 87838 with CURING AGENT 95830

Description: HEMPELS HS GAS PIPE COATING 87831 is a two-component epoxy polyamine cured
coating. Formulated according to the requirements in AMERICAN PETROLEUM
INSTITUTES STANDARD RP 5L2.

Recommended use: As a one-coat system for internal coating of gas pipes designed for carrying of dry,
sweet gas. The coating is designed to reduce the drag resistance in the pipeline by
making the pipe walls smoother.

Service temperatures: Maximum, dry exposure only: 140C/284F.

Availability: Not included in Group Assortment. Availability subject to special agreement.

PHYSICAL CONSTANTS:
Colours/Shade nos: Reddish brown/50890
Finish: Semi-gloss
Volume solids, %: 82 1
Theoretical spreading rate: 11.6 m/litre - 70 micron
464 sq.ft./US gallon - 2.8 mils
Flash point: 28C/82F
Specific gravity: 1.4 kg/litre - 11.4 lbs/US gallon
Dry to touch: 4 hours at 20C/68F
Fully cured: 7 days at 20C/68F
V.O.C.: 155 g/litre 1.4 lbs/US gallon

The physical constants stated are nominal data according to the HEMPEL Group's approved formulas. They are
subject to normal manufacturing tolerances and where stated, being standard deviation according to ISO 3534-1.

APPLICATION DETAILS:
Mixing ratio for 87831: Base 87838 : Curing agent 95830
4 : 1 by volume (see REMARKS overleaf)
Application method: Dual feed hot airless Airless spray Brush (see REMARKS overleaf)
Thinner (max.vol.): No thinning recommended
Pot life: 60 minutes (20C/68F) (API standard method)
10 minutes (60C/140F)
Nozzle orifice: .018"-.021"
Nozzle pressure: 150 bar/2200 psi
(Airless spray data are indicative and subject to adjustment)
Cleaning of tools: HEMPELS TOOL CLEANER 99610
Indicated film thickness, dry: 70 micron/2.8 mils
Indicated film thickness, wet: 100 micron/4 mils
Recoat interval, min: 5 hours (20C/68F) (see REMARKS overleaf)
Recoat interval, max: 8 days (20C/68F)

Safety: Handle with care. Before and during use, observe all safety labels on packaging and
paint containers, consult HEMPEL Material Safety Data Sheets and follow all local or
national safety regulations. Avoid inhalation, avoid contact with skin and eyes, and do
not swallow. Take precautions against possible risks of fire or explosions as well as
protection of the environment. Apply only in well ventilated areas.

Product Data Sheet

Issued: December 2010 Page 2 of 2

SURFACE Remove oil and grease thoroughly with suitable detergent. Remove salt and other contaminants
PREPARATION: by high pressure fresh water cleaning.
Abrasive blasting to Sa 2 with a surface profile corresponding to Rugotest No. 3, BN9a, Keane-
Tator Comparator, 2.0 G/S, 2S, or ISO Comparator, FINE (G).

APPLICATION Use only where application and curing can proceed at temperatures above 20C/68F at all times
CONDITIONS: until curing is completed. Apply only on a clean and dry surface with a temperature above the dew
point to avoid condensation. Maximum steel temperature approximately 45C/113F. Relative
humidity max. 85%. In confined spaces provide adequate ventilation..

SUBSEQUENT None or according to specification.
COAT:

REMARKS:
Application Application by duel feed hot airless spray equipment is recommended. Each component must be
equipment: preheated in heating caps to 60C/140F prior to mixing. If ordinary airless spray is used the
mixture should be made at 20C/68F and heated after the pump to 50C/122F. Hoses must be
kept at 50C/122F during the entire application. Note the short pot life at 60C/140F,
approximately 10 minutes.

Curing conditions: Initial curing must take place at temperatures above 25C/77F.

Mixing ratio: Base 87838 : Curing agent 95830
6 : 1 by weight
Mixing tolerance 5%

Recoating: Recoating will normally only apply in connection with touch-up of too low dry film thickness.

Note: HEMPELS HS GAS PIPE COATING 87831 is for professional use only.

ISSUED BY: HEMPEL A/S - 8783150890CR001

This Product Data Sheet supersedes those previously issued.
For explanations, definitions and scope, see Explanatory Notes in the HEMPEL Book.
Data, specifications, directions and recommendations given in this data sheet represent only test results or
experience obtained under controlled or specially defined circumstances. Their accuracy, completeness or
appropriateness under the actual conditions of any intended use of the Products herein must be determined
exclusively by the Buyer and/or User.
The Products are supplied and all technical assistance is given subject to HEMPEL's GENERAL CONDITIONS OF
SALES, DELIVERY AND SERVICE, unless otherwise expressly agreed in writing. The Manufacturer and Seller
disclaim, and Buyer and/or User waive all claims involving, any liability, including but not limited to negligence,
except as expressed in said GENERAL CONDITIONS for all results, injury or direct or consequential losses or
damages arising from the use of the Products as recommended above, on the overleaf or otherwise.

This Product Data Sheet supersedes those previously issued.
For explanations, definitions and scope, see Explanatory Notes in the HEMPEL Book.
Data, specifications, directions and recommendations given in this data sheet represent only test results or
experience obtained under controlled or specially defined circumstances. Their accuracy, completeness or
appropriateness under the actual conditions of any intended use of the Products herein must be determined
exclusively by the Buyer and/or User.
The Products are supplied and all technical assistance is given subject to HEMPEL's GENERAL CONDITIONS
OF SALES, DELIVERY AND SERVICE, unless otherwise expressly agreed in writing. The Manufacturer and
Seller disclaim, and Buyer and/or User waive all claims involving, any liability, including but not limited to
negligence, except as expressed in said GENERAL CONDITIONS for all results, injury or direct or
consequential losses or damages arising from the use of the Products as recommended above, on the overleaf
or otherwise.
Product data are subject to change without notice and become void five years from the date of issue.
1.1 Product identifier
1.3 Details of the supplier of the safety data sheet
1.2 Relevant identified uses of the substance or mixture and uses advised against
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Safety Data Sheet
Safety Data Sheet
HEMPEL'S HS GAS PIPE COATING 87838
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II. - Europe
Product identity : 8783850890
Ready-for-use mixture : 87838 4 Li / 95830 1 Li
Product type : epoxy paint (base for 2-component product)
Field of application : metal industry
Identified uses : Industrial applications, Used by spraying.
Emergency telephone number (with hours of operation) Company details :
+45 45 93 38 00 (08.00 - 17.00)
See section 4 First aid measures.
HEMPEL A/S
Lundtoftevej 150
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 11 February 2011
16 December 2010. Date of previous issue :
HEMPEL'S HS GAS PIPE COATING 87838 Product name :
Classification : R10
Xi; R36/38
R43
N; R51/53
Physical/chemical hazards : Flammable.
Human health hazards : Irritating to eyes and skin. May cause sensitization by skin contact.
Environmental hazards : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
2.2 Label elements
Supplemental label elements :
Containers to be fitted with child-
resistant fastenings :
Not applicable.
Tactile warning of danger : Not applicable.
Contains epoxy constituents. See information supplied by the manufacturer.
Special packaging requirements
Hazard symbol or symbols :
Safety phrases : S23- Do not breathe vapor or spray.
S24- Avoid contact with skin.
S37- Wear suitable gloves.
S51- Use only in well-ventilated areas.
R10- Flammable.
R36/38- Irritating to eyes and skin.
R43- May cause sensitization by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Risk phrases :
Hazardous ingredients :
Irritant, Dangerous for the environment
bisphenol A-(epichlorhydrin) epoxy resin MW =< 700
Indication of danger :
Page: 1/9
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Safety Data Sheet
Date of issue: February 2011
8783850890
bisphenol A-(epichlorhydrin)
epoxy resin MW =< 700
EC: 500-033-5
CAS: 25068-38-6
Index: 603-074-00-8
35-50 Xi; R36/38
R43
N; R51/53
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
SKIN SENSITIZATION - Category 1
AQUATIC TOXICITY (CHRONIC) - Category 2
[1]
xylene EC: 215-535-7
CAS: 1330-20-7
Index: 601-022-00-9
5-10 R10
Xn; R20/21
Xi; R38
FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY: SKIN - Category 4
ACUTE TOXICITY: INHALATION - Category 4
[1] [2]
n-butanol EC: 200-751-6
CAS: 71-36-3
Index: 603-004-00-6
1-3 R10
Xn; R22
Xi; R41, R37/38
R67
ACUTE TOXICITY: ORAL - Category 4
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) [Respiratory tract irritation and Narcotic
effects] - Category 3
[1] [2]
ethylbenzene EC: 202-849-4
CAS: 100-41-4
Index: 601-023-00-4
1-3 F; R11
Xn; R20
[1] [2]
alpha'-(1,3-xylenediyl)bis(12-
hydroxyoctadecanamide)
- 0.1-1 Xn; R20
R43
R53
[1]
See Section 16 for the full
text of the R-phrases
declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
SECTION 3: Composition/information on ingredients
Type Regulation (EC) No. 1272/2008 [CLP]
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
Type
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive 67/548/EEC or
assigned an occupational exposure limit or PBT or vPvB.
Product/ingredient name Identifiers % 67/548/EEC
Classification
Skin contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
4.1 Description of first aid measures
Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and seek
medical advice.
Ingestion :
Inhalation :
Eye contact :
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to
the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.
SECTION 4: First aid measures
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
No known significant effects or critical hazards.
Irritating to mouth, throat and stomach.
Irritating to skin. May cause sensitization by skin contact.
Irritating to eyes.
Over-exposure signs/symptoms
Adverse symptoms may include the following:
irritation
watering
redness
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If swallowed, seek medical advice immediately and show this container or label. Keep person warm and
at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that
vomit will not re-enter the mouth and throat.
Eye contact :
Inhalation :
Skin contact :
Ingestion :
Eye contact :
Page: 2/9
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Safety Data Sheet
8783850890
Notes to physician : Not applicable.
Specific treatments :
No specific data.
No specific data.
irritation
redness
4.3 Indication of any immediate medical attention and special treatment needed
No specific treatment.
Inhalation :
Skin contact :
Ingestion :
Hazardous combustion products :
Hazards from the substance or
mixture :
Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
5.1 Extinguishing media
Extinguishing media :
SECTION 5: Firefighting measures
5.2 Special hazards arising from the substance or mixture
5.3 Advice for firefighters
Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.
Decomposition products may include the following materials: carbon oxides halogenated compounds
metal oxide/oxides
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.
6.2 Environmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.
6.3 Methods and materials for containment and cleaning up
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.4 Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer to protective
measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training. If the product
contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.
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Safety Data Sheet
8783850890
SECTION 7: Handling and storage
7.1 Precautions for safe handling
7.2 Conditions for safe storage, including any incompatibilities
7.3 Specific end use(s)
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy and
amine containing products, they may cause allergic reactions.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.
Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from incompatible materials and
ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent
unauthorized access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.
See separate Product Data Sheet for recommendations or industrial sector specific solutions.
Product/ingredient name Exposure limit values
Recommended monitoring procedures
xylene EU OEL (Europe, 12/2009). Absorbed through skin.
STEL: 442 mg/m 15 minute(s).
STEL: 100 ppm 15 minute(s).
TWA: 221 mg/m 8 hour(s).
TWA: 50 ppm 8 hour(s).
n-butanol ACGIH TLV (United States, 2/2010).
ethylbenzene EU OEL (Europe, 12/2009). Absorbed through skin.
STEL: 884 mg/m 15 minute(s).
STEL: 200 ppm 15 minute(s).
TWA: 442 mg/m 8 hour(s).
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous substances.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates
this is necessary to avoid exposure to liquid splashes, mists or dusts.
Eye/face protection :
Appropriate engineering controls
8.2 Exposure controls
Hygiene measures :
No DELs available.
Predicted effect concentrations
No PECs available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Derived effect levels
Individual protection measures
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
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Safety Data Sheet
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Hand protection :
Respiratory protection :
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. When the product is applied by spraying and for
continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an approved/certified respirator
or equivalent.
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type.
Physical state :
Melting point/freezing point :
Boiling point/boiling range :
Vapor pressure :
Relative density :
Vapor density :
Solubility(ies) :
Solvent-like Odor :
pH :
Evaporation rate :
Auto-ignition temperature :
Flash point :
Highly explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Viscosity :
Partition coefficient (LogKow) :
Upper/lower flammability or
explosive limits :
Explosive properties :
Oxidizing properties :
9.1 Information on basic physical and chemical properties
9.2 Other information
Decomposition temperature :
SECTION 9: Physical and chemical properties
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Liquid.
Testing not relevant or not possible due to nature of the product.
1.498 g/cm
3
Partially soluble in the following materials: cold water and hot water.
Closed cup: 28C (82.4F)
0.8 - 11.2 vol %
Weighted average: 17 % Solvent(s) % by weight :
Water % by weight : Weighted average: 0 %
Solvent Gas : Weighted average: 0.052 m
3
/l
TOC Content : Weighted average: 166 g/l
VOC content : 255.3 g/l
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10.6 Hazardous decomposition products
10.4 Conditions to avoid
The product is stable.
10.2 Chemical stability
10.5 Incompatible materials
10.3 Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
SECTION 10: Stability and reactivity
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides halogenated compounds metal oxide/oxides
Highly reactive or incompatible with the following materials: oxidizing materials and acids.
Reactive or incompatible with the following materials: reducing materials.
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or
sources of ignition.
Acute toxicity
bisphenol A-(epichlorhydrin) epoxy
resin MW =< 700
LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat >2000 mg/kg -
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LD50 Dermal Rabbit >1700 mg/kg -
LD50 Oral Rat 4300 mg/kg -
n-butanol LC50 Inhalation Gas. Rat >8000 ppm 4 hours
LC50 Inhalation Vapor Rat 24000 mg/m3 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
alpha'-(1,3-xylenediyl)bis(12-
hydroxyoctadecanamide)
LC50 Inhalation Gas. Rat 3.6 mg/L 4 hours
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >2000 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity estimates
Oral 31549.2 mg/kg
Dermal 21992.2 mg/kg
Inhalation (gases) 52922.3 ppm
Inhalation (vapors) 589.3 mg/l
Route ATE value
Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Epoxy and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after only a short exposure
period.
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Potential chronic health effects
resin MW =< 700
Eyes - Moderate irritant Rabbit - - -
Skin - Moderate irritant Rabbit - - -
xylene Eyes - Severe irritant Rabbit - - -
Skin - Mild irritant Rat - - -
n-butanol Eyes - Severe irritant Rabbit - - -
ethylbenzene Eyes - Severe irritant Rabbit - - -
Skin - Mild irritant Rabbit - - -
Product/ingredient name Result Score Exposure Observation Species
Other information :
Sensitization : Contains bisphenol A-(epichlorhydrin) epoxy resin MW =< 700, alpha'-(1,3-xylenediyl)bis(12-
hydroxyoctadecanamide). May produce an allergic reaction.
No additional known significant effects or critical hazards.
Mobility :
LogPow BCF Potential
12.3 Bioaccumulative potential
12.6 Other adverse effects
Product/ingredient name
xylene - 6 - 23.4 low
n-butanol 0.88 - low
ethylbenzene 3.15 - high
No known data avaliable in our database.
12.1 Toxicity
resin MW =< 700
Acute EC50 1.4 - 1.7 mg/l Daphnia - Daphnia magna 48 hours
Acute LC50 3.1 mg/l Fish - fathead minnow (Pimephales
promelas)
96 hours
xylene Acute LC50 8500 ug/L Marine water Crustaceans - Palaemonetes pugio 48 hours
Acute LC50 8200 - 10032 ug/L Fresh water Fish - Oncorhynchus mykiss - 0.6 g 96 hours
n-butanol Acute EC50 1983000 - 2072000 ug/L Fresh
water
Daphnia - Daphnia magna - 6 - 24 hours 48 hours
Acute LC50 1730000 - 1840000 ug/L Fresh water Fish - Pimephales promelas - 33 days -
20.6 mm - 0.119 g
96 hours
ethylbenzene Acute EC50 2930 - 4400 ug/L Fresh water Daphnia - Daphnia magna - Neonate -
<=24 hours
48 hours
Acute LC50 >5200 ug/L Marine water Crustaceans - Americamysis bahia - <24
hours
48 hours
Acute LC50 11900 ug/L Fresh water Fish - Pimephales promelas - 30 days -
0.079 g
96 hours
Chronic NOEC 6800 ug/L Fresh water Daphnia - Daphnia magna - <=24 hours 48 hours
Chronic NOEC 3300 ug/L Marine water Fish - Menidia menidia 96 hours
Product/ingredient name Species Result Exposure
12.2 Persistence and degradability
PBT : Not applicable.
vPvB : Not applicable.
SECTION 12: Ecological information
12.4 Mobility in soil
Soil/water partition coefficient
(KOC) :
12.5 Results of PBT and vPvB assessment
Do not allow to enter drains or watercourses. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
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SECTION 13: Disposal considerations
13.1 Waste treatment methods
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.
The generation of waste should be avoided or minimized wherever possible.
Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable regulations.
Spillage, remains, discarded clothes and similar should be discarded in a fireproof container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
SECTION 14: Transport information
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable.
UN1263
UN1263
Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.1
UN no.
14.2
Proper shipping name
14.4
PG*
14.3
Transport hazard class(es) Additional information
III 3 PAINT ADR/RID
Class
IMDG
Class
PAINT. (bisphenol A-(epichlorhydrin)
epoxy resin MW =< 700)
3 III
IATA
Class
UN1263 PAINT 3 III -
PG* : Packing group
Env.* : Environmental hazards
14.5
Env*
14.6 Special precautions for user
Yes.
Not available.
Yes.
Special provisions
640 (E)
Tunnel code
(D/E)
Emergency schedules
(EmS)
F-E, S-E
Yes.
Other EU regulations
Not applicable.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
15.2 Chemical Safety Assessment
This product contains substances for which Chemical Safety Assessments are still required.
None of the components are listed.
Seveso category : 9.ii
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Indicates information that has changed from previously issued version.
SECTION 16: Other information
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
Notice to reader
Hazard pictograms :
Warning
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Hazard statements :
Signal word :
R11- Highly flammable.
R10- Flammable.
R20- Harmful by inhalation.
R22- Harmful if swallowed.
R20/21- Harmful by inhalation and in contact with skin.
R41- Risk of serious damage to eyes.
R38- Irritating to skin.
R37/38- Irritating to respiratory system and skin.
R67- Vapors may cause drowsiness and dizziness.
R53- May cause long-term adverse effects in the aquatic environment.
Full text of abbreviated R phrases :
F - Highly flammable
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
Full text of classifications [DSD/DPD] :
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
AQUATIC TOXICITY (CHRONIC) - Category 2 Calculation method
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1.1 Product identifier
1.3 Details of the supplier of the safety data sheet
1.2 Relevant identified uses of the substance or mixture and uses advised against
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Safety Data Sheet
Safety Data Sheet
HEMPEL'S CURING AGENT 95830
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II. - Europe
Product identity : 9583000000
Ready-for-use mixture : 87839 16 LI / 95830 4 LI
Product type : polyamine curing agent.
Field of application : used only as part of two- or multi component products.
Identified uses : Industrial applications, Used by spraying.
Emergency telephone number (with hours of operation) Company details :
+45 45 93 38 00 (08.00 - 17.00)
See section 4 First aid measures.
HEMPEL A/S
Lundtoftevej 150
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 3 December 2010
No previous validation. Date of previous issue :
HEMPEL'S CURING AGENT 95830 Product name :
Classification : Xn; R22
C; R35
R43
R52/53
Human health hazards : Harmful if swallowed. Causes severe burns. May cause sensitization by skin contact.
Environmental hazards : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
2.2 Label elements
Special packaging requirements
Hazard symbol or symbols :
Safety phrases : S23- Do not breathe vapor or spray.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S51- Use only in well-ventilated areas.
R35- Causes severe burns.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Risk phrases :
Hazardous ingredients :
Corrosive
m-Xylylene-diamine
2,2,4- and 2,4,4- trimethylhexamethylene diamine
tetraethylenepentamine
Indication of danger :
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Safety Data Sheet
Date of issue: December 2010
9583000000
Containers to be fitted with child-
resistant fastenings :
Not applicable.
Tactile warning of danger : Not applicable.
m-Xylylene-diamine EC: 216-032-5
CAS: 1477-55-0
10-20 Xn; R20/22
C; R35
R43
R52/53
SKIN CORROSION/IRRITATION - Category 1B
[1] [2]
p-tert-butylphenol EC: 202-679-0
CAS: 98-54-4
10-20 Xi; R36/37/38
N; R51/53
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE): INHALATION [Respiratory tract irritation] -
Category 3
AQUATIC TOXICITY (ACUTE) - Category 1
[1]
benzyl alcohol EC: 202-859-9
CAS: 100-51-6
Index: 603-057-00-5
7-25 Xn; R20/22
[1]
2,2,4- and 2,4,4-
trimethylhexamethylene
diamine
EC: 247-134-8
CAS: 25620-58-0
7-10 Xn; R22
C; R34
R43
N; R51/53
[1]
2,4,6-
tris(dimethylaminomethyl)phenol
EC: 202-013-9
CAS: 90-72-2
Index: 603-069-00-0
3-5 Xn; R22
Xi; R36/38
[1]
tetraethylenepentamine EC: 203-986-2
CAS: 112-57-2
Index: 612-060-00-0
2.5-3 Xn; R21/22
C; R34
R43
N; R51/53
ACUTE TOXICITY: SKIN - Category 4
[1]
See Section 16 for the full
text of the R-phrases
declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
SECTION 3: Composition/information on ingredients
Type Regulation (EC) No. 1272/2008 [CLP]
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
Type
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive 67/548/EEC or
assigned an occupational exposure limit or PBT or vPvB.
Product/ingredient name Identifiers % 67/548/EEC
Classification
Skin contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners. In case of burns flush with water until the
pain ceases. While flushing remove clothing from the affected area unless it is burnt into the skin. If
hospital treatment is necessary flushing must continue during transfer and until the hospital staff takes
over the treatment.
4.1 Description of first aid measures
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Ingestion :
Inhalation :
Eye contact :
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If swallowed, seek medical advice immediately and show this container or label. Keep person warm and
at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that
vomit will not re-enter the mouth and throat.
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Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed.
Specific treatments :
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to
decomposition products may cause a health hazard. Serious effects may be delayed following
exposure.
Harmful if swallowed. May cause burns to mouth, throat and stomach.
Severely corrosive to the skin. Causes severe burns. May cause sensitization by skin contact.
Severely corrosive to the eyes. Causes severe burns.
Over-exposure signs/symptoms
No specific data.
stomach pains
pain or irritation
redness
blistering may occur
pain
watering
redness
4.3 Indication of any immediate medical attention and special treatment needed
No specific treatment.
Eye contact :
Inhalation :
Skin contact :
Ingestion :
Eye contact :
Inhalation :
Skin contact :
Ingestion :
Hazardous combustion products :
Hazards from the substance or
mixture :
In a fire or if heated, a pressure increase will occur and the container may burst.
5.1 Extinguishing media
Extinguishing media :
SECTION 5: Firefighting measures
5.2 Special hazards arising from the substance or mixture
5.3 Advice for firefighters
Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.
Decomposition products may include the following materials: carbon oxides nitrogen oxides
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.
6.2 Environmental precautions
6.1 Personal precautions, protective equipment and emergency procedures
Avoid all direct contact with the spilled material. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving
any personal risk or without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in
accordance with local regulations.
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Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Contaminated absorbent material may pose the same hazard as the spilled product.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.
6.3 Methods and materials for containment and cleaning up
6.4 Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
7.2 Conditions for safe storage, including any incompatibilities
7.3 Specific end use(s)
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.
Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources. Keep
out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized access.
Containers that are opened must be carefully resealed and kept upright to prevent leakage.
See separate Product Data Sheet for recommendations or industrial sector specific solutions.
Product/ingredient name Exposure limit values
Recommended monitoring procedures
m-Xylylene-diamine ACGIH TLV (United States, 2/2010). Absorbed through skin.
C: 0.1 mg/m
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous substances.
Appropriate engineering controls
8.2 Exposure controls
Hygiene measures :
No DELs available.
Predicted effect concentrations
No PECs available.
8.1 Control parameters
Derived effect levels
Individual protection measures
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
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9583000000
Hand protection :
Safety eyewear complying with an approved standard should be used when a risk assessment indicates
this is necessary to avoid exposure to liquid splashes, mists or dusts.
Eye/face protection :
Respiratory protection :
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Chemical-resistant apron.
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. When the product is applied by spraying and for
continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an approved/certified respirator
or equivalent.
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type.
Physical state :
Melting point/freezing point :
Boiling point/boiling range :
Vapor pressure :
Relative density :
Vapor density :
Solubility(ies) :
Non-characteristic. Odor :
pH :
Evaporation rate :
Auto-ignition temperature :
Flash point :
Slightly explosive in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Viscosity :
Partition coefficient (LogKow) :
Upper/lower flammability or
explosive limits :
Explosive properties :
Oxidizing properties :
9.1 Information on basic physical and chemical properties
9.2 Other information
Decomposition temperature :
SECTION 9: Physical and chemical properties
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge.
Flammable in the presence of the following materials or conditions: heat.
Liquid.
0.992 g/cm
3
Partially soluble in the following materials: cold water and hot water.
Closed cup: 93C (199.4F)
1.7 - 15 vol %
Weighted average: 8 % Solvent(s) % by weight :
Water % by weight : Weighted average: 0 %
Solvent Gas : Weighted average: 0.018 m
3
/l
TOC Content : Weighted average: 15 g/l
VOC content : 16 g/l
Page: 5/9
-
Safety Data Sheet
9583000000
10.6 Hazardous decomposition products
10.4 Conditions to avoid
The product is stable.
10.2 Chemical stability
10.5 Incompatible materials
10.3 Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
SECTION 10: Stability and reactivity
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides nitrogen oxides
Reactive or incompatible with the following materials: oxidizing materials.
Slightly reactive or incompatible with the following materials: reducing materials.
No specific data.
Acute toxicity
m-Xylylene-diamine LC50 Inhalation Gas. Rat 700 ppm 1 hours
LD50 Dermal Rabbit 2 g/kg -
p-tert-butylphenol LD50 Dermal Rabbit 2520 uL/kg -
benzyl alcohol LD50 Oral Rat 1230 mg/kg -
2,2,4- and 2,4,4-
trimethylhexamethylene diamine
2,4,6-
LD50 Dermal Rat 1280 mg/kg -
tetraethylenepentamine LD50 Dermal Rabbit 660 uL/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Product/ingredient name Result Score Exposure Observation Species
11.1 Information on toxicological effects
Acute toxicity estimates
Oral 2429.4 mg/kg
Dermal 37950.1 mg/kg
Inhalation (gases) 4387.9 ppm
Inhalation (vapors) 137.7 mg/l
Route ATE value
Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Inhalation of a corrosive substance may result in health effects such as stinging, coughing and in extreme cases, dyspnoea or loss of
consciousness with a risk of lung damage, possibly lung oedema. Cauterization of skin and mucous membrane. If splashed in the eyes, the
liquid may cause ireversible damage. Accidental swallowing may cause stinging and cauterization to mouth, oesophagus and stomach.
Symptoms and signs include bloody vomiting, chock and loss of consciousness.
Page: 6/9
-
Safety Data Sheet
9583000000
Potential chronic health effects
m-Xylylene-diamine Eyes - Severe irritant Rabbit - - -
Skin - Severe irritant Rabbit - - -
p-tert-butylphenol Eyes - Severe irritant Rabbit - - -
Skin - Mild irritant Rabbit - - -
benzyl alcohol Skin - Mild irritant Man - - -
2,4,6-
Eyes - Severe irritant Rabbit - - -
Skin - Mild irritant Rat - - -
Skin - Severe irritant Rat - - -
tetraethylenepentamine Eyes - Moderate irritant Rabbit - - -
Other information :
Sensitization : Contains m-Xylylene-diamine, 2,2,4- and 2,4,4- trimethylhexamethylene diamine,
tetraethylenepentamine. May produce an allergic reaction.
No additional known significant effects or critical hazards.
Mobility :
12.3 Bioaccumulative potential
12.6 Other adverse effects
12.1 Toxicity
p-tert-butylphenol Acute EC50 3900 - 4500 ug/L Fresh water Daphnia - Daphnia magna - 6 - 24 hours 48 hours
Acute LC50 5140 - 5620 ug/L Fresh water Fish - Pimephales promelas - 31 - 35
days - 97 mg
96 hours
benzyl alcohol Acute LC50 10000 ug/L Fresh water Fish - Lepomis macrochirus - 33 - 75
mm
96 hours
Product/ingredient name Species Result Exposure
12.2 Persistence and degradability
PBT : Not applicable.
vPvB : Not applicable.
SECTION 12: Ecological information
12.4 Mobility in soil
Soil/water partition coefficient
(KOC) :
12.5 Results of PBT and vPvB assessment
Do not allow to enter drains or watercourses. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.
The generation of waste should be avoided or minimized wherever possible.
Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable regulations.
European waste catalogue no. (EWC) and national waste group, catalouge, code or number is given below.
European waste catalogue (EWC) : 08 01 11*
Page: 7/9
-
Safety Data Sheet
9583000000
SECTION 14: Transport information
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable.
UN3066
UN3066
Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.1
UN no.
14.2
Proper shipping name
14.4
PG*
14.3
Transport hazard class(es) Additional information
II 8 PAlNT ADR/RID
Class
IMDG
Class
PAlNT. (p-tert-butylphenol) 8 II
IATA
Class
UN3066 PAlNT 8 II -
PG* : Packing group
Env.* : Environmental hazards
14.5
Env*
14.6 Special precautions for user
Yes.
Not available.
Yes.
Tunnel code
(E)
Emergency schedules
(EmS)
F-A, S-B
Yes.
Other EU regulations
Not applicable.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
15.2 Chemical Safety Assessment
This product contains substances for which Chemical Safety Assessments are still required.
None of the components are listed.
Seveso category : -
Indicates information that has changed from previously issued version.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
R20/22- Harmful by inhalation and if swallowed.
R21/22- Harmful in contact with skin and if swallowed.
R34- Causes burns.
R35- Causes severe burns.
R36/37/38- Irritating to eyes, respiratory system and skin.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Full text of abbreviated R phrases :
C - Corrosive
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
Full text of classifications [DSD/DPD] :
Page: 8/9
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Safety Data Sheet
9583000000
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Modified data or content compared with the previous version are maked with a triangular marker in the upper-left corner within the Safety
Data Sheet.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
Notice to reader
Hazard pictograms :
Danger
Harmful if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Hazard statements :
Signal word :
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
ACUTE TOXICITY: INHALATION - Category 4 Calculation method
SKIN CORROSION/IRRITATION - Category 1B Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
AQUATIC TOXICITY (CHRONIC) - Category 2 Calculation method
Page: 9/9
-
Safety Data Sheet
Institut fr Lackprfung
Andreas Kei ner GmbH

nicht akkreditiertes Verfahren

Die Ergebnisse beziehen sich ausschlielich auf die vom Antragsteller eingereichten und
untersuchten Proben. Falls nicht anders schriftlich vereinbart, wird das eingereichte
Probenmaterial 4 Wochen nach Erstellung des Prfungs-Berichtes entsorgt.

manager: Andreas Keiner, Amtsgericht Gieen HRB-Nr. 3614
office and laboratory: Felsweg 10, 35435 Wettenberg phone: (+49) 06 41/8 61 88
Postfach 10 04 39, 35334 Gieen fax: (+49) 06 41/8 63 87
banking accounts: Volksbank Mittelhessen (BLZ: 513 900 00) Kto.: 819603 internet: www.institut-lackpruefung.de
Sparkasse Gieen (BLZ: 513 500 25) Kto.: 225001756 e-mail: info@institut-lackpruefung.de
Sparkasse Wetzlar (BLZ: 515 500 35) Kto.: 2014488 USt-IdNr. DE 213687861

Test-Report

Application No.: 6-12-10/1

Applicant: HEMPEL A/S
Lundtoftevej 150
DK-2800 Kgs. Lyngby

Application for
inspection on the: 2010-06-15 Order No. or sign: Mr. Barreiro

Applied for: Recommended Practice for Internal Coating for Non-Corrosive Gas
Transmission Service according to API RP 5L2:2002

Recieve of samples: 2010-07-02

Testing-Material: - 80 test panels 150 75 0,8 mm
coated with: Hempels HS Gas Pipe Coating 87831
Color: redbrown

- 2,0 kg Hempels HS Gas Pipe Coating 87838 Part A
MR by volume: 4 : 1 with
Hempels Curing Agent 95830 Part B
Color: redbrown

- 1,0 kg Hempels Curing Agent 95830 Part B

- 2,0 l Hempels Thinner 08080

INSTITUT FR LACKPRFUNG ANDREAS KEINER GMBH

- Test-Report 6-12-10/1 Page 2 -

Recommended Practice for Internal Coating for Non-Corrosive Gas Transmission
Service according to API RP 5L2:2002

This Recommended Practice provides for the internal coating of line pipe used for non-corrosive
natural gas service.

2. COATING MATERIAL SPECIFICATION

2.1 Purpose

This section describes laboratory methods of identifying and qualifying coating materials suitable for
use under the intent of this Recommended Practice.

2.2 Description

2.2.1 Coating Materials

2.2.1.1 The material normally consists of the following:

a. Pigmented or clear base
b. Pigmented or clear converter
c. Pigment that includes sufficient rust inhibitor to pass salt spray test. (See Par. 3.5.1)
d. Application solvent for adjusting to suitable spray viscosity

Result: meets description

2.2.1.2 The coating material shall contain no substances which could be released from the coating in
service and prove detrimental to the operation of the pipeline and/or quality of the Gas.

2.2.1.3 The coating material, including repair materials, shall neither degrade nor produce hazardous
vapors when later subjected to external coating thermal cycles up to 575 F (300 C)



2.2.2 Mixing

The coating materials shall be mixed before use by agitating together portions of base and converter as
recommended by the supplier.

Result: 4 parts by volume base, 1 part by volume converter

2.2.3 Thinning

The coating material may be thinned by mixing with the solvent supplied and/or specified by the
supplier.

2.3 Physical Properties

2.3.1 Individual Components

Property Value Method
Base Gal. Wt. 12,61 ASTM D 1475
Converter Gal. Wt. 8,32 ASTM D 1475
Solvent Boiling Range designated ASTM D 1078
Base Boiling Range value ASTM D 1078
Converter Boiling Range specified ASTM D 1078
Application Boiling Range by supplier ASTM D 1078
Base Settling 10
ASTM D 1309 (testing)
ASTM D 869 (reporting)
Converter Settling 10
ASTM D 1309 (testing)
ASTM D 869 (reporting)

2.3.2 Mixed Components

Volume Solids 83,20 % Appendix #1
Grind 6 ASTM D 1210
Coarse Particles none
ASTM D 185
(except use ETHYLENE GLYCOL
MONOBUTYL ETHER as washliquid)



2.3.3 Thinned (In ratio according to Supplier`s instructions)

Flow
Uniform appearance when
applied on vertical surface
of given temperatures
Spray application on steel at 50 F [10 C],
100 F [37 C], 150 F [66 C] to result in
3.0 mil [76 micron] minimum dry film.
Pot Life cured ASTM D 1200
Viscosity 95 sec. # 4 Ford Cup at 77 F [25 C]

3. LABORATORY COATING TESTING

3.1 Purpose

This section describes laboratory tests required to qualify coating materials and laboratory methods.
Qualification of coating by laboratory methods is required prior to production. Once qualification is
made, no further qualification tests are required unless the coating materials or laboratory application
methods change. For each qualified material, the supplier shall provide a qualitative analysis. An
acceptable method is an infra-red spectrum. The supplier shall certify to the applicator and/or
purchaser the results of tests performed under section 3 for each qualified coating material.

3.2 Steel Panels for Performance Testing

Test panels shall be mild carbon steel 3 6 0,032 in. (75 150 0,8 mm). The surface to be coated
shall be sand blasted to any of the following standards:

(1) NACE No. 1 white metal finish in accordance with NACE Visual Standard TM-01-75
(2) Steel Structures Painting Council SSPC-Vis-1-82T SP5.
(3) Swedish Pictorial Standard SIS 05-59-00 SA3.
(4) DIN 55 928 Part 4

3.3 Laboratory Application of Coating Materials

3.3.1 Mixing

Coating material shall be mixed or thinned to normal spray viscosity in accordance with supplier`s
recommendation.



3.3.2 Application

Application shall be made by spray on the prepared side of a test panel. The atmospheric environment,
during spraying, shall be controlled to (77 5) F (25 3 C), and a maximum relative humidity of
80 %. The back and edges of the panel shall be protected.

3.3.3 Dry Film Thickness

Test thickness of film on completed panel (conditioned per Par. 3.4) shall be 2.0 0.2 mils (51 5)
microns measured by a film thickness gauge calibrated with a National Bureau of Standards Coating
Thickness Calibration Standard of a thickness within 20 % of specified nominal thickness.

Result: meets requirements dry film thickness 61 - 135 m / 2,4 - 5,3 mils

3.4 Conditioning of coated Panels

3.4.1 For qualification tests, the following schedule of conditioning shall apply:

Air dry for 10 days at 77 5 F (25 3 C), followed by a 24 hour bake in a circulating air
oven at 120 5 F (49 3 C). Relative humidity during the air drying shall not exceed 80 %.

3.4.2 After completing the schedule of conditioning outlined above, panels may be stored at room
temperature until needed for testing, but not longer than 90 days.

3.5 Performance of Laboratory coated Steel Panels

3.5.1 Testing

The tests in table 3.5 shall be performed on the test panels which have been prepared, coated and
conditioned in accordance with the above procedures. Tests shall be performed on duplicate panels. A
test result is acceptable when results of both test panels comply with the criteria listed below. In case
of failure of either panel, the test shall be repeated on duplicate panels. One such retest shall be permit-
ted.



Table 3.5
Test
Acceptance
Criterion
Test
Method
Results
Salt Spray Appendix #2
ASTM B 117, 500 hr.
(see Appendix #2)
meets requirements
Water Immersion
No blistering over
0.25 in. (6.3 mm)
from edges. (1)
Saturated CaCO
3
solution in distilled
water 100 %
immersion, room
temperature, 21 days.
meets requirements
Mixture, equal parts
by volume, methanol
& water
No blistering over
0.25 in. (6.3 mm)
from edges. (1)
100 % immersion,
room temperature,
21 days.
meets requirements
Stripping Appendix #8 Appendix #8 meets requirements
Bend
At 0.5 in. (13 mm)
diameter and larger,
the panel shall show
no flaking, loss of
adhesion or cracking
of the coating as
determined by
unaided visual
inspection.
ASTM D 522 meets requirements
Adhesion
No lifting of any
material other than
cuttings.
Appendix #4 meets requirements
Hardness
Min. 94 Buchholz at
77 2 F (25 1 C)
DIN 53 153
meets requirements
(125)
Gas Blistering No blistering Appendix #5 meets requirements
Abrasion
Minimum 23
Coef. of Abrasion
ASTM D 968,
Method A
meets requirements
Hydraulic Blistering No blistering Appendix #6 meets requirements

3.5.2 Additional Tests

At the option of the purchaser or applicator, additional performance tests may be specified to meet
individual requirements.



3.6 Performance Testing Glass Panels

3.6.1 Panel Preparation

3.6.1.1 Panel Size

The test panel shall be standard 1 3 in. (25 75 mm) glass slides, frosted one side.

3.6.1.2 Cleaning

Panels shall be solvent cleaned by rinsing first in xylol, than in acetone, immidiately prior to coating
application.

3.6.2 Application of Coating Material

Follow Par. 3.3.1 and 3.3.2, making the coating application on the frosted side of the panel only. The
wet film thickness shall result in a 2.0 0.2 mil (51 5 micron) dry film.

3.6.3 Performance of Laboratory coated Glass Panels

Test
Appeptance
Critierion
Test Method Result
Pinhole (Wet Film)
meets requirements
no pinholes
Pinhole (Dry Film)
no pinholes Appendix G
meets requirements
no pinholes

5. PRODUCTION INSPECTION AND ACCEPTANCE

5.1 Purpose

This section defines the limits of acceptance of internally coated pipe and methods of final testing to
assure compliance therewith.

5.2 General



5.2.1 Working Area

A safe working area that is suitable for the performance of their duties shall be provided by the
applicator for the purchasers inspectors and representatives.

5.2.2 Applied Coating Film

The applied coating film should be uniform in gloss, thickness and colour and should be free of
irregularities. Blushing, regardless of the degree of colour change, shall not considered detrimental
provided the affected area meets the requirements of Par. 5.3.4.4 Bond (Adhesion) Test and Par.
5.3.4.2 Film Thickness Test.

Result: meets requirements

5.2.3 Special Requirement

Any pipe which requires closer inspection shall be set aside upon curing of the coating. Purchaser may
require that the applicator set aside such pipe as their representative may request for testing, providing
that the amount of such pipe shall not exceed two joints for each eight-hour production period on a
current basis, or one joint from each four-hour period.

5.3 Production Tests

The following production tests are recommended for proper quality control of the coated pipe and
should be conducted at a frequency that will assure control. The pinhole test (Par. 5.3.4.1) and the film
thickness test (Par. 5.3.4.2) shall be conducted hourly and whenever production is interrupted, or
production parameters change. All other production tests shall be conducted once per shift.

5.3.1 Test for pH on Bare Surface of pickled or Wet Cleaned Pipe

Water having an initial pH value of 6.0 to 8.5 as determined with a pH meter, is poured into a pipe at
one end and gathered in a cup at the other end. Limits of pH: within 0.5 of initial pH value, and
between 6.0 to 8.5, immediately prior to coating application.

This test for pH is not applicable to the bare surface of mechanically cleaned pipe.

Result: no laboratory test

5.3.2 Panel and Slide Preparation

Metal panels shall be prepared in accordance with 3.2 or in a manner simulating pipe surface condition
before coating.



5.3.3 Coating and Curing of Panel or Slide

A panel or slide is attached to the inside of a clean pipe. The panel is coated. The panel or slide is to
remain in the pipe for a minimum of five minutes. After the panel or slide is removed, the test area on
the pipe is spot repaired. After 15 to 30 minutes of air drying, the test panel or slide is dried for 10
minutes at 150 to 175 F (66 to 79 C). The slide or panel is baked in an oven at 300 10 F
(149 6 C) for 30 minutes or as supplier specifies.

5.3.4 Evaluation of Test Panels or Slides

5.3.4.1 Pinhole Test

Observe glass slide before and after curing, holding slide over a slot in a container which houses a 100
Watt bulb, the bulb being a distance of between 4 and 5 inches [100 to 130 mm] from the coated slide.
Evaluation shall be made by purchasers representative. Pinhole dispersion shall be held to a
minimum.

Result: meets requirements no pinholes visible

5.3.4.2 Film Thickness Test

Using a micrometer with rachet, measure the uncoated slide, then coat and measure the cured slide at
the same location for slide-plus-coating thickness. The difference of the two is the coating thickness
and shall be at least 0.2 mil (5 micron) greater than the minimum dry film thickness specified by the
purchaser.


5.3.4.3 Bend Test

Bend a cured panel 180 around a conical mandrel at 0.5 in. (13 mm ) diameter and larger, the panel
shall show no flaking, loss of adhesion or cracking of the coating, as determined by unaided visual
inspection.


5.3.4.4 Bond (Adhesion) Test

See Appendix #4




5.3.4.5 Cure Test

Immerse cured panel or slide in solvent* for a period of four hours. No softening, wrinkling or
blistering of the coating film shall be observed after 30 minutes recovery period at room temperature.

* Same as thinner used for the coating material.


5.3.4.6 Water Test

After a minimum of 4 hours immersion in either fresh water or an aqueous solution, containing (by
weight) 1 % sodium chloride, 1 % sodium sulfate and 1 % sodium carbonate, the cured panel shall
exhibit no loss of adhesion, softening, wrinkling or blistering of the coated film.


5.3.4.7 Stripping Test

See Appendix # 3


5.3.5 Production Tests on Pipe

Any of applicable production tests in Par. 5.3.4 may be made on cured coating for quality control
purposes.

The tested material
Hempels HS Gas Pipe Coating 87831
fulfils the tested requirements of API RP 5L2:2002
.

Wettenberg, 2010-11-02 No. of Pages: 10
Sign: Se/zu Attachment: 1

The director of the institute The official in charge

Keiner Seim

by the Chamber of Commerce and Trade
certified expert for painting materials and coatings
responsible: IHK Lahn-Dill
INSTITUT FR LACKPRFUNG . ANDREAS KEINER GMBH

- Test-Report 6-12-10/1 Attachment -

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15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120,0
cm-1
%T
3507,64
3056,09
3037,12
2999,56
2966,41
2927,74
2871,77
2757,30 2537,10
2292,25
2064,94 1889,85
1733,83
1607,57
1582,21
1510,01
1455,68
1429,85
1413,74
1384,53
1362,14
1346,02
1297,46
1247,97
1184,26
1157,55
1132,26
1120,04
1107,39
1085,11
1036,34
1011,87
971,14
915,68
862,79
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736,90
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84
86
88
90
92
94
96
98
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102
104
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cm-1
%T
3287,71
3007,70
2956,37
2928,72
2857,14
1877,72
1646,98
1610,83
1591,03
1515,94
1500,11
1465,67
1362,00
1299,65
1255,48
1201,67
1179,61
1110,41
1081,90
1024,78
988,08
887,89
831,54
789,04
730,47
700,86
661,58
596,40
552,22
505,04
441,21
,



Sparkasse Gieen (BLZ: 513 500 25) Kto.: 225001756 e-Mail: info@institut-lackpruefung.de

Test-Report


Lundtoftevej 150
DK-2800 Kgs. Lyngby

Application for

Applied for: Steel tubes and fittings for on and offshore pipelines Internal coatings
for the reduction of friction for conveyance of non corrosive gas according
to DIN EN 10 301:2004


Color: redbrown

Color: redbrown





Steel tubes and fittings for on and offshore pipelines Internal coatings for the
reduction of friction for conveyance of non corrosive gas according to DIN EN
10 301:2004

4. COATING MATERIAL

4.1 General

Principly the coating material shall consist of two parts: Base component and hardener.

The coating material shall not contain any substances which will be released from the paint film after it
has cured and are proven to be detrimental to the operation of the pipeline.

The coating material must be qualified in accordance with 4.2 and shall not be changed after
qualification.

The applied coating must be smooth, to reduce the friction.

Unless otherwise agreed, the applied coating shall provide corrosion protection during storage and
transport for a minimum period of one year without significant breakdown of the coating.

4.2 Qualification of the coating material

4.2.1 General

This section describes the required laboratory test methods by the manufacturer of the coating material
for the qualification of the coating material.

The required properties of the coating material for the qualification are listed in Table 1 and the
reported tests must, if not agreed otherwise, carried out on the coating material and test-panels (steel),
which are applied in accordance with EN ISO 1513 and EN ISO 1514 and the instructions of the
coating material manufacturer.

The dry film thickness shall be measured on panels in accordance with 4.2.8

The applied coating on glass- or steel-panels shall be conditioned under one of the following
conditions, available to perform the test procedure.

Cycle A: - Substrate: glass
- 23 C and 80 % relative humidity, until the coating is at least tack free;
- dry in a circulating-air oven for 30 minutes at (75 5 ) C;


Cycle B: - Substrate: steel
- condition at 18 C to 25 C and 80 % relative humidity until the coating is at
least tack free;
- dry in a circulating-air oven for 30 minutes at (150 5 ) C;

If agreed other conditioning cycles are allowed.

4.2.2 Non-volatile matter (mass)

When determined in accordance with ISO 3251, the non-volatile matter (by mass) of the coating
material shall comply with the value specified by the coating material manufacturer in the qualification
certificate.

Result: meets requirements non-volatile matter (by mass): 92,4 %

4.2.3 Viscosity at (23 2) C

The viscosity must be measured in accordance with ISO 2431.

The viscosity must comply with the value specified by the coating material manufacturer in the
qualification certificate.

Result: meets requirements 60 seconds in ISO-cup 6 mm

4.2.4 Density

The density must be determined in accordance with ISO 2811.

The density of the coating material must comply with the value specified by the coating material
manufacturer.

Result: meets requirements Base : 1,514 g/cm
Hardener : 0,991 g/cm
Mixture : 1,410 g/cm

4.2.5 Ash content

The ash content must be determined in accordance with the method described in annex A,

It must comply with the value, specified by the coating material manufacturer in the qualification
certificate.

Result: meets requirements 38,20 % by weight


4.2.6 Pot life

By determination, according to the test method, given from the coating manufacturer, the pot life is
considered to be the time taken by the ready-mixed coating material to reach a condition at which it
can no longer be applied satisfactorily and shall be specified in the product data sheet

Result: meets requirements approximate 1 hour

4.2.7 Appearance

The appearance and continuity of the coating shall be inspected visually without any magnification.

The paint film must show a constant colour and a smooth surface without any pin holes and other
deteriorations for example running or sagging.


4.2.8 Dry film thickness

The thickness of the coating must be measured in accordance with the required number of
measurements and the test method given in annex B.

Glass- and steel panels with the applied coating must be conditioned according to cycle A or B (see
4.2.1) before measured.

If the measurement was carry out on glass panels, the dry film thickness must be determined according
with method 2 or 3 in EN ISO 2808.

Result: meets requirements Average: 95,2 m

4.2.9 Adhesion cross-cut test

The test must be carried out on coated steel panels, preferably conditioned according with cycle B (see
4.2.1).

The adhesion must be determined in accordance with EN ISO 2409, the cross-cut classification must
be equal to or lower than 1. The test must be carried out in duplicate.

Result: meets requirements Classification 0

4.2.10 Buchholz hardeness

4.2.1).



The adhesion must be determined in accordance with EN ISO 2815.

In any case the Buchholz-hardness must be 94.

Result: meets requirements 100

4.2.11 Resistance to neutral salt spray

4.2.1).

The resistance of the coating to neutral salt spray must be tested and determined according to ISO
7253.

The duration of exposition must amount to 480 hours.

The test must be carried out in duplicate. The dry film thickness of the coating must be from 60 m to
75 m.

The coating on each test panel must be signed with an X-cut down to the substrate located at lest 20
mm from any edge.

After the test, the test panel must dry for at least 30 min. at 23 C and 80 % relative humidity.

The coating shall be free from any signs of deterioration, for example blistering (except in the area
within 3 mm from the X-cut), cracking and staining. Any corrosion shall extend not more than 2,0 mm
at the most from the X-cut.

It shall not be possible to remove be means of clear plastic tape more than 3,0 mm of the coating in
any direction from the area around the X-cut.

Result: meets requirements no blistering and no signs of corrosion

4.2.12 Resistance to artificial ageing

The test must be carried out on coated steel panels in the dimension of the panels shall be approx. 100
50 0,8 mm.

After application carry out the following procedure:
- 10 days conditioning at 18 C to 25 c and 80 % relative humidity;
- baking in a circulating-air oven at (50 2) C for 24 h, followed by conditioning for 4 days at
(80 2) C and followed at 18 C to 25 C for 24 h;

After ageing, subject the test panels to test in accordance with 4.3.13.

Result: meets requirements no loss of adhesion at 13 mm



4.2.13 Bend test (conical mandrel)

4.2.1). The inspection must be without any magnification.

The test must be carried out according to EN ISO 6860.
The maximum extent of cracking along the panel from the small end of the mandrel shall be less than
or equal to 13 mm.


4.2.14 Resistance to pressure variations

4.2.1).

The pressure must be 100 bar.

The coating shall fulfil general after the test, described in annex C after a exposition of 24 hours, 48
hours and 72 hours at (23 2) , an appearance according to 4.2.7 and a adhesion according to 4.2.9

Result: meets requirements no blistering Adhesion classification 0

4.2.15 Resistance to blistering (fluid immersion)

4.2.1).

The test must be carried out in accordance with the method described in annex D.

After removal of the test panels from the pressure equipment, the test panels must be examined within
3 minutes, according to 4.2.7

The coating shall show no blistering or softening.

A change in colour or brightness of the coating shall not constitute as a change of the coating quality.

After removal from the pressure equipment and conditioning for 24 hours at (23 2) C the coating
must show a adhesion in accordance with 4.2.9

Result: meets requirements no blistering, softening or other deteriorations



4.2.16 Resistance to water immersion

4.2.1).

The dry film thickness of the coating must be from 60 m to 75 m.

After exposition of the coated specimen in distilled water at roomtemperature for 480 hours, according
to ISO 2812-2, the coating shall show no blistering or softening. The first examination must be 3
minutes after removal from the water.


After removal from the water and conditioning for 24 hours at (23 2) C the coating must show a
adhesion in accordance with 4.2.9


4.2.17 Resistance to chemicals

4.2.1).

After exposition of the coated specimen in distilled water at roomtemperature for 168 hours, according
to ISO 2812-1, the coating shall show no blistering or softening. The first examination must be 3
minutes after removal from the test-liquid.


After removal from the testliquids and conditioning for 24 hours at (23 2) C the coating must show
a adhesion in accordance with 4.2.9

The coated test-panel must be immersed to following testliquids:

- cyclohexane
- diethylene glycol solution 95 % in water
- hexane
- methanol
- toluene
- lubricating oil

Adhesion classification 0



4.2.18 Infrared spectrograms

The infrared spectrograms of the base component and the curing agent component shall be submitted
on request of the purchaser.

Infrared referencespectra, determined on KBr-Standard or other method, shall be provided for the
material-qualification and coater-qualification (required are spectra from base component; curing agent
and mixture).

Result: meets requirements see attachment

The tested material
fulfils the tested requirements of DIN EN 10 301:2004
.



Keiner Seim



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4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400,0
0,0
5
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15
20
25
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55
60
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115
120,0
cm-1
%T
3507,64
3056,09
3037,12
2999,56
2966,41
2927,74
2871,77
2757,30 2537,10
2292,25
2064,94 1889,85
1733,83
1607,57
1582,21
1510,01
1455,68
1429,85
1413,74
1384,53
1362,14
1346,02
1297,46
1247,97
1184,26
1157,55
1132,26
1120,04
1107,39
1085,11
1036,34
1011,87
971,14
915,68
862,79
831,07
772,92
736,90
727,63
697,10
665,20
639,20
574,39
502,00
455,68

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65,0
66
68
70
72
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76
78
80
82
84
86
88
90
92
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96
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100
102
104
105,0
cm-1
%T
3287,71
3007,70
2956,37
2928,72
2857,14
1877,72
1646,98
1610,83
1591,03
1515,94
1500,11
1465,67
1362,00
1299,65
1255,48
1201,67
1179,61
1110,41
1081,90
1024,78
988,08
887,89
831,54
789,04
730,47
700,86
661,58
596,40
552,22
505,04
441,21



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68,0
69
70
71
72
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74
75
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77
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80
81
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83
84
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97,0
cm-1
%T
3677,57
3322,01
2925,31
2854,23
2092,31
1606,98
1582,19
1508,07
1446,41
1361,71
1295,23
1244,23
1181,36
1106,06
1014,82
875,10
827,15
770,22
727,73
711,97
669,01





Test-Report


Lundtoftevej 150
DK-2800 Kgs. Lyngby

Application for

Applied for: Paints and varnishes Friction-reduction coatings for the interior of on-
and offshore steel Pipelines for non-corrosive gases according to
ISO 15 741:2001


Color: redbrown

Color: redbrown





Paints and varnishes Friction-reduction coatings for the interior of on- and
offshore steel Pipelines for non-corrosive gases according to ISO 15 741:2001

This International Standard specifies requirements and methods of test for liquid epoxy paints and
internal coatings of such paints in steel pipes and fittings for the conveyance of non-corrosive gas.

The applied and cured paint film must be smooth to give the desired reduction in friction.

4. COATING MATERIAL

4.1 General

The coating material shall typically be a two-pack epoxy paint. It shall not contain any substances
which will be released from the paint film after it has cured and are proven to be detrimental to the
operating of the pipeline and the quality of the gas.

Unless otherwise agreed, the coating material shall be qualified in accordance with 4.2 and 4.3 and
shall not be changed after qualification.

The manufacturer of the coating material shall provide on request infrared spectrograms of the base
component and the curing agent component.

In addition, the manufacturer shall provide a product data sheet, a health and safety data sheet and a
certificate stating the test results obtained in accordance with 4.2 and 4.3 respectively and , if
applicable, deviating test conditions.

The manufacturer shall also provide with every batch of the coating material a batch certificate stating
the information as given in 4.8.

Unless otherwise agreed, the applied coating shall provide corrosion protection during storage and
transport for a minimum period of one year without significant breakdown of the coating.

The typical operating-temperature range for this type of coating is between -20 C and 110 C.

Where, subsequently, external coatings have to be applied, care shall be taken not to allow the internal
coating to be damaged by the elevated temperatures which may occur.



4.2 Particular requirements for qualification of coating Material

4.2.1 General

The following subclauses describe the laboratory test methods which are required for qualification of
the coating material.

4.2.2 Non-volatile matter (by mass)

When determined in accordance with ISO 3251, the non-volatile matter (by mass) of the coating
material shall comply with the value specified by the coating material manufacturer in the qualification
certificate.

Result: meets requirements non-volatile matter (by mass): 92,4 %

4.2.3 Non-volatile matter (by volume)

When determined in accordance with ISO 3233, the non-volatile matter (by volume) of the coating
material shall comply with the value specified by the coating material manufacturer in the product data
sheet.

Result: meets requirements non-volatile matter (by volume): 83,1 %

4.2.4 Viscosity

When determined by the method specified by the manufacturer, the viscosity of the ready mixed
coating material shall comply with the value specified by the coating material manufacturer in the

The viscosity should preferably be measured in accordance with ISO 2431.

Result: meets requirements 60 seconds in ISO-cup 6 mm

4.2.5 Density

When determined in accordance with one of the parts of ISO 2811, the density of the coating material
shall comply with the value specified by the coating material manufacturer in the product data sheet.

Result: meets requirements Base : 1,514 g/cm
Hardener : 0,991 g/cm
Mixture : 1,410 g/cm



4.2.6 Ash (residue on ignition)

When determined in accordance with the method described in annex A, the ash (residue on ignition) of
the coating material shall comply with the value specified by the coating material manufacturer in the

Result: meets requirements 38,2 % by weight

4.2.7 Pot life

The pot life is considered to be the time taken by the ready-mixed coating material to reach a condition
at which it can no longer be applied satisfactorily. The pot life shall be specified in the product data
sheet

Result: meets requirements approximate 1 hour

4.2.8 Infrared spectrograms

The infrared spectrograms of the base component and the curing agent component shall be submitted
on request.

Result: meets requirements see attachments

4.2.9 Appearance

The appearance and continuity of the coating shall be inspected visually without any magnification.


4.3 Particular requirements for qualification of the cured paint film

4.3.1 Preparation of the test panels

Perform the tests specified in 4.3.3 to 4.3.12 on coatings applied to the required dry film thickness
specified in 4.3.3 by spraying on to the test panels (steel or glass). Prepare steel panel as specified in
5.2 and glass panels as specified in annex E. Apply the paint in accordance with the instructions of the
coating material manufacturer. Perform each test at least in duplicate.



4.3.2 Conditioning of test panels

If specified, condition the coated test panels using one of the following cycles, depending on the
substrate and on the individual test. Cycle B and cycle C are optional and the choice of the
conditioning cycle depends on the time available to perform the test procedure.

Cycle A - Substrate: steel or glass
least tack free;
- dry for 30 minutes in a circulating-air oven at (75 2) C;
- condition for a minimum of 30 minutes 18 C to 25 C and 80 % relative
humidity before testing.

Cycle B - Substrate: steel or glass
least tack free;

Cycle C - Substrate: steel or glass
least tack free;

4.3.3 Dry film thickness

Unless otherwise agreed, the dry film thickness of the coating, applied on a glass or steel panel, shall
be between 60 m and 100 m except for the test described in 4.3.6 (resistance to neutral salt spray).

Unless otherwise agreed, the dry film thickness shall be measured in accordance with ISO 2808:1997,
Method No. 2 for glass and Method No. 10 for blast-cleaned steel, following the procedure given in
annex B.

Result: meets requirements Average: 95,2 m

4.3.4 Adhesion

When determined in accordance with ISO 2409, the cross-cut classification of the coating applied on
steel panels and conditioned using cycle B or C shall be equal to or lower than 1.

Result: meets requirements adhesion classification 0



4.3.5 Buchholz hardeness

When determined in accordance with ISO 2815, the Buchholz hardness of the coating, applied on glass
or steel panels and conditioned using cycle B or C shall have a value of 94 or more.

Result: meets requirements 100

4.3.6 Resistance to neutral salt spray

The coating, applied on steel panels with a dry film thickness of 60 m to 75 m, conditioned using
cycle B or C, and with an X-cut down to the substrate located at lest 20 mm from any edge, shall be
tested in accordance with ISO 7253 for 480 hours.

After the test, allow the test panel to dry for at least 30 minutes at 18 C to 25 C and 80 % relative
humidity.

The coating shall be free from any signs of deterioration, for example blistering (except in the area
within 2,0 mm from the X-cut), cracking and staining. Any corrosion shall extend not more than 2,0
mm at the most from the X-cut. It shall not be possible to remove by means of clear plastic tape more
than 3,0 mm of the coating in any direction from the area around the X-cut.

Result: meets requirements no blistering and no signs of corrosion

4.3.7 Resistance to artificial ageing

Prepare two different sets of coated panels, each set consisting of 3 steel panels. The dimension of the
panels shall be approx 100 50 0,8 mm.

Carry out the following procedure:

- condition 1 set using cycle C
- condition set 2 using cycle C and than age the panels at 80 C in a circulating-air oven for 100 h,
followed by conditioning for 24 hours at 18 C to 25 C and 80 % relative humidity;
- after ageing, subject the test panels to a bend test in accordance with 4.3.8.

The result of the bend test shall comply with the requirements specified in 4.3.8.


4.3.8 Bend test (conical mandrel)

Prepare steel panels and condition them using cycle B or cycle C. When the panels are tested in
accordance with ISO 6860, the maximum extent of cracking along the panel from the small end of the
mandrel shall be less than or equal to 13 mm, and there shall be no loss of adhesion.




4.3.9 Resistance to gas pressure variations

accordance with annex C, they shall have a general good appearance when examined in accordance
with 4.2.9 and shall not show any blistering. The adhesion value shall fulfil the requirements as given
in 4.3.4 after conditioning for 24 hours and 40 hours at 18 C to 25 C and 80 % relative humidity.

Result: meets requirements no blistering adhesion classification 0

4.3.10 Resistance to water immersion

accordance with ISO 2812-2 for 480 h, the coating shall not show any blistering or appreciable
softening. The examination shall carried out 3 minutes after the panels have been removed from the
test liquid.

Result: meets requirements no blistering

4.3.11 Resistance to chemicals

accordance with ISO 2812-1:1993, method No.1, procedure A, for 168 h, the coating shall not show
any blistering or appreciable softening. Use following test liquids:

- cyclohexane
- 95 % by volume diethylene glycol solution in water
- hexane
- methanol
- toluene
- and lubricating oil (e.g. compressor seal oil in accordance with ISO 6743-4)

The test panels shall be completely immersed in the test liquids.

The examination shall be carried out at 18 C to 25 C and 80 % relative humidity 3 min after the
panels have been removed from the test liquid. After conditioning for 24 hours at 18 C to 25 C and
80 % relative humidity, the adhesion value shall fulfil the requirements given in 4.3.4. A change in
the colour of the coating shall not be considered as an indication of inferior coating quality.

adhesion classification 0



4.3.12 Resistance to hydraulic blistering

accordance with annex D, the coating shall not show any blistering. The examination shall be carried
out at 18 C to 25 C and 80 % relative humidity 3 minutes after the panels have been removed from
the test liquid. The adhesion value shall fulfil the requirements given in 4.3.4 after conditioning at 18
C to 25 C and 80 % relative humidity for 24 hours.

Result: meets requirements no blistering adhesion classification 0

The tested material
fulfils the tested requirements of ISO 15 741:2001
.



Keiner Seim



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105
110
115
120,0
cm-1
%T
3507,64
3056,09
3037,12
2999,56
2966,41
2927,74
2871,77
2757,30 2537,10
2292,25
2064,94 1889,85
1733,83
1607,57
1582,21
1510,01
1455,68
1429,85
1413,74
1384,53
1362,14
1346,02
1297,46
1247,97
1184,26
1157,55
1132,26
1120,04
1107,39
1085,11
1036,34
1011,87
971,14
915,68
862,79
831,07
772,92
736,90
727,63
697,10
665,20
639,20
574,39
502,00
455,68

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72
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80
82
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88
90
92
94
96
98
100
102
104
105,0
cm-1
%T
3287,71
3007,70
2956,37
2928,72
2857,14
1877,72
1646,98
1610,83
1591,03
1515,94
1500,11
1465,67
1362,00
1299,65
1255,48
1201,67
1179,61
1110,41
1081,90
1024,78
988,08
887,89
831,54
789,04
730,47
700,86
661,58
596,40
552,22
505,04
441,21



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68,0
69
70
71
72
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74
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80
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83
84
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89
90
91
92
93
94
95
96
97,0
cm-1
%T
3677,57
3322,01
2925,31
2854,23
2092,31
1606,98
1582,19
1508,07
1446,41
1361,71
1295,23
1244,23
1181,36
1106,06
1014,82
875,10
827,15
770,22
727,73
711,97
669,01





Test-Report


Lundtoftevej 150
DK-2800 Kgs. Lyngby

Application for

Applied for: Technical Specification for Internal Coating Materials for Steel Line Pipe
and Fittings according to TRANSCO CM2
, Edition March 2003


Color: redbrown

Color: redbrown





Technical Specification for Internal Coating Materials for Steel Line Pipe and
Fittings according to TRANSCO CM2
, Edition March 2003

6. BASIC PHYSICAL PROPERTIES DATA

6.1 When required, the contractor shall, in confidence, furnish details of formulation together with
the typical physical constants and manufacturing tolerances associated with materials submitted.

6.2 Any change of formulation of material may be proposed for consideration as a variant by
TRANSCO and supply of the modified material shall not be implemented until such time as the
modification has been approved. Details of the physical constants shall be submitted to
TRANSCO and shall be applicable to all materials.

7. TYP APPROVAL

7.1 Basic paint properties

The contractor shall supply the information given in table 1 in respect of the components of the
paint as supplied and when mixed and thinned to application-viscosity, as required.

7.2 Basic film properties

The tests given in table 2 shall be carried out on 1 mm thick steel panels (BS 1449: Part 1,
CR1/FF) polished to 5 m and glass panels. The paint shall be applied by spray to give a
minimum dry film thickness between 50 m and 75 m in one coat and allowed to dry for 24
hours unless otherwise specified.

7.2 Basic performance requirements

7.3.1 Physical Performance Requirements

The tests given in table 3 shall be carried out on standard surfaces unless otherwise specified.
The coating shall be applied to give a minimum dry film thickness of 50 m and shall be allowed
to dry at 20 C to 25 C and 60 % to 70 % relative humidity for the time specified under each
test.

7.3.2 Environmental resistance requirements

The tests given in table 4 shall be carried out on standard surfaces unless otherwise specified.
The coating shall be applied to give a minimum dry film thickness of 50 m and shall be allowed
to dry at 20 C to 25 C and 60 % to 70 % relative humidity for the timesecified under each test.

7.3.3 Chemical resistance requirements

After a drying period of seven days at 20 C to 25 C, test panels prepared in accordance with
7.2 shall be subjected to partial immersion under the conditions given in table 5. Tests shall be
carried out on standard surfaces unless specified otherwise. After removal from the test liquid,
the coating shall show no signs of damage or breakdown and no corrosion of the substrate.


TABLE 1 - Information to be suppied by the contractor

Information required Method of test Result of test
Mixing ratio of base and curing agent
4 parts by volume base
1 parts by volume curing agent
Nature of thinner and quantity required
for adjustment to application viscosity

Cure time
Appendix D,
clause D.1
No signs of deterioration
Stability
Appendix D,
clause D.2

In progress until
june 2011

Pot-life
Appendix D,
clause D.3
Approximate 1 hours
Relative density
Appendix D,
clause D.4

Base: 1,452 g/ml
Curing agent: 0,951 g/ml
Mixture: 1,359 g/ml

Drying times
BS 3900:
Parts C2 and C3
1 hour 10 minutes
< 16 hours
Total non-volatile content
(by weight and by volume)
BS 3900: Part B2
92,4 % by weight
83,1 % by volume
Viscosity
BS EN 535
(break point
procedure)
60 sec. (6 mm cup)
Pigment dispersion BS 3900: Part C6
35 m
(# 6 Hegman scale)
Flash point BS 3900: Part A9 28 C
Wet film thickness to give a dry film
thickness of 50 m in one coat
BS 3900: Part C5 60 m



TABLE 2 - Test conditions and required results for basic film property tests

Propertiy Panel reference Method of test Result required Result of test
Cissing 300 mm 100 mm
steel

150 mm 100 mm
glass
(blast cleaned)

Viewed over bright
light source
No cissing No cissing
Blistering and
flow
As for cissing - No blistering and
uniform flow
No blistering and
uniform flow
Sagging 300 mm 100 mm
steel
Panel dried
vertically
No sagging No sagging
Drying Steel Drying at 20 C to
25 C, 60 % to
70 % relative hu-
midity
Surface dry
< 2 hours
hard dry
< 16 hours
1 hour 10 minutes

< 16 hours

TABLE 3 - Test conditions and required results for physical performance tests


Flexibility
(bend test)

Appendix E, clause
E.1 -
dried seven days
and 28 days

ASTM D522 - 60
No damage to
coating
No damage to
coating

Reverse im-
pact (falling
weight)

Appendix E, clause
E.1 -
dried seven days
and 28 days
BS 3900: Part E3-
indentation depth
2,5 mm
No damage to
coating
No damage to
coating

Scratch re-
sistance

Appendix E, clause
E.1 -
dried seven days
and 28 days

BS 3900: Part E2 Pass at 2000 grams
Pass at 5000
grams

Adhesion
(cross-cut
test)

Appendix E, clause
E.1 -
dried seven days
and 28 days

BS 3900: Part E6
spacing of cuts
1,5 mm
Classification 0
(no lifting other
than cuttings)
Classification 0
(no lifting other
than cuttings)



TABLE 4 - Test conditions and required results for environmental resistance tests


Salt spray

Dried seven days
BS 3900: Part F4
No breakdown after
500 hours
No breakdown
after 500 hours

Humidity

Dried seven days
ISO 6270
No breakdown after
10 days
No breakdown
after 10 days

Pressure
blistering

Dried seven days
Pneumatic pressure
testing
24 h / 70 bar
72 h / 70 bar
Hydrostatic
pressure testing
24 h / 140 bar
No blistering or
detachment
No blistering or
detachment

TABLE 5 - Test conditions and recovery time for chemical resistance test

Medium
Temperatu-
re C
Pressure bar
Immersion
time h
Recovery
time h
Result of test

Distilled water in
equilibrium with carbon
dioxide (pH 4)

20 to 25 7 1000 - Pass

Distilled water

20 to 25 Atmospheric 1000 - Pass

Triethylene glycol

20 to 25 Atmospheric 500 4 Pass

Lubricating oil


Benzene


Xylene




Medium
Temperatu-
re C
Pressure bar
Immersion
time h
Recovery
time h
Result of test

n- Hexane


iso - Octane


Methyl alcohol


Odorizing agents

Dialkyl sulphide /
mercaptan odorant


The tested material
fulfils the tested requirements of TRANSCO CM2
, Edition March 2003.



Keiner Seim



H
e
m
p
e
l
s

H
S

G
a
s

P
i
p
e

C
o
a
t
i
n
g

8
7
8
3
8

P
a
r
t

A

4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400,0
0,0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120,0
cm-1
%T
3507,64
3056,09
3037,12
2999,56
2966,41
2927,74
2871,77
2757,30 2537,10
2292,25
2064,94 1889,85
1733,83
1607,57
1582,21
1510,01
1455,68
1429,85
1413,74
1384,53
1362,14
1346,02
1297,46
1247,97
1184,26
1157,55
1132,26
1120,04
1107,39
1085,11
1036,34
1011,87
971,14
915,68
862,79
831,07
772,92
736,90
727,63
697,10
665,20
639,20
574,39
502,00
455,68

H
e
m
p
e
l
s

C
u
r
i
n
g

A
g
e
n
t

9
5
8
3
0

P
a
r
t

B

4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400,0
65,0
66
68
70
72
74
76
78
80
82
84
86
88
90
92
94
96
98
100
102
104
105,0
cm-1
%T
3287,71
3007,70
2956,37
2928,72
2857,14
1877,72
1646,98
1610,83
1591,03
1515,94
1500,11
1465,67
1362,00
1299,65
1255,48
1201,67
1179,61
1110,41
1081,90
1024,78
988,08
887,89
831,54
789,04
730,47
700,86
661,58
596,40
552,22
505,04
441,21

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, Edition March 2003

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, Edition March 2003.

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