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This e-offprint is for personal use only and shall not be self-archived in electronic repositories. The aim of this study is to understand the various sources and factors controlling the abundance and distribution of clay minerals, sand, silt, clay and organic matter. Organic matters in the sediments appeared to be the main mechanisms for the distribution of clay and silt.
This e-offprint is for personal use only and shall not be self-archived in electronic repositories. The aim of this study is to understand the various sources and factors controlling the abundance and distribution of clay minerals, sand, silt, clay and organic matter. Organic matters in the sediments appeared to be the main mechanisms for the distribution of clay and silt.
This e-offprint is for personal use only and shall not be self-archived in electronic repositories. The aim of this study is to understand the various sources and factors controlling the abundance and distribution of clay minerals, sand, silt, clay and organic matter. Organic matters in the sediments appeared to be the main mechanisms for the distribution of clay and silt.
Arab J Geosci (2013) 6:1371-1380 DOI 10.1007/s12517-011-0423-3 Distribution of grain size, clay mineralogy and organic matter of surface sediments from Tirumalairajanar Estuary, Tamilnadu, east coast of India Senapathi Venkatramanan, Thirunavukkarasu Ramkumar & Irudhayanathan Anithamary 1 3 Your article is protected by copyright and all rights are held exclusively by Saudi Society for Geosciences. This e-offprint is for personal use only and shall not be self- archived in electronic repositories. If you wish to self-archive your article, please use the accepted manuscript version for posting on your own website. You may further deposit the accepted manuscript version in any repository, provided it is only made publicly available 12 months after official publication or later and provided acknowledgement is given to the original source of publication and a link is inserted to the published article on Springer's website. The link must be accompanied by the following text: "The final publication is available at link.springer.com. ORIGINAL PAPER Distribution of grain size, clay mineralogy and organic matter of surface sediments from Tirumalairajanar Estuary, Tamilnadu, east coast of India Senapathi Venkatramanan & Thirunavukkarasu Ramkumar & Irudhayanathan Anithamary Received: 4 May 2011 / Accepted: 27 September 2011 / Published online: 18 October 2011 # Saudi Society for Geosciences 2011 Abstract The aim of this study is to understand the various sources and factors controlling the abundance and distribution of clay minerals, sand, silt, clay and organic matter of the surface sediments of Tirumalair- ajanar Estuary in two different seasons. The study was undertaken for two seasons, based on ten selected stations all along the estuary, mouth and freshwater zone. Furthermore, along the estuary region, clay and silt were observed and also at few stations in the upstream end. Organic matters in the sediments appeared to be the main mechanisms for the distribution of clay minerals in estuary indicated that the distribu- tions of clay minerals were comparatively higher during postmonsoon than in premonsoon season. The clay mineral assemblage consists mainly of chlorite, kaolin- ite, montmorillonite, illite and very scarce gibbsite. The clay from the sediments has been separated and studied for mineral identification using X-ray diffraction analy- sis. The present study also reveals that sediment texture is one of the main controlling factors for the distribution of organic matter. Keywords Clay minerals . Sand . Silt . Clay . Organic matter . Tirumalairajanar . East coast of India Introduction Textural characteristics of estuarine sediments are strongly influenced by several factors, including source area composition of adjacent lands, climate, length and energy of sediment transport and redox conditions in the deposi- tional environments (Bhatia and Cook 1986; Fralick and Kronberg 1997; Dickhudt et al. 2011). Numerous studies have analysed grain size properties which can suggest sources and hydrodynamic conditions of marine sediments (Carranza-Edwards et al. 2005). Moreover, spatial varia- tions in sand, silt and clay ratio can help to determine present estuary environment conditions (Anithamary et al. 2011). The wave activity, the near bed currents, the prevailing climatic conditions, the extreme variations of the discharged load, as well as the grain size and the mineralogical composition of the suspended load, control the grain size distribution in the Thermaikos Gulf (Poulos et al. 2000). The general scarcity of clay-sized sediments in estuary, due to winnowing through the action of waves, tides and currents, contrasts with the huge accumulations of argillaceous deposits in the rest of the oceans. Where they do occur, source mixing during transportation, flocculation and differential settling processes appear to be the main mecha- nisms for their distribution (Griffin et al. 1968; Chamley 1989). Additionally, Chamley (1989) suggests that the aggregation of clay particles by marine organic matter appears to be a widespread phenomenon, mainly responsible for the rapid sinking of land-derived materials. In this present study, the grain size distribution, clay mineralogy and organic matter of surface sediments from S. Venkatramanan (*) : T. Ramkumar : I. Anithamary Department of Earth Sciences, Annamalai University, Chidambaram, Tamilnadu, India e-mail: venkatramanansenapathi@gmail.com T. Ramkumar e-mail: tratrj@gmail.com Arab J Geosci (2013) 6:13711380 DOI 10.1007/s12517-011-0423-3 Author's personal copy the Thirumalairajanar Estuary are examined. In addition, the mechanisms responsible for the grain size distribution into the estuary are investigated. Description of the study area River Tirumalairajanar is one of the important tributar- ies of Cauvery River, state of Tamilnadu. It is a bar- built estuary along the east coast of India. The sampling locations are shown in Fig. 1. The study area is surrounded by Tanjore District in the west, Cudda- lore District in the North, Palk straight in the South and Bay of Bengal in the east. Distribution of the Cauvery, Arasalar, Tirmalarajanar, Vellar, Adappar, Vettar and Vedaranyam canal are the main rivers flowing in this area and debauches into the Bay of Bengal. Geologically, the study area of Tirumalairajanar is covered by Quaternary sediments. The average annual rainfall in premonsoon season is 148.8 and 235.39 mm in postmonsoon. Materials and methods Surface sediment samples were collected from ten selected stations in two different seasons (post- and premonsoon of 2009), all along the length of the estuary, mouth and fresh water zone onboard a fishing trawler. Sediment samples were collected by using Van Veen grab. From the grab sampler, the upper 5-cm sediment was collected by using plastic spatula as a representative of surface sediment. Collected sediment samples were transferred to pre-cleaned polyethylene bags. The sediment samples were preserved in the deep freezer. Sieving technique is applied to separate the grains of various size classes (Ingram 1970). Initially 100 g of sample is prepared by treating with 10% dilute hydrochloric acid and 6% hydrogen peroxide, respective- ly. Sieving was carried out in ASTM sieve at one fourth intervals for about 20 min in a digital sieve shaker (Retsch AS 200). This basic data, i.e. weight percentage frequency data, are converted into cumulative weight percentage data, which served as basic tool for the generation of other statistical parameters using GSSTAT and SEDPLOT programs developed by USGS. The input for the sediment fractions (inclusive graphics, Folk 1974) is weight percentages in one half phi notation (Krumbein 1934; Inman 1952). The analysed data to generate the spatial distribution map using Arc GIS 9.3. Another part of the sample was used to determine organic matter using Loss on Ignition method (Watson et al. 1985). Clay mineral samples were analysed under air-dried conditions, under ethylene glycol-solvated conditions, and after enough heating, to collapse any expandable layers. The air-dried oriented clay slide was immediately analysed using an Fig. 1 Location map of the study area 1372 Arab J Geosci (2013) 6:13711380 Author's personal copy X-ray diffractometer. The clay slide was then exposed to ethylene glycol vapour in desiccators for 24 h and subsequently reanalysed. Another slide was treated by heating at 540 C for 3 h and 30 min and then analysed. The X-ray diffractometer used was a PANalytical XPert MRD equipped with a Co target operating at 30 kV/ 40 mA. The relative abundance of major clay minerals was semiquantitatively determined by peak area on d001 reflections, on ethylene glycol diffractograms. This method was adapted from (Holtzapffels 1985) and took ground noise into account (Dunoyer de Segonzac 1969). Test runs revealed an average error of 5%. Major clay minerals like kaolinite+chlorite, illite, montmorillonite and gibbsite were identified from the reflection peaks (Table 1). Results and discussion Spatial distribution of sand, silt, clay and organic matter Seasonal variations in sediment components and organic matter are detailed below. During postmonsoon, sand Fig. 2 Spatial distribution of sand (postmonsoon) Table 1 Distribution of sand, silt, clay and organic matter of the study area Station Postmonsoon Premonsoon Sand% Silt% Clay% Organic matter% Sand% Silt% Clay% Organic matter% S1 96.78 3.21 0.01 1.988 97.04 2.53 0.43 1.471 S2 72.02 24.77 3.21 1.795 59.92 39.83 0.25 1.067 S3 77.56 22.23 0.21 2.598 62.43 37.35 0.22 2.128 S4 68.76 26.92 4.32 3.334 66.03 33.74 0.23 2.566 S5 96.61 2.5 0.89 2.216 97.47 2.45 0.08 3.19 S6 98.21 1.34 0.45 1.876 98.38 1.08 0.54 2.761 S7 96.68 3.24 0.08 2.349 95.92 3.65 0.43 1.697 S8 95.23 4.54 0.23 1.362 94.45 4.32 1.23 1.119 S9 96.62 2.04 1.34 1.814 96.45 2.33 1.22 1.618 S10 97.34 2.62 0.04 1.221 96.71 3.21 0.08 1.412 Minimum 68.76 1.34 0.01 1.221 59.92 1.08 0.08 1.067 Maximum 98.21 26.92 4.32 3.334 98.38 39.83 1.23 3.19 Average 88.57 10.14 1.26 2.092 85.26 14.28 0.50 1.941 Arab J Geosci (2013) 6:13711380 1373 Author's personal copy content for the studied samples varies from 68.76% to 98.21%, whereas silt and clay content varies from 1.34% to 26.92% and 0.01% to 4.32%, respectively (Figs. 2, 3, 4, 5 and 6). Sand content shows decreasing trend from station 2 up to the station 4 and further upstream shows an increasing trend. Whereas silt and clay show an increasing trend up to stations 2, 3, 4 and 5 respectively, these decrease towards the upstream. This majority of the sediments are relatively coarse and represent bed load derived from the Cauvery River Basin. Due to selective deposition, the fine particle sediments are transported into the mouth bar area and the outer estuary, while the coarse sediments are deposited in the upper reaches of the estuary. So, this is may be due to the nonlinear sandmud mixing under complex hydrodynamic conditions. Organic matter in the same season varies from 1.22% to 3.33% which follows similar trend as that of the silt and clay. It is mainly controlled grain size patterns. The abundance of organic matter depicts that the sedi- ments are immature and appears to have been derived Fig. 4 Spatial distribution of clay (postmonsoon) Fig. 3 Spatial distribution of silt (postmonsoon) 1374 Arab J Geosci (2013) 6:13711380 Author's personal copy from marine sources (Evans and Tokar 2000; Dubrulle et al. 2007; Liu et al. 2009). In the case of premonsoon, sand, silt, clay and organic matter vary from 59.92% to 98.38%, 1.08% to 39.83%, 0.08% to 1.23% and 1.06% to 3.19%, respectively (Figs. 7, 8, 9 and 10). Sand content shows decreasing trend from station 1 up to the station 4 and further increases towards the upstream side. Silt shows an increasing trend up to the stations 14 with lower value at stations 510 showing a decreasing trend. In general, clay and organic matter show a decreasing trend from station 7 up to the station 10, and further downstream, they show an increasing trend till station 1 and then show an increasing trend towards the estuary. It indicates the tidal mixing of shallow near shore waters and different current speeds of near- and offshore surface waters. In general, sand is dominating in the freshwater region, i.e. up to the stations 510, whereas silt, clay and organic matter are mostly enriched in the estuary region. In the present study, highest organic matter contents were found in the silt and clay fraction. Sorption behaviour is known to differ the origin and composition of the organic material (Chen et al. 1995; Flemming et al. 1996). In contrast to the organic matter, decreases were observed continuously from the clay to the sand fraction. This similar Fig. 6 Spatial distribution of sand (premonsoon) Fig. 5 Spatial distribution of organic matter (postmonsoon) Arab J Geosci (2013) 6:13711380 1375 Author's personal copy kind of observation was made by Dessai and Nayak (2009) and Manning et al. (2010). Clay mineral distribution Clay minerals that are identified in this work are kaolinite+chlorite, montmorillonite, illite and gibbsite. There are no significant regional variations in the lithology or climate of the adjacent land mass and reported soil and estuarine clay mineralogy (Nair 1976; Varghese and Aiyer 1980) is markedly different from the clay minerals observed in the study area. The main clay minerals were chlorite and kaolinite, this peak indicating its dominance and abundance over other minerals. It should be noted here that geologically the Tirumalairajanar Estuary comprises of quaternary sedi- mentary formation of ferruginous laterite. In postmonsoon Fig. 8 Spatial distribution of clay (premonsoon) Fig. 7 Spatial distribution of silt (premonsoon) 1376 Arab J Geosci (2013) 6:13711380 Author's personal copy season (Fig. 11), kaolinite and chlorite peak were recorded in the stations (S1S10). There is no marked variation in the premonsoon season. More or less the same kind of result was observed in sediment sample. A montmorillonite show on smaller amount occurred in the both seasons, but lowest peak value observed at station S8. The variability of kaolinite +chlorite contents is very high in both seasons. That regional variability in river sediments is controlled by local and regional factors such as mixing of clay minerals from rivers by along-shore drift and currents; topography sediment type, especially grain size and urbanization of the coastal zone (Lim et al. 2006; Liu et al. 2007). Despite all these variables, it is clear from the nearly identical mean claymineral suites for the rivers that the primary source of clay minerals to the Tirumalairajanar rivers draining the adjacent region. Illite and gibbsite is the least abundant clay mineral in the sediments of the Tirumalairajanar River in both seasons. Illite concentration observed in mouth region may be attributed to the formation of this mineral from montemor- illonite. It is observed on illite by absorbing more potassium ions from saline waters (Mohan and Damodaran 1992; Liu et al. 2008). Gibbsite is most important product of silicate alteration in laterites and lateritic soils wherein strong leaching produces moderate dislocation and results in the formation of kaolinite. While intense leaching results in complete dislocation so that octahedral layer remains free eventually crystallising to gibbsite. It is generally accepted that most of the clay minerals in the Tirumalairajanar River principally originate from terrigenous matters. After the terrigenous clay minerals are discharged into the sea, transportation, diffusion and flocculation could be involved in the formation process. But the chemical character of the clay minerals would be kept with few changes (Riley and Chester 1976; Yang et al. 2004; Zhou et al. 2004), i.e. they would still take on the primary properties of the sources. However, in this study area, chemical or colloid chemical differentiation and mechanical sedimentary differentiation usually cause the zonation of clay minerals. Conclusions Based on this study, it can be concluded that the spatial distribution of the sand is deposited in the freshwater zone and silt and clay are transported to the estuary region by the ebb-dominated tidal flow and current in both seasons. However, intensive sediment exchange occurs in the inner estuary due to the sandsiltclay mixing, which is controlled by the bidirectional tidal flows. In both seasons, higher organic matter was found in the clay and silt fractions. The organic matter associated with different size fractions of the sediment in the Tirumalairajanar Estuary. The X-ray diffraction analysis of sediment samples from the different stations of Tirumalairajanar indicates the presence of kaolinite, chlorite, montmorillonite, ilite and gibbsite. During post- and premonsoon seasons, kaolinite and chlorite are the dominate clay minerals formed due to chemical weathering of the bed rocks. Higher contents of chlorite, kaolinite and montmorillonite in the estuary sediments are prostrated mainly from the contribution of Tirumalairajanar and Arasalar rivers via the Bay of Bengal. Fig. 9 Spatial distribution of organic matter (premonsoon) Arab J Geosci (2013) 6:13711380 1377 Author's personal copy Fig. 10 XRD diffractograms (postmonsoon) 1378 Arab J Geosci (2013) 6:13711380 Author's personal copy Fig. 11 XRD diffractograms (premonsoon) Arab J Geosci (2013) 6:13711380 1379 Author's personal copy Acknowledgements The authors acknowledge the valuable sugges- tions given by Abdullah M. 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