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[


FIITJEE INTERNAL TEST
PHASE I
BATCHES:
ANSWERS IIT MAINS
QP CODE: 120762.1

SR.
NO
PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE
1. A P110201 C C110202 C M110109
2. C P110403 B C110108 B M120509
3. A P110507 C C110706 B M110203
4. A P110320 D C110306 C M120508
5. B P110508 C C111202 D M110202
6. B P110409 D C110803 A M120701
7. A P110314 A C111003 A M120803
8. D P110405 C C111102 B M110606
9. D P110403 B C110103 C M111402
10. C P110310 C C110704 A M111308
11. C P110403 B C110305 D M111303
12. C P110401 C C111207 B M111402
13. B P110504 B C110903 B M111411
14. C P110403 C C111006 B M111403
15. D P110403 C C111101 C M111407
16. B P110320 B C110103 A M110701
17. C P110310 C C110702 A M110714
18. A P110405 A C110306 B M110718
19. C P110326 D C111206 C M110728
20 B P110502 B C110902 D M110712
21. A P110404 B C111006 D M110822
22. C P110415 B C110202 B M110802
23. C P110326 D C110107 A M110704
24. A P110320 B C110112 D M110820
25. C P110416 A C110703 A M110809
26. B P110404 C C111204 A M110821
27. B P110404 B C110808 B M110815
28. C P110325 C C111006 A M110702
29. C P110404 C C110304 B M110823
30. C P110318 B C110107 C
Answers & Solutions
Physics
1. A (Concept code: P110201)
1.
1 2
1 2
R R
R R
+
+

=
A
A



2. C (Concept code: P110403)
2.
1
2
T m(g a)
T m(g a)

=
+


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2
3. A (Concept code: P110507)
3. W =
0.2
3 12
0.1
F dx (5x 16x )dx 8.1 10

= + =



4. A (Concept code: P110320)

4.

r


3
45
r

r
is same in both cases.

5. B (Concept code: P110508)
5.
1
2
5gl v
v
4gl
=

6. B (Concept code: P110409)
6.
2 2 2
res
a a a 2a cos(180 ) = + +
=2a sin
2




(180 )

a
a
7. A (Concept code: P110314)
7. AB =
ucos60t
cos30


8. D (Concept code: P110405)
8. N
Q
=(60 +15) 10 =750 N.
N
R
=150 tan 53 =200 N

9. D (Concept code: P110403)
9.
o o
T w
sin120 sin120
=
10. C (Concept code: P110310)
10. ucos usin gt =

11. C (Concept code: P110403)
11.
2
tan
3
=


g

O
3
g
2

12. C (Concept code: P110401)
12. a g =

2 2
6 0 2 gS = +

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3
13. B (Concept code: P110504)
13. E
k
=
4
2
Pdt

=46J

14. C (Concept code: P110403)
14. 2Fsin mg =
T =F cos

F


F


15. D (Concept code: P110403)
15. >1

16. B (Concept code: P110320)
16. T a


=0
2 1
m m
a 2a =

17. C (Concept code: P110310)
17. tan =
2 2
2
V sin
tan 2g
2 V sin cos
g

=



18. A (Concept code: P110405)
18. If A is pushed with acceleration =g tan, the block B will be at rest wrt A and it has no
slipping tendency.

19. C (Concept code: P110326)
19. s =
2
1
gt
2
=
2
1
10 0.2 0.2m.
2
= Block haves contact will the floor.

20. B (Concept code: P110502)
20. Energy cost due to air friction =
2
1
1 (20) 1 10 18
2
=20J .

21. A (Concept code: P110404)
21. 4g T =
o
a T
4 & 2gsin30 2a
2 2
=
6a =2g

22. C (Concept code: P110415)
22. At y =a, x =2a,
dy
dx
=1 =45 a
f
=gcos 45 =
g
2
.

23. C (Concept code: P110326)
23. Dist. =
2
2 2
1
(10 2) g (2)
2

+




24. A (Concept code: P110320)
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4
24. tan =
V
1
V
=

25. C (Concept code: P110416)
25. V
1
cos
1
=V
2
cos
2


26. B (Concept code: P110404)
26. k 2 k3 =
k =
3
k
2


27. B (Concept code: P110404)
27. F
net
=
2 2
M a a 2ma + =

28. C (Concept code: P110325)
28. a =
Vdv
dx

dv a
dx v
= =constant.

29. C (Concept code: P110404)
29. W =m g
eff

30. C (Concept code: P110318)
30.
2
v
a
r
=
Chemistry

1. C (Concept Code: C110202)
1. ( )
4 10 3 4
2
P O 6MgO 2Mg PO +

2. B (Concept Code: C110108)
2.
( ) ( )
2 2 2 3
C 2s 2p e C 2s 2p

+
2p
3
is a half filled electronic configuration.

3. C (Concept Code: C110706)
3. All are isoelectronic anions. The ion with least number of protons, has the largest size.

4. D (Concept Code: C110306)
4.
( ) ( )
2 5 2 5
2
F 2s 2p F 2s 2p F +
z
2p
z
2p
z
2p
z
2p

5. C (Concept Code: C111202)
5. Let the pressure of the gas in the 9 L vessel be x atm.
P
1
V
1
=P
2
V
2
x 9 =(x +1) 6
x =2, The pressure in smaller vessel =2 +1 =3 atm.

6. D (Concept Code: C110803)

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5
7. A (Concept Code: C111003)
7. Atomic hydrogen is formed in the hydrogen torch by applying very high voltaget on
hydrogen molecules. The combination of these hydrogen atoms releases a large amount
of energy in forms of heat which is sufficient for welding purposes.

8. C (Concept Code: C111102)
8. Moles of HCl =
200 0.4
1000

=0.08
Moles of NaOH =0.08
Mass of NaOH =0.08 40 =3.2 g

9. B (Concept Code: C110103)
9. 2r =n
or,
2 r

=n

10. C (Concept Code: C110704)
10. The amount of energy required to remove one electron from a neutral gaseous atom is
called ionization energy.

11. B (Concept Code: C110305)
11. Species Bond angle

4
NH
+
109
o
28


2
NO
+
180
o

3
CH
+
120
o


4
PH
+
Less than 109
o
28

12. C (Concept Code: C111207)
12. Let mass of CH
4
=mass of He =x g
Moles of CH
4
=
x
16
and moles of He =
x
4

Mole fraction of CH
4
=
x
16
x x
16 4
1
5
+
=
Partial pressure of CH
4
=
1
5
800 =160 mm Hg

13. B (Concept Code: C110903)
13. ( )
3 2 2 3
2
Mg N 6H O 3Mg OH 2NH + +

14. C (Concept Code: C111006)
14. The octet of one oxygen atom is not satisfied in (C). Hence, it is the most unstable
structure.

15. C (Concept Code: C111101)
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6
15.
( )
4 2 7 2 3 2 2
2
NH Cr O Cr O 4H O N + +
12 +
gainof 6e 's

6 +
-6 0
loss of 6 electrons

n-factor =6 E =
M
6


16. B (Concept Code: C110103)
16. The ionization energy of H or H-like species is given as:

2
2
Z
I.E 13.6 eV
n

=




17. C (Concept Code: C110702)
17. Be and Al are diagonally related elements.

18. A (Concept Code: C110306)

19. D (Concept Code: C111206)

20. B (Concept Code: C110902)
20. Be
2+
(2s
0
2p
0
) makes four vacant orbitals available for coordination with H
2
O.

21. B (Concept Code: C111006)
21.
3 2
I I I

+

2 2 2 2
I H O H I H O
+
+ + +

22. B (Concept Code: C110202)
22. Mol. mass of Na
2
CO
3
.xH
2
O =(106 +18x)
Meq. of HCl in 20 mL solution =19.8 0.1 =1.98
Meq. of HCl in 100 mL solution =1.98 5 =9.9
Meq of Na
2
CO
3
.xH
2
O =Meq of HCl =9.9

( )
W
1000 9.9
E
0.7
1000 9.9
106 18x
2
=
=
+

On solving, x =2

23. D (Concept Code: C110107)
23. The orbitals with n + =5 are 5s, 4p and 3d which can contain maximum of 2, 6 and 10
electrons respectively.
Total no. of electrons =18

24. B (Concept Code: C110112)
24. Spin value =n
n =no. of unpaired electrons.
The number of unpaired electrons present in
2
O
+
, O
2
,
2
O

and
2
2
O

are respectively 1, 2, 1
and zero.
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7

25. A (Concept Code: C110703)
25.
( ) ( ) ( )
1 2
I.E I.E 1 6 o 2 5
Na 3s Na 2p 3s Na 2p
+ +

For I.E
2
the electron is removed from an ion which has inert gas configuration.

26. C (Concept Code: C111204)
26. Excluded volume per molecule of a real gas
=4 molecular volume =4
3
4
r
3
=
3
16
r
3


27. B (Concept Code: C110808)
27. NaOH CO HCOONa +

28. C (Concept Code: C111006)
28.
2 2 4 2
PbS 4H O PbSO 4H O + +

29. C (Concept Code: C110304)
29. XeF
4
has square planar(symmetrical) structure.

30. B (Concept Code: C110107)
30. Zn(Z =30) =1s
2
2s
2
2p
6
3s
2
3p
6
4s
2
3d
10

No. of electrons with =1 is 12.
Mathematics
1. The solution of
( ) ( ) ( )
3
x 1 x 2 x 4
0
x 2

is
[ ] { } x 1,4 2 . Hence, the integral solutions
are { } x 1,3,4 .

2.
( )
dy
dy asint sint 1 cost 1 cost
dt
dx
dx a 1 cost 1 cost 1 cost sint
dt
+ +
= = = =
+


3.
( )
( ) ( )
2 2
log 2 2 log x 1
2 x 5 x 1 x 5 x 1 x 5

> + > + > +



2
x 3x 4 0 x 1 > < or x 4 >
Also, x 1 0 > for log to be defined. Hence, x 4 > .

4.
( ) ( ) ( ) ( )
( )
( ) ( ) ( ) ( )
( )
2
2
2
2
2 2
2
2
1 t 2 2t 2t
dy
1 t
dy 1 t x
dt
dx
dx 2t y 1 t 2t 1 t 2t
dt
1 t
+
+

= = = =
+
+


5.
4 2 2 3
1
ab log 6 2ab log 6 log 3 1 log 2
2ab 1
= = = + =



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8
6.
( )
7
8
7
dx dx
1
x x 1
x 1
x
=
+
+




Put
7
1
1 t
x
+ = .

7.
( )
2 2
/3 /3 /3
2 2
2 2 2 2
/4 /4 /4
1 sin x cos x
dx dx sec x cosec x dx
sin xcos x sin xcos x


+
= = +


( ) ( )
/3
/4
1 2
tanx cotx 3 1 1
3 3


= = =




8.
4 2
3
x x x
3 3
1
sin
1
x
1 1 1 1
x
x sin x xsin
1 0
x x x x
lim lim lim 1
1 1
0 1 1 x
1 1
x x

+
+ +
+
= = = =
+ +
+ +


9.
A
tan6 tan42 tan66 tan78
B
=

( ) ( ) ( ) ( ) tan6 tan 60 6 tan 60 6 tan18 tan 60 18 tan 60 18
tan54 tan18
+ +
=



( ) ( ) tan 3 6 tan 3 18
1
tan54 tan18

= =



10. ( ) 1 cosx 1 sin1 sin cosx sin1

11. ( ) ( )
2
2 2 2cos4 2 2 2cos 2 2 2 cos2 2 2cos2 + + = + = + =
( ) ( )
2
2 2sin 2 sin 2sin = = =

12.
3cos20 sin20 2sin60 cos20 sin20
3cosec20 sec20
1
sin20 cos20
sin40
2

= =




( ) ( ) ( ) 2 sin80 sin40 sin20 2 2sin30 cos50 sin40 2 sin40 sin40
4
sin40 sin40 sin40
+ + +
= = = =



13. ( )
2
2
12sin 9sin 4 3sin 2 =

14. ( )
3 1 1 2 2
cos 0.2
2 3 2 3
+ =

15. ( ) ( )
3
sin x.sin3x
3sinx sin3x 3 1
.sin3x cos2x cos4x 1 cos6x
4 8 8
=

=

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9
16.
5
x
4m 3
=
+

There is no positive integral value of m for which the value of x is an integer.

17. The smallest value of
2 2
+ is the square of the perpendicular distance of the origin from
the line.

18. Equation of PQ is ( ) ( ) y 1 1 x 4 = or
x y 5 + = .
The point Q is
5 15
,
4 4



.

2 2
5 15 11 2
PQ 4 1
4 4 4

= + =




Q
y =3x
P (4, 1)

19. After reflection about the line y x = , point
P becomes Q ( ) 1,4 .
After translation through a distance of 2
units, point Q becomes R ( ) 3,4 .
OR OR' 5 = =

4
tan
3
=
The point R is given by
( ) ( ) ( )
5cos 45 ,5sin 45 + +
( ) ( )
5 5
cos sin , cos sin
2 2

= +


,
where
4
sin
5
= and
3
cos
5
= .

R'
y
R (3, 4)

O
x
45
o


20. Let P
( )
,2 be any point on the curve. Equation of normal at P is given by
( ) y 2 x = . It passes through the point ( ) 21,30 . Hence,
( )
3
19 30 0 = . Solving, we get 5 = .

21. ( ) ( )
1 2 1 2
C 3,7 , C 3,0 , r 10, r 3 = =

1 2 1 2
C C 7 r r = > +
Hence, 4 common tangents.

22. The required circle is the one having (2, 0) and (0, 4) as the end-points of a diameter.

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10
23. Use the formula
1 2 3 1 2 3
ax bx cx ay by cy
,
a b c a b c
+ + + +

+ + + +

for the
incentre.

C(1, 1)
y
B (1, 1)
A(0, 0)
y =1
y=x y=x
x

24. ( )
2
C 0,0 . Equation of AB is given by
1 2
S S 0 = , i.e. x y 4 + = .

2
2 2
0 0 4
C P 2 2
1 1
+
= =
+


2 2 1
cos 2
4 4 2
2

= = = =

C1
A
B
C2
P


25. Let P ( ) h,4 2h be any point on the line 2x y 4 + = . The chord of contact is given by
( ) hx 4 2h y 1 + = or ( ) ( ) h x 2y 4y 1 0 + = . This represents a family of lines passing
through the point of intersection of the lines x 2y 0 = and 4y 1 0 = , which is
1 1
,
2 4



.

26. Let the equation of the required circle be
2 2
x y 2gx 2fy c 0 + + + + = . According to the given
conditions, we have

2 2
a b 2ga 2fb c 0 + + + + = and ( ) ( )
2 2
2g 0 2f 0 c p c p + = =
Hence,
2 2 2
a b 2ga 2fb p 0 + + + + = . Replace g by x and f by y to get the equation of
the locus of the center.

27. The center of the second circle lies on the common chord of the two circles.

28. Solve graphically.

29.
( )
2
2 2 2
n
AB 4AM 4 4 2 8 n
2

= = =



Hence, required sum
( ) ( )
2 2
2 8 1 2 8 2 14 8 22 = + = + = .


B
M
A
C
30. ( ) p q

p q ~q
p ~q ~q p p ~q
( ) p q
T T F F T F T
T F T T T T F
F T F T T T F
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11
F F T T F F T

p Q p q q p p q
T T T T T
T F F T F
F T T F F
F F T T T

QP CODE: 120762.2

SR.
NO
PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE
1. C P110403 B C110305 D M111303
2. C P110401 C C111207 B M111402
3. B P110504 B C110903 B M111411
4. C P110403 C C111006 B M111403
5. D P110403 C C111101 C M111407
6. B P110320 B C110103 A M110701
7. C P110310 C C110702 A M110714
8. A P110405 A C110306 B M110718
9. C P110326 D C111206 C M110728
10. B P110502 B C110902 D M110712
11. A P110404 B C111006 D M110822
12. C P110415 B C110202 B M110802
13. C P110326 D C110107 A M110704
14. A P110320 B C110112 D M110820
15. C P110416 A C110703 A M110809
16. B P110404 C C111204 A M110821
17. B P110404 B C110808 B M110815
18. C P110325 C C111006 A M110702
19. C P110404 C C110304 B M110823
20 C P110318 B C110107 C
-
21. A P110201 C C110202 C M110109
22. C P110403 B C110108 B M120509
23. A P110507 C C110706 B M110203
24. A P110320 D C110306 C M120508
25. B P110508 C C111202 D M110202
26. B P110409 D C110803 A M120701
27. A P110314 A C111003 A M120803
28. D P110405 C C111102 B M110606
29. D P110403 B C110103 C M111402
30. C P110310 C C110704 A M111308

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12
QP CODE: 120762.3

SR.
NO
PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE
1. A P110404 B C111006 D M110822
2. C P110415 B C110202 B M110802
3. C P110326 D C110107 A M110704
4. A P110320 B C110112 D M110820
5. C P110416 A C110703 A M110809
6. B P110404 C C111204 A M110821
7. B P110404 B C110808 B M110815
8. C P110325 C C111006 A M110702
9. C P110404 C C110304 B M110823
10. C P110318 B C110107 C
-
11. A P110201 C C110202 C M110109
12. C P110403 B C110108 B M120509
13. A P110507 C C110706 B M110203
14. A P110320 D C110306 C M120508
15. B P110508 C C111202 D M110202
16. B P110409 D C110803 A M120701
17. A P110314 A C111003 A M120803
18. D P110405 C C111102 B M110606
19. D P110403 B C110103 C M111402
20 C P110310 C C110704 A M111308
21. C P110403 B C110305 D M111303
22. C P110401 C C111207 B M111402
23. B P110504 B C110903 B M111411
24. C P110403 C C111006 B M111403
25. D P110403 C C111101 C M111407
26. B P110320 B C110103 A M110701
27. C P110310 C C110702 A M110714
28. A P110405 A C110306 B M110718
29. C P110326 D C111206 C M110728
30. B P110502 B C110902 D M110712

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13
QP CODE: 120762.4

SR.
NO
PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE
1. B P110404 C C111204 A M110821
2. B P110404 B C110808 B M110815
3. C P110325 C C111006 A M110702
4. C P110404 C C110304 B M110823
5. C P110318 B C110107 C
-
6. A P110201 C C110202 C M110109
7. C P110403 B C110108 B M120509
8. A P110507 C C110706 B M110203
9. A P110320 D C110306 C M120508
10. B P110508 C C111202 D M110202
11. B P110320 D C110803 A M120701
12. C P110310 A C111003 A M120803
13. A P110405 C C111102 B M110606
14. C P110326 B C110103 C M111402
15. B P110502 C C110704 A M111308
16. C P110403 B C110305 D M111303
17. C P110401 C C111207 B M111402
18. B P110504 B C110903 B M111411
19. C P110403 C C111006 B M111403
20 D P110403 C C111101 C M111407
21. A P110404 B C110103 A M110701
22. C P110415 C C110702 A M110714
23. C P110326 A C110306 B M110718
24. A P110320 D C111206 C M110728
25. C P110416 B C110902 D M110712
26. B P110409 B C111006 D M110822
27. A P110314 B C110202 B M110802
28. D P110405 D C110107 A M110704
29. D P110403 B C110112 D M110820
30. C P110310 A C110703 A M110809

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14
FIITJEE INTERNAL TEST
Batches: Two Year CRP(1416)
IIT JEE 2016
PHASE I
PAPER I
ANSWERS
QP CODE: 120763.1
SECTION I (PHYSICS) SECTION II (CHEMISTRY) SECTION III (MATHS)
PART A PART A PART A
Q.N. Ans. Con.Code Q.N. Ans. Con.Code Q.N. Ans. Con.Code
1. C P110320 1. C C110111 1. B M111305
2. D P110320 2. C C110207 2. D M111304
3. B P110404 3. A C110304 3. B M110722
4. B P110414 4. B C110704,
C110703
4. A M110730
5. D P110414 5. C C111102 5. D M110731
6. B P110507 6. C C111203 6. C M110710
7. B P110507 7. C C110809 7. C M110712
8. C P110507 8. B C111003 8. B M110708
9. C P110513 9. C C110103 9. A M110723
10. D P110320 10. B C110305 10. B M110202
11. BC P110404 11. AC C110808,
C110908
11. AB M110801
12. AB P110413 12. BD C110103 12. A BCD M110802
13. CD P110502 13. AB C110307 13. ABCD M110715
14. BC P110404 14. ACD C111101 14. BCD M111402
15. ABCD P110404 15. ABCD C110703 15. ACD M110723
PART C PART C PART C
1. 4 P110316 1. 8 C110112 1. 1 M111411
2. 8 P110507 2. 8 C110305 2. 5 M110811
3. 4 P110204 3. 4 C111208 3. 9 M110813
4. 2 P110502 4. 5 C110802,
C110902
4. 8 M110710
5. 5 P110513 5. 5 C111102 5. 1 M110707
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15
Answers & Solutions
Physics
Part A
1. C (Concept code: P110320)
1.
pk
V

=
1 1

V sin i V cos j

pk, p 2

V V j =



p pk pk,p 1 2 1

V V V V sin i (V V cos )j = = +



But
2 1
V V cos 0 = cos =
2
1
V
V


p 1

V V sin i, =


2 2
p 1 2
V V V =



V
2

V1



2. D (Concept code: P110320)
2. y =u
y
t +
2
y
1
a t
2

2
1
y ut gt
2
= (1)

dy
(u gt)
dt
= (2)
From eq. (2), slope dy/dt first decrease and then it will increase in (ve) direction. So, (D)
option is correct.

3. B (Concept code: P110404)
3. F =N
1
+f
1
=N
1
+m
1
g (1)
N
1
=N
2
+f
2
=N
2
+m
2
g (2)
N
2
=f
3
=m
3
g (3)
N
1
=(m
2
+m
3
)g
m3
F
m2
m1 N2
f3
N1
f2
f1
N1


4. B (Concept code: P110414)
4. T
1
=T
2
+m
1
R
1
w
2
(1)
T
2
=m
2
R
2
w
2
(2)

2
1 1 1 2 2
2
2 2 2
T (mR mR )w 9
T 8 mR w
+
= =
m1 T1
m1R1w
2
T2 M2 T2 m2R2w
2


5. D (Concept code: P110414)
5. Mv
2
/l =T mgcos
T =mv
2
/l +mgcos
At lowest point
cos =1 =0
v =u
T
L
=mu
2
/l +mg

l


l

mgsin
T
V
mgsin
mg
u


6. B (Concept code: P110507)
6. Force is conservative and displacement zero so work done is zero.

7. B (Concept code: P110507)
7. For a varying force, we must integrate: W F dr =


=
3m
y
0
F dy

=(2N/m
3
)
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16

3m
3m
3 3 4
0 0
1 81
y dy (2N/ m ) y N m 40.5J
4 2

= = =



8. C (Concept code: P110507)
8. At the highest elevation v
y
vanishes, since the cannon ball has been going upward and has
stopped its vertical motion as it is about to start downward. V
x
is constant during the motion,
so
At highest point E
k
=
2 2
x
1 1
m| v| mu
2 2
=


So work done by gravity =
2
y
1
mu
2


9. C (Concept code: P110513)
9. Elongation in the spring =
Mg
k

And mgx =
2
1
kx
2


10. D (Concept code: P110320)
10.
2 1 2 2
V t V t
1
V Vt V V t

+ =
1 2
1 2
2v v
v
v v
=
+


11. BC (Concept code: P110404)
11. F T =10 a (1)
T =10 a (2)
F =20a a =1
T =10 N, a
a
=a
b
=1, a
c
=0

b T
c
T
a F T
T
T
T


12. AB (Concept code: P110413)
12. a v

a v



13. CD (Concept code: P110502)
13. Work energy theorem

14. BC (Concept code: P110404)
14. N =W F cos N <W
F sin =f
k
<90, sin <1
F >f
k

N
W
f
k
N
W
Fsin
f
k
Fcos
F

15. ABCD (Concept code: P110404)


15. Incline may accelerate in any direction.

Part C

1. 4 (Concept code: P110316)
1. At maximum height R =
2 2
0
u cos
g


Maximum height of projectile H =
2 2
0
u sin
2g


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Given: R =2H

2 2 2 2
u cos u sin
2
g 2g

=


tan =1 =45.

2. 8 (Concept code: P110507)
2. a
BR
=1/2 =0.5 m/s
2

V
BR
=0 +0.5 2 =1 m/s
V
RG
=2m/s
V
BG
=v
BR
+v
RG
=2 +1 =3m/s
K
Q
=
2
1
2 (3)
2
=9 J
K
p
=
2
1
2 (1)
2
=1 J
K
Q
K
P
=9 1 =8 J

3. 4 (Concept code: P110204)
3.
( ) ( )
1

Area 3i j k i j k
2
= + +

4. 2 (Concept code: P110502)
4. Work energy theorem
W
G
+W
F
=k
mgd +
2
1
F d mv
2
=
5 10 0.2 +100 0.2 =
2
1
5 v
2

On solving, we get v =2 m/s

5. 5 (Concept code: P110513)
5. Conservation of mechanical energy
mgH =mgh +
2
1
mv
2

0.45 mg =3mg
2
R 1
mv
2 2
+
9 30R =v
2
(i)
AC =
R 3
2

For reaching at B let particle takes t sec.

v R 3
t
2 2
= (ii)

2
v 3 1 R
t g t
2 2 2
= (iii)

60
A
B
R/2
C
60
V

On solving, v
2
=15R by eq. (i)
9 30R =15R R =
9
100
45
=20 cm
=1/5 meter.

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Chemistry
Part A
1. C (Concept Code: C110111)
1. (i) The energy difference between 4s and 3d subshells is the lowest in comparison to
other given subshell.
(ii) Due to maximum exchange energy associated with 3d
5
in comparison to np
3
.

2. C (Concept Code: C110207)
2. H
3
BO
3
is a monobasic acid
( )
3 3 2
4
H BO H O B OH H

+
+ +



3. A (Concept Code: C110304)
3. In OF
2
, the bond pair moments are cancelled by the lone pair moments. In other case
both type of moments are reinforced with each other.
O
F F


4. B (Concept Code: C110704, C110703)
4. The first electron gain enthalpy of N is positive and that of oxygen is negative. The
second electron affinity of sulphur is endothermic and the I.E
1
of Na is also endothermic.

5. C (Concept Code: C111102)
5. The balanced equation is:

2 2
4 2 4 2 2
2MnO 5C O 16H 2Mn 10CO 8H O
+ +
+ + + +

6. C (Concept Code: C111203)
6. The variation of Z with P at Boyle temperature is given as:

Z

P
1

7. C (Concept Code: C110809)
7.
2 3 2 2
2NaOH 2NO NaNO NaNO H O + + +

8. B (Concept Code: C111003)
8.
2 2
MO H M H O + +
Ca is more electropositive than hydrogen. Hence it is not reduced by it.

9. C (Concept Code: C110103)
9. Orbital angular momentum = ( )
h
1
2
+


=Azimuthal quantum number
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The values of for the electrons given in (A), (B), (C) and (D) are respectively 0, 1, 2 and
0.

10. B (Concept Code: C110305)
10. Species Hybridization

2
ICl
+
sp
3


2
ICl

sp
3
d

2
3
SO

sp
3


2
NH

sp
3

XeF
2
sp
3
d
BeF
2
sp

2
3
CO

sp
2

11. AC (Concept Code: C110808, C110908)
11. ( )
3 3 2 2
2
Ca HCO CaCO CO H O

+ +

2 3
3 2 2
Na CO No decomposition product
2NaNO 2NaNO O

+


2
KNO No decomposition product



12. BD (Concept Code: C110103)
12.
34 8
9 19
hc 6.6 10 3 10
E 4.16eV
300 10 1.6 10



= = =


Metals having work function less than 4.16 eV will show photoelectric effect.

13. AB (Concept Code: C110307)
13. BF
3
Due to p- p back bonding

2
3
CO

Due to -bond formation

14. ACD (Concept Code: C111101)
15. ABCD (Concept Code: C110703)
Part C
1. 8 (Concept Code: C110112)
1. The atoms are Li, Fe, Al, Cl, Ni, Ti, S and P.

2. 8 (Concept Code: C110305)
2. The compounds are SO
2
, SO
3
. SF
4
, PF
5
, XeF
2
, POCl
3
, ClF
3
and IF
7


3. 4 (Concept Code: C111208)
3.
2 2 4
4 4 2
SO SO CH
CH CH SO
r n M
2 16 2 1 2 1 1
r n M 3 64 3 4 3 2 3
= = = = =

x 1
y 3
= and x +y =3 +1 =4

4. 5 (Concept Code: C110802, C110902)
4. The required substances are KO
2
, Ca
3
N
2
, Mg
2
C
3
, CaH
2
, Ca
3
P
2
.

5. 5 (Concept Code: C111102)
5. Meq. of
4
MnO

=Meq of metal
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300 0.4 =
W W W
1000 1000 n 1000
E M/ n M
= =
or, 300 0.4 =mole n 1000 =0.04 n 1000
n =3
Let the oxidation number of the metal ion after oxidation is +x
x 2 =3
or x =5

Mathematics
Part A
1. B M111305
1. cos cos sin sin + = +
On squaring,
2 2
cos cos 2cos cos + +
2 2
sin sin 2sin sin = + +
( ) cos2 cos2 2cos + = +

2. D M111304
2. 2cos sin 1 + =

( )
( )
( )
( )
2
2 2
2 1 tan / 2
2tan / 2
1
1 tan / 2 1 tan / 2


+ =
+ +


1
tan / 2 1, tan / 2
3
= =

7cos 6sin + =6 ,2

3. B M110722
3. ( ) ( )
2 2
3x 8xy 3y 3x y x 3y + = + and
2 2
3x 8xy 3y 2x 4y 1 + + ( ) ( ) 3x y 1 x 3y 1 = + +
The first pair intersects at (0, 0) and the second pair intersects as
1 2
,
5 5




Equation of one diagonal is y =2x
Slope of second diagonal is
1
2
and it will pass through
1 1
,
10 5




So equation of second diagonal is 2x 4y 1 =

4. A M110730
4. Let m and m
2
be the slopes of the lines. Then
2 3
2h a
m m , m
b b

+ = =
We have

( ) ( )
3
2 3 6 3 2
m m m m 3m m m + = + + +

3 2
3 2 2
8h a a 6ha
b b b b

= +
( )
2
a b
8h
6
h ab
+
+ =

5. D M110731
5. Let lines make and with x axis
Then
1 2
tan m, tan m = =
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1 2 2
2h 2tan 2
m m
b sin cos sin

+ = = =



2 2
1 2 2
a tan cos
mm
b sin
+
= =


( ) ( ) ( )
2 2 2
1 2 1 2 1 2
tan tan m m m m 4mm = = +

2 4
2 2
4
1 sin cos
sin cos



( )
( )
2 2
2 2
4 sin cos
4
sin cos

= =


tan tan 2 =

6. C M110710
6. Angle made by the lines with the x axis in the positive directions are
( )
o
1
90 + and
( )
o
2
90 + respectively.
Angle between the lines
( ) ( )
o o
1 2
90 90 = + + or
( ) ( )
o o
2 1
90 90 + +

1 2
= or
2 1


7. C M110712
7. Let
1
BC L 11x 6y 14 0 = + + =

2
CA L 9x y 12 0 = + =

3
AB L 2x 5y 17 0 = + =
Solving the equation, the vertices are obtained as
( ) ( ) A 1, 3 ,B 4,5 and ( ) C 2, 6
( )
1
L A 11 1 6 3 14 0 = + + >
( )
2
L C 2 2 5 6 17 0 = + <
A
P (k, k
2
)
B C

Since P and A are to lie on the same side of BC,
2
11k 6k 14 0, + + > .(I)
Since P and B are to lie on the same of CA,
2
9k k 12 0 + < ------(II)
Since P and C are to lie on the same side of AB, 2k +5k
2
17 <0 (III)
From (I), (II), (III) we see that k should satisfy the inequality

1 86 9 129
k
5 2
+
< <
Number of integer values of k =3

8. B M110708
8.


B
C
A (1, 0)
x +2y =1
x =0
0, 1/2
x 2y =1
0, 1/2

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Required area ( ) ( )
1
BC OA
2

=


( ) ( )
1 1
1 1
2 2
= =

9. A M110723
9. ( ) ( ) ( ) sin sin sin 2sin sin + = +

2 2 2
sin sin 2sin sin sin = +
( )
2
2
sin sin sin 0 =
( ) ( ) sin sin sin sin sin sin 0 + + =
Since 0 , , < <
Since, 0 <, sin , sin >0
sin sin sin 0 + +
so, sin sin sin 0 =
or, ( ) 1 sin 1. sin sin 0 + + =
Hence ( ) xsin ysin sin 0 passes through 1, 1 + + =

10. B M110202

11. AB M110801
11. Let P (x, y) be any point of the circle on the chord joining A (1, 2) and B (2, 1)
The slope of
y 2
AP
x 1

and slope of
y 1
BP
x 2
+
=


Since they include an angle of
4

so,

y 1 y 2
x 2 x 1
tan 1
y 2 y 1
4
1
x 1 x 2
+



= =
+
+


( ) ( ) ( ) ( ) y 1 x 1 x 2 y 2 + ( ) ( ) ( ) ( ) x 1 x 2 y 2 y 1 = + +



2 2
x y 5 0 + = or
2 2
x y 6x 2y 5 0 + + =

12. A BCD M110802
12. Let slope of OA is m,
Then
o
m 1
tan45
1 m

=
+


m 1
1
1 m

=
+


m=0 or undefined
Solving y =3 and
2 2
x y 10x 6y 30 0 + + =

C
B
(5, 3)
D
A
2
2
y =x +
m
O
45
o

Two vertices are (3, 3) and (7, 3)
other diagonal is by solving x =5 and
2 2
x y 10x 6y 30 0 + + =
Other two vertices are (5, 1) and (5, 5)

13. ABCD M110715
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13. Equation of any line through P (3, 4) making an angle with the positive direction of x
axis is
x 3 y 4
r
cos sin

= =

(i)
where r is the distance of any point on the line from P.
Therefore, coordinates of any point on the line (i) are ( ) 3 rcos , 4 rsin + + ..(ii)
If Eq. (ii) represents R, then

3
3 rcos 6 r PR
cos
+ = = =


If Eq. (ii) represents S, the 4 rsin 8 + =
r 4/ sin PS = =
Hence, PR 3sec , PS 4cosec = =

( ) 2 3sin 4cos
3sin 4cos
PR PS
sin cos sin2
+
+
+ = =


and ( ) ( )
2 2
2 2
3/ PR 4/ PS cos sin 1 + = + =

( )
( )
2
9 16
1
PS
PR
+ =

14. BCD M111402
14. We have,
1 sin 1 cos
x , y
cos sin
+
= =


Multiplying, we get
( ) ( ) 1 sin 1 cos
xy
cos sin
+
=



1 sin cos sin cos sin cos
xy 1
cos sin
+ +
+ =



1 sin cos
cos sin
+
=


and
( ) ( ) 1 sin sin cos 1 cos
x y
cos sin
+
=



2 2
sin sin cos cos
cos sin

=


( )
sin cos 1
xy 1
cos sin

= = +


Thus, xy x y 1 0 + + =

y 1
x
y 1

=
+
and
1 x
y
1 x
+
=



15. ACD M110723
15. Reflected ray is a line which passes through the inter section of the lines 3x y 8 0 + =
and 2x 7y 8 0 + = is ( ) 3x y 7 2x 7y 8 0 + + + =
( ) ( ) ( ) ( ) 2 3 x 7 1 y 8 9 0 1 + + + + =
Slope of the line (1) is
( )
( )
2 3
7 1
+
+

Slope of 3x y 9 0 + = is 3
Slope of 2x 7y 8 0 + = is
2
0
7


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24
If is the angle between the above lines ,
2
3
19
7
tan
6
13
1
7
+

= =
+
19
13
=
For the reflected ray,
( )
( )
2 3 2
19 7 1 7
2 2 3 13
1
7 7 1
+
+

+

=
+
+
+
26
0,
53

=
Hence the reflected ray corresponds to
26
53


Equation of the reflected ray is 107x 129y 269 0 =
Solving 3x y 9 0 + = and 2x 7y 8 0 + = ,We get the point P as
55 6
,
19 19





Part C
1. 1 M111411
1. On adding ( )
2 3 cos4 4sin2
a 1 sin2
2
+
= = +
On subtracting ( )
2
4
b 1 sin2 ab cos 2 1 = =

2. 5 M110811
2. Equation of chord of contact (QR) is
2
6x 8y r 0 + =

( )
2 2
2 2
6.6 8.8 r 100 r
PM
10
6 8
+
= =
+

and
( )
2
2
2 2
0 0 r
r
OM
10
6 8
+
= =
+

Then ( ) ( )
{ }
2 2
QR 2.QM 2 OQ OM = =

4
2
r
2 r
100

=



Area of QPR =
1
2
. QR. PM
( )
2
4
2
100 r
1 r
say .2 r .
2 100 10


=




( )
( )
3
2 2
2
r 100 r
z say
1000

= =

( ) ( ) ( )
{ }
2 3
2 2 2
dz 1
r .3 100 r . 2r 100 r .2r
dr 1000
= +

( )
{ }
2
2
2 2
2r 100 r
100 r 3r
1000

=
For maximum or minimum
dz
0,
dr
= then we get
P(6, 8)
(0, 0)
Q
R
O
r
r
M
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[


25
( ) r 5 r 10 as P is outside the circle =
and
2
2
r 5
d z
ve
dr
=
=
Area of triangle is also maximum at r =5

3. 9 M110813
3. The given circle
2 2
1
S x y 14x 4y 28 0 = + + + =
and
2 2
2
S x y 14x 4y 28 0 = + + =
Centres and radii of circles
1
S and
2
S are
( )
1 1
C 7, 2 , r 49 4 28 5 = + =
and ( )
2 2
C 7, 2 , r 49 4 28 = + +
=9 respectively
Here ( ) ( )
2 2
1 2
d C C 7 7 2 2 = = + +

1 2
212 r r 5 9 14 = > + = + =

1 2
d r r > +
Hence circles dont touch or cut.
Length of external common tangent
( )
2
2
ex 2 1
L d r r =
( )
2
212 5 9 212 196 = + =
16 4 = = =
18 + =

4. 8 M110710
4. Let be the acute angle between AD and BE.
Then
2 1 1
tan
1 2 3

= =
+

Now
o o o
180 90 360 + + + =

o
90 = +
( ) tan tan = +

2 2
2b 2a
tan tan 2b 2a
a b
3
2b 2a 1 tan tan 3ab
1 .
a b
+
+ +
= = =


2
9ab 2c =



E
A A
C B
c
D a/2 a/2


5. 1 M110707
5. ( )
1
ax bz cy area of ABC
2
+ + =
( )
2
a 3
2014 a
2 4
=

3
2
a=length of altitude=2014

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QP CODE: 120763.2
SECTION I (PHYSICS) SECTION II (CHEMISTRY) SECTION III (MATHS)
PART A PART A PART A
Q.N. Ans. Con.Code Q.N. Ans. Con.Code Q.N. Ans. Con.Code
1. B P110404 1. A C110304 1. B M110722
2. B P110414 2. B
C110704,
C110703
2. A M110730
3. D P110414 3. C C111102 3. D M110731
4. B P110507 4. C C111203 4. C M110710
5. B P110507 5. C C110809 5. C M110712
6. C P110507 6. B C111003 6. B M110708
7. C P110513 7. C C110103 7. A M110723
8. D P110320 8. B C110305 8. B M110202
9. C P110320 9. C C110111 9. B M111305
10. D P110320 10. C C110207 10. D M111304
11. CD P110502 11. AB C110307 11. ABCD M110715
12. BC P110404 12. ACD C111101 12. BCD M111402
13. ABCD P110404 13. ABCD C110703 13. ACD M110723
14. BC P110404 14. AC
C110808,
C110908
14. AB M110801
15. AB P110413 15. BD C110103 15. ABCD M110802
PART C PART C PART C
1. 4 P110204 1. 4 C111208 1. 9 M110813
2. 2 P110502 2. 5
C110802,
C110902
2. 8 M110710
3. 5 P110513 3. 5 C111102 3. 1 M110707
4. 4 P110316 4. 8 C110112 4. 1 M111411
5. 8 P110507 5. 8 C110305 5. 5 M110811

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QP CODE: 120763.3
SECTION I (PHYSICS) SECTION II (CHEMISTRY) SECTION III (MATHS)
PART A PART A PART A
Q.N. Ans. Con.Code
Q.
N.
Ans. Con.Code Q.N. Ans. Con.Code
1. B P110507 1. C C111203 1. C M110710
2. B P110507 2. C C110809 2. C M110712
3. C P110507 3. B C111003 3. B M110708
4. C P110513 4. C C110103 4. A M110723
5. D P110320 5. B C110305 5. B M110202
6. C P110320 6. C C110111 6. B M111305
7. D P110320 7. C C110207 7. D M111304
8. B P110404 8. A C110304 8. B M110722
9. B P110414 9. B
C110704,
C110703
9. A M110730
10. D P110414 10. C C111102 10. D M110731
11. ABCD P110404 11. ABCD C110703 11. ACD M110723
12. BC P110404 12. AC
C110808,
C110908
12. AB M110801
13. AB P110413 13. BD C110103 13. ABCD M110802
14. CD P110502 14. AB C110307 14. ABCD M110715
15. BC P110404 15. ACD C111101 15. BCD M111402
PART C PART C PART C
1. 5 P110513 1. 5 C111102 1. 1 M110707
2. 4 P110316 2. 8 C110112 2. 1 M111411
3. 8 P110507 3. 8 C110305 3. 5 M110811
4. 4 P110204 4. 4 C111208 4. 9 M110813
5. 2 P110502 5. 5
C110802,
C110902
5. 8 M110710

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QP CODE: 120763.4
SECTION I (PHYSICS) SECTION II (CHEMISTRY) SECTION III (MATHS)
PART A PART A PART A
Q.N. Ans. Con.Code Q.N. Ans. Con.Code Q.N. Ans. Con.Code
1. C P110513 1. C C110103 1. A M110723
2. D P110320 2. B C110305 2. B M110202
3. C P110320 3. C C110111 3. B M111305
4. D P110320 4. C C110207 4. D M111304
5. B P110404 5. A C110304 5. B M110722
6. B P110414 6. B
C110704,
C110703
6. A M110730
7. D P110414 7. C C111102 7. D M110731
8. B P110507 8. C C111203 8. C M110710
9. B P110507 9. C C110809 9. C M110712
10. C P110507 10. B C111003 10. B M110708
11. AB P110413 11. BD C110103 11. ABCD M110802
12. CD P110502 12. AB C110307 12. ABCD M110715
13. BC P110404 13. ACD C111101 13. BCD M111402
14. ABCD P110404 14. ABCD C110703 14. ACD M110723
15. BC P110404 15. AC
C110808,
C110908
15. AB M110801
PART C PART C PART C
1. 8 P110507 1. 8 C110305 1. 5 M110811
2. 4 P110204 2. 4 C111208 2. 9 M110813
3. 2 P110502 3. 5
C110802,
C110902
3. 8 M110710
4. 5 P110513 4. 5 C111102 4. 1 M110707
5. 4 P110316 5. 8 C110112 5. 1 M111411

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FIITJEE INTERNAL TEST
Batches: Two Year CRP(1416)
IIT JEE 2016
PHASE I
PAPER II
ANSWERS
QP CODE: CODE: 120764.1
SECTION I (PHYSICS) SECTION II (CHEMISTRY) SECTION III (MATHS)
PART A PART A PART A
Q.N. Ans. Con.Code Q.N. Ans. Con.Code Q.N. Ans. Con.Code
1. D P110420 1. B C110113 1. C M110202
2. B P110308 2. C C111101 2. C
M110705,
M110706
3. A P110409 3. D C110702 3. A M110731
4. D P110316 4. C C110306 4. B M110814
5. D P110301 5. C C111204 5. D M110801
6. B P110504 6. C C110908 6. C M111301
7. A P110325 7. D
C111004,
C111006
7. C M111403
8. A P110327 8. B C110113 8. D M110602
9. A P110310 9. C C110104 9. B M110724
10. C P110310 10. B C110109 10. A M110724
11. C P110402 11. B C110305 11. C M110802
12. B P110403 12. A C110204 12. C M110802
13. A P110420 13. C C110207 13. D M111402
14. C P110420 14. D C110207 14. B M111402
15. ABCD P110403 15. BCD C111208 15. AD M110725
16. CD P110306 16. ABC
C110107,
C110108
16. ACD M110819
17. AD P110404 17. ACD C110306 17. BCD M111304
18. AB P110201 18. AC C110205 18. ACD M110707
19. ACD P110325 19. AB C110904 19. BD M110202
20. ABD P110416 20. B C110006 20. AD M110808

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Answers & Solutions
Physics
1. D (Concept code: P110420)
1. Kx =
Mg
3
; x =
Mg
3k


2. B (Concept code: P110308)
2. 2.45 =
2
1
gt
2
t =
1
2


3. A (Concept code: P110409)
3. 2 a +1 2 +1 4 =0.

4. D (Concept code: P110316)
4. 2R =V 60 =
175
60
6

1750 =2R
R =
1750
2

T =60 sec and T should be same for both.

jeep jeep
cheetah cheetah
v r
v r
=

cheetah jeep
R 60 60(2 )
v v 1 105
R 1750

= =


=82.37 km/hr.

5. D (Concept code: P110301)
5. Average velocity =
2
2
R
H
2 net displacement
total time T/ 2

+


= .

6. B (Concept code: P110504)
6. Avg. power =
2
1
10(2)
2
1W
20

= .

7. A (Concept code: P110325)
7.
dv
a v
dx
=

8. A (Concept code: P110327)
8.
av
s
v
t
=

9. A (Concept code: P110310)
9. v u a t = + =
o o
a v
0
g
+

10. C (Concept code: P110310)
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10. x =
2
2 0
o
v 1 1
ut at 0 a
2 2 g

+ = +




11 C (Concept code: P110402)
11. F.B.D.

12. B (Concept code: P110403)
12. T cos =mg

13. A (Concept code: P110420)
13. For stable equilibrium,
2
2
d U
0
dr
> .

14. C (Concept code: P110420)
14. W
ext
=
2
A B
0
2A
2A
B
B










=
2 2 2
B B B
0
4A 2A 4A

=



.

15. ABCD (Concept code: P110403)
15. T
2
sin
2
=mg and T
2
cos
2
=mg
T
1
sin
1
=T
2
sin
2
and T
1
cos
1
=mg +T
2
cos
2


16. CD (Concept code: P110306)
16. Sign of velocity of acceleration indicate their direction in the co-ordinate axis. If they are
of same sign, speed increases.

17. AD (Concept code: P110404)
17. Newtons third law state that force applied by one object on other is exactly of same
magnitude that applied by other on one.

18. AB (Concept code: P110201)
18. C
2
=A
2
+B
2
+2AB cos

19. ACD (Concept code: P110325)
19. Concept of slope
ds
v
dt
= and
2
2
d s
a
dt
=

20. ABD (Concept code: P110416)
20. F
net
=ma

Chemistry
1. B (Concept Code: C110113)
1. The orbitals in (A), (B), (C) and (D) are respectively 4d, 3s, 3p and 4f,
No. of radial nodes =(n - - 1)
3s has maximum number(2) radial nodes.

2. C (Concept Code: C111101)
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2.
2
2 2
Cu S Cu SO
+
+
6e
2e


3. D (Concept Code: C110702)
3. Except the valence electrons, the remaining electrons are called core electrons.
Hydration of the ions decreases on moving down the group. Hence, the radii of hydrated
ions decrease on moving down the group.

4. C (Concept Code: C110306)
4. Orbitals having maximum amount of directional character(p-orbital) undergo overlapping
by maximum extent. So, the order should be
p >sp
3
>sp >s
Since the hybrid orbitals are formed by such a manner that electron density remains
maximum along one direction and minimum along other direction.
Atomic orbital
Hybrid orbital
Due to high electron density the hybrid orbitals undergo better overlapping along one
direction. The atomic orbitals undergo equal overlapping along both directions.

5. C (Concept Code: C111204)
5. The van der Waals equation for one mole of real gas is given as
( )
2
a
P V b RT
V

+ =



At high P,
2
a
V
is neglected, making P(V - b) =RT

6. C (Concept Code: C110908)
6. MgCl
2
.6H
2
O does not form anhydrous salt on heating. It undergoes partial hydrolysis
during heating.
2 2 2 2 2
MgCl .6H O MgCl .H O 5H O

+
HCl + Mg
Cl
OH

7. D (Concept Code: C111004, C111006)

8. B (Concept Code: C110113)
8. The probability of finding electrons at a certain region is represented by
2
.
2
is zero at
nucleus as there is no electron present at the nucleus.

9. C (Concept Code: C110104)
9. By supplying 12.75 eV energy, the maximum excitation of electrons takes place from the
ground state to fourth orbit(n =4)
No. of photons =
( ) ( ) n n 1 4 4 1
4 3
6
2 2 2


= = =

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10. B (Concept Code: C110109)
10. E
4 1
=E
4 3
+E
3 1


4 1 4 3 3 1
4 1 4 3 3 1
o
4 1
hc hc hc
or,
1 1 1 1 1 5
or,
8000 2000 8000
8000
1600A
5

= +

= + = + =

= =


11. B (Concept Code: C110305)
11. Hybridization is sp
3
as Cl forms three sigma bonds and contains a lone pair.
The structure of
3
ClO

is
Cl
O
O
O

12. A (Concept Code: C110204)
12. in +4 oxidation state chlorine contains an unpaired electron and a lone pair. E.g. ClO
2
.

13. C (Concept Code: C110207)
13. ( )
3 4 2 3 4
2
2Na AsO 3CaCl Ca AsO 6NaCl + +
Initial moles
800 0.4 1000 0.5
0 0
1000 1000


=0.32 =0.5
Moles after 0 0.02 0.16 0.96
reaction
Total moles of Cl

=(0.02 2) +0.96 =1
Molarity of Cl

=
1 1
1800
1.8
1000
= =0.55 M

14. D (Concept Code: C110207)
14. All the
3
4
AsO

ions are precipitated as calcium arsenate. Hence its molarity is zero.

15. BCD (Concept Code: C111208)
15. The gases have same molecular mass.

16. ABC (Concept Code: C110107, C110108)
16. It contains four unpaired electrons. Hence magnetic moment =
( ) ( ) n n 2 4 4 2 2 6 + = + = B.M.

17. ACD (Concept Code: C110306)
17. p-d back bond formation takes place in (Y).

18. AC (Concept Code: C110205)

19. AB (Concept Code: C110904)

20. B (Concept Code: C110006)
20.
2 2 2 2
H O I H I H O
+
+ + +

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Mathematics
1. C M110202
1. ( ) ( ) ( )
1/2 2
3 2 x
log 3 log 2 log 83
4 9 10 + =
( ) ( )
x
1/2 log 83
2
4 9 10 + =
( ) ( )
x
1 log 10
83 83 =

x
1 log 10 x 10 = =

2. C M110705 & M110706
2. Slope of
8
OB
6
=
Slope of
3
OC
4
=
BOC
2

=
OBC is right angled at O
Circumcentre =mid point of hypotenuse =
11
1,
2




Orthocentre =vertex O (0, 0)
Distance
121 5 5
1
4 2

= + =


unit
B(6, 8)
(4, 3)
O
C


3. A M110731
3. Here,
( )
2
1 1
2 h ab
tan m tan
a b


=

+




1
25
2 6
4
tan
2 3







=

+





1
1
tan
5


=



Here,
1
m
5
=

4. B M110814
4. The common chord must be a diameter of the second circle. The equation to the
common chord is
1 2
S S 0 = i.e. ( ) 6x 14y c d 0 + + + = . The centre of the second circle
(1, 4) lies on it. ( ) ( ) 6 1 14 4 c d 0 + + + =
c d 50 + =

5. D M110801
5. Let the given lines be
1 1 1 1
L a x b y c 0 = + + = and
2 2 2 2
L a x b y c 0 = + + = .
Suppose L
1
meets the coordinates axes at A and B and L
2
meets at C and D. Then
coordinates of A, B, C, D are
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1 1
1 1
c c
A , 0 , B 0,
a b




,

2
2
c
C ,0 ,
a



and
2
2
c
D 0,
b





Since A, B, C, D are concyclic, therefore OA . OC =OD . OB


y
X
X
C
O
A
D
y'
B

1 2 2 1
1 2 2 1
c c c c
a a b b

=




1 2 1 2
a a bb =

6. C M111301
6. 4n =
( ) ( ) tan 2n 1 tan 2n tan cot
2

= = =



( ) tan tan2 tan3 ....tan 2n 1
( ) ( ) ( ) ( )
tan tan 2n 1 tan2 tan 2n 2 .....tan n
( ) 1.1.1....1 tan n =
tan n tan 1
4

= = =

7. C M111403
7.
3
sin cos , sin cos
2 2

= + =



( ) sin 3 sin , + =
( ) sin 5 sin =
( )
4 4
3
3 sin sin 3
2

+ +




( )
6 6
2 sin sin 5
2

+ +




{ } { }
4 4 6 6
3 cos sin 2 cos sin = + +

{ } { }
2 2 2 2
3 1 2sin cos 2 1 3sin cos =
=1

8. D M110602
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8.
x
x
1 1
lim 0
7 7


= =



(not an indenterminant form)

x
x
lim1 1 1

= = (not an indeterminate form)



x
x
lim5 5

= = (not an indeterminant form)


( )
x
x
1
lim 1 1 0 1
x


+ = + =


(indeterminant form)

9. B M110724
9. Centroid is

acost bsint 1
x
3
+ +
=
3x 1 acost bsint = + (i)
and
asint bcost 0
y
3
+
=
3y asint bcost = (ii)
Squaring and adding Eqs. (i) and (ii), we get
( ) ( ) ( ) ( )
2 2 2 2
3x 1 3y acost bsint asint bcos + = + +
or ( ) ( )
2 2
2 2
3x 1 3y a b + = +

10. A M110724
10. Let (x, y) be coordinate of vertex C and ( )
1 1
x , y be coordinates of centroid of the triangle

1
x 2 2
x
3
+
= and
1
y 3 1
y
3
+
=

1
x
x
3
= and
1
y 2
y
3

=
The centroid ( )
1 1
x ,y lies on the line 2x 3y 1 + =

1 1
2x 3y 1 + =

x y 2
2 3 1
3 3

+ =



2x 3y 9, + = which is the required locus of the vertex C.

11. C M110802
11. Particle covers an arc of k unit on a circle of radius k unit and the moves on the next
circle.


2
2

1
(1, 0)
x
O
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The particle starts at (1, 0) (i.e. it covers a distance of 1 radian) and to cross the positive
direction of x axis for the first times particle has to cover a distance
2 r 2 1 2 = = radian

2 rad
2 2 3.14
1rad

= =



6.28 =
i.e. on the 7
th
circle

12. C M110802
12. Particle moves 1 radian on each circle starts from (1, 0)
To cross x axis again should cover rad

rad
3.14
1rad

= =



i.e. will be on 4
th
circle
point (4, 0)

13. D M111402
13.
2 4 6
cos cos cos
7 7 7



2 4 8
cos cos cos 2
7 7 7

=




2 4 8
cos cos cos
7 7 7

=

3
3
2 2 2
sin 2 . sin 2 sin
1 7 7 7
2 2 2 8
2 sin 8 sin 8sin
7 7 7

+


= = = =





14. B M111402
14.
5 7
sin sin sin
18 18 18





5 7
cos cos cos
2 18 2 18 2 18

=




8 4 2
cos cos cos
18 18 18

=




2 4
cos cos cos
9 9 9

=



3
here
2 1

=

+



3
1
2
=

1
8
=

15. AD M110725
15.
2
1 2 6
3 1 4 0
4

=


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2
2 8 0 + =
( ) ( ) 4 2 0 + =
4, 2 =

16. ACD M110819
16.
2 2
1
c x y 2x 4y 4 0 = + = ..(i)
and
2 2
2
c x y 2x 4y 4 0 = + + + + = ..(ii)
Radical axis is
1 2
c c 0 =
x 2y 2 0 + + = which is L=0
Centre and radius of
1
C 0 = are (1, 2) and 3.
Length of from (1, 2) on L =0
is
1 4 2
7
5 1 4
+ +
=
+
radius
L is also the common chord of C
1
and C
2

Centres of
1
C 0 = and
2
C 0 = are (1, 2) and ( ) 1, 2
Slope of Line joining centres of circles
1
C 0 = &
2
C 0 = is
1
2 2
2 m
1 1

= =

(say)
and slope of L =0 is
2
1
m
2
= (say)

1 2
m m 1 =
Hence L is perpendicular to the line joining centres of C
1
and C
2
.

17. BCD M111304
17.
3
cos
5
=

4
sin
5
=
and
5
cos
13
=

12
sin
13
=
( ) cos cos cos sin sin + =

4 5 4 12
. .
5 13 5 13
=
33
65
=
( ) sin sin cos cos sin + = +

4 5 3 12
. .
5 13 5 13
= +
56
65
=

( )
2
1 cos
sin
2 2


=




{ } 1 cos cos sin sin
2
+
=

3 5 4 12
1 . .
5 13 5 13
2

+


=
63
1
65
2

=
1
65
=

Two Year CRP(1416)-Phase Test-1_PCM-IITJEE/16

FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[


39
( ) cos cos .cos sin .sin = +

3 5 4 12
. .
5 13 5 13
= +
63
65
=

18. ACD M110707

19. BD M110202

20. AD M110808
20. Circle possible in IV quadrant. Equation of circle is
( ) ( )
2 2
2
x c y c c + + =
Its passes through (3, 6)
( ) ( )
2 2
2
3 c c 6 c + =

2
c 18c 45 0 + =
( ) ( ) c 15 c 3 0 =


x' x
y'
y
c
(c, c) c
(3, 6)
c =3, 15
From Eq. (i) equation of circles are

2 2
x y 6x 6y 9 0 + + + =
and
2 2
x y 30x 30y 225 0 + + + =
Two Year CRP(1416)-Phase Test-1_PCM-IITJEE/16

FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[


40
QP CODE: 120764.2
SECTION I (PHYSICS) SECTION II (CHEMISTRY) SECTION III (MATHS)
PART A PART A PART A
Q.N. Ans. Con.Code Q.N. Ans. Con.Code Q.N. Ans. Con.Code
1. A P110409 1. D C110702 1. A M110731
2. D P110316 2. C C110306 2. B M110814
3. D P110301 3. C C111204 3. D M110801
4. B P110504 4. C C110908 4. C M111301
5. A P110325 5. D
C111004,
C111006
5. C M111403
6. A P110327 6. B C110113 6. D M110602
7. D P110420 7. B C110113 7. C M110202
8. B P110308 8. C C111101 8. C
M110705,
M110706
9. C P110310 9. B C110109 9. A M110724
10. A P110310 10. C C110104 10. B M110724
11. B P110403 11. A C110204 11. C M110802
12. C P110402 12. B C110305 12. C M110802
13. C P110420 13. D C110207 13. B M111402
14. A P110420 14. C C110207 14. D M111402
15. AD P110404 15. ACD C110306 15. BCD M111304
16. AB P110201 16. AC C110205 16. ACD M110707
17. ACD P110325 17. AB C110904 17. BD M110202
18. ABD P110416 18. B C110006 18. AD M110808
19. ABCD P110403 19. BCD C111208 19. AD M110725
20. CD P110306 20. ABC
C110107,
C110108
20. ACD M110819

Two Year CRP(1416)-Phase Test-1_PCM-IITJEE/16

FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[


41
QP CODE: 120764.3
SECTION I (PHYSICS) SECTION II (CHEMISTRY) SECTION III (MATHS)
PART A PART A PART A
Q.N. Ans. Con.Code Q.N. Ans. Con.Code Q.N. Ans. Con.Code
1. D P110301 1. C C111204 1. D M110801
2. B P110504 2. C C110908 2. C M111301
3. A P110325 3. D
C111004,
C111006
3. C M111403
4. A P110327 4. B C110113 4. D M110602
5. D P110420 5. B C110113 5. C M110202
6. B P110308 6. C C111101 6. C
M110705,
M110706
7. A P110409 7. D C110702 7. A M110731
8. D P110316 8. C C110306 8. B M110814
9. A P110310 9. C C110104 9. B M110724
10. C P110310 10. B C110109 10. A M110724
11. C P110402 11. B C110305 11. C M110802
12. B P110403 12. A C110204 12. C M110802
13. A P110420 13. C C110207 13. D M111402
14. C P110420 14. D C110207 14. B M111402
15. ACD P110325 15. AB C110904 15. BD M110202
16. ABD P110416 16. B C110006 16. AD M110808
17. ABCD P110403 17. BCD C111208 17. AD M110725
18. CD P110306 18. ABC
C110107,
C110108
18. ACD M110819
19. AD P110404 19. ACD C110306 19. BCD M111304
20. AB P110201 20. AC C110205 20. ACD M110707

Two Year CRP(1416)-Phase Test-1_PCM-IITJEE/16

FIITJEE Ltd., North West Delhi Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
[


42
QP CODE: 120764.4
SECTION I (PHYSICS) SECTION II (CHEMISTRY) SECTION III (MATHS)
PART A PART A PART A
Q.N. Ans. Con.Code Q.N. Ans. Con.Code Q.N. Ans. Con.Code
1. A P110325 1. D
C111004,
C111006
1. C M111403
2. A P110327 2. B C110113 2. D M110602
3. D P110420 3. B C110113 3. C M110202
4. B P110308 4. C C111101 4. C
M110705,
M110706
5. A P110409 5. D C110702 5. A M110731
6. D P110316 6. C C110306 6. B M110814
7. D P110301 7. C C111204 7. D M110801
8. B P110504 8. C C110908 8. C M111301
9. C P110310 9. B C110109 9. A M110724
10.
A
P110310 10. C C110104 10. B M110724
11. B P110403 11. A C110204 11. C M110802
12. C P110402 12. B C110305 12. C M110802
13. C P110420 13. D C110207 13. B M111402
14. A P110420 14. C C110207 14. D M111402
15. ABD P110416 15. B C110006 15. AD M110808
16. ABCD P110403 16. BCD C111208 16. AD M110725
17. CD P110306 17. ABC
C110107,
C110108
17. ACD M110819
18. AD P110404 18. ACD C110306 18. BCD M111304
19. AB P110201 19. AC C110205 19. ACD M110707
20. ACD P110325 20. AB C110904 20. BD M110202

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