SULIT 4541/1 dan 2

4541/1 dan 2
Chemistry
Mark Scheme
Paper 1 and 2

PERSID!"! #E$!"S! PE!"ETU%PE!"ETU
SE#&L' ME!E!"' ML(SI )P#PSM* C+!"! MEL#
DE!"! #ER,SM
,$T! PEL,R! MEL#
____________________________________________________

PEPERI#S! PERCU$!
SI,IL PEL,R! ML(SI 2-1-
C'EMISTR(
Mark Scheme
Paper 1 and Paper 2
SET 1
Skema Pemarkahan ini mengandungi 11 halaman bercetak.
!S+ERS .&R C'EMISTR( PPER 1
)SET 1*
1 $ 2 C / $ 4 5 C
0 $ 1 2 $ 3 C 1-
11 D 12 $ 1/ $ 14 D 15 C
10 C 11 12 C 13 D 2- $
21 $ 22 D 2/ C 24 $ 25
20 C 21 D 22 $ 23 $ /- $
/1 C /2 C // D /4 /5 C
/0 D /1 /2 /3 $ 4-
41 D 42 C 4/ 44 D 45 $
40 C 41 D 42 43 5- D
2
SECTI&!
1 (a) Number of proton in an atom 1
(b) Atom 1
(c) (i) 2.8.6 1
(ii) 6 1
(d) (i) Atom of the ame element !ith different number of neutron""
Atom of the ame element !ith different nucleon number ""
Atom that ha the ame number of proton but different number
of neutron
1
(ii) #timate the age of foil"artefact 1
(e) (i) 1. $unctional diagram
2. %abeled &a&'(
1
1 2
(ii) 1. &orrect formula of reactant
2. &orrect formula of product
(. )alance the e*uation
&u&'( + &u' , &'2 2
-otal 1-
2 (a) (i) $ ./ 1
(ii) -he0 ha1e ame 1alence electron 1
(b) #"Aluminium 1
(c) (i) & 1
(ii) Achie1ed table "octate electron arrangement 1
(d) &. ). A. $ .# .2 1
(e) (i) %o! boiling point "" inoluble in !ater"" oluble in inorganic ol1ent""
cannot conduct electricit0 ( an0 other acceptable ph0ical propertie
1
(ii) 31. correct number of occupied electron hell and correct electron
in each hell for all the atom. nuclei ho!n 4
32. four atom of $ combine co1alentl0 (haring a pair of
electron)!ith one atom of A 4
1
1
(


(iii) &o1alent bond 1
T4ta5 1-
/ (a) (i) 5olecule 1
(ii) 6on 1
(b) 7ater 1
(c) 1. 6n ol1ent 8 h0drogen chloride e9it a molecule"" in ol1ent :
h0drogen chloride ioni;e to produce h0drogen ion
1
2. /0drogen ion react !ith marble chip to produce carbon dio9ide ga 1 2
(d) (i) <inc o9ide 1
(ii) 1. &orrect formula for reactant and product
2. )alance the e*uation
2<n(N'()2 + 2<n' , =N'2 , '2
1
1 2
(e) >add odium h0dro9ide" ammonia olution to olution < until e9ce 1
>!hite precipitate oluble in e9ce odium h0dro9ide" oluble in
e9ce ammonia olution
1 2
1-
=
4 (a) &ell 1 ? &hemical cell "@oltaic cell &ell 2 ? #lectrol0tic &ell 2
(b) #lectrical energ0 to &hemical energ0 1
(c) (i) ;inc ion 1
(ii) <n <n
2,
, 2e 1
(d) 3arro! from the ;inc electrode to the il1er electrode through the e9ternal
circuit4
1
(e) &u
2,
. S'=
2>
. /
,
. '/
>
1
(f) (i) )ro!n olid depoited at the cathode 1
(ii) &u
2,
in the electrol0te accept electron and form copper atom 1
(g)
&ell1 &ell 2
No dr0 cell
#lectrode are made up of
different metal
/a t!o different electrol0te
Preence of alt bridge
/a dr0 cell
#lectrode are made up of carbon
'nl0 one electrol0te
No alt bridge
3 an0 1 pair 4
1
T4ta5 1-
5 (a) (i) &ontact Proce 1
(ii) 1. &orrect formula of reactant
2. )alance the e*uation
2S'2 , '2 + 2S'(
1
1 2
(iii) @anadium(@) o9ide" @anadium pento9ide 1
(i1) An0 uitable correct ue
5anufacture of paint"electrol0te
1
(b) (i) Saponification 1
(ii) Soap 1
(iii) Aeduce olubilit0 of oap in mi9ture 1
(i1) B ? Soap
C ? 2etergent
1
1 2
-otal 1-
D
0 (a) Propanol 1
(b)
&(/6 , /2' + &(/E'/
1
(c) (i) 2eh0dration 1
(ii) >functional apparatu 1
>labeled diagram ? gla !ool oaked !ith alcohol P" propanol.
Porcelain chip. deli1er0 tube. a tet tube in1ert in a bain of !ater to
collect propene.
1
(d) (i) '9idi;ing agent 1
(ii) '9idation 1
(iii) 'range to green 1
(e) (i) #terification 1
(ii) &/(&''&(/E'/ 1
1-
6
SECTI&! $
1 (a) (i)
(ii)
(iii)
$i9ed ma of ulphur produced per time
Sulphur
S2'(
2>
, 2/
,
S , S'2 , /2'
1
1
1 (
(b) (i) 1. A9i labelled and !ith unit
2. Scale appropriate (i;e? min F of graph paper) and
conitent
(. Point correctl0 plotted and mooth cur1e dra!n
1
1
1 (
(ii) 1. A concentration of odium thioulphate increae. the
time taken for the reaction decreae
2. 6ncreae in concentration of odium thioulphate !ill
increae the number of thioulphate ion"ion per unit
1olume
(. $re*uenc0 of colliion bet!een thioulphate ion and
h0drogen ion increae
=. $re*uenc0 of effecti1e colliion increae
D. 6ncreae in concentration of odium thioulphate
increae the rate of reaction
1
1
1
1
1 D
(c) (i)
(ii)
1. 'nl0 a mall amount of catal0t i needed to increae
the rate of reaction.
2. &atal0t remained chemicall0 unchanged
(. &atal0t undergoe ph0ical change during a chemical
reaction.
=. &atal0t change onl0 the rate of reaction but not the
amount of product.
D. &atal0t i pecific in it reaction
6. 6ncreae the catal0t !ill increae the rate of reaction
3 An0 ( 4
&atal0t Aeaction
Nickel

@anadium (@) o9ide
>5anufacture of margarine
>/0drogenation of alkene to
form alkane
>&ontact Proce " ulphur
dio9ide react !ith o90gen to
form ulphur trio9ide
3 or an0 correct e9ample of
catal0t and their reponding
reaction4
(
2,2
G
(iii) 1. :>a9i labelled energ0 . 8>a9i labelled progre of
reaction .
2. Acti1ation energ0 !ith catal0t i dra!n lo!er than the
acti1ation energ0 !ithout catal0t for an e9othermic
reaction
1
1
E
T4ta5 2-
2 (a) (i) 1. #lectronegati1it0 decreae do!n the group
2. atomic radiu "i;e become larger do!n the group
(. the force of attraction bet!een nucleu and
electron become !eaker
=. 5elting point and boiling point increae do!n the
group becaue
D. molecular i;e increae do!n the group.
6. attraction force bet!een molecule become tronger ""
intermolecular force become tronger
E. more heat i needed to o1ercome thi force of attraction
8. -he denit0 of halogen increae do!n the group
becaue
G. e1en though both atomic ma and 1olume(i;e) of
halogen increae do!n the group
1H -he increae in atomic ma i bigger than 1olume
(i;e).
1
1
1
1
1
1
1
1
1
1 1H
(ii) 1. Aeaction of chlorine . bromine and iodine !ith iron ?
Aeacti1it0 of chlorine I bromineIiodine
/alogen 'ber1ation
&hlorine 6ron (!ool) ignite rapidl0
!ith bright flame. bro!n
olid formed.
)romine 6ron (!ool) glo! brightl0 .
bro!n olid formed
6odine 6ron (!ool) glo! diml0.
bro!n olid formed.
1
1
1
1 =
(b) (i)
(ii)
1. 6onic bond
1. 3correct number of occupied electron hell. correct
electron in each hell and nuclei ho!n for both ion 4
2. 3one odium ion combine !ith one chloride ion.
charge of ion ho!n 4

(. can conduct electricit0 in the molten tate
=. cannot conduct in the olid tate
D. in molten tate the ion are free to mo1e
6 in olid tate ion are not free to mo1e but held fi9ed in
lattice
1
1
1
1
1
1
1
1
5a9 D
T4ta5 2-
8
SECTI&! C
3 (a) (i) &ompound formed !hen h0drogen ion from an acid i
replaced b0 metal ion or ammonium ion
1
(ii) %ead(66) chloride 1
2ouble decompoition 1
(iii) 1. Pour 3DH>1HH cm
(
4 3H.D>2.H mol dm
>(
4 lead(66) nitrate olution in a
beaker
1
2. Add 3DH>1HH cm
(
4 3H.D>2.H mol dm
>(
4 odium chloride " an0
oluble alt olution contain chloride ion into the beaker
1
(. Stir the mi9ture 1
=. filter the mi9ture 1
D. Aine the reidue !ith ditilled !ater 1
6. dr0 the alt !ith filter paper 1
E. #*uation?
Pb
2,
, &l
>
+ Pb&l2
1
(b) 3&alculate the molar ma of C&l re*uired4
1. 5olar ma of C&l J (G , (D.D J E=.D g mol
>1
1
3&alculate number of mole of C&l re*uire4
2. No. of mole J (5@)"1HHH J (H.D 9 2DH)"1HHH J H.12D mol
1
3&alculate ma of C&l re*uired4
(. 5a J H.12D 9 E=.D J G.(12D g
1
=. 7eigh out G.(12D g of C&l 1
D. 2iol1e the olid C&l !ith a little ditilled !ater in a beaker 1
6. -ranfer the olution into 2DH cm
(
1olumetric flak uing filter
funnel.
1
E. Aince the beaker and filter funnel !ith ditilled !ater and add
the !ahing to the flak
1
8. Add ditilled !ater into the flak lo!l0 until the graduation
mark.
1
G. &loed the flak !ith topper 1
1H. Shake !ell""in1ert e1eral time until the olution mi9ed !ell 1
1-
T4ta5 2-
G
1- (a) /eat change"releae !hen 1 mol of !ater formed from the reaction
bet!een an acid and alkali.
1
(b)(i) 1. &orrect formula of reactant
2. &orrect formula of product
/&l , Na'/ + Na&l , /2' 2
(ii) 1. No. of mole J (2.H9 2D.H)"1HHH J H.HD
2. /eat change J H.HD 9 DE J 2.8D kB "2.8DH B
1
1 2
(iii) 1. @ertical e9e labeled energ0 !ith t!o energ0 le1el
2. #nerg0 le1el of reactant i higher than product and K/J >DE kBmol
>1
#nerg0
/&l , Na'/

K/ J >DE kBmol
>1
Na&l , /2'
1
1 2
(i1) 1. #thanoic acid i !eak acid"" #thanoic acid ioni;e partiall0 in !ater
2. /eat aborbed to ioni;ed ethanoic acid
1
1 2
(c) 1. 5aterial? odium h0dro9ide. h0drochloric acid
2. DH cm
(
of 2 mol dm
>(
odium h0dro9ide olution i meaured uing a
meauring c0linder and poured into a platic cup.
(. DH cm
(
of 2 mol dm
>(
h0drochloric acid i meaured uing another
meauring c0linder and poured into a platic cup.
=. -he initial temperature of the olution are meaured after a fe!
minute.
D. -he h0drochloric acid i then poured *uickl0 and carefull0 into the
odium h0dro9ide olution
6. -he mi9ture i tirred uing a thermometer and the highet
temperature reached i recorded.
E. Aeult?
6nitial temperature of odium h0dro9ide olution J -1
H
&.
6nitial temperature of h0drochloric acid J -2
H
&
/ighet temperature J -(
H
&

1
1
1
1
1
1
1
1H
&alculation
8. A1erage temperature of acid and alkali J -1 , -2
2
J -9
H
&
G. 6ncreae in temperature J (-(>-9) J L
H
&
1H. /eat releaed in the reaction J (DH ,DH) ( & ) L
J P Boule
11. Number of mole of odium h0dro9ide and h0drochloric acid
J DH 9 2
1HHH
J H.1 mol
12. /eat of neutraliation. M/ J P "(H.191HHH) kBmol
>1

5a9
1
1
1
1
1
1-
T4ta5 2-
S#EM PEMR#'! TMT
11