for Your Business Intermediates BASF is the worlds leading chemical company: The Chemical Company. Its portfolio ranges from oil and gas to chemicals, plastics, per - formance products, agricultural products and fine chemicals. As a reliable partner BASF helps its customers in virtually all industries to be more successful. With its high-value products and intelligent solutions, BASF plays an important role in finding answers to global challenges such as climate protection, energy efficiency, nutrition and mobility. Just as the whole is greater than the sum of its parts, BASFs intermediates are more than just chemical components for making countless products. Indeed, innovative intermediates not only make the manufacture of many products possible, but also improve the properties of substances made with them and efciencies in producing them. Be Part of Innovation Top Intermediates Supplier The operating division Intermediates of the BASF Group develops, produces and markets the worlds largest range of intermediates. The most important of the divisions more than 600 products include amines, diols, polyalcohols, acids and specialties. Among other applications, intermediates are used as starting materials for coatings, plastics, pharmaceuticals, textile fibers, detergents and crop protec- tants. Innovative BASF intermediates help to improve the properties of the final product and the efficiency of production processes. The ISO 9001:2000-certified operating division Intermediates operates plants in Europe, Asia and the Americas. 2 BASF The Chemical Company 3 If you have any questions, please contact us or our representative. See contact details on back. Application Characteristic Benefit Textiles Crosslinking agent or building block for crosslinker Softer and less wrinkled textiles Paper Crosslinking agent or building block for crosslinker Paper wet strength (e.g. toilet paper) Paper dry strength (e.g. recycled paper) Efficient paper coating additive for high-quality papers Leather Crosslinking in tanning process Preservation of leather quality Cosmetics Use of glyoxal-crosslinking polymers (hydrocolloids) Better viscosity Epoxy Building block for specific epoxy applications Higher epoxy stability performance Oil & Gas Biocide Sulfur scavenger Use of glyoxal-crosslinking polymers (hydrocolloids) Anti-corrosive Safety at work Improves viscosity in oil-drilling fluids Disinfection Biocidal active ingredient for disinfection formulations Co-biocide for disinfectants used in the health industry and in veterinary hygiene Effective when formulated together with e.g. glutaraldehyde Glyoxylic Acid Raw material Serves as an intermediate for vanillin, agricultural chemicals, antibiotics, allantoin, complexing agents Wood Hardening Crosslinking agent or building block for crosslinker Cures wood Protection from moisture Current Applications Glyoxal the All-Rounder BASF has over 55 years of glyoxal R&D experience. We developed a vast number of applications for glyoxal. Our team in research and development of our know- how Verbund make sure that there is more to come. Due to its diverse properties glyoxal can be used in a wide range of innovative applications. To discover new fields of use, we are working with our cus- tomers in innovative partnerships. As their partner we are highly interested in supporting our customers with our expertise to maximize their innovative outcome. Yingtong Tan (Glyoxal Supply Chain Management) ensures that glyoxal reaches our customers reliably in the requested quantities wherever they are. Glyoxal from BASF is a solution for your needs. Thus we offer you more than just a product: Reliable Supply With 80,000 metric tons annual world- scale production in NAFTA and Europe we are a leading player in the glyoxal industry. Our backward-integrated produc- tion of glyoxal guarantees efficient and reliable supply wherever you are. Application Expertise At BASF we pool our knowledge in the know-how Verbund to make our expertise available to our partners. Working together with our customers in successful partnerships will offer mutual benefits. Logistics Services Whether you need bulk or packaged material, we ensure efficient solutions. Our advice on packaging and dedicated storage facilities guarantee reliable supply to allow you to run your business steadily. Sustainable Development The accreditation of specific chemical substances is an important step to a long-term and sustainable development of your business. We are registering glyoxal in the EU under REACH, and together with BASFs specialist biocide group in our Care Chemicals division we support customers who want to obtain registrations for their biocidal products according to the EU Biocidal Products Directive. We also offer to advise you with respect to these legal requirements. Ethylene Ethylene glycol Glyoxal (40 %) Textile resins Imidazoles Paper resins Backward-integrated production process of glyoxal 4 The Sustainable Solution for Your Business Christian Horn, Glyoxal Plant Supervisor, and his team are responsible for the quality of glyoxal. He checks for example the color index to ensure the low color number which is a unique feature of BASFs glyoxal. Nomenclature Name: glyoxal, 40 % aqueous solution Chemical name: ethanedial, oxalaldehyde CAS No.: 107-22-2 EINECS No.: 203-474-9 INDEX No.: 605-016-00-7 Chemical structure Chemical properties Form: liquid Color: colorless to pale yellow Odor: almost odorless Solubility: miscible with water and with all water-miscible organic solvents Physical properties Freezing point: approximately -14 C [6.8 F] Boiling point: approximately 104 C [219.2 F] Density at 20 C [68 F]: approximately 1.27 g/cm Vapor pressure at 20 C [68 F]: 24 mbar pH: 2 to 3.5 Ignition temperature: 285 C [545 F] (DIN 51794) 5 Properties of a Solution Since its discovery in 1856, glyoxal has become an important component in successful chemical applications. As an essential ingredient for your ideas, glyoxal offers numerous advantages: Versatile Crosslinker Glyoxal links a wide range of polymers, e.g. starch, cellulose, proteinaceous material, polyacrylamide, polyvinyl alcohols. Biodegradability Glyoxal is readily biodegradable by showing more than 90 % decrease of dissolved organic carbon according to OECD guidelines 301 C-E and 303 A. Appropriate for Food Packaging Glyoxal is listed as an accredited chemical substance in the production of paper for food packaging by the Federal Institute for Risk Assessment (BfR) in Germany, and by the Food and Drug Administration (FDA) in the U.S. Substitution Potential Glyoxal shows high potential in the substitution of aldehydes, e.g. for formaldehyde or glutaraldehyde. Additionally in disinfection it can be used as a co-biocide formulated together with glutaraldehyde from BASF. Due to its diverse properties glyoxal is an all-rounder in crosslinking polymers, e.g. in the textile, wood and paper industries. In addition, glyoxal works as an effective co-biocide in disinfection and as a sulfur scavenger and biocide in oil and gas applications. 6 Glyoxal a Classic Intermediate with a Future The data contained in this publication is based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, the data does not relieve processors from carrying out their own investigations and tests; neither does the data imply any guarantee of certain properties, nor the suitability of the product for a specic purpose. Any descriptions, drawings, photographs, data, proportions, weights etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. It is the responsibility of the recipient of our products to ensure that any proprietary rights and existing laws and legislation are observed. The safety data given in this publication is for information purposes only and does not constitute a legally binding Material Safety Data Sheet (MSDS). The relevant MSDS can be obtained upon request from your supplier or you may contact BASF directly at product-safety.intermediates@basf.com. 2008 edition Contact Us Europe Phone: +49 621 60 42786 Asia Phone: +852 27311 111 NAFTA Phone: +1 800 426 8696 South America Phone: +55 11 3043 2263 glyoxal@basf.com www.glyoxal-solutions.com http://intermediates.basf.com C Z