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FULL TEST
INSTRUCTIONS
Time : 3 hrs.
Chemistry (120 marks)
Negative Marking
One fourth () marks will be deducted for indicating incorrect response of each question.
. . . Best of Luck
6.
1.
2.
7.
4.
5.
(a)
Kw
Ka
(b)
Kw
Ka Kb
(c)
Kh
C
(d)
Ka
Kb
NO2
(a) 58.2
(b) 29.1
(c) 55.83
(c) 27.91
The correct relation for hydrolysis constant of NH4CN is
NH2
3.
8.
9.
10.
CH3
is
COOH
mechanism :
(a) CH3CH2CH2CH2Cl
(b) CH3CH2CH2Cl
(c) CH3 O CH2Cl
(d) CH3Cl
In the esterification reaction of alcohol
(a) OH is replaced by C6H5OH
(b) H is replaced by CH3OH- gp
(c) OH is replaced by CH3COO- gp
(d) OH is replaced by Cl
The process of the extraction of Au and Ag is based on their
solubility in
11.
12.
13.
14.
20.
21.
22.
23.
24.
16.
17.
18.
19.
(a) CH 3 - CH 2 - CH 2 - CH 2 - COOC 2 H 5
(b) C6H5COOC2H5
(c) C6H5CH2COOC2H5
(d) C6H11CH2COOC2H5
In recovery of silver from photographic film, you have
decided to dissolve the silver ion with dilute nitric acid.
Addition of dilute HCl to precipitate AgCl seems to result in
unacceptable losses. You might improve recovery by addition
of_______ in the latter step.
(a) NaNO3
(b) NaCl
(c) Ag2SO4
(d) sodium acetate
The reaction of phenol with concentrated HNO3 gives
(a) Picric acid
(b) Benzoic acid
(c) Salicylic acid
(d) Phthalic acid
In the reaction,
HOCl
25.
(a) 2.36V
(b) 2.36V
(c) 2.42V
(d) 2.42V
Among the following compounds (I-III) the correct order of
reactivity with electrophile is
OCH3
26.
27.
No2
I
II
III
(a) II > III > I
(b) III < I < II
(c) I > II > III
(d) I = II > III
One desires to prepare a positively charged sol of silver
iodide. This can be achieved by
(a) adding a little AgNO3 solution to KI solution in slight
excess
(b) adding a little KI solution to AgNO3 solution in slight
excess
(c) mixing equal volumes of equimolar solutions of AgNO3
and KI
(d) none of these
In the reaction of KMnO4 with an oxalate in acidic medium,
MnO-4 is reduced to Mn 2 + and C 2 O 24 - is oxidised to
CH 2 = CH2
A CH2 - OH
|
CH2OH
(b) 50 ml of 0.05 M H 2C 2O 4
(c) +
15.
OH
(c) 25 ml of 0.2 M H 2C 2O 4
28.
(d) 50 ml of 0.10 M H 2C 2O 4
Lassaignes test for nitrogen is positive for which
compound?
29.
30.
31.
(a) NH2OH
(b) NH2NH2
(c) H2NCONH2
(d) All the three
Which of the following is true?
(a) Tollens reagent gives a positive result with all
aldehydes
(b) Tollens reagent gives a negative result with all ketones
(c) Both are true
(d) None is true
Which of the following complexes will give white precipitate
with BaCl2 (aq.)?
(a) [Co(NH3)4SO4]NO2
(b) [Cr(NH3)4SO4]Cl
(c) [Cr(NH3)5Cl]SO4
(d) Both (b) & (c)
(c)
K 1K 2
( K1 - K 2 ) m
(b)
(d)
K2 + K2
1
2
( K1 + K 2 ) m
1/ 2
32.
33.
34.
35.
E
C
A
1m
B
O
37.
1m
(a) it is zero when it is at A and moving along OA.
(b) the same at all points along the line DE.
(c) of the same magnitude but oppositely directed at B
and D.
(d) increases as it moves along the line BC
Three progressive waves A, B and C are shown in the figure
below. With respect to the wave A, the wave C
B
1/ 2
K1K 2
m (K 1 + K 2 )
1/ 2
K1 + K 2
36.
1/ 2
117 km / hr
(b)
340 km / hr
(c)
17 km / hr
(d)
3 40 km / hr
38.
[aw 2 - bw + c]
39.
40.
w=
b
2a
(b)
w=
b
a
(c) w = c
(d) w = 0
The insulation property of air breaks down at
E = 3 106 volts/ metre. The maximum charge that can be
given to a sphere of diameter 5 m is approximately
(a) 2 102 coulomb
(b) 2 103 coulomb
4
(c) 2 10 coulomb
(d) 2 105 coulomb
In the following diagram the reading of the ammeter is (when
the internal resistance of the battery is zero)
A
4W
5W
10V
4
40
A
29
(a)
41.
(b)
10
A
9
(c)
45.
5
A
3
(d) 2 A
R = 200 W
0.5V
3V
42.
43.
(a) 5.2 mA
(b) 8.25 mA
(c) 12.5 mA
(d) 15.5 mA
If a bar magnet of magnetic moment 80 units be cut into two
halves of equal lengths, the magnetic moment of each half
will be
(a) 80 units
(b)
40 units
(d)
20 units
47.
48.
w
Rev/min
T1 = 120C, T2 = 84C
95
cm
6
(b)
95
cm
89
(c)
5
cm
6
(d)
25
cm
6
60
(a)
20p
10
(c)
10p
17
10 rev
(b)
17p
10
(d)
10p
13
q
(Radians)
49.
50.
44.
(d)
9 sec
51.
52.
(a)
la
lw
(b)
la
la - l w
(c)
lw
la - l w
(d)
lw
la
5
that the mass will land 1 meter below the track end. A photogatetimer system will allow the speed of the blocks to be measured
just as they leave the track end. Some data from students is given
in the table.
6
5
4
3
2
1
O
Block 1
1 2 3 4 5 6 7 8 9
Input voltage (V)
(a) 5 V
(b)
Block 2
Mass (grams)
200
0.4
200
0.77
200
1.2
300
0.4
300
0.77
300
1.2
6V
6
5
(d) V
V
5
6
In diagrams (1 to 4), variation of volume with changing
pressure is shown. A gas is taken along the path ABCD.
The change in internal energy of the gas will be
(c)
53.
h
V
45
30
0
B
(1)
1m
B
(2) P
54.
D
C
V
A
(3)
(a)
(b)
(c)
(d)
B
(4)
55.
56.
57.
(b) are smaller for the 30 arc than for the 45 arc.
(c) are the same for the 30 arc and 45 arc.
(d) depend on their masses.
Block 1 and Block 2 are again released from h = 1.2 m.
Block 1 flies off the track end at 30 and Block 2 at 45. Their
speeds when they hit the floor 1 meter below the track end:
(a) are smaller for Block 1 than Block 2.
(b) are larger for Block 1 than Block 2.
(c) are the same for Block 1 and Block 2.
(d) depend on mass and angle, so the question cannot be
answered.
The most common isotope used in diagnostic work is
Technicium. It is furnished from a generator or "cow" in
which the negative beta decay of Molybdenum-99 produces
the desirable metastable isotope of Technicium according
to the following decay scheme :
z Tc A + -1e0 .
What are the atomic number, Z, and mass number, A, of the
Tc isotope ?
(a) 41,99
(b) 42,99
(c) 43,98
(d) 43,99
The Thallium-201 half-life is 74 hours. If the sample has an
activity of 80 millicuries initially, what will be the activity
after 9.25 days ?
42 Mo
58.
99
(b)
5 mCi
(c) 10 mCi
(d)
20 mCi
59.
68.
62.
63.
64.
65.
70.
71.
67.
p
2
<q<
p
, then
2
x
3
(a)
x
2
(b)
(c)
x
6
(d) 0
x
(a) 20 c
(b) 10 c
(c) 10 c3
(d) 20 c3
Let Sp and Sq be the coefficient of xp and xq respectively in
(1 + x)p + q, then
(a) Sp Sq
q
(b) Sp = p Sq
p
(c) Sp = q Sq
(d) Sp = Sq.
(b)
10!
2!.(3!) 2 .5!
10!
(d) 10!
2!.5!
The medians of a triangle meet at (0, 3) and two vertices are
at (1, 4) and (5, 2). Then the third vertex is at
(a) (4, 15)
(b) (4, 15)
(c) (4, 15)
(d) ( 4, 15)
(c)
72.
73.
74.
2
then B is equal to
3
(a) 30
(b) 60
(c) 90
(d) 120
If w is a cube root of unity, then a root of the following
w
x +1
equation w x + w2
If e
2
log cos q
3
(a)
1
where |x| < and |an| < 2, is
3
(a) n if n is even
(b) 0 for any natural number n
(c) 1 if n is odd
(d) none of these.
69.
66.
lim
integer.
Statement-2 : In a binomial distribution Mean > Variance.
Statement 1 : If f is even function, g is odd function then
x 3 n 3
a2
is a positive
a -b
f
, ( g 0 ) is an odd function.
g
Statement 2 : If f(x) = f(x) for every x of its domain, then
f(x) is called an odd function and if f(x) = f(x) for every x of
its domain, then f(x) is called an even function.
Statement-1 : If the general equation x2 + y2 + 2xy + 2gx +
2fy + 4 = 0 represents a pair of real lines then | g | 2 .
Statement-2 : The equation ax2 + 2hxy + by2 + 2gx + 2fy + c = 0
represents pair of real lines if abc + 2fgh af2 bg2 ch2 = 0.
Let in a triangle ABC, the line joining orthocentre and
circumcentre be parallel to the side BC.
Statement-1 : tan A, tan B, tan C are in A.P.
Statement-2 : If tan A, tan B, tan C are in A.P.
then tan A tan C = 3.
Let f be a periodic function of period 2.
w2
75.
76.
w2
1 =0 is
x+w
(a) x = 1
(b) x = w
(c) x = w2
(d) x = 0 .
The lines lx + my + n = 0, mx + ny + l = 0 and nx + ly + m = 0
are concurrent if
(a) l m n = 0
(b) l + m n = 0
(c) l m + n = 0
(d) l2 + m2 + n2 = lm + mn + nl
If (x, y) are the co-ordinates of a point in the plane , then
8
3 4 2
84.
5 8 2 = 0 represent
x y 2
77.
78.
79.
80.
81.
h(x) =
p
4
(b) x = n p + (1)n +
(c) x =2n p +
p
,n I
4
85.
86.
83.
(a) a = 1, b = 1
(c) a = 1, b = 1
(b) a = 1, b = 1
(d) a = 1, b = 1
, then
(b) 1
(a)
ab
(r + 1) (s + 2) (s + r)
2
(b)
ab
(r 1) (s 1) (s r)
2
(c)
ab
(r 1) (s + 1) (s r)
2
(d) (r + 1) (s + 1) (s r).
87.
1
x
uuur
uuur
such that OP.i = 1 and OQ.i = -1 where i is a unit vector
88.
(b) 3 5
(c) 2 5
(d)
5 5
5
2
The area bounded by parabola y = x, st. line y = 4 and
y-axis is
(a)
(a) 1
(b) 6
(c) 0
(d) 3
r
r
r
B = 4i + 3j + 4k and C = i + aj + bk
If A = i + j + k,
r
are linearly dependent vector and C = 3 , then
x 2 + x - 12
(c)
16
3
(b)
64
3
(c)
(d) x = n
82.
2(2 x + 1)
2
(d) 0
7
p : Every quadratic equation has one real root and
q : Every quadratic equation has two real roots, then truth
value of p and q are
(a) p is true and q is false (b) p is false and q is true
(c) p and q both true
(d) p and q both false
If (a, b), (c, d), (e, f) are the vertices of a triangle such that a,
c, e are in G.P. with common ratio r and b, d, f are in G.P. with
common ratio s then the area of the triangle is
(a) 2
p
,n I
2
p
, n I
2
r r r r r r
r
r
The value of [A - B, B - C, C - A] where | A |= 1, | B |= 2
r
and | C |= 3 is
x -3
2
and
, g (x) =
x -3
x+4
4 3p
- a + sin 4 (3p + a )
The expression 3 sin
(a) 0
(b) 1
(c) 3
(d) sin 4a + cos6a
The general solution of the trigonometric equation
sin x cos x = 1 is given by
(a) x = 2n p, n I
If f(x) =
89.
(d) None
7 2
If for a real number y, [y] is the greatest integer less than or
3p / 2
90.
is
(a) p
(b) p
(c) p /2
(d) -p/2
2
If f(x) = ax + b, b 0 x 1;
= bx2 + ax + c, x > 1,
then f(x) is continuous and differentiable at x = 1 if
(a) c = 0, a = 2b
(b) a = b, c arbitrary
(c) a = b, c = 0
(d) a = b, c 0