acom
No 4-1985
High Temperature
Behaviour of the Austenitic
Stainless Steel
ASTM UNS S30815
(253 MA) and Weldments
by
A. Dhooge, Head of the Welding Research Dept, Research Center of the Belgian Welding Institute, Gent, Belgium,
W. Hoek, Materials Engineer at DOW CHEMICAL (Nederland) B.V., Terneuzen, The Netherlands,
W. Provost, Research Engineer at the WTCM-CRIF, Gent, Belgium, and
M. Steen, Research Engineer at the Laboratory Soete for Strength of Materials and Welding Technology,
University Gent, Belgium
Introduction
Materials used in high temperature installations are
subjected to severe loads, such as creep, mechanical
or thermal fatigue, thermal shock, environmental attack
and their interaction. In order to obtain a safe and
reliable operation, the selection of the base material,
weld metal and welding procedures is very important
and must be based on a complete knowledge of operating environment, loads, temperature and external
loading conditions together with sufficient test data of
the potential materials.
The weldments are the most critical areas, as they are
obvious sites for crack initiation and propagation.
A correct selection of welding procedures and consumables is therefore vital for the construction to reach
the design lifetime. In general, sufficient test data are
available on base metals, but there is a lack of information about the behaviour of weldments at elevated
temperatures.
2
In this paper some high temperature data on the fully
austenitic Cr-Ni-N-RE material 253 MA* (ASTM UNS
S30815) and weldments are presented. According to
the data of high temperature material vendors (1),
253 MA shows some interesting advantages over the
common high temperature materials AISI type 304H
(UNS S30409) and Alloy 800H (UNS N08810):
- higher creep-strength than AISI 304H (Figure 1)
- lower coefficient of thermal expansion than AISI type
304H (Figure 2)
- only about 60% more expensive than AISI type 304H
while Alloy 800H is about 2.5 times more expensive.
In the present paper, no attention is paid to the influence, of the environment on the materials' high temperature behaviour, although it is recognized that such
influences may be very important. Attention is given to
the weldability and high temperature tensile and creep
properties of the base material and manual metal arc
(MMA) weldments.
Figure 1
Elevated temperature properties of three austenitic high temperature materials (1)
Figure 2
Thermal expansion coefficient of three austenitic high temperature materials (1)
Test material
The test specimens are taken out of a 12 mm thick
fully austenitic Cr-Ni stainless steel plate 253 MA; its
chemical composition is given in Table 1. In addition to
the conventional alloying elements, this grade contains
rare-earth-metals, added in very small but carefully controlled amounts, and has a high silicon content in order
to provide good oxidation resistance and high creep
properties. Some nitrogen is added to make the steel
fully austenitic and which, together with the comparatively high carbon content, provides good high temperature strength.
For comparison some specimens of Alloy 800H are
taken out of plate material of 15 mm thickness; the
chemical composition is also given in Table 1.
% Mn
% Si
%S
%P
% Cr
% Ni
% AI
%N
Others
253 MA
0.090
0.56
1.52
0.001
0.024
20.80
11.20
0.179
0.05 Ce
Alloy 800H
0.084
1.05
0.37
0.002
0.004
19.28
31.13
0.23
0.34 Ti
Figure 3
Hot ductility test
Figure 4
Hot ductility results on cooling from TNS - 253 MA base
material
Weldment A
Welding procedures
Weld preparation
Weldment B
Welding sequence
Weldment C
Weld preparation
Weld preparation
Welding sequence
Welding sequence
Weldment B
Weldment C
Base material
Avesta 253 MA
Avesta 253 MA
Avesta 253 MA
Plate thickness
Filler material
12 mm
Coated electrode - 253 MA
( = 3.25 and 4 mm)
No
1.3 kJ/mm
12 mm
Coated electrode E309-16
12 mm
Coated electrode E310-16
No
1.3 kJ/mm
No
1.2 kJ/mm
Preheat
Heat input
Base material
Mn
Si
Cr
Ni
Ce
0.09
0.56
1.52
0.001
0.024
20.8
11.2
0.05
0.179
0.039
0.77
1.68
0.004
0.015
21.0
10.2
ND
ND
0.017
0.021
1.14
1.16
0.80
0.72
0.014
0.015
0.015
0.014
24.3
23.5
12.7
12.8
ND
ND
ND
ND
0.09
2.60
0.73
0.007
0.011
25.0
19.8
ND
ND
Weldment A
Deposited weld metal
Weldment B
Deposited weld metal 3.25
4.00
Weldment C
Deposited weld metal
Test
temp.
(C)
0.2%
Yield
strength
(N/mm2)
Ultimate
tensile
strength
(N/mm2)
Elongation
(%)
Reduction
in area
(%)
550
500
437
342
235
125
70
30.8
24.8
16.8
10.0
4.8
3.6
10.8
48.2
46.7
39.2
32.8
17.2
11.6
12.8
337
270
165
90
58
12.0
6.0
4.0
5.6
46.7
40.7
26.0
19.0
17.8
393
191
179
177
163
115
51
630
478
435
314
192
129
58
20.5
22.5
18.5
9.0
6.3
7.5
7.5
30.6
26.2
32.7
19.5
17.1
19.5
10.0
Weldment A:
400
500
600
700
800
900
1000
Weldment B:
600
700
800
900
1000
Weldment C:
20
500
600
700
800
900
1000
800
0.2%
Yield
strength
(N/mm2)
330
280
235
201
196
172
168
153
165
143
151
400
113
98
67
Ultimate
tensile
strength
(N/mm2)
715
653
603
597
593
555
498
465
365
378
229
242
118
161
61
Elongation
Reduction
in area
(%)
(%)
60.5
52.2
47.0
47.5
49.3
45.0
43.0
43.8
31.8
46.7
78.8
78.8
51.6
84.0
62.0
73.7
73.7
71.0
68.1
68.1
62.1
58.9
34.4
40.8
38.4
52.0
52.0
90.5
68.0
93.4
Figure 5
Tensile test results (Strength)
Figure 6
Tensile test results (Ductility)
Figure 7
LSRTT test specimen (dimension in mm)
Figure 8
Low strain rate tensile test curve
Figure 9
Creep curve
s (N/mm2)
10-5
10-6
10-7
10-8
150.2
109.0
68.3
45.8
Weldment A
10-5
10-6
10-7
10-8
165.0
128.1
87.7
63.2
Weldment B
10-5
10-6
10-7
10-8
140.6
104.0
88.7
48.9
10-5
10-6
10-7
10-8
97.0
78.3
51.2
37.9
Metallurgical stability
It is well known that austenitic stainless steels after
long-time exposure at high temperature (> 600C)
can give rise to sigma-phase formation. In the case of
253 MA, the formation of Pi-phase (Cr12Si12Fe4Ni2N4)
is also reported (1). These hard and brittle phases
usually adversely affect the mechanical properties,
particularly the impact strength at ambient temperature; the toughness at higher temperatures may remain
satisfactory.
Welded test plates (Weldment C) were artifically aged
up to 1000 hrs at 500, 600, 700, 800 and 900C, a
second series was aged up to 10,000 h at 550C only.
Subsequently, the mechanical properties were determined in conventional tensile testing at 20C and at the
ageing temperature; the room temperature toughness
was evaluated by means of Charpy-V notch impact
testing.
Figure 10
Low strain rate tensile test results at 800C
8
Figures 11 and 12 respectively show the room temperature strength and ductility after 1000 hrs ageing at the
above mentioned temperatures. Both base metal and
weld metal strength remain approximately constant
after ageing at all temperatures. Although the weld
metal has initially a lower ductility than the base metal,
comparable values are found when tested at room temperature after ageing at temperatures above 700C.
For the base metal, there is a significant decrease of
elongation and reduction in area after 1000 hrs ageing
at 700C; this loss of room temperature toughness,
which is most pronounced at 800C, is also observed
by impact testing (Figure 13).
Figure 14 shows the elevated temperature strength and
ductility after 1000 hrs ageing. Strength values for both
base metal and weld metal, when tested at the ageing
temperature, hardly deviate from the results of the
unaged base and weld metal (Figure 5), obtained previously.
With regard to ductility, the following trends are found:
a. after 1000 hrs ageing at temperatures above 600C,
an increase in the elevated temperature ductility of
the base material is observed.
Figure 11
Influence of 1000h ageing on the room temperature strength
Microstructural
and fractographic
examinations
(253 MA Base Material)
Figure 12
Influence of 1000h ageing on room temperature ductility
Figure 13
Influence of 1000h ageing on the Charpy V notch impact
strength at room temperature
Figure 14
Influence of 1000h ageing on the elevated temperature
strength and ductility of 253 MA base material (Test temperature = ageing temperature)
Figure 15
Influence of different ageing treatments on the room temperature impact strength
10
As received
1000h - 700C
1000h - 500C
1000h - 800C
1000h - 600C
1000h - 900C
Figure 16
Influence of artificial ageing on the microstructure of 253 MA
- x 400
A: x 250
C: x 400
B: x 550
D: x 2000
Figure 17
SEM-pictures - fracture surface of Charpy-V test specimen
artificially aged for 1000h at 700C
11
The microstructural evolution after ageing for 1000 hrs.
at different temperatures ranging from 500 to 900C is
shown in Figure 16. Precipitation of carbides is clearly
visible after ageing at 600C, the M23C6-carbides being
mainly located at grain boundaries and along the crystallographic planes of the matrix.
After 1000 hrs ageing at 800C a coalescence of precipitates was found. On the grain and twin boundaries,
Cr23C6-carbides, some Pi-phase and an almost continuous network of sigma-phase could be observed and
identified (Figures 18 and 19). The Pi-phase could be
discriminated from sigma-phase by EDAX-analysis from
a higher Si-content of the former. The fracture surface
shows an almost intergranular-ductile aspect with
locally some flat areas (Figure 20).
Figure 18
Optical micrograph - sigma-phase in 253 MA
after artificial ageing for 1000h at 800C etched
in INKOH
Figure 19
TEM-picture - carbon extraction replica from Charpy-V fracture surface (253 MA artificially aged for 1000h at 800C)
Fracture through sigma-phase x 10,500
A: x 570
B: x 1000
C: x 1600
D: x 6500
Figure 20
SEM-picture - fracture surface of Charpy-V test specimen
artificially aged for 1000h at 800C
12
A: x 150
B: x 600
C: x 775
D: x 3100
Figure 21
SEM-picture - fracture surface of Charpy-V test specimen
artificially aged for 1000h at 900C
A: 1000h at 550C
B: 10,000h at 550C
Figure 22
Influence of artificial ageing at 550C on the microstructure
- x 500
13
After ageing for 1000 hrs at 900C, coarse precipitates
are found at the grain and twin boundaries (coherent
and incoherent). The discontinuous network of precipitates on the grain boundaries could be clearly identified as sigma-phase by electron diffraction analysis.
SEM-investigations on the fracture surface show a combination of more ductile features (dimples) and intergranular decohesions (Figure 21).
Long time exposure (10,000 hrs) at 550C shows a
pronounced grain boundary and a slight twin boundary
precipitation (Figure 22B). The Charpy fracture surfaces show mixed intergranular and ductile features
(Figure 23). TEM-investigations on carbon-replicas
show the presence of only M23C6-carbides while no
embrittling phases, i.e. sigma or Pi, could be revealed
in this specimen (Figure 24).
A: x 570
Discussion
The fully austenitic stainless steels are generally sensitive to hot-cracking; however, the hot ductility tests
showed that 253 MA material in the as-received condition is not sensitive to the formation of heat-affectedzone hotcracks. Subsequent test welds with three
different types of coated electrodes confirmed this
result; indeed no welding problems such as (hot-)cracking were experienced.
253 MA base metal, in the as-received condition, has
a high strength at elevated temperature; short-time
elevated temperature tensile testing shows even better
results than given in the technical documentation. The
ductility at elevated temperatures remains on a high
level although in the temperature range 600-750C a
ductility dip was found. However, both reduction in area
and elongation are still acceptable (>30%) and superior to those of all investigated weld metals.
B: x 570
Figure 23
SEM-picture - fracture surface of Charpy-V test specimen
artificially aged for 10,000h at 550C (253 MA base metal)
-x 570
Figure 24
TEM-picture - carbon extraction replica from Charpy-V fracture surface (253 MA artificially aged for 10,000h at 550C)
-x 3900
14
Limitations in application will be imposed by the low
ductility at elevated temperatures of the weld metal, if
a 309, 310 or a matching type of filler metal is used.
After ageing for 1000 hrs at several temperatures, the
room temperature and high temperature strength of
base metal and weld metal are almost unaffected.
However, the room temperature ductility of base and
weld metal has strongly decreased after ageing at
temperatures above 550C and most importantly at
800C; where low figures for ductility (15%) and absorbed energy (10 Joule) are obtained.
The room temperature embrittlement after ageing at
temperatures of 700, 800 and 900C can be attributed
to the formation of sigma phase which leads to mainly
intergranular fractures. Also Cr23C6-carbides were
formed and found along the grain boundaries and those
will also contribute to the embrittlement. This is
evidenced by the fact that a serious loss of impact
strength due to M23C6 precipitation only, is found after
extended ageing at 550C.
Other embrittling phases such as Pi-phase are found
in very small amounts after ageing at 800C only.
From these observations it is possible to summarize
the effect of ageing on the room temperature impact
strength in a time-temperature diagram (fig. 25). In this
diagram an "iso-embrittlement" corresponding to a
room temperature impact value of 30-50 J can be
drawn. It should be noted that this "embrittlement" is
found after ageing times as low as 100 hours and not
only after ageing for over 2000 hours (5). An interesting
feature is the stability of impact strength (about 50-60
Joule) after ageing between 10 and 1000 h at 900C.
Although sigma-phase is known to be present, the room
temperature impact strength remains relatively high;
coalescence of sigma-phase and a discontinuous network was found. These features seem to be very beneficial for the room temperature toughness. Because of
this, a further decrease in room temperature impact
strength and toughness is not expected, even after
longer exposure times.
Conclusions
1. The fully austenitic stainless steel UNS S30815
(253 MA) is not sensitive to heat affected zone hotcracking.
2. In high temperature applications i.e. 500 to 900C.
room temperature embrittlement due to sigmaphase formation should be taken into account.
3. At 800C, the creep strength of 253 MA is superior
to AISI type 304H and even better than that of the
tested Alloy 800H (solution annealed at 1150C).
Figure 25
Time-temperature diagram (Influence of ageing) encircled
numbers are impact values (J) at room temperature
15
Acknowledgments
References
acom 4-85
to Dr. Sten Nordin, Avesta Projects AB, P.O. Box 557, S-651 09 KARLSTAD, Sweden