Chemical Reaction:
CH3
150C 270C
+ 3O2
CH3
COOH
------------------------->
1500kPa 3000kPa
+ 2H2O
COOH
OVERALL BALANCE:
Basis: 2 x 105 Kg of Terephthalic acid
Assume working plant days = 300 days
Given:
Purity of Product - 99%
Conversion
- 95%
Solvent
- 0.05 Kg / Kg of product
O2
Feed:
From the chemical equation 1 Kmole of p-Xylene = 1 Kmole of
Product
But given that conversion is 95%
Therefore 1 Kg mole of p- xylene = 0.95 of Terephthalic acid
Therefore amount of p-Xylene reqd. = 3975/0.95 = 4185 Kmoles
Unconverted Feed = 0.05 x 4185 = 209.25 Kmoles
Air:
1 Kmole of p-Xylene = 3 Kmoles of Oxygen
Therefore theoretical amount of Oxygen reqd. = 4185 x 3 = 12555 Kmoles
Kmoles
Kg x 10-3
p-Xylene
4185
443.610
Acetic Acid
555.55
33.333
Air
68763.1
1983.12
3
Total : 2460.06 x 10 Kg
OUTLET:
Component
p-Xylene
Kmoles
209.25
Kg x 10-3
Acetic Acid
555.55
33.333
Water Formed
7950
143.10
Air(N2+O2)
56835
1601.21
Terephthalic acid
3975
659.859
22.18
Surge Tank:
INLET:
Kg x 10-3
Component
Kmoles
p-Xylene
209.25
22.18
Acetic Acid
555.55
33.333
Water Formed
7950
143.10
Terephthalic acid
3975
659.859
Total: 858.472 x 103 Kg
OUTLET:
Component
p-Xylene
Kmoles
209.25
Kg x 10-3
Acetic Acid
555.55
33.333
Water Formed
7950
143.10
Terephthalic acid
3975
659.859
22.18
Kmoles
209.25
Kg x 10-3
Acetic Acid
555.55
33.333
Water Formed
7950
143.10
Terephthalic acid
3975
659.859
22.18
ii.
Kmoles
926.37
Kg x 10-3
Terephthalic acid
3975
659.85
16.67
Total: 676.52 x 103 Kg
OUTLET:
Component
Water
Kmoles
370.55
Kg x 10-3
Terephthalic acid
3975
659.85
6.67
Residue Still:
INLET:
Component
p-Xylene
Kmoles
209.25
Kg x 10-3
Acetic Acid
555.55
33.333
Water Formed
7023.63
126.42
22.18
OUTLET:
p-Xylene is a heavy key and hence in trace amounts in the distillate.
From the data, it is given that about 80 95 % of acetic acid is recovered hence assume
that 5% (mole) goes in the residue stream and about 10% (mole) of water entering goes in
the residue.
Component
p-Xylene
22.18
Acetic Acid
31.66
1.66
Water Formed
113.77
12.64
Total : 181.933 x 103 Kgs
Dehydration Tower:
INLET:
Acetic Acid : 0.527 X 103Kmol
Water
: 6.3207 X 103Kmol
XF = 0.923 ,
XD = 0.998 ,
Xw = 0.012 , - From Perrys Handbook / Acetic Acid Water Properties
F XF = D XD + W XW
W (Residue) = 0.527 X 103 Kmol
D (Distillate) = 6.3062 X 103 Kmol
F= (0.527 + 6.307) X 103 = 6.834 X 103 Kmol
Acetic-Acid recycled back to reactor 95% recover