Safety data sheet

Page: 1/10
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

1. Identification of the substance/mixture and of the company/undertaking

Glysantin G 05-23
Use: engine coolant
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Contact address:
BASF plc
PO Box 4, Earl Road, Cheadle Hulme, Cheadle, Cheshire
SK8 6QG, UNITED KINGDOM
Telephone: +44 161 485-6222
Telefax number: +44 161 488-4274
E-mail address: product-safety-north@basf.com
Emergency information:
International emergency number:
Telephone: +49 180 2273-112

2. Hazards Identification
According to REGULATION (EC) No 1272/2008 on classification, labelling and packaging of
substances and mixtures
Label elements and precautionary statement:
Pictogram:

Signal Word:
Warning
Hazard Statement:
Harmful if swallowed.

Page: 2/10
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

Precautionary Statements (Prevention):

Do no eat, drink or smoke when using this product. Wash with plenty of water and soap thoroughly
after handling.
Precautionary Statements (Response):
Call a POISON CENTER or doctor/physician if you feel unwell. IF SWALLOWED: rinse mouth.
Precautionary Statements (Disposal):
Dispose of contents/container to hazardous or special waste collection point.
Classification of the substance and mixture:
Acute toxicity: Cat. 4 (oral)

Possible Hazards (according to Directive 67/548/EWG or 1999/45/EC)

Harmful if swallowed.

3. Composition/Information on Ingredients
Chemical nature
ethyleneglycol, inhibitors
This product contains (a) substance(s) included on the candidate list according to article 59 (1,10) of
regulation EC No. 1907/2006 ('REACH') in a concentration above 0.1% w/w: disodium tetraborate
pentahydrate; borax pentahydrate
Hazardous ingredients (GHS)
according to Regulation (EC) No. 1272/2008
ethyleneglycol
Content (W/W): 85 % - 95 %
CAS Number: 107-21-1
EC-Number: 203-473-3
INDEX-Number: 603-027-00-1
sodium nitrite
Content (W/W): > 0.1 % - < 0.5 %
CAS Number: 7632-00-0
EC-Number: 231-555-9
INDEX-Number: 007-010-00-4

Acute tox.: Cat. 4 (oral)

Ox. Sol.: Cat. 2

Acute tox.: Cat. 3 (oral)
Eco acute: Cat. 1

disodium tetraborate pentahydrate; borax pentahydrate

Content (W/W): >= 1 % - <= 2 %
Eye dam./irr.: Cat. 1
CAS Number: 12179-04-3
Repro.: Cat. 1B (fertility)
INDEX-Number: 005-011-02-9
Repro.: Cat. 1B (unborn child)

Hazardous ingredients
according to Directive 1999/45/EC

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

ethyleneglycol
Content (W/W): 85 % - 95 %
CAS Number: 107-21-1
EC-Number: 203-473-3
INDEX-Number: 603-027-00-1
Hazard symbol(s): Xn
R-phrase(s): 22
sodium nitrite
Content (W/W): > 0.1 % - < 0.5 %
CAS Number: 7632-00-0
EC-Number: 231-555-9
INDEX-Number: 007-010-00-4
Hazard symbol(s): O, T, N
R-phrase(s): 8, 25, 50
disodium tetraborate pentahydrate; borax pentahydrate
Content (W/W): >= 1 % - <= 2 %
CAS Number: 12179-04-3
INDEX-Number: 005-011-02-9
Hazard symbol(s): T, Xi
R-phrase(s): 60, 61, 41
The wording of the hazard symbols and R-phrases is specified in chapter 16 if dangerous ingredients
are mentioned.

4. First-Aid Measures
General advice:
Remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Administer 50 ml of
pure ethanol in a drinkable concentration.
Note to physician:
Treatment: Symptomatic treatment (decontamination, vital functions).

Page: 4/10
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

5. Fire-Fighting Measures
Suitable extinguishing media:
dry powder, alcohol-resistant foam, water spray, carbon dioxide
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

6. Accidental Release Measures

Personal precautions:
Use personal protective clothing.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Methods for cleaning up or taking up:
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.
Additional information: High risk of slipping due to leakage/spillage of product.

7. Handling and Storage

Handling
Ensure thorough ventilation of stores and work areas. Shut containers immediately after taking product
because product takes up the humidity of air.
Protection against fire and explosion:
No special precautions necessary.
Storage
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage in galvanized containers is not recommended.

8. Exposure Controls/Personal Protection

Components with workplace control parameters

Page: 5/10
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

Refer to the current edition of HSE Guidance Note EH40 Occupational Exposure Limits (United
Kingdom).
107-21-1: ethyleneglycol
TWA value 52 mg/m3 ; 20 ppm (OEL (EU))
indicative
STEL value 104 mg/m3 ; 40 ppm (OEL (EU))
indicative
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
TWA value 10 mg/m3 (EH40 (UK)), Particulate
TWA value 52 mg/m3 ; 20 ppm (EH40 (UK)), vapour
STEL value 104 mg/m3 ; 40 ppm (EH40 (UK)), vapour
Skin Designation (EH40 (UK)), Particulate
The substance can be absorbed through the skin.
Skin Designation (EH40 (UK)), vapour
The substance can be absorbed through the skin.

Personal protective equipment

Respiratory protection:
Respiratory protection in case of vapour/aerosol release.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
nitrile rubber (NBR) - 0.4 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
General safety and hygiene measures:
Do not inhale gases/vapours/aerosols. Handle in accordance with good industrial hygiene and safety
practice. Wearing of closed work clothing is recommended.

9. Physical and Chemical Properties

Form:
Colour:
Odour:

liquid
according to specification
product specific

solidification temperature:
approx. -15 C
boiling temperature:
> 160 C

(DIN ISO 3016)

(ASTM D1120)

Flash point:
Lower explosion limit:
Upper explosion limit:

(DIN 51758)

> 100 C
3 %(V)
15 %(V)

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

Ignition temperature:

> 200 C

Vapour pressure:

approx. 2 mbar
(20 C)

Density:

1.132 g/cm3
(20 C)

(DIN 51794)

Miscibility with water:

miscible in all proportions
Solubility (qualitative) solvent(s): polar solvents
soluble
Viscosity, kinematic:

20 - 30 mm2/s
(20 C)

(DIN 51562)

10. Stability and Reactivity

Substances to avoid:
strong oxidizing agents
Hazardous reactions:
The substance/product may react with secondary and tertiary amines to form nitrosamines.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information

Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 2,000 mg/kg

Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant
Serious eyes damages/irritation rabbit: non-irritant

Carcinogenicity
Information on: sodium nitrite
Assessment of carcinogenicity:
Under certain conditions the substance can form nitrosamines. Nitrosamines are carcinogenic in
animal studies.
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Page: 7/10
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

Developmental toxicity
Information on: Ethane-1,2-diol
Assessment of teratogenicity:
Developmental toxicity was observed after oral ingestion of high doses in studies with rats and mice,
but this effect was not seen in a study with rabbits.
----------------------------------

Experiences in humans
Information on: Ethane-1,2-diol
Experimental/calculated data:
mean lethal dose: 1.2 - 1.5 g/kg , oral, Adults
consciousness is affected, kidney damage, Damage to the central nervous system:
The symptoms/diagnosis/findings mentioned may result with smaller doses.
----------------------------------

Other relevant toxicity information

The statements are based on the properties of the individual components.
Information on: Ethane-1,2-diol
There is no reason to fear a risk of damage to the developing embryo or fetus when the MAK value is
adhered to.
Skin resorption hazard. The whole of the information available provides no indication of a carcinogenic
effect.
----------------------------------

12. Ecological Information

Ecotoxicity
Toxicity to fish:
LC50 (96 h) > 100 mg/l, Leuciscus idus
Aquatic invertebrates:
EC50 (48 h) > 100 mg/l, Daphnia magna
Aquatic plants:
EC50 (72 h) > 100 mg/l, algae
Microorganisms/Effect on activated sludge:
Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction
of low concentrations.

Persistence and degradability

Elimination information:
> 70 % DOC reduction (OECD 301 A (new version)) Readily biodegradable.

Page: 8/10
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

Other adverse effects

Adsorbable organically-bound halogen (AOX):
This product contains no organically-bound halogen.

Additional information
Other ecotoxicological advice:
The product has not been tested. The statement has been derived from the properties of the individual
components.
Do not release untreated into natural waters.

13. Disposal Considerations

Must be dumped or incinerated in accordance with local regulations.
The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted
(United Kingdom).
This product and any uncleaned containers must be disposed of as hazardous waste in accordance
with the 2005 Hazardous Waste Regulations and amendments (GB)

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.

14. Transport Information

Land transport
ADR
Not classified as a dangerous good under transport regulations
RID
Not classified as a dangerous good under transport regulations

Inland waterway transport

ADNR
Not classified as a dangerous good under transport regulations

Sea transport
IMDG

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

Not classified as a dangerous good under transport regulations

Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations

15. Regulatory Information

Regulations of the European union (Labelling) / National legislation/Regulations
Directive 1999/45/EC ('Preparation Directive'):
Hazard symbol(s)
Xn

Harmful.

R-phrase(s)
R22

Harmful if swallowed.

S-phrase(s)
S2
S24/25
S46

Keep out of the reach of children.

Avoid contact with skin and eyes.
If swallowed, seek medical advice immediately and show this container
or label.

Hazard determining component(s) for labelling: ETHANE-1,2-DIOL/ETHYLENEGLYCOL

Other regulations
This product is classified under the Chemicals (Hazard Information and Packaging) Regulations,
(CHIP) (United Kingdom).
The data should be considered when making any assessment under the Control of Substances
Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials'
(United Kingdom).

16. Other Information

Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 3:
Xn
Harmful.
O
Oxidizing.
T
Toxic.
N
Dangerous for the environment.
Xi
Irritant.
22
Harmful if swallowed.
8
Contact with combustible material may cause fire.
25
Toxic if swallowed.

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 28.06.2010
Product: Glysantin G 05-23

Version: 3.0
(30062852/SDS_GEN_GB/EN)
Date of print 27.05.2011

50
60
61
41

Very toxic to aquatic organisms.

May impair fertility.
May cause harm to the unborn child.
Risk of serious damage to eyes.

Vertical lines in the left hand margin indicate an amendment from the previous version.
If you have any queries relating to this MSDS, it's contents or any other product safety related questions,
please write to the following e-mail address: product-safety-north@basf.com
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of
the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.