liquid water
The H bonds are 'forced' to be longer in ice, due to the rigid lattice structural arrangement in solid ice.
No such rigid lattice arrangement occurs in liquid water, which means closer proximity, and therefore
shorter (hence stronger) H bonds, are possible for liquid water.
The difference in lengths of the H bonds in solid vs liquid water, is unlikely to be part of the Cambridge
mark scheme (at least for the Singapore syllabus). The exact H bond length in solid ice, also depends on
the exact cystalline form of ice, for which over a dozen different forms have been identified.
The so-called 'open structure' of ice, refers to the fact that there are lots of empty (or 'open') spaces
between the H2O molecules in solid ice. In contrast, there is very little empty space between H2O
molecules in liquid water.
Why? Because H2O molecules are forced to spread apart with some distance between them, in the fixed
lattice (ie. regular repeating patterns) crystalline structures in solid ice (analogy : 100 disciplined soldiers
doing a weapons precision drill parade, would have to keep some distance apart from each other and
occupy a huge space in an open field), while in the liquid state, the H2O molecules are milling in close
contact with each other, with no fixed lattice structure (analogy : 100 frenzied women now squeezing
chaotically at some super discount sale in some small clothes/shoes departmental store).
This is the reason why solid ice is less dense than liquid water.
The toxic Ba2+(aq) is thus freed from the solid BaCO3(s) lattice structure, and available to do its
merciless, murderous, lethal work coursing through the arteries and veins of the helpless rodent, who
will soon experience multiple organ failure and die a terrible, excruciating, shrieking, convulsive, woeful
death. The counter anion for the Ba2+(aq) ion, would be the Cl-(aq) ions of the HCl(aq) acid in the rat's
stomach.