CHEMISTRY

1.

What will be the % of N2H4 that has reacted with water in solution, when 0.32 gm of N 2H4 are
dissolved in water and the total volume was made 4L (given kb for N 2H4= 6 10-8 m)
(A) 3 %
(B) 3.6 %
(C) 2 %
(D) 0.489%

2.

The reaction A + B
C + D is studied in one liter vessel at 250 0C. The initial
concentration of A was 3n and that of B was n. When equilibrium was attained equilibrium
concentration of C was found to be equal to the equilibrium concentration of B then
concentration of D at equilibrium will be
1
n
(A)
(B) 3n
2
2
(C) n

n
2

(D) n

3.

Which of the following behaviour is true for an ideal binary liquid solution.
(A) plot of Ptotal v/s 1/YA (mole fraction of A in vapour phase) is linear.
(B) plot of Ptotal v/s 1/YB is linear.
(C) plot of 1/Ptotal vs 1/YA is linear.
(D) plot of Ptotal v/s 1/(YA) is linear.

4.

For the reaction N2O4 (g)

2NO2 (g) the relation connecting the degree of dissociation
( ) of N2O4 (g) with the equilibrium constant K p is
Kp / p
Kp
(A) =
(B) =
4 Kp / p
4 Kp
(C)

5.

Kp / p
4

Kp / p

1/ 2

(D)

Kp
4

1/ 2

Kp

A metal crystallizes into two cubic faces (FCC) and (BCC) whose unit cell lengths are 3.5
0

A and 3.0 A respectively. The ratio of densities of FCC and BCC will be
(A) 1.26
(B) 3.14
(C) 2.18
(D) 4.26
6.

An organic compound crystallises in an orthorhombic system with two molecules per unit
0

cell. The unit cell dimensions are 12.05, 15.05 and 2.69 A . If the density of the crystal is
1.419 g cm-3, then molar mass of compound will be
(A) 207 g mol-1
(B) 209 g mol-1
-1
(C) 308 g mol
(D) 317 g mol-1
7.

50gm of saturated aqueous solution of potassium chloride at 30 0C is evaporated to dryness,

when 13.2 gm of dry KCl was obtained. The solubility of KCl in water at 30 0C is
(A) 35.87 g
(B) 25.62 g
(C) 28.97 g
(D) 27.81 g

8.

235
92U

9.

According to Bohrs theory the energy required for an electron in He + ion to be emitted from
n = 2 state is
(A) 10.2 eV
(B) 13.6eV
(C) 3.4 eV
(D) 27.2 eV

10.

One mole of potassium dichromate completely oxidises which of the following number of
mole(s) of ferrous oxalate in acidic medium.
(A) 1
(B) 4
(C) 2
(D) 6

11.

An alkane C5H12 gives only one monochloro substitution product. It is

(A) 2,2-dimethyl propane
(B) 3-methyl pentane
(C) Isopentane
(D) Either of these

12.

A chemist wishes to prepare a buffer solution of pH = 2.90 that efficiently resists a change in
pH yet contains only small concentration of buffering agent. Which one of the following weak
acid along with its salt would be best to use.
(A) m-clolorobenzoic acid (pKa = 3.98)
(B) Acetoacetic acid (pKa = 3.58)
(C) 2, 5-dihydroxybenzoic acid (pKa = 2.97) (D) p-chlorocinnamic acid (pKa= 4.41)

13.

C - Cl bond of cholorobenzene in comparision to C - Cl bond of methyl chloride is

(A) longer and weaker
(B) Shorter and stronger
(C) Shorter and weaker
(D) Longer and stronger

14.

Which of the following is not soluble in sodium carbonate solution

belongs to group III B of periodic table. If it loses one -particle, then the new element
will belong to group.
(A) I B
(B) III B
(C) II B
(D) IV B

OH

COOH

NO 2

O 2N

(A)

(B)
NO 2
SO 2OH

(C)

OH
NO 2

(D)

15.

The ion which when added to silver nitrate does not produce a precipitate.
(A) I
(B) F
(C) CrO42
(D) CO32

16

The first five ionization energies of an element are respectively 801, 2428, 3661, 25033 and
32836 in KJ/mol then the element could be
(A) A halogen
(B) A third group element
(C) A noble gas
(D) A second group element

17.

The cumulated alkadiene is

(A)

(B)
(D)

(C)

18.

The dipole moments of diatomic molecules AB and CD are 10.41 and 10.27 Debye
0

respectively while their bond distances are 2.82 & 2.67 A , respectively. Then
(A) Bonding is nearly covalent in both the molecules.
(B) Bonding is 100% ionic in both the molecule.
(C) AB has more ionic character than CD.
(D) AB has lesser ionic bond character than CD.
19.

For the gas phase decomposition, A

2B, the rate constant is 6.93
The percentage of A remaining at the end of 300 minutes is
(A) 75
(B) 50
(C) 25
(D) 12.5

20.

Out of
1.

2.

CH 3O

CH 2

3.

CH 2

4.
H3C

CH 2

Relative stabilities order are

(A) 4 < 2 < 3 < 1
(C) 4 < 2 < 1 < 3

CH3CH2

(B) 2 < 4 < 3 < 1

(D) 2 < 4 < 1 < 3

21.

Kw(H2O) at 250C is 1 10-14. Dissociation constant of

2H2O
H3O+ + OH is
-16
(A) 1.8 10
(B) 10-14
(C) 55.5
(D) 18

22.

For an ideal gas a plot of (PV/RT) v/s T will look like

PV

(A)

PV

(B)

RT

RT

T
T

PV

(C)

PV

(D)

RT

RT

T
T

10-3 min-1 at 300K.

23.

The pairs of compounds which cannot exist together in solution is

(A) NaHCO3 and NaOH
(B) Na2CO3 and NaOH
(C) Na2CO3 and NaHCO3
(D) NaHCO3 and NaCl

24.

The hydration energy of Mg2+ is greater than

(A) Al3+
(B) Na+
2+
(C) Be
(D) Mg3+

CH2

*
CH2

CH

AlCl 3

100.

OH
(A)

OH
CH2
*

CH

CH2
*

CH

CH2
*

CH2

CH

CH2

(B)

OH
(C)

26.

CH2
(D)

none

The reaction of

H3CHC

CH

OH

with HBr gives

(A)

CHCH3 CH2

OH

(B) CH3

CH2 CH
Br

Br
(C) H3C

HC

CH2

Br

(D)

CH3CH2

CH

Br

Br

Br

27.

OH

The structure shows

CH 3

H
C

H3C

H
COOH
CH3

(A) geometrical isomerism

(C) geometrical and optical isomerism
28.

(B) optical isomerism

(D) tautomerism

The standard reduction potential values of three metallic cations X, Y & Z are 0.52, -3.03 and
-1.18 V respectively. The order of reducing power of corresponding metals is
(A) Y > Z > X
(B) X > Y > Z

(C) Z > Y > X

(D) Z > X > Y

29.

14

C6 is a beta active nucleus. A sample of 14CH4 gas kept in a closed vessel shows
increase in pressure with time. This is due to the
(A) formation of 14NH3 and H2
(B) formation of 11BH3 and H2
14
(C) formation of C2H4 and H2
(D) formation of 12CH3, 14NH2 and H2

30.

pKa (NH4+) = 9.26. 500 mL of 0.01 M NH4OH solution will have pH = 8.26 if X mol of
(NH4)2SO4 is added. X is
(A) 005 mol
(B) 0.005 mol
(C) 0.025 mol
(D) 0.10 mol

31.

If the solubility of calcium phosphate (mol. Wt = M) in water at 25 0C is w gm/100 mL, its

solubility product at 25 0C is
(A) 109

w
M

(C) 105

w
M

(B) 107

w
M

(D) 103

w
M

32.

Among the following the compound that is both coloured and paramagnetic is
(A) K2Cr2O7
(B) (NH4)2[TiCl6]
(C) VOSO4
(D) K3[Cu(CN)4]

33.

The Cl C Cl bond angle in 1, 1, 2, 2 tetrachloro ethene and tetrachloro methane

respectively will be about
(A) 1200 and 109.50
(B) 900 and 109.50
0
0
(C) 109.5 120
(D) 109.50 and 900

34.

Which halide is not oxidized by MnO 2?

(A) F
(C) Cl

35.

(B) Br
(D) I

Which of the following would readily give Tollens test?

(A)

CH3

H2C
O

CH3
O

(B)

CH3

C
O

O
(C)

36.

37.

OH

Ozonolysis of
gives
(A) Butane-1-4-dione
(C) Butanoic acid

O
(D)

OCH 3

(B) Butane-1-4-dial
(D) none

3-methyl-2-pentene on reaction with HOCl gives

CH3

(A)

CH2CH3

Cl

OH

CH

CH3

(B)

CH3

CH3

(C)

CH3 H2C

CH3

OH

CH

CH3

CH3

Cl

Cl

CH3

CH3

(D) CH3

CH2

OH

Cl

CHCH 3

CH3

38.

30 gm AgNO3 is added with 0.37 mole of KCl. The no. of moles of ppt produced will be
[atomic wt. of Ag = 108]
(A) 0.37
(B) 0.1765
(C) 0.2572
(D) 0.739

39.

What is the equivalent weight of MnO 2 when it reacts with dil. HCl and liberates Cl2 gas
[atomic weight of Cl = 35.5, Mn = 55]
(A) 43.5
(B) 87
(C) 21.75
(D) none of these

40.

Oxidation no. of chlorine atoms in Ca(OCl)Cl

(A) 1
(B) +1, 1
(C) 0
(D) 1, 0

41.

Which of the following elements is Nobel metal?

(A) Au
(B) Cu
(C) K
(D) Zn

42.

Which of the following has maximum bond energy?

(A) C = C
(B) C = O
(C) O = O
(D) N = O

43.

The value of kP for the following reaction is 2 atm-1 at 600 K. The steady pressure of oxygen
such that equal number of moles of poly atomic gases are present at steady state is
(A) 2 atm
(B) 1 atm
(C) 0.25 atm
(D) 0.5 atm

44.

At equilibrium if kP = 1, then
(A) G0 > 1
(C) G0 = 0

(B) G0 < 1
(D) G0 = 1

45.

If LPG cylinder contains mixture of butane and isobutane, then the amount of oxygen that
would be required for combustion of 1 kg of it will be
(A) 2.5 103 g
(B) 4.5 kg
(C) 1.8 103 kg
(D) 3.58 103 g

46.

The bond angle around the central atom is highest in

(A) SO2
(B) BBr3
(C) CS2
(D) SF4

47.

At room temperature the reaction between NO and O 2 to give NO2 is fast while that of
between CO and O2 is slow. It is because
(A) the intrinsic energy of the reaction 2NO + O 2
2NO2 is less
(B) CO is smaller is size than that of NO
(C) CO is poisonous
(D) the activation energy for the reaction 2NO + O2
2NO2 is less

48.

Zinc is used to protect iron from corrosion because

(A) Ered of Zn < Ered of iron
(B) Eoxidation of Zn < Eoxidation of iron
(C) Eoxidation of Zn = Eoxidation of iron
(D) Zn is cheaper than iron

49.

In neighboring group participation mechanism, the intermediate formed is

(A) a carbocation
(B) carbanion
(C) cyclic intermediate
(D) both (A) and (C)

50.

What will be the product of the following reaction

CF 3
CH2CH2CH3
CH3 CH 2 CH 2 Cl
FeCl3

CF3

CF3

CH2CH2CH3

(A)

(B)

CH2CH2CH3
CF3

(C)

CH(CH 3)2

CF3

(D)
CH(CH 3)2