Rt-SUMt:
A B S T R A C T
1. INTRODUCTION
Edi:~al not~
A~iiihworks::a:theD e p ~ m of CivilEngi~e~ngi:
Uni:ersi~deSher~w~k~Canada,
0025-5432/98 9 R_ILEM
111
Neville, ARcin
Mix
(kg/m3)
Portland cement
Silica fume
Fly ash
Slag
Fine aggregate
Coarse aggregate
Total water
534
40
59
5OO
3O
315
36
513
43
163
54
228
46
425
40
623
1069
139
7O0
1100
143
137
745
1130
150
685
1080
139
325
730
1100
755
1045
136
182
800
1110
138
0.22
0.27
0.31
0.25
0.25
0.30
255
200
220
13
19
72
114
62
105
126
136
121
126
Water/cementitious
material ratio
Slump, mm
4s0
45
460
175~
736
1118
143
78O
1080
138
0.38
0.29
0.30
230
230
110
35
36
68
111
83
Cylinderstrength
(MPa) at age (days)
I
2
7
28
56
91
365
93
83
65
91
119
107
93
145
67
95
124
105
89
* Further inJbrmationabout the mixes: (A) United States; (B) Canada; (C) Canada; (D) United States; (El} Canada; (F) Canada; (G) Morocco; (H) France;
(I) Canada.
t It is suspected that the h{qh water content was occasionedby a high ambient temperature in Morocco.
because the relative volume of the space originally occupied by water determines the total volume of solid matter in the hardened concrete. In very general terms, the
higher the volume of the solid matter, the higher the
compressive strength [5]. It follows that, with high performance concrete, just the same as with ordinary concrete, strength at, say 28 days, is a function of the
water/cement ratio. By this time, slag will have reacted
to a significant extent and fly ash somewhat less so;
however, the extent of the reaction of fly ash is very sensitive to the effectiveness of curing.
But what is the situation at 24 hours or at two or
three days? Fly ash and, to a lesser extent, slag occupy
only the volume represented by their original, that is dry
powder, form. It follows that the water/cement ratio relevant to the very early strength is approximately the mass
ratio of water to the Portland cement only. This ratio is
much higher than the ratio of the mass of water to the
mass of all the cementitious materials taken together.
This is why the inclusion of fly ash or slag, at a given
water content in the mix, leads to a lower very early
strength. The preceding statement is true not only for
high performance concrete but for all concrete mixes.
4. COMPATIBILITY OF PORTLAND
CEMENT AND SUPERPLASTICIZER
At the beginning of the paper, we said that high performance concrete does not require a special cement and
that usually a Type I Portland cement is used. The
problem is that the cement and the superplasticizer must
be suited to one another, that is, there must be no
incompatibility between the two materials. This needs
to be explained at some length.
First of all, we should re-state how a superplasticizer
acts so as to give the concrete a high workability.
Superplasticizers are long and heavy molecules, which
wrap themselves around the cement particles and give
them a highly negative electrical charge so that they
repel each other. This results in a deflocculation and
dispersion of the cement particles and, therefore, in a
higher workability of the mix. The fundamental structure of the hydrated cement paste is not affected, but
superplasticizers interact with tricalcium aluminate
(C3A) in the Portland cement. We should remember
that CBA is the first component of cement to hydrate,
and this reaction is controlled by the gypsum added in
the manufacture of Portland cement.
We have thus a situation such that both the superplasticizer and the gypsum can react w i t h C3A.
Although a certain amount of superplasticizer is necessary during mixing in order to achieve an adequate
workability, it is essential that all the superplasticizer
does not become fixed by C3A. Such fixing would
occur if the gypsum does not release the sulfate ions fast
enough to react with C3A. When the sulfate ions are
released too slowly, the Portland cement and the superplasticizer are said to be incompatible.
Thus, in practice, the controlling factor is the solu-
114
Neville, ARcin
Neville, Aitcin
native materials.
One such material is rice husks, appropriately
processed so as to produce a very fine powder with a
high silica content. Rice husks are plentiful in many
countries, but in the majority of those countries, the
transportation and processing facilities are poor. On the
other hand, the demand for a high quality, very fine pozzolanic material is mainly in the industrialized countries.
There is thus a mismatch. However, this is likely to be
resolved by technology transfer, and one large cement
manufacturer is already involved in developing appropriate facilities for rice husk processing in Asia.
Superplasticizers are also expensive because of the
high cost of producing long and heavy molecules, but
there, too, ways of reducing cost are possible. For example, superplasticizers have been diluted with lignosulfonate water reducers, which are cheaper. This situation
is, however, changing because modern paper mills use a
technology that does not yield usable lignosulfonates as a
by-product or produces lignosulfonates with so many
impurities that they cannot be used as water reducers in
concrete. No doubt, human ingenuity will find a way of
producing reasonably-priced, highly effective water
reducers.
Nevertheless, the cost of what we have called 'good
concrete' is likely to be higher than the cost of presentday concrete with a high water/cement ratio. This concrete, however, is not durable, and consequently often
requires repairs, then repairs to the repairs, and possibly
replacement. All this costs money, although the initial
cost and the cost of repairs and maintenance may come
from different purses. It is logical to look at the lifecycle cost, and we are beginning to use this approach.
Once the value of life-cycle costing is fully appreciated,
we shall, in the main, be producing good concrete.
Concrete, good, bad, or indifferent, has been the leading construction material for nearly a century. At the present time, in the world as a whole, it is used at an annual
rate of 1 cubic metre or 2 1/2 tonne per capita. There is no
economically viable competitor in sight. We can therefore
expect that high performance concrete, or just good concrete, will serve the world for a long time to come.
117
REFERENCES
[1] Bramforth, P.B., 'In situ measurement of effect of partial Portland
cement replacement using either fly ash or ground granulated
blast furnace slag on the performance of mass concrete', Proc. Inst.
Cir. Engineers, Part 2 (September, 1980) 777-800.
[2] Neville, A.M., 'Concrete technology - an essential element of
structural design', ConcreteInternational (1998).
[3] Aitcin, P.-C., 'High Performance Concrete', 1st edn (E & FN
Sport, 1998).
[4] Neville, A.M., 'Aggregate bond and modulus of elasticity', A C I
MaterialsJournal 4 (1) (1997) 71-74.
[5] Neville, A.M., 'Properties of Concrete', 4th edn (Longman, 1995
and John Wiley, 1996).
[6] Aitcin, P.-C., Neville, AM., and Acker, P., 'Integrated view of
shrinkage deformation', ConcreteInternational 19 (9) (1997) 35-41.
[7] Pigeon, M., Pleau, R., 'Durability of Concrete in Cold Climates',
1st edn (E & FN Sport, 1995).