Fundamentals of
Thermodynamics
SOLUTION MANUAL
CHAPTER 12
8e
PROB NO.
a-f
1-15
16-33
34-43
44-59
60-81
82-120
121-133
134-138
139-148
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Tr
Pr
Zf
Zg
d(h/RT)f
d(h/RT)g
d(s/R)f
d(s/R)g
0.96
0.78
0.14
0.54
3.65
1.39
3.45
1.10
0.94
0.69
0.12
0.59
3.81
1.19
3.74
0.94
0.92
0.61
0.10
0.64
3.95
1.03
4.00
0.82
0.90
0.53
0.09
0.67
4.07
0.90
4.25
0.72
0.88
0.46
0.08
0.70
4.17
0.78
4.49
0.64
0.86
0.40
0.07
0.73
4.26
0.69
4.73
0.57
0.84
0.35
0.06
0.76
4.35
0.60
4.97
0.50
0.82
0.30
0.05
0.79
4.43
0.52
5.22
0.45
0.80
0.25
0.04
0.81
4.51
0.46
5.46
0.39
0.78
0.21
0.035
0.83
4.58
0.40
5.72
0.35
0.76
0.18
0.03
0.85
4.65
0.34
5.98
0.31
0.74
0.15
0.025
0.87
4.72
0.29
6.26
0.27
0.72
0.12
0.02
0.88
4.79
0.25
6.54
0.23
0.70
0.10
0.017
0.90
4.85
0.21
6.83
0.20
0.68
0.08
0.014
0.91
4.92
0.18
7.14
0.17
0.66
0.06
0.01
0.92
4.98
0.15
7.47
0.15
0.64
0.05
0.009
0.94
5.04
0.12
7.81
0.12
0.60
0.03
0.005
0.95
5.16
0.08
8.56
0.08
0.58
0.02
0.004
0.96
5.22
0.06
8.97
0.07
0.54
0.01
0.002
0.98
5.34
0.03
9.87
0.04
0.52
0.0007
0.0014
0.98
5.41
0.02
10.38
0.03
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hif = Tsif;
hig = Tsig
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12.f
What is the benefit of the generalized charts? Which properties must be known
besides the charts themselves?
The generalized charts allow for the approximate calculations of enthalpy
and entropy changes (and P,v,T behavior), for processes in cases where specific
data or equation of state are not known. They also allow for approximate phase
boundary determinations.
It is necessary to know the critical pressure and temperature, as well as
ideal-gas specific heat.
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12.1
The slope dP/dT of the vaporization line is finite as you approach the critical
point, yet hfg and vfg both approach zero. How can that be?
The slope is
hfg
dP
dT = Tv
sat
fg
Recall the math problem what is the limit of f(x)/g(x) when x goes
towards a point where both functions f and g goes towards zero. A finite limit for
the ratio is obtained if both first derivatives are different from zero so we have
dP/dT [dhfg /dT] / d(Tvfg)/dT as T Tc
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C.P.
V
T
S
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v < v Cr.P.
c
S
v
medium
v
large
T
v < vc
C.P.
v > vc
vmedium
S
V
large
v
The figures are for water where liquid is denser than solid.
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12.6
The equation of state in Example 12.3 was used as explicit in v. Is it explicit in P?
Yes, the equation can be written explicitly in P.
RT
P=
C
v+ 3
T
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12.9
Most equations of state are developed to cover which range of states?
Most equations of state are developed to cover the gaseous phase, from
low to moderate densities. Many cover high-density regions as well, including
the compressed liquid region. To cover a wider region the EOS must be more
complex and usually has many terms so it is only useful on a computer.
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12.11
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Clapeyron Equation
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B = hevap R-1
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Clapeyron Eq.:
B.4:
P = 1085.7 kPa,
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T
T
T T
P- P
qH = Tsfg;
sfg at T
P- P
T- T
vfg at T
wnet = qH - qL = Tsfg
qL = (T-T)sfg ;
Pdv
The boundary movement work, w =
3
Approximating,
3
P
Pdv (P - ) (v3 - v2);
2
2
P
Pdv (P - ) (v1 - v4)
2
1
v2+v3
v1+v4
wNET P[( 2 ) - ( 2 )]
Collecting terms:
1
T
(v + v ) (v + v )
2
In the limit as
T 0:
v3 v2 = vg ,
v4 v1 = vf
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Clapeyron Eq.:
B.3:
P = 4072.0 kPa,
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CP = 0.7 kJ/kg K
State 3
1 3
dPg
d ln Pg
hfg
=
P
=
P
g dT
dT
RT2 g
RT
vfg vg = P ,
g
d ln Pg
2
2
dT = +1000/T = hfg/RT
hfg = 1000 R = 1000 8.3145/100 = 83.15 kJ/kg
Substitute into the energy equation
q = -83.15 + 0.7(45.3 - 70) = -100.44 kJ/kg
1 3
.
QCOND = 1.5(-100.44) = -150.6 kW
1
3
1
v
2
s
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Table B.6.1:
Comparison not very close because Pg not linear function of T. Using 71 K &
69 K from the software, we can then get
(44.56-33.24
71-69 ) = 208.0 kJ/kg
(1938.8-1084.2
115-105 ) = 134.82 kJ/kg
134.82
sfg = hfg/T = 110 = 1.226 kJ/kg K
Table B.6.1: hfg = 134.17 kJ/kg and sfg = 1.22 kJ/kg K
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T
-70 -50
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1933.4
273.15 = 13.7611
1933.4
273.15 + 5 = 6.8102
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12.26
The triple point of CO2 is -56.4oC. Predict the saturation pressure at that point
using Table B.3.
The lowest temperature in Table B.3 for CO2 is -50oC, so it must be extended to
-56.4oC = 216.75 K using the Clapeyron Eq. 12.7 integrated as in Ex. 12.1
Table B.3:
at T1 = -50oC = 223.15 K,
Table A.5:
R = 0.1889 kJ/kg-K
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Helium boils at 4.22 K at atmospheric pressure, 101.3 kPa, with hfg = 83.3
kJ/kmol. By pumping a vacuum over liquid helium, the pressure can be lowered,
and it may then boil at a lower temperature. Estimate the necessary pressure to
produce a boiling temperature of 1 K and one of 0.5 K.
Solution:
Helium at 4.22 K: P1 = 0.1013 MPa,
dPSAT
hFG
dT = TvFG
hFGPSAT
RT2
hFG 1
1
ln P = R [T T ]
1
1
2
For T2 = 1.0 K:
P2
1
1
83.3
ln 101.3 = 8.3145[4.22 1.0]
For T2 = 0.5 K:
P2
1
1
83.3
ln 101.3 = 8.3145[4.22 0.5]
P2 = 2.160110-6 kPa = 2.1601 10-3 Pa
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T1 = 273.16 K
[kPa]
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30 MPa
T.P.
T
At the triple point,
vif = vf - vi = 0.001 000 - 0.001 090 8 = -0.000 090 8 m3/kg
hif = hf - hi = 0.01 - (-333.40) = 333.41 kJ/kg
dPif
333.41
dT = 273.16(-0.000 090 8) = -13 442 kPa/K
at P = 30 MPa,
(30 000-0.6)
T 0.01 + (-13 442) = -2.2 oC
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dPif
P dT T = -13 442(-3 - 0.01) = 40 460 kPa
P = Ptp + P = 40 461 kPa
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The saturated pressure versus temperature has a positive slope for carbon dioxide
and a negative slope for water.
Clapeyron
dPif
hf - hi
=
dT (vf - vi)T
So if we assume hf - hi > 0 then we notice that the volume change in the melting
gives
Water:
vf - vi < 0 so vf < vi
Carbon dioxide:
vf - vi > 0
so
vf > v i
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P2 hIG
1
1
574.5
1
1
ln P = R [183.2 100] = 0.188 92 [183.2 100] = 13.81
1
or P2 = P1 1.00510-6 P2 = 3.8310-5 kPa = 3.8310-2 Pa
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Solid
101.3 kPa
PTP
Liquid
Vap.
T
TTP TNMP T NBP
1) TTP TNMP
T
P
TP
hFG
2 dT
(1/P
)
dP
SAT
SAT
RT
TP
2)
0.1013 MPa
TNMP
Since hFG const hFG NBP the integral over temperature becomes
hFG NBP 1
PTP
1
ln 0.1013 R [T
-T ]
NBP
TP
get PTP
ln P
TP
hIG 1
hIG
1
=
(1/P
)
dP
dT
[
T]
2
SUB
SUB
R
T
RT
TP
SUB
PTP
TTP
or PSUB = fn(T)
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Property Relations
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u
s
v
v
v
= T P = T P
PT
PT
PT
TP
PT
where we have used Maxwell Eq.12.19. Now for an ideal gas we get
RT
Ideal gas: Pv = RT v = P
then the derivatives are
R
v
v
and
=P
= RTP2
T
P
PT
and the derivative of u is
R
u
v
v
= T P = T P P( RTP2) = 0
PT
TP
PT
This confirms that u is not sensitive to P and only a function of T.
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P h
= 1
h T TP
h
Then we have the definition of specific heat as CP = so solve for the first
TP
term
1 P
1 h
T
J = = C / = C
P h
P hT
P PT
= P + P =T+ P
TP
TP
TP
so then
RT2 Z
RT2 Z
v
T v=v + P v= P
TP
TP
TP
and we have shown the last expression also.
v
T v
TP
RT2 Z
T
J = =
=
CP
PCP TP
P h
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h
(hv)T and (T
)v
dh = Tds + vdP
=T
P
(T
)v + v(P
)
v T
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h
P
T
)
= T + v( )v = T - v( )s
v
s
s
v
But
s
s
(T
)
= - ( )T / ( )v = s
v
v
T
vT P
(h
)
= T + C ( )v
v
s
v T
P
)
T v
Cv
(Eq.12.20)
T(
(Eq.12.22)
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12.40
Evaluate the isothermal changes in the internal energy, the enthalpy and the
entropy for an ideal gas. Confirm the results in Chapters 3 and 6.
We need to evaluate duT, dhT and dsT for an ideal gas: P = RT/v.
From Eq.12.31 we get
duT = [ T
P
(T
)v P ] dvT = [ T ( Rv ) P ] dvT = [ P P] dvT = 0
v
R
)
] dPT = [ v T ( P ) ] dPT = [ v v ] dPT = 0
P
T
These two equations confirms the statements in chapter 5 that u and h are
functions of T only for an ideal gas.
From Eq.12.32 or Eq.12.34 we get
v
P
dsT = ( )P dPT = ( )v dvT
T
T
R
R
= P dPT = v dvT
so the change in s can be integrated to find
P2
v2
s2 s1 = R ln P = R ln v
1
when T2 = T1
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(T
) =P s
s
(P
)T
s
(T
)P
v
)
T P T v
= - (C /T) = C ( )P
P
P T
-(
s
v
{(P
)T = -(T
)P, Maxwell relation Eq. 12.23 and the other is Eq.12.27}
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dT
P
ds = Cv T + ( )v dv
T
so then in a constant s process we have ds = 0 and we find
T P
(T
)
= C ( )v
s
v
v T
As T is higher the slope is steeper (but negative) unless the last term (P/T)v
counteracts. If we have an ideal gas this last term can be determined
P
(T
)v = Rv
P = RT/v
T R
P
(T
)
=
=
s
Cv v
Cv
v
and we see the slope is steeper for higher P and a little lower for higher T as Cv is
an increasing function of T.
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What are the volume expansivity p, the isothermal compressibility T, and the
adiabatic compressibility s for an ideal gas?
The volume expansivity from Eq.12.37 and ideal gas v = RT/P gives
1 R
1 v
1
p = v( )P = v ( P ) = T
T
The isothermal compressibility from Eq.12.38 and ideal gas gives
1 v
1
1
T = v( )T = v ( RT P2 ) =
P
P
The adiabatic compressibility s from Eq.12.40 and ideal gas
1 v
s = v( )s
P
From Eq.12.32 we get for constant s (ds = 0)
v
T v
T R
(T
)
= C ( )P = C P = C
s
P
p T
p
p
and from Eq.12.34 we get
C P
C
C
v
(T
)s = Tv (T
)v = Tv Rv = Pv
Finally we can form the desired derivative
Cv v
v
v
v
(P
)s = (T
)s (T
)
=
P Cp = kP
P s
1 v
1
1
v
1
s = v( )s = ( v) ( ) = kP = T
kP
k
P
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LxLyLz
1 V
1
(
)
=
(
)P
V T P LxLyLz
T
LxLz Ly
LyLz Lx
LxLy Lz
=L L L (
)
+
(
)
+
( )
x y z T P LxLyLz T P LxLyLz T P
1
=L
1
1
x
y
z
(
)
+L (
)
+L (
)
P
P
x T
y T
z T P
= 3 T
This of course assumes isotropic properties (the same in all directions).
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1 v
1 v
T = - v( )T - v( )T
P
P
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1 v
1 v
T = - v( )T - v( )T
P
P
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w
=
Pdv
=
P
dP
=
1 2
vT PdPT
P T T
( )
vT 2 2
= - 2 P2 - P 1
0.011220
(20)2 - (0.1)2
2
] = 2440 J = 2.44 kJ
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P
(P
)
=
v
(
) =1
s
v s
2
1
1
=
s
v
-v
P s
( )
1
1
s2 m 3
1000
1
=
=
2
2
2
2
kPa
m
kg
c 4800 8300
4800 8300
Cu
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Use Eq. 12.32 to solve for (T/P)s in terms of T, v, Cp and p. How large a
temperature change does 25oC water (p = 2.1 10-4 K-1) have, when
compressed from 100 kPa to 1000 kPa in an isentropic process?
From Eq.12.32 we get for constant s (ds = 0) and Eq.12.37
(T
) = T (v ) = CTp p v
P s Cp T P
Assuming the derivative is constant for the isentropic compression we estimate
with heat capacity from Table A.3 and v from B.1.1
T
T
Ts =
P
=
v Ps
P s s Cp p
( )
273.15 + 25
2.1 10-4 0.001003 (1000 100)
4.18
= 0.013 K
barely measurable.
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c2 =
P
(P
)
= v ( )s =
s
v
1
1
1
=
s
v
-v
s
P
c=
(940101
)
783
-12
( )
= 783 kg/m3
1/2
= 1166 m/s
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(P
) = v (P
)
s
v s
2
We will use the 2000 kPa and 3000 kPa table entries. We need to find the change
in v between two states with the same s at those two pressures.
At 100oC, 2500 kPa:
(P
) = 0.027705
v
s
v = 0.031822 m3/kg
v = 0.0230556 m3/kg
3000 - 2000
kJ
J
0.0230556-0.031822 kg = 87 557.8 kg
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(P
) = 0.02653
v
s
2531 - 2469
kJ
J
=
83
919.5
0.02627 - 0.02679 kg
kg
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c2 =
P
(P
)
=
-v
(
)
s
v s
2
c2 = -
J
kg
c = 1415 m/s
= 2.002106
=>
v = 0.9766 m3/kg
) MJ
kg = 0.2558 10
m2/s2
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(P
) = -v (P
)
s
v s
P
P
Liquid water at 20 C, 2.5 MPa, assume ( )s ( )s
v
v
From Eq. 12.41:
c2 =
-2
MJ
(0.001 -30.001
)
001 kg
J
kg
c = 1001 m/s
= 1.002106
=>
) MJ
kg = 0.28114 10
m2/s2
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P s
2
( )
( )
( )
s
s
V P
Bs
then
V
P
1000
4
V = Bs = 2.82 106 = 3.55 10
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P
1
1
(P
)
(
)
=
=
v
=
s
v s
1.05 10-9 787
2
w = P
P dP
dv =
P (-sv ) dP =
sv P dP = s v
1
= s v 0.5
2
2
(P2 P1)
0.5
= 1.05 10-9 m2/N 787 m3/kg (10 0002 1002) 10002 Pa2
= 66.7 J/kg
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Use Eq. 12.32 to solve for (T/P)s in terms of T, v, Cp and p. How much higher
does the temperature become for the compression of the methanol in Problem
12.57? Use p = 2.4 10-4 K-1 for methanol at 25oC.
From Eq.12.32 we get for constant s (ds = 0) and Eq.12.37
(T
) = T (v ) = CTp p v
P s Cp T P
Assuming the derivative is constant for the isentropic compression we estimate
with heat capacity and density (v = 1/) from Table A.4
T
T
Ts =
P =
v Ps
P s s Cp p
( )
298.15 K kg K
1 m3
-4 -1
= 2.55
kJ 2.4 10 K 787 kg (10 000 100) kPa
= 0.353 K
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c2 =
(P
) = -v (P
)
s
v s
2
For every 3
seconds after the
lightning the
sound travels
about 1 km.
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Equations of State
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R = 0.1889 kJ/kg-K
Pv 7377.3 0.002139
Z = RT = 0.1889 304.15 = 0.27
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dvT = 2 dPT
v = P C R 3
P
T
so now
P2
1
duT = 3 C 4 dvT = 3 C R 3 dPT
T
T
and the integration becomes
u2 u1 = 3 C R T3 (P2 P1)
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b)
c)
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v
P
[ (T
) v - P]dv = [ RT
v
EA
(dB
dT)]dv
A
EA
RT
dB
= v T ( dT)
A
RT 8.3145293.15
1 RT
v = 2 P 1 + 1 + 4BP/RT
where: P =
= 2.43737
1000
E
EA
EA
EA
[1 +
EA
1
v = 2 2.43737
A
1 + 4(-0.128)/2.43737
EA
] = 2.3018 m /kmol
A
-8.3145 293.15
0.266 / 44.01 = 6.4 kJ/kg
2.3018
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Pv 1000 0.05236
Z = RT = 0.1889 293.15 = 0.9455
A
To get u* let us look at the lowest pressure 400 kPa, 20oC: v = 0.13551 m3/kg
and u = 331.57 kJ/kg.
E
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RT B(T) RT C(T) RT
P= v +
+
+ .
v2
v3
Virial EOS:
The work is
1
2
3
w=
[ v + B(T) v + C(T) v + .. ] dv
P dv = RT
A
EA
1
E
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RT/P*
RT/P*
*
sP*
A
P
- sP =
dv ;
T v
A
( )
ID Gas:
EA
R
P
- sP =
v dv = R ln *
*
sP*
A
EA
v(P)
v(P)
RT/P*
E
P
P
* + T v dv
P
Therefore, at P:
sP - sP = -R ln
A
( )
EA
v(P)
RT BRT
P
R BR RT dB
P= v + 2
and
= v + 2 + 2 dT
v
T
v
v
v
Integrating,
P
RT
dB
1 P*
*
sP - sP = -R ln * + R ln * + R B + T dT
v - RT
P
Pv
RT
dB 1
= R ln Pv + B + T dT v
virial:
( )
( )](
( )) ]
( )
Using values for CO2 from solution 12.63 and R = 0.1889 kJ/kgK
A
2.437 37
1
*
sP - sP = 0.1889 ln 2.3018 + -0.128 + 0.266 2.3018
= 0.02214 kJ/kg K
From Table B.3 take the ideal as the lowest P = 400 kPa:
*
The lowest P = 400 kPa in B3 is not exactly ideal gas ( Z = Pv/RT = 0.9788)
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valve is opened and remains open for a long time. Is the final pressure P2 greater
A
than, equal to, or less than P1/2? Hint: Recall Fig. 12.5.
A
Assume the temperature stays constant then for an ideal gas the pressure will be
reduced to half the original pressure. For the real gas the compressibility factor
maybe different from 1 and then changes towards one as the pressure drops.
VA = VB V2 = 2V1, T2 = T1 = T
P2 V1 Z2 mRT
1 Z2
=
=
P1 V2 Z1 mRT
2 Z1
A
Z
1T > T
B
1.0
1
P <2
1
A
P2
B
EVAC.
A
GAS
P2 1
If T < TB, Z2 > Z1 P > 2
1
A
2
2
P2
T < T
B
1
P1 P
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P=
RTc
(vc b)
+
A
2a
3
vc
A
=0
2RTc
(1) ;
(vc b)
6a
4
vc
=0
(2)
RTc
a
2
vc b v
(3)
Now we need to solve theses three equations for vc, a and b. Solve the first
equation for a and substitute into the second equation to give
RTc
3RTc
2a
6a
=
=>
=
substitute into Eq.(2)
3
2
4
2
vc (vc b)
vc vc (vc b)
A
3RTc
vc (vc b)
2RTc
(vc b)3
vc = 3b
RTc
a RTc RTc 8 b
Pc =
2 = 2b
= RTc (0.5 3/8) /b
vc b v
9 b2
A
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27 Pr2
27 Pr
+
Z
=0
64 T2
512 Tr 3
r
(8T + 1)
Z3
EA
Z2
AE
EA
RT a
P = v-b - 2
v
2 2
27 R TC
a = 64 P
C
A
RTC
b = 8P
C
EA
EA
AE
AE
v2(v-b)
multiply equation by P
A
Get:
RT
a
ab
v3 - (b + P ) v2 + (P) v - P = 0
E
Multiply by
P3
Pv
3 3 and substitute Z = RT
R T
Get:
bP
aP
abP2
2
(RT + 1) Z + ( 2 2) Z ( 3 3) = 0
RT
R T
Z3
A
Z3 (8T + 1) Z2 +
3=0
2 Z
512
T
r
6
4
T
r
r
EA
EA
AE
Where
P
Pr = P ,
c
A
EA
AE
T
Tr = T
c
A
EA
AE
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12.70
Evaluate changes in an isothermal process for u, h and s for a gas with an
equation of state as P (v b) = RT.
From Eq.12.31 we get
duT = [ T
P
(T
)v P ] dvT = [ T ( v R b ) P ] dvT = [ P P] dvT = 0
A
v
R
)
] dPT = [ v T ( P ) ] dPT = b dPT
P
T
A
R
R
= P dPT = v b dvT
A
EA
P2
v2 b
s2 s1 = R ln P = R ln v b
1
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P
(T
)v = v-bR
P
RT RT a
(uv)T = T(T
)v - P = v-b
v-b +
v
A
P
a
1 1
(u2-u1)T = [T
dv = a(v v )
- P]dv =
2
v
T
v
1
2
A
( )
EA
EA
1 1
(h2-h1)T = (u2-u1)T + P2v2 - P1v1 = P2v2 P1v1 + a(v v )
1
2
A
v -b
P
R dv = R ln 2
(s2-s1)T =
dv
=
v1-b
v-b
T v
A
( )
EA
EA
( )
A
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and temperature: Z = 1 + (Pr/14Tr)[1 6Tr ]. What does this predict for the
reduced Boyle temperature?
A
Pr
Pv
6
Z = RT = 1 + 14 T (1 - 2)
Tr
r
A
1
6
Z
= 14P T (1 - 2)
P
T
Tr
c r
A
EA
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AE
Pr -2
Pr
-2
-3
Z
= - 14T Tr (1 6 Tr ) + 14 T ( 12 Tr /Tc )
T P
c
r
A
Pr -2
-2
= 14T Tr ( 18 Tr - 1)
c
A
-2
or
Tr = 18
A
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RT
a
P = v-b 2
vT
v-b
Multiplying by P gives:
Using for TBoyle:
A
RT a(1-b/v)
v b = P PvT
Z-1
1 lim
RT
lim Z
( ) = lim
= RT P0(v - P )
P0 P T
P0 P-0
A
a(1-0)
a
(v RT
)
=
b
=
b
= 0 at TBoyle
P
RTT
RT2
lim
P0
A
or
TBoyle =
A
a
Rb =
EA
2
27 R TC 1 8PC
64 PC R RTC =
E
EA
27
T
8 C
EA
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1 lim
RT
lim Z
lim Z-1
(
)
=
=
(
v
P0 P T
P0 P-0
RT P0
P)
RT a
van der Waals:
P = v-b 2
v
v-b
multiply by P , get
RT a(v-b)
RT
a(1-b/v)
v-b = P or v - P = b Pv
2
Pv
But
a(1-0)
lim Z
& RT P0( )T = b RT = 0
P
a 27
or TBoyle = Rb = 8 TC = 3.375 TC
RT
a
Redlich-Kwong:
P = v-b
v(v+b)T1/2
as in the first part, get
RT
a(1-b/v)
v- P =b
Pv(1+b/v)T1/2
A
only at TBoyle
a(1-0)
lim Z
& RT P0( )T = b
=0
P
Pv(1+0)T1/2
A
or
3/2
TBoyle
A
only at TBoyle
A
2 5/2
PC
a 0.427 48 R TC
= Rb =
RPC
0.08 664 R TC
E
0.427 48 2/3
TBoyle = (0.086 64) TC = 2.9 TC
E
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Solve for the constants a, b, and vC using the same procedure as for the van der
Waals equation.
From the equation of state take the first two derivatives of P with v:
A
RT
2a
(P
) = - (v-b)
2+ 3
v T
vT
2P
2RT 6a
and ( 2 )T = v
(v-b)3 v4T
Since both these derivatives are zero at the critical point:
RT
2a
2RT 6a
and =0
2+ 3 =0
(v-b) v T
(v-b)3 v4T
RTC
a
Also,
PC = v -b 2
vC TC
C
A
vC = 3b,
A
2
27 R TC
a = 64 P ,
C
E
RTC
b = 8P
A
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P=
RT
a
v b v(v + b)T1/2
A
P
(T
)v = v R b + 2v(v +ab)T
A
3/2
From Eq.12.31
2
v2 + b
v1
3a
3a
(u2 u1)T =
dv
=
ln
[(
)
(
2v(v + b)T1/2
1/2
v2
v1 + b)]
2bT
AE
[(
)(
)]
R
a/2
(s2 s1)T =
+
3/2 dv
v b v(v + b)T
A
= R ln
3/2
A
ln
2
E
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A
E
RT
where Eq. 12.44: = P v
lim
B(T) = - P0
From Eq.12.48:
Taking the limit for P -> 0 then (Pv -> RT and v -> ) we get :
RTC 1 27 TC
B(T) = b a/RT = P ( 8 64 T )
C
A
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A
E
RT
where Eq.12.44: = P v
lim
B(T) = - P0
From Eq.12.48:
Taking the limit for P -> 0 then (Pv -> RT and v -> ) we get :
a
=> B(T) = b
RT3/2
Now substitute Eqs. 12.54 and 12.55 for a and b,
RTC
TC3/2
B(T) = P
0.08664 - 0.42748 T
C
A
AE E
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5/2
R2Tc
0.25982 154.65/2
a = 0.427 48 P = 0.427 48
= 1.7013
5040
c
E
P=
RT
a
v b v(v + b)T1/2
A
v = 0.01 m3/kg
v = 0.008 m3/kg
v = 0.0075 m3/kg
v = 0.007 m3/kg
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h1 + 0 = h2 + 0
A
so constant h
so entropy generation
A
E
A
E
RT
a
v b v(v + b)T1/2
P=
A
P
(T
)v = v R b + 2v(v +ab)T
A
3/2
From Eq.12.31
2
v2 + b
v1
3a
3a
(u2 u1)T =
dv
=
ln
[(
)
(
1/2
v2
v1 + b)]
2bT1/2
2v(v + b)T
A
AE
[(
)(
)]
R
a/2
(s2 s1)T =
+
3/2 dv
v b v(v + b)T
A
= R ln
3/2
A
ln
2
E
Tc = 154.6 K;
R = 0.2598 kJ/kg K
Pc = 5040 kPa;
RTc
0.2598 154.6
b = 0.08664 P = 0.08664
= 0.000 690 5 m3/kg
5040
c
A
A
E
5/2
R2Tc
0.25982 154.65/2
a = 0.427 48 P = 0.427 48
= 1.7013
5040
c
E
A
E
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and we will evaluate it similar to Fig. 12.4, where the first term is done from state
x to 2 and the second term is done from state 1 to state x (at T1 = 230 K). We do
this as we assume state 2 is close to ideal gas, but we do not know T2.
We first need to find v1 from the EOS, so guess v and find P
A
A
E
A
E
A
E
v1 = 0.011 m /kg
A
too low
A
E
3a
ln
2bT1/2
0.59704 0.01082
= 59.635 5000 0.01082 243.694 ln [
]
0.59635 0.01151
= 59.635 54.1 + 14.78335 = 20.318 kJ/kg
A
= R ln
3/2
A
ln
x
E
p
A
T2
ln T
A
0.59566
208
= 0.2598 ln(0.0101295) 0.35318 ln (0.94114) + 0.922 ln(230)
A
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Generalized Charts
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A
E
Tc = 309.6 K,
A
A
E
278.6
Pc = 7.24 MPa => Tr1 = 309.6 = 0.9
A
Look in Fig. D.1 following the curve Tr1 = 0.9 to the point where Z = 0.95
A
Pr1 = 0.125
A
so
P < 0.125 7.24 MPa = 0.9 MPA = 900 kPa
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A
E
278.6
Pc = 7.24 MPa => Tr1 = 309.6 = 0.9
Tc = 309.6 K,
A
(h - hg)/RTc = 0.875
A
A
E
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273.15
Pc = 4.06 MPa => Tr1 = 374.2 = 0.73
Tc = 374.2 K,
A
Saturated liquid:
(h - hg)/RTc = 0.3
hfg = hg - hf = RTc [-0.3 (-4.7)] = 4.4 RTc
Saturated vapor:
A
A
E
A
E
The approximation is not very good and can be improved by using the
accentric factor.
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cool to T2 = 50 oC = 323.2 K
E
Tc = 369.8 K,
A
Pc = 4.25 MPa
A
E
9
553.2
Pr1 = 4.25 = 2.118, Tr1 = 369.8 = 1.496
A
v2 = v1 =
A
Z1RT1
P1
A
0.8250.188 55553.2
= 0.00956 m3/kg
9 000
x2 = 0.354
A
These tanks
contain liquid
propane.
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C2 H4
cool to x2 = 1.0
3
Pr1 = 5.04 = 0.595,
A
Final state: x = 1, v2 = v1
A
Fig. D.1:
303.2
Tr1 = 282.4 = 1.074
A
Z1 = 0.82
A
Trial & error, Table D.4 may be easier to use than Fig. D.1:
Tr2
A
0.866
ZG2
A
0.72
Pr2
A
0.42
Pr2 CALC
A
0.421
~ OK
=> T2 = 244.6 K
A
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Since we do not have the printed tables for R-152a we will use generalized charts.
The critical properties are: Tc = 386.4 K, Pc = 4.52 MPa.
A
A
E
Evaporator:
Tr1 = T/Tc = (273.15 20)/386.4 = 0.655
A
A
E
Fig. D.1:
Condenser:
Tr2 = T/Tc = (273.15 + 30)/386.4 = 0.785
A
A
E
Fig. D.1:
A
E
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10
Pr1 = 4.88 = 2.05,
A
373.15
Tr1 = 305.4 = 1.22
PV
m = ZRT =
10 000 4
= 692.3 kg
0.56 0.2765 373.15
A
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273.15
Tr2 = 305.4 = 0.8944
Since Z and P are unknown this becomes trial and error solution.
The new final state is given by: (T2, v2 = v1)
A
A
E
Assume it is saturated
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10
Pr1 = 4.88 = 2.05,
A
373.15
Tr1 = 305.4 = 1.22
PV
m = ZRT =
A
CATT3: Z = 0.605
10 000 4
= 640.8 kg
0.605 0.2765 373.15
A
Problem 12.89:
273.15
Tr2 = 305.4 = 0.8944
Since Z and P are unknown this becomes trial and error solution.
The new final state is given by: (T2, v2 = v1)
A
A
E
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C4H10 cycle
.
WT
Turbine
Ht.
Exch
.
QH
*
(h1-h1) = 0.143 04425.20.56 = 34.1
*
(s1-s1) = 0.143 040.475 = 0.0680
Cond
.
-WP
303.2
Tr3 = 425.2 = 0.713
A
353.2
1235
* *
(s1-sg3) = 1.7164 ln 303.2 - 0.143 04 ln 429 = 0.1107
A
A
E
T
1
2s 2
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and
353.2
1235
*
*
(s1 - s2S) = 1.7164 ln 315 - 0.143 04 ln 429 = +0.0453
(s1 - s2S) = -0.0680 + 0.0453 + 0.027 0
T2S = 315 K
*
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6Tc2
RT RTc
v = P + 14P (1 - 2 ) ;
T
c
R 12RTc
v
=P+
Tp
14PcT3
3
RTc 18RTc
v
v - T = 14P 2
Tp
c 14PcT
Now Eq.12.27 is integrated with limits similar to Eq.12.62
P
RTc
18
v
h h* = [v T ] dP = 14 (1 2) Pr = 0.606 RTc
Tp
Tr
0
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dT v
dT R
R v
dP
[
C
dP
]
=
[
p
T T p
T P
P T p] dP
R 12RTc
v
=P+
T p
14PcT3
3
P
12RTc
R v
6 Pr
s - s* = [ P - ] dP = [
]
dP
=
7 R T3
T p
14PcT3
P
0
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h1 = 138.3 kJ/kg,
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P1V1 = P2V2
500
5
Tr1 = 425.2 = 1.176, Pr1 = 3.8 = 1.316
3
460
=
1.082,
P
=
= 0.789 From Fig. D.1:
r2 3.8
425.2
mZRT 5 0.68 0.1430 500
V1 = P =
= 0.0486 m3
5000
Tr2 =
Z1 = 0.68
Z2 = 0.74
W = PdV =
1 2
1
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W2 = 125 kJ
500
5
Tr1 = 425.2 = 1.176, Pr1 = 3.8 = 1.316
Z1 = 0.68
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x1 = 0.0
Z1 = 0.04
1063510-6
= 0.00238 kg
0.040.188 55296.2
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C3 H8
T
1
v
h1-h1
EA
Fig D.2:
SAT
A
AE
SAT
= 0.30 P1
A
m=
Pr
A
E
= 1.275 MPa
12750.25
= 7.842 kg
0.7110.188 55303.2
A
7.842Z20.188 55573.2
Pr2 =
Z2
= 1.254
0.254250
at Tr2 = 1.55 Trial and error on Pr2
A
Pr2 = 0.743 => P2 = 3.158 MPa, Z2 = 0.94 , (h*- h)2 = 0.35 RTC
E
(h2-h1) = 1.6794(300-30)
A
= 453.4 kJ/kg
*
(h2-h2)
A
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A
E
A
E
= 271.5 kJ/kg
CATT3:
The generalized charts are not super accurate, some improvement can be done
using the accentric factor.
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A
E
Z1 = 0.85
A
A
E
Z2 = 0.17 ,
A
A
E
A
E
5.12
= -0.3568
1.536
1q2 = T(s2-s1) = 260.2(-1.067 - 0.3568 + 0.0889) = -347.3 kJ/kg
*
Ideal gas:
(h2-h1) = 0
A
* *
and
(s2-s1) = 0 - 0.2964 ln
A
1w2
A
A
E
A
E
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Energy Eq.:
Substituting :
*
(h2-h2)
A
Substituting :
T2 = -6.0 oC
E
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.
WT
Turbine
Cond
*
(h1-h1) = 0.1430 425.20.5685 =
*
(s1-s1) = 0.1430 0.4996 = 0.0714
P
4
Ht.
Exch
.
QH
34.6
.
-WP
303.2
Tr3 = 425.2 = 0.713
A
*
E
* *
(s1-sg3)
A
353.2
1005
= 1.716 ln 303.2 - 0.1430 ln 282.8 = 0.0806
A
A
E
T
1
2s 2
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From CATT3:
*
and
353.2
1005
*
*
(s1 - s2S) = 1.716 ln 315 - 0.1430 ln 282.8 = +0.01509
(s1 - s2S) = -0.0714 + 0.01509 + 0.025 = -0.031
Repeat at T2S = 310 K to get Tr2S = 0.729,
*
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T1 = -13oC = 260.2 K
Z1RT1
P1
0.850.29637260.2
= 0.042675
1536
Z2RT2
P2
0.050.29637232.7
= 0.002245 m3/kg
1536
q12
= -62.1 kJ/kg
= (u2 - u1) + w12 = (h2 - h1) = -369.9 - 42.6 + 33.5
= -379 kJ/kg
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T1 = T2 = 40 oC, x1 = 0
P2 = 100 kPa
1
2
Heat
q + h 1 = h 2,
Entropy Eq.:
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243
Tre = 304.1 = 0.80,
From D.2 and D.3:
*
4
Pre = 7.38 = 0.542
(s*-s)re/R = 4.74
* *
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si = 2.015 kJ/kg-K
se = 0.07349 kJ/kg-K
wrev = (hi he) T0(si se) = 376.1 20.21 278.2 (2.015 0.07349)
= -184.1 kJ/kg
q
rev
The work is very accurate but the heat transfer a little less so. The enthalpy and
entropy differences are both under-estimated by the generalized charts.
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Pump:
vF3 =
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Check first law (he- hi) = -0.4 -20.3 + 20.1 0 OK => Te = 208 K
From D.3,
*
and
0.1
208
* *
(se -si ) = 0.9216 ln 230 - 0.2598 ln 5 = 0.9238 kJ/kg K
sgen = (se- si) = -0.0026 + 0.9238 + 0.0649 = 0.9861 kJ/kg K
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Propene C3H6:
x1 = 0.50,
From D.1:
P1V1
m = Z RT =
11500.010
= 0.471 kg
0.42250.197 58292.2
V1 = 10 L
Q = TdS = Tm(s2-s1)
1 2
460
*
*
(s2 - s1) = 0 - 0.197 58 ln 1161 = + 0.1829 kJ/kg K
At Tr2 = 0.80, Pr2 = 0.10, from D.1, D.2 and D.3, Z2 = 0.93
*
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1 2
=>
Q = m 1q2 = 101.2 kJ
1 2
1 2
1
W2 = m 1w2 = 36.0 kJ
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TC = 304.1 K,
6
Pri = 7.38 = 0.813,
PC = 7.38 MPa
373.2
Tri = 304.1 = 1.227
~
h = 0.70
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0.1
Pri = 4.25 = 0.024
Ze = 0.036
ZiTi/Pi
0.99 350 0.935
= Z T /P = 0.036 290 0.1 = 310.3
e e e
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(h*1 h1)g
P1V1
*
= 0.9 RTC, (s1 s1)g/R = 0.72, m = Z RT = 2.262 kg
1
1
State 2: T2 = -30oC
Tr2 = 0.8, P2 = Pr2Pc = 0.25 7380 = 1845 kPa
Entropy Eq.:
Sgen = m(s2 s1) 1Q2/T ;
1Q2 = 0,
*
s2 - s1 = (s2 s2)
Sgen = 0
T2
P2
*
*
*
s2 s1 = CP ln T R ln P = 0.044 kJ/kg-K, s1 s1 = 0.136 kJ/kg-K
1
1
*
s2 - s2 = 0.180 kJ/kg K,
x2 = 0.889
Energy Eq.:
1Q2
(h*2 h2)f
= 4.51 RTC ,
52.2 kJ/kg
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Z1RT1
P1
0.920.143353.2
= 0.09296 m3/kg
500
State 2:
Therefore
vF =
0.050.143353.2
= 0.00205 m3/kg
1235
vG =
0.7750.143353.2
= 0.0317 m3/kg
1235
1 2
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Availability of Octane at
From Table A.5:
TC = 568.8 K,
3
Pri = 2.49 = 1.205,
PC = 2.49 MPa
673.2
Tri = 568.8 = 1.184
This is relative to the dead ambient state, assume T0 = 298.2 K, P0 = 100 kPa
298.2
Tr0 = 568.8 = 0.524 ,
0.1
Pr0 = 2.49 = 0.040
From D.2 and D.3, The s correction is outside chart (extrapolate or use CATT3)
*
and
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2
3
4
h3 - h3 = 4.56RTC = 221.8
v
T1 = -20 oC = 253.2 K, Tr1 = 0.655, Pr1 = 0.058 P1 = 262 kPa
*
h1 - h1 = 0.14RTC = 6.8
and
s1 - s1 = 0.14R = 0.0176
h2 - h2 = 0.40RTc = 19.5
307
994
*
*
s2 - s1 = 0.996 ln 253.2 - 0.125 88 ln 262 = 0.0241
s2 - s1 = -0.0428 + 0.0241 + 0.0176 = -0.001 0 OK
h2 - h1 = -19.5 + 0.996(307-253.2) + 6.8 = 40.9
h2 - h3 = -19.5 + 0.996(307-303.2) + 221.8 = 206.1
qH h2 - h3 206.1
= w = h - h = 40.9 = 5.04
IN
2
1
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2
3
1
h3 - h3 = 4.56RTC = 221.8
v
T1 = 0 oC = 273.2 K, Tr1 = 0.707 => Pr1 = 0.106, P1 = 479 kPa
*
h1 - h1 = 0.22RTC = 10.7
and
s1 - s1 = 0.21R = 0.0264
s2 - s2 = 0.35R = 0.0441
and
h2 - h2 = 0.38RTC = 18.5
305.0
994
*
*
s2 - s1 = 0.996 ln 273.2 - 0.125 88 ln 479 = 0.0178
s2 - s1 = -0.0441 + 0.0178 + 0.0264 = 0.0001 0 OK
h2 - h1 = -18.5 + 0.996(305.0-273.2) + 10.7 = 23.9
h2 - h3 = -18.5 + 0.996(305.0-303.2) + 221.8 = 205.1
h2 - h3 205.1
= h - h = 23.9 = 8.58
2
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ZeRTe
Pe
Ze = 0.69
0.690.296 37367.2
= 0.0073 m3/kg
10 240
2
D = 0.007 85 m2
4 e
=>
302
- 300 = -97.9 kJ/kg
21000
.
.
Qcv = mq = 32.26(-97.9) = -3158 kW
.
Qcv .
.
3158
Sgen = T + m(se - si) = + 298.2 + 32.26(0.5562) = 28.53 kW/K
o
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Fig. D.2:
*
h4 = h3
qL = h1 - h3 = (h1 h1)
*
h4 = h3
wc = h1 - h2 + q; h1 - h2 = (h1 h1)
*
.
Q = -1.0 kW,
.
m = 0.1 kg/s
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sat. vap.:
P2VLIQ 2
4890.050
= 50.4 kg
mLIQ 2 = Z RT =
0.020.082 73293.2
F
2
P2VVAP 2
mVAP 2 = Z RT = 1.15 kg,
G
2
m2 = 51.55 kg
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Mixtures
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mRT
V = Z M P = 0.925 0.044 = 0.0407 m3
mix
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2
27 R Tc 27 (0.2081 150.8)2
aAr = 64 P = 64
= 0.08531
4870
c
A
2
27 R Tc 27 (0.2968 126.2)2
aN2 = 64 P = 64
= 0.17459
3390
c
RTc 0.2081 150.8
bAr = 8P =
= 0.000 805
8 4870
c
RTc 0.2968 126.2
bN2 = 8P =
= 0.001 381
8 3390
c
Now the mixture parameters are from Eq.12.84
AE
1/22
amix =
ci ai = (0.5 0.08531 + 0.5 0.17459)2 = 0.126
bmix = ci bi = 0.5 0.000 805 + 0.5 0.001 381 = 0.001 093
RT
a
Using now Eq.12.52:
P=
2
vb v
0.25245 180 0.126
2000 =
2
v 0.001 093
v
By trial and error we find the specific volume, v = 0.02097 m3/kg
V = mv = 0.04194 m3
A
E AE
EA
EA
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Fig. D.1:
1.2
Pr2 = 4.70 = 0.255,
Reduced properties 1:
*
h2 h2
Fig. D.1:
393.15
Tr2 = 345.25 = 1.139
A
E
A
E
The main difference is in the value of specific heat, about 1 kJ/kg-K at the avg.
T, whereas it is 0.8 kJ/kg-K at 25oC.
E
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5/2
R2Tc
0.20812 150.82.5
aAr = 0.42748 P
= 0.42748
= 1.06154
4870
c
AE
5/2
R2Tc
0.29682 126.22.5
aN2 = 0.42748 P
= 0.42748
= 1.98743
3390
c
RTc
0.2081 150.8
bAr = 0.08664 P = 0.08664
= 0.000 558
4870
c
RTc
0.2968 126.2
bN2 = 0.08664 P = 0.08664
= 0.000 957
3390
c
Now the mixture parameters are from Eq.12.84
AE
1/22
amix =
ci ai = (0.5 1.06154 + 0.5 1.98743)2 = 1.4885
bmix = ci bi = 0.5 0.000 558 + 0.5 0.000 957 = 0.000 758
RT
a
Using now Eq.12.53:
P=
v b v(v + b)T1/2
0.25245 180
1.4885
2000 =
E AE
EA
EA
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R2Tc
0.29642 282.42.5
aC2H4 = 0.42748 P
= 0.42748
= 9.9863
5040
c
AE
5/2
R2Tc
0.31932 308.32.5
aC2H2 = 0.42748 P
= 0.42748
= 11.8462
6140
c
RTc
0.2964 282.4
bC2H4 = 0.08664 P = 0.08664
= 0.001 439
5040
c
RTc
0.3193 308.3
bC2H2 = 0.08664 P = 0.08664
= 0.001 389
6140
c
Now the mixture parameters are from Eq.12.84 so we need the mass fractions
y M 0.6 28.054
cC2H4 = M
=
= 0.6175,
cC2H4 = 1 - cC2H4 = 0.3825
27.26
mix
AE
1/22
amix =
ci ai = (0.6175 9.9863 + 0.3825 11.8462)2 = 10.679
bmix = ci bi = 0.6175 0.001 439 + 0.3825 0.001 389 = 0.001 42
RT
a
Using now Eq.12.53:
P=
v b v(v + b)T1/2
0.305 300
10.679
6000 =
E AE
EA
EA
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*
h1 h1
Fig. D.1:
6
Pr2 =
= 1.095,
5.48
Reduced properties 2:
Tr2 =
*
h2 h2
Fig. D.1:
400
= 1.366
292.8
A
A
E
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Pi =10 MPaA
o
Ti = 25 C
T1 = 25 oC
E
P2 = 10 MPa, T2 = 25 oC
E
V=0.05 3
m B
Mixture at 2 :
PC2 = 0.8 5.04 + 0.2 7.38 = 5.508 MPa
A
D.1 :
Z2 = 0.32
A
P2V
10 0000.05
- = 0.328.3145298.2 = 0.6302 kmol
Z2RT2
n2 =
A
298.2
Tr1 = 304.1 = 0.981
A
n1ZB1RT1
Pr1 =
A
PCBV
A
73800.05
A
= 0.8466 ZB1
A
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h1 = 4.57
h2 = 0.08
= 10 419 kJ/kmol
Kays rule Eq.12.84
Tcmix = (1 190.4 + 2 305.4)/3 = 267.1 K
Pcmix = (1 4.60 + 2 4.88)/3 = 4.79 MPa
Tr3 = 323.2/267.1 = 1.21 ,
h3 = 0.15
.
QCV = 3(-333) - 1(-13528) - 2(10 419) = - 8309 kW
E
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A
E
A
E
Tca = 150 K, Pca = 4.87 MPa, Ma = 39.948 kg/kmol, Cpa = 0.52 kJ/kg K
ha3 - ha2 = MaCpa(T3 - Ta2) = 1973.4 kJ/kmol
.
Inlet: Ethane, Tb1 = 14oC, sat. liq., xb1 = 0, n1 = 0.25 kmol/s
Tcb = 305.4 K, Pcb = 4.88 MPa, Mb = 30.07 kg/kmol, Cpb = 1.766 kJ/kg-K
Tr1 = 0.94, Pb1 = Pr1Pcb = 0.69 4880 = 3367 kPa
hb1 hb1 = 3.81 RTcb = 9674.5 kJ/kmol, s-b1 s-b1 = 3.74 R = 31.1
E
hb3 - h b1 = MbCpb(T3 - Tb1) = 5629.6 kJ/kmol
Exit: Mix, T3 = 120oC, P3 = 800 kPa consider this an ideal gas mixture.
. . . . . . Energy Eq.: n1hb1 + n2ha2 +Q = n3h3 = n1hb3 + n2ha3
E
= 5306 kW
.
.
.
.
Entropy Eq.: Sgen = n1(s-b3 s-b1) + n2(s-a3 s-a2) - Q/TH ;
E
TH = 150oC
. .
ya = n2/ntot = 0.75;
. .
yb = n1/ntot = 0.25
T3 yaP3
s-a3 s-a2 = MaCpalnT - R ln P = 8.14 kJ/kmol-K
a2
a2
E
T3 ybP3
s-b3 s-b1 = MbCpblnT - R ln P + s-b1 s-b1 =
E
b1
b1
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EA
h2 = 1.35,
Z2 = 0.58,
s2 = 1.0
W12 = Q12
+ 0.08 ] = - 10.85 kJ
- n(u- - u- ) = -10.85 - 0.00142(-2143) = - 7.81 kJ
E
2
A
1
A
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EA
For C2H6 :
EA
EA
8.3145*308.2 456.384
- 5500 = 0
v- - 0.05393
v- 2
A
0.2815 - 0.05392
= 0.00142 8.3145 308.2 ln 3.5329 - 0.05392 = - 9.93 kJ
A
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Helmholtz EOS
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h* = ho +
CPo dT
E
* CPo
T
s* = so + T dT R ln
oTo
a*
Now from Eq.12.89 we need to look at so following 12.92
T
*
h
a*
s*
RT
=
T
T T T
T
T
= 0 0 + TR ln
oToT
= RT /
So then
a*
2 = P = RT
Ideal gas OK
T
E
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h* = ho +
CPo dT = ho + CPo(T To)
E
* CPo
T
s* = so + T dT R ln
oTo
*
T
= so + CPo ln(T /To) R ln
oTo
So now we get
E
a* = ho + CPo(T To) RT T s*
E
T
*
*
T
= ho T so + CPo(T To) CPoT ln ( T ) RT + RT ln
o
oTo
T
= Co + C1 T C2 T ln ( T ) + RT ln
o
o
A
where
*
Co = ho CPoTo ;
A
C1 = CPo R so ;
A
C2 = CPo R
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P
(T
)v P ] dvT = [ T ( v R b ) P ] dvT = [ P P] dvT = 0
A
R
R
= P dPT = v b dvT
A
(u2 u1)v =
Cv dT
and
Cv
(s2 s1)v = T dT
Finally since the Helmholtz function contains the product Ts we need the absolute
value of the entropy so
1
v1 b
Cv
s1 = so + T dT + R ln b
vo
v2 b
Cv
=
C
dT
T
[
dT
+
R
ln
v
2
v1 b ] + (T1 T2) s1
T
1
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Pv
P
=
1
C
RT
T4
A
RT C
v= P 3
T
or
A
P2
4C
C
3C
= 3 (P2 P1)T + 3(P2 P1)T + RT ln P + 3 (P2 P1)T
T
T
1T T
This now reduces to the final answer
P2
(a2 a1)T = RT ln P
1T
A
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a* = Co + C1 T C2 T ln ( T ) + RT ln ( )
E
where Co, C1, C2 are constants and To and o reference values for temperature
and density, see Eqs. 12.92 - 95. Find the properties P, u and s from this
expression. Is anything assumed for this particular form.
Given Helmholtz function we can find the pressure and entropy from Eq. 12.21
and then u from the definition: a = u Ts.
T
v
a* = Co + C1 T C2 T ln ( T ) RT ln ( v )
o
o
E
a*
= RT ln ( v ) = RT / v
v
v T
o
*
a
P = = RT / v
i.e. Ideal gas.
v T
A
T
v
a*
s = = C1 + C2 ln ( T ) + C2 + R ln ( v )
T v
o
o
Notice how it looks like Eq.6.17.
T
v
u = a + Ts = Co + C1 T C2 T ln ( T ) RT ln ( v )
o
o
T
v
C1T + C2T ln ( T ) + C2T + RT ln ( v )
o
o
= Co + C2 T
We find that u is linear in T.
A
Not only is it ideal gas but it also has constant specific heats.
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Review Problems
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*
(h1-h1)
A
= 0.2765305.44.12 = 347.9
From D.2:
A
E
From D.3,
*
T3
100
* *
(s3-s2) = 1.766 ln 611 - 0.2765 ln 2440
A
A
E
at Pr3 = 0.020
A
A
E
* *
From D.3,
*
A
E
Therefore, T3 = 368 K
A
A
E
From D.2,
*
A
E
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A
E
Fig. D.1:
A
E
Fig. D.1:
A
E
*
*
*
h1 = h 1o + CP(T1 - To) + (h 1 - h 1 ) ; h1o = 0,
A
*
*
*
h 1 - h 1 = (1 - x1) (h 1 - h 1)f + x1 (h 1 - h 1)g = 7748 kJ/kmol
A
A
E
*
Tr2 = 1.182, Pr2 = 0.131, Z2 = 0.97, (h 2 - h2)/RTc = 0.06
*
*
*
h2 = h 2o + CPmix(T2 - To) + (h 2 - h 2 ) ; h2o = 0, T2 - To = 0
A
A
E
a) ni = n1 => n2 = n1 + ni = 0.1024,
V2 = n2Z2RT2/P2 = 0.0484 m3
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b) Energy Eq.:
u- = h - PvE
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kJ/kg K and TC = 500 K, PC = 5 MPa. Calculate the work input, per kilogram, to
A
.
WT
Turbine
.
QH
T3 = 20 C = 293.2 K, x3 = 0.0
A
Properties known:
M = 80, CPO = 0.8 kJ/kg K
A
Ht.
Exch
Cond
P
4
.
-WP
vF3 =
A
wP = -
vdP vF3(P4 -P3) = -0.00106(3600-115) = -3.7 kJ/kg
A
EA
qH + h4 = h1 , but h3 = h4 + wP
A
=>
qH = (h1-h3) + wP
A
*
(h3-h3)
A
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293.2
115
* *
(s2-s1) = 0.80 ln 473.2 - 0.103 93 ln 3600 = -0.0250
A
Substituting,
*
*
(h2-h2)
A
*
(h2-hF2)
- x2hFG2
A
=> x2 = 0.922
A
TH =
A
wNET
qH
A
104.1-3.7
345.6 = 0.29
A
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1.4
= const inside
400
3.5
Tr1 = 369.8 = 1.082, Pr1 = 4.25 = 0.824 Fig D.1: Z1 = 0.74
A
A
E
0.740.188 55400
= 0.01594, v2 = 2v1 = 0.03188
3500
0.2
1
m1 = 0.015 94 = 12.55 kg, m2 = 2 m1 = 6.275 kg,
v1 =
A
v1
P2 = P1 v
2
A
E
1.4
3500
= 1326 kPa
21.4
Trial & error: saturated with
1.326
T = 0.826369.8 = 305.5 K &
Pr2 = 4.25 = 0.312
2
Z = 13260.03188 = 0.734
P2v2 = Z2RT2
2 0.188 55305.5
Z2 = ZF2 + x2(ZG2 - ZF2) = 0.734 = 0.05 + x2(0.78-0.05) => x2 = 0.937
A
( )
*
(h1-h1)
* *
(h2-h1)
A
A
E
= 1.6794(305.5-400) = -158.7
= 55.3
Energy Eq.:
A
E
h1 = 0 + (h1-h1) = -62.8
A
E
Let h1 = 0 then
A
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C4H10 cycle
Turbine
.
WT
ST = SP = 0.80
353.2
Tr1 = 425.2 = 0.831
From D.1, D.2 and D.3:
P1 = 0.3253800 = 1235 kPa
A
Ht.
Exch
.
QH
Cond
*
(h1-h1) = 0.143 04425.20.56 = 34.1
*
(s1-s1) = 0.143 040.475 = 0.0680
.
-WP
303.2
Tr3 = 425.2 = 0.713
A
353.2
1235
* *
(s1-sG3) = 1.7164 ln 303.2 - 0.143 04 ln 429 = 0.1107
A
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2s 2
s
From D.2 and D.3:
*
and
353.2
1235
* *
(s1-s2S) = 1.7164 ln 315 - 0.143 04 ln 429 = +0.0453
A
T2S = 315 K
A
At state 3,
0.0190.143 04303.2
v3 =
= 0.001 92 m3/kg
429
E
-wP =
A
SP
A
-wSP
1.55
= 0.8 = 1.94 kJ/kg
A
But
h1-h4 = h1-h3+wP
A
*
(h1-h1)
h1-h3 =
A
* *
(h1-h3)
E
+ (h3-h3)
A
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State 1:
(h*1 h1) = 0.13RTc = 11.0 kJ/kg, (s*1 s1) = 0.09 R = 0.025 kJ/kg K
State 2: T2 = 20oC, x2 = 0.5, 1W2 = 1.25Wrev
Tr2 = 0.96, Pr2 = 0.78, P2 = Pr2Pc = 3806 kPa
Zf2 = 0.14, Zg2 = 0.54, Z2 = (1 - x2)Zf + x2Zg = 0.34
V2 = mv2 = 0.005 m3
Polytropic process
n
P1V1 = P2V2 ,
P2
V1
ln P = n ln V
1
n = 0.6783
P2V2 - P1V1
= -96.3 kJ,
1-n
1W2 = 1.25Wrev = -120.4 kJ
Wrev = P dV =
a) Energy Eq.:
1Q2
*
h 2 h2
h2 - h1 = (
u = h - Pv
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b) Entropy Eq.:
s2 - s1 = (s2 s2)
To = 0oC = 273.15 K
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Substituting,
w = -29.9 + 82.7 + 9.8 = 62.7 62.1
T2 = 275 K
w
62.1
=
= 0.725
1-2 85.7
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0.0250.5183140.9
= 0.00261
700
0.870.5183140.9
= 0.0908
700
2.5
7.5
mLIQ 1 = 0.00261 = 957.9 kg, mVAP 1 = 0.0908 = 82.6 kg
Total m = 1040.3 kg
Z20.5183190.4Tr2
V
10
v2 = v1 = m = 1040.5 = 0.00961 =
10 000
vG1 =
T2 = 1.334190.4 = 254.0 K
b) Energy Eq.:
Q12 = m(u2-u1) = m(h2-h1) - V(P2-P1)
82.6
Using D.2 & x1 = 1040.5 = 0.0794
*
] = 431.1
uF1 = -178.47
7.5
mVAP 1 = 0.090 45 = 82.9
m = 1017.5 kg and
10
v2 = 1017.5 = 0.009 828 m3/kg
T2 = 259.1 K
At v2 & P2 = 10 MPa u = 296.11
2
Q12 = m(u2-u1) = 1017.5296.11 - 934.6(-178.47) - 82.9(199.84)
= 451 523 kJ
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LIQ 0
*
s-0 = 200 kJ/kmol K
*
s-0 CH4 = s-LIQ 0 P + (s-*-s-LIQ)at P - R ln (P0/PG)
G
Pr = 0.844
*
s-TP MIX - s-TP MIX = 0.43638.3145 = 3.63 kJ/kmol K
Therefore,
s-TP MIX = 188.41 - 3.63 = 184.78 kJ/kmol K
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P ,T
G 0
at P , T
G 0
293.2
4
= 100 + 33.34 + 16.042.254 ln 173.2 - 8.3145 ln 2.6
= 100 + 33.34 + 19.03 - 3.53 = 148.84 kJ/kmol K
293.2
4
*
s-TP C2H6 = 200 + 30.071.766 ln 173.2 - 8.3145 ln 1
= 200 + 27.96 - 11.53 = 216.43 kJ/kmol K
*
s= 0.5148.84 + 0.5216.43
TP MIX
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Pi =10 MPaA
o
Ti = 25 C
T1 = 25 oC
P2 = 10 MPa, T2 = 25 oC
V=0.05 3
m B
Z2 = 0.32
P2V
10 0000.05
- = 0.328.3145298.2 = 0.6302 kmol
Z2RT2
4560
Pr1 = 7380 = 0.618
4.56
= 0 + (0-8.3145 ln 0.1 ) - 0.60 8.3145 = -36.75 kJ/kmol K
*
*
*
*
s-i = s-A0 + (s-Pi Ti-s-P0 T0)A + (s-i-s-Pi Ti)A
10
= 0 + (0-8.3145 ln 0.1) - 2.448.3145 = -58.58 kJ/kmol K
*
*
*
*
s-2 = s-MIX 0 + (s-P2 T2-s-P0 T0)MIX + (s-2-s-P2 T2)MIX
10
= 4.161 + (0-8.3145 ln 0.1) - 2.5518.3145 = -55.34 kJ/kmol K
Sgen = 0.6302(-55.33) - 0.126(-36.75) - 0.5042(-58.58) + 1149/298.2
= +3.15 kJ/K
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Borgnakke Sonntag
Fundamentals of
Thermodynamics
SOLUTION MANUAL
CHAPTER 12
English Units
8e
UPDATED JULY 2013
CHAPTER 12
CONTENT CHAPTER 12
SUBSECTION
PROB NO.
Clapeyron equation
Volume Expansivity and Compressibility
Equations of State
Generalized Charts
Mixtures
Review problem
149-153
154-160
161-162
163-178
179-181
182
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Clapeyron Equation
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12.149E
Verify that Clapeyrons equation is satisfied for R-410A at 30 F in Table F.9.
Clapeyron Eq.:
F.9:
P = 111.796 psia,
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12.150E
Use the approximation given in Problem 12.16 and Table F.7 to determine A and
B for steam from properties at 70 F only. Use the equation to predict the
saturation pressure at 80 F and compare to table value.
dPsat
-2
dT = Psat (-B)(-T )
so we notice from Eq.12.7 and Table values from F.7.1 and F.4 that
hfg
1053.95
B = R = 85.76 / 778 = 9561.3 R
Now the constant A comes from the saturation pressure as
9561.3
A = ln Psat + B/T = ln 0.363 + 459.67 + 70 = 17.038
Use the equation to predict the saturation pressure at 80 F as
9561.3
ln Psat = A B/T = 17.038 - 459.67 + 80 = -0.6789
Psat = 0.5071 psia
compare this with the table value of Psat = 0.507 psia and we have a very accurate
approximation.
ln Psat = A B/T
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12.151E
Find the saturation pressure for refrigerant R-410A at 100 F assuming it is higher
than the triple point temperature.
The lowest temperature in Table F.9 for R-410A is -80 F, so it must be
extended to -100 F using the Clapeyron Eq. 12.7 integrated as in example 12.1
At T1 = -80 F = 379.7 R ,
P1 = 8.196 lbf/in.2
and
1.9859
R = 72.585 = 0.027 36 Btu/lbm R
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12.152E
Using thermodynamic data for water from Tables F.7.1 and F.7.3, estimate the
freezing temperature of liquid water at a pressure of 5000 lbf/in.2.
P
5000 psia
dPif hif
H2O dT = Tv constant
if
At the triple point,
T.P.
at P = 5000 lbf/in2,
(5000-0.09)
T 32.02 + (-1085.8) = 27.4 F
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12.153E
Ice (solid water) at 27 F, 1 atm is compressed isothermally until it becomes liquid.
Find the required pressure.
Water, triple point T = 32.02 F = 491.69 R,
vf = 0.016 022 ft3/lbm,
hf = 0.00 Btu/lbm
Clapeyron
P = 0.088 67 lbf/in.2
hi = -143.34 Btu/lbm
dPif
hf - hi
143.34778.2
=
=
dT (vf - vi)T -0.001 451491.69144 = -1085.8 psia/R
dPif
P dT T = -1085.8 (27 - 32.02) = 5450.7 lbf/in.2
P = Ptp + P = 5451 lbf/in.2
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12.154E
Determine the volume expansivity, P, and the isothermal compressibility, T, for
water at 50 F, 500 lbf/in.2 and at 400 F, 1500 lbf/in.2 using the steam tables.
Water at 50 F, 500 lbf/in.2 (compressed liquid)
1 v
1 v
P = v( )P v( )P
T
T
Using values at 32 F, 50 F and 100 F
1
0.016 1 - 0.015 99
P 0.015 99
= 0.000 101 F-1
100 - 32
1 v
1 v
T = - v( )T - v( )T
P
P
Using values at saturation, 500 and 1000 lbf/in.2
1
0.015 99 - 0.016 02
T - 0.015 99
= 0.000 0019 in.2/lbf
1000 - 0.178
Water at 400 F, 1500 lbf/in.2 (compressed liquid)
1
0.019 25 - 0.017 85
= 0.000 76 F-1
P 0.018 45
450 - 350
1
0.0184 - 0.0185
T - 0.018 45 2000 - 1000 = 0.000 0054 in.2/lbf
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12.155E
Use the CATT3 software to solve the previous problem.
The benefit of the software to solve for the partial derivatives is that we can
narrow the interval over which we determine the slope.
Water at 50 F, 500 lbf/in.2 (compressed liquid)
1 v
1 v
1 v
1 v
P = v( )P v( )P ; T = - v( )T - v( )T
T
T
P
P
Estimate by finite difference using values at 40 F, 50 F and 60 F,
1
0.01601 - 0.01599
= 0.000 0625 F-1
P 0.01600
60 - 40
Using values at saturation, 500 psia and 1000 psia,
1 0.01597 - 0.01602
T - 0.0160 1000 - 0.178 = 0.000 0031 psi-1
Water at 400 F, 1500 lbf/in.2 (compressed liquid)
Estimate by finite difference using values at 350 F, 400 F and 450 F,
1
0.019 26 - 0.017 86
P 0.01 849
= 0.000 757 F-1
450 - 350
Using values at 1000 psia, 1500 psia and 2000 psia,
1
0.01 844 - 0.01 855
T - 0.018 49
= 0.000 0059 psi-1
2000 - 1000
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12.156E
A cylinder fitted with a piston contains liquid methanol at 70 F, 15 lbf/in.2 and
volume 1 ft3. The piston is moved, compressing the methanol to 3000 lbf/in.2 at
constant temperature. Calculate the work required for this process. The isothermal
compressibility of liquid methanol at 70 F is 8.3 106 in.2/lbf.
2
2
v
w
=
Pdv
=
P
dP
=
v PdPT
1 2
T
P T T
( )
=>
vT 2 2
w
=
1 2
2 P2 - P1
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12.157E
Sound waves propagate through a media as pressure waves that causes the media
to go through isentropic compression and expansion processes. The speed of
sound c is defined by c2 = (P/)s and it can be related to the adiabatic
compressibility, which for liquid ethanol at 70 F is 6.4 10-6 in.2/lbf. Find the
speed of sound at this temperature.
c2 =
P
(P
)
=
-v
(
)=
s
v s 1
1
1
=
s
v
-v
P s
( )
32.174144
(6.410
)
48.9
-6
1/2
= 48.9 lbm/ft3
= 3848 ft/s
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12.158E
Consider the speed of sound as defined in Eq. 12.42. Calculate the speed of sound
for liquid water at 50 F, 250 lbf/in.2 and for water vapor at 400 F, 80 lbf/in.2 using
the steam tables.
From Eq 12.42 :
c2 =
P
(P
)
=
-v
(
)
s
v s
2
(P
) (P
)
v s
v
(0.016024+0.015998
) ((500-0.18)14432.174
2
0.015998-0.016024 ) = 22.83210
2
c2 = -
c = 4778 ft/s
Superheated vapor water at 400 F, 80 lbf/in.2
v = 6.217 ft3/lbm,
s = 1.6790 Btu/lbm R
((100-60)14432.174
) = 2.856 10
5.2394-7.7471
c = 1690 ft/s
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12.159E
Liquid methanol at 77 F has an adiabatic compressibility of 7.1 10-6 in2/lbf.
What is the speed of sound? If it is compressed from 15 psia to 1500 psia in an
insulated piston/cylinder, what is the specific work?
From Eq.12.41 and Eq.12.42 and the density from table F.3
c2 =
(P
) = v (P
) = 1 = 7.1 101-6 49.1 144 32.174 ft2/s2
s
v s
2
w = P
dv =
P dP
P (-sv ) dP =
sv P dP = s v
1
= s v 0.5
2
(P2
2
P1)
0.5
= 7.1 10-6 in2/lbf 49.1 ft3/lbm (15002 152) psi2
= 0.163 (ft-lbf/lbm) (ft/in)2 = 23.4 ft-lbf/lbm = -0.03 Btu/lbm
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Equations of State
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12.160E
Use Table F.9 to find the compressibility of R-410A at 140 F and a) saturated
liquid b) saturated vapor and c) 400 psia
.
Table F.1:
a)
b)
c)
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12.161E
Calculate the difference in internal energy of the ideal-gas value and the real-gas
value for carbon dioxide at the state 70 F, 150 lbf/in.2, as determined using the
virial EOS. At this state B = -2.036 ft3/lb mol, T(dB/dT) = 4.236 ft3/lb mol.
Solution:
virial:
RT BRT
P= v + 2 ;
v
RT2 dB
P
RT2 dB
u-u = - T
dv = - v dT
- P dv = -
2
T v
v
v v dT
*
[( ) ]
B = -2.036 ft3/lbmol
( )
dB
T dT = 4.236 ft3/lbmol
( )
But
1+4BP/RT
RT 1545529.7
P = 150144 = 37.8883
] = 35.7294 ft /lbmol
v- = 0.537.8883 1 + 1+4(-2.036)/37.8883
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Generalized Charts
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12.162E
How low should the pressure be so that nitrous oxide (N2O) gas at 501.6 R can be
treated as an ideal gas with 5% accuracy or better?
From Table F.1:
Tc = 557.3 R,
Pc = 1050 psi
501.6
=> Tr1 = 557.3 = 0.9
Look in Fig. D.1 following the curve Tr1 = 0.9 to the point where Z = 0.95
Pr1 = 0.125
so
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12.163E
Nitrous oxide (N2O) at 501.6 R is at a pressure so that it can be in a two-phase
state. Find the generalized enthalpy departure for the two saturated states of liquid
and vapor.
From Table F.1:
Tc = 557.3 R,
Pc = 1050 psi
501.6
=> Tr1 = 557.3 = 0.9
From Fig. D.2:
Saturated liquid:
Saturated vapor:
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12.164E
Find the heat of evaporation, hfg, for R-134a at 30 F from the generalized charts
and compare to the value in Table F.10.
Tc = 673.6 R,
489.7
Pc = 589 psia => Tr1 = 673.6 = 0.727
Saturated vapor:
The approximation is not very good and can be improved by using the
accentric factor.
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12.165E
A 7-ft3 rigid tank contains propane at 1300 lbf/in.2, 540 F. The propane is then
allowed to cool to 120 F as heat is transferred with the surroundings. Determine
the quality at the final state and the mass of liquid in the tank, using the
generalized compressibility charts.
Propane C3H8:
V = 7.0 ft3, P1 = 1300 lbf/in.2, T1 = 540 F = 1000 R
cool to T2 = 120 F = 580 R
From Table F.1 : TC = 665.6 R, PC = 616 lbf/in.2
1300
1000
Pr1 = 616 = 2.110, Tr1 = 665.6 = 1.502
From D.1: Z1 = 0.83
v2 = v1 =
Z1RT1
P1
From D.1 at Tr2 = 0.871, saturated => PG2 = 0.43 616 = 265 lbf/in.2
vG2 =
vF2 =
=>
x2 = 0.3388
7.0
mLIQ 2 = (1 - 0.3388) 0.1554 = 29.8 lbm
These tanks
contain liquid
propane.
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12.166E
A rigid tank contains 5 lbm of ethylene at 450 lbf/in.2, 90 F. It is cooled until the
ethylene reaches the saturated vapor curve. What is the final temperature?
C2H4 m = 5 lbm
C2 H4
T
1
450
Pr1 = 731 = 0.616,
2
Fig. D.1
549.7
Tr1 = 508.3 = 1.082
Z1 = 0.82
v
Z2Tr2
ZG2Tr2
Pr2 = Pr1 Z T = 0.616
= 0.6943 ZG2Tr2
0.82 1.082
1 r1
Trial & error to match a saturated Pr2, Tr2 and the ZG2 so Eq. is satisfied.
Guess a Tr2 and find the rest and compare with computed Pr2 from Eq.
Tr2
ZG2
0.871 0.715
Pr2
Pr2 CALC
0.43
0.432
~ OK
=> T2 = 442.7 R
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12.167E
A piston/cylinder contains 10 lbm of butane gas at 900 R, 750 lbf/in.2. The butane
expands in a reversible polytropic process with polytropic exponent, n = 1.05,
until the final pressure is 450 lbf/in.2. Determine the final temperature and the
work done during the process.
C4H10 ,
m = 10 lbm , T1 = 900 R ,
P1 = 750 lbf/in.2
n
P2V2
Z1 = 0.67
750
V2 = 1.484 450
( )
1
1.05
= 2.414 ft3
W = PdV =
1 2
1
Tr2 = 1.068,
P2V2 - P1V1
1-n
Z2 = 0.72
=>
T2 = 817.4 R
- 750 1.484
(450 2.414
) 144
778 = 98.8 Btu
1 - 1.05
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12.168E
Calculate the heat transfer during the process described in Problem 12.167E.
From solution 12.167,
V1 = 1.473 ft3,
V2 = 2.396 ft3,
Tr1 = 1.176,
Pr1 = 1.361,
From D.1:
h*-h
RTC
( )
= 1.36,
W2 = 98.8 Btu
Tr2 = 1.068,
h*-h
RTC
( )
26.58765.4
(-0.95 + 1.36) = -23.6 Btu/lbm
778
4501442.414 7501441.484
+
= -231.1 Btu
778
778
1 2
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12.169E
The new refrigerant R-152a is used in a refrigerator with an evaporator
temperature of -10 F and a condensing temperature of 90 F. What are the high and
low pressures in this cycle?
Since we do not have the printed tables for R-152a we will use generalized charts.
The critical properties are: Tc = 695.5 R, Pc = 656 psi.
Tr1 = T/Tc = (459.67 10)/ 695.5 = 0.646
Fig. D.1:
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12.170E
A cylinder contains ethylene, C2H4, at 222.6 lbf/in.2, 8 F. It is now compressed in
a reversible isobaric (constant P) process to saturated liquid. Find the specific
work and heat transfer.
Ethylene C2H4 P1 = 222.6 lbf/in.2 = P2, T1 = 8 F = 467.7 R
State 2: saturated liquid, x2 = 0.0
R = 55.07 ft lbf/lbm R = 0.070 78 Btu/lbm R
467.7
222.6
Tr1 = 508.3 = 0.920 Pr1 = Pr2 = 731 = 0.305
*
Z1 = 0.85 ,
v1 =
Z1RT1
P1
h -h
(RT
)
C
= 0.40
Z2RT2
P2
h*-h
RTC
( )
=
= 4.42
144
Pdv = P(v2-v1) = 222.6(0.035 89 - 0.683)
w =
778 = -26.7 Btu/lbm
1 2
1 2
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12.171E
Saturated vapor R-410A at 80 F is throttled to 30 lbf/in.2 in a steady flow process.
Find the exit temperature, neglecting kinetic energy, using the generalized charts,
Fig. D.2 and repeat using Table F.9.
R-410A throttling process, R = 1.98589/72.585 = 0.02736 Btu/lbm-R
T1 = 80 F, x1 = 1.00, P2 = 30 lbf/in.2,
*
Energy Eq.:
Generalized charts,
From D.2:
539.7
Tr1 = 620.1 = 0.87
To get CP0, use h values from Table F.9 at low pressure (5 psia).
CP0
137.6-133.75
= 0.1925 Btu/lbm R
80-60
30
at Pr2 = 711 = 0.042
469.7
Assume T2 = 10 F = 469.7 R => Tr2 = 620.1 = 0.757
*
T1 = 80 F, x1 = 1.0
12.172E
Find the heat of evaporation, hfg, for isobutane (Tc = 735.8 R, Pc = 529.4
psia, M = 58.124) at 54.7 F from the generalized charts and compare to the values
in the CATT3 computerized tables.
To read the charts we need the reduced temperature
Tr1 = T/Tc = (54.7 + 459.7)/735.8 = 0.70
R = 1.98589 / 58.124 = 0.03417 Btu/lbm-R
From Fig. D.2:
The generalized charts are not super accurate, some improvement can be
done using the accentric factor.
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12.173E
A 10-ft3 tank contains propane at 90 F, 90% quality. The tank is heated to 600 F.
Calculate the heat transfer during the process.
P
V = 10 ft3
T1 = 90 F = 549.7 R, x1 = 0.90
PC = 616 lbf/in.2
h1-h1
Pr
= 0.31 ;
PV
m = ZRT =
Pr2 =
SAT
P1
191 144 10
= 20.2 lbm
0.707 35.04 549.7
Pr2 = 0.79
Trial & error:
Z2 = 0.94
*
Z2
= 1.183
at Tr2 = 1.592
h2-h2
and RT = 0.36
c
144 10
778
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12.174E
Carbon dioxide collected from a fermentation process at 40 F, 15 lbf/in.2 should
be brought to 438 R, 590 lbf/in.2 in a steady flow process. Find the minimum
amount of work required and the heat transfer. What devices are needed to
accomplish this change of state?
35.1
R = 778 = 0.045 12 Btu/lbm R
500
Tri = 547.4 = 0.913 ,
15
Pri = 1070 = 0.014
*
h -h
(RT
) = 0.02, (sR-s) = 0.01 R
438
Tre = 547.4 = 0.80,
From D.2 and D.3:
*
590
Pre = 1070 = 0.551
se-se = 4.70 R
* *
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12.175E
A cylinder contains ethylene, C2H4, at 222.6 lbf/in.2, 8 F. It is now compressed
isothermally in a reversible process to 742 lbf/in.2. Find the specific work and
heat transfer.
Ethylene C2H4 ,
T2 = T1 = 8 F = 467.7 R
222.6
Pr1 = 731 = 0.305
*
Z1 = 0.85 ,
h -h
(RT
)
C
= 0.40
= 0.0212 Btu/lbm R
742
Pr2 = 731 = 1.015 (comp. liquid)
From D.1, D.2 and D.3:
Z2 = 0.17
(h2-h1) = 0
742
* *
(s2-s1) = 0 - 0.070 78 ln 222.6 = -0.0852
q = T(s2-s1) = 467.7(-0.2548 - 0.0852 + 0.0212) = -149.1 Btu/lbm
1 2
1 2
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12.176E
A geothermal power plant on the Raft river uses isobutane as the working fluid.
The fluid enters the reversible adiabatic turbine at 320 F, 805 lbf/in.2 and the
condenser exit condition is saturated liquid at 91 F. Isobutane has the properties
Tc = 734.65 R, Pc = 537 lbf/in.2, Cpo = 0.3974 Btu/lbm R and ratio of specific
heats k = 1.094 with a molecular weight as 58.124. Find the specific turbine work
and the specific pump work.
R = 26.58 ft lbf/lbm R = 0.034 166 Btu/lbm R
Turbine inlet: Tr1 = 779.7 / 734.7 = 1.061,
Condenser exit: T3 = 91 F , x3 = 0.0 ;
From D.1 :
=> x2 = 0.9955
ZF3RT3
P3
144
vdP vF3(P4 -P3) = -0.031 55(805-88.6)
wP = -
778 = -4.2 Btu/lbm
3
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12.177E
A line with a steady supply of octane, C8H18, is at 750 F, 440 lbf/in.2. What is
your best estimate for the availability in an steady flow setup where changes in
potential and kinetic energies may be neglected?
Availability of Octane at
and
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12.178E
A distributor of bottled propane, C3H8, needs to bring propane from 630 R, 14.7
lbf/in.2 to saturated liquid at 520 R in a steady flow process. If this should be
accomplished in a reversible setup given the surroundings at 540 R, find the ratio
of the volume flow rates Vin /Vout, the heat transfer and the work involved in the
process.
.
Zi = 0.99
Ze = 0.035
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Mixtures
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12.179E
A 4 lbm mixture of 50% argon and 50% nitrogen by mole is in a tank at 300 psia,
320 R. How large is the volume using a model of (a) ideal gas and (b) Kays
rule with generalized compressibility charts.
a) Ideal gas mixture
Eq.11.5:
Mmix = yi Mi = 0.5 39.948 + 0.5 28.013 = 33.981
R = 1545.36 / 33.981 = 45.477 lbf-ft/lbm-R
mRT 4 45.477 320
lbf-ft
V= P =
= 1.347 ft3
300 144
psi in2/ft2
b) Kays rule Eq.12.84
Pc mix = 0.5 706 + 0.5 492 = 599 psia
Tc mix = 0.5 271.4 + 0.5 227.2 = 249.3 R
300
320
Reduced properties:
Pr = 599 = 0.50, Tr = 249.3 = 1.284
Fig. D.1: Z = 0.92
mRT
V = Z M P = Z VID gas = 0.92 1.347 = 1.24 ft3
mix
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12.180E
R-410A is a 1:1 mass ratio mixture of R-32 and R-125. Find the specific volume
at 80 F, 200 psia using Kays rule and the generalized charts and compare to Table
F.9
Kays rule Eq.12.84
Pc mix = 0.5 838 + 0.5 525 = 681.5 psia
Tc mix = 0.5 632.3 + 0.5 610.6 = 621.45 R
200
539.67
Reduced properties: Pr = 681.5 = 0.293, Tr = 621.45 = 0.868
Table F.1: R = 1545.36 / 72.585 = 21.29 lbf-ft/lbm-R
Fig. D.1: Z = 0.82
ZRT 0.82 21.29 539.67 lbf-ft/lbm
= 0.327 ft3/lbm
v= P =
200 144
psi in2/ft2
Table F.9:
v = 0.3174 ft3/lbm
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12.181E
The R-410A in Problem 12.180E flows through a heat exchanger and exits at 280
F, 200 psia. Find the specific heat transfer using Kays rule and the generalized
charts and compare this to solution found using Table F.9.
200
Reduced properties 1: Pr1 = 681.5 = 0.293,
539.67
621.45 = 0.868
Fig. D.1:
Reduced properties 2:
Fig. D.1:
Tr1 =
Pr2 =
200
681.5 = 0.293,
739.67
Tr2 = 621.45 = 1.19
The main difference is in the value of specific heat, about 0.25 Btu/lbm-R at
the avg. T, whereas it is 0.1925 Btu/lbm-R at 77 F.
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Review Problem
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12.182E
A new compound is used in an ideal Rankine cycle where saturated vapor at 400
F enters the turbine and saturated liquid at 70 F exits the condenser. The only
properties known for this compound are a molecular mass of 80 lbm/lbmol, an
ideal gas heat capacity of Cpo = 0.20 Btu/lbm-R and Tc = 900 R, Pc = 750 psia.
Find the specific work input to the pump and the cycle thermal efficiency using
the generalized charts.
T1 = 400 F = 860 R
1
.
WT
Turbine
.
QH
Ht.
Exch
T3 = 70 F = 530 R
2
Cond
P
4
.
-W P
x1 = 1.0
x3 = 0.0
Properties known:
M = 80, CPO = 0.2 Btu/lbm R
TC = 900 R, PC = 750 lbf/in.2
860
530
Tr1 = 900 = 0.956, Tr3 = 900 = 0.589
Zf3 = 0.0045
wP = -
vdP vf3(P4 -P3) = -0.0168 (570 - 19)
3
144
= -1.71 Btu/lbm
778
wNET
qH
43.9 - 1.7
150.4 = 0.281
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