SCIENCE &
ENGINEERING
ELSEVIER
Abstract
Residual thermal stresses in ceramic matrix composites containing ellipsoidal inclusions are analyzed using a modified Eshelby
model. Closed-form analytical solutions are obtained; however, their formulations are formidable. When the inclusion is
disc-shaped, spherical, or fiber-shaped, simple analytical solutions can be obtained using different models, and they are in excellent
agreement with those obtained from the modified Eshelby model. The analytical solutions are compared with the experimental
and finite element results. Also, effects of the aspect ratio and the volume fraction of inclusions on residual thermal stresses are
examined.
Keywords: Residual thermal stresses; Ceramic composites; Mechanicalproperties
1. Introduction
C.-H. Hsueh, P.F. Becher / Materials Science and Engineering A212 (1996) 22-28
The aspect ratio of the ellipsoid is c/a (e.g. c/a < < 1
for disc-shaped, = 1 for sphere, and > > 1 for fibershaped). When the composite is cooled from its fabrication
temperature,
stresses develop
owing to
thermomechanical mismatch between the matrix and
inclusions. This problem can be analyzed using a
modified Eshelby model, and it is described as follows.
The Eshelby model consists of a sequence of imaginary cutting, straining, and welding operations [8].
During cooling of a composite, the inclusion is subjected to mismatch strains: (71-0~m)ATin the X~ and J[z2
directions and (~3-2m)ATin the X3 direction where AT
is the temperature range for stress development. Hence,
if the inclusion is cut and removed from the matrix
before cooling, the above mismatch strains exist between the inclusion and the matrix after cooling. These
mismatch strains are defined as "transformation
strains", %, in the Eshelby model, such that
e'*
11 --- '*
2 2 = (~l - ~,,)AT
(2a)
(2b)
23
(3a)
Ge(t e lcl -
(3b)
tt*]
"Ill
Gin( ' e lc l - - , e lt l )
(4a)
(4b)
Whereas Eq. (3a) dictates sameness of the dilatational stress, Eq. (3b) dictates sameness of the deviatoric stress between the true and the equivalent
inclusions. It is noted that since the strain in the
inclusion is transversely isotropic (i.e., ell=e22), only
one equation (i.e., Eq. (4b)) is required for the condition of sameness of the deviatoric stress.
The Eshelby model was modified by Mori and
Tanaka to account for the finite volume fraction of
inclusions [9]. Besides the constrained strain induced by
relaxation of the body force at the interface, an additional constrained strain is induced owing to the presence of surrounding inclusions. Hence, for a finite
volume fraction of inclusions, the constrained strain,e}),
consists of two components, such that
C.-H. Hsueh, P.F. Becher / Materials Science and Engineering A212 (1996) 22-28
24
g~j
. .--. . .e~j
. . + esj
(5)
Vmgm
(1 + Vm)(1 ~
2Vn~ ~
gm
( g - - g ) ' q - ,. ~
l-]-v m
(12a)
(6)
eij = Sii~lgkl
Vmgm
Em
0"33 = ( 1 + Vm)(1 -- 2Vm) (ec -- et) + ~
(e33 --833)
(12b)
The average stress in the inclusion, ~, is
6=
20"11 + 0"33
3
(13)
-f#
(14)
1-f
(7)
(8)
g~3 =
t*
t*
-(a21Ke-a1,Ge)g33-(2a21kKe+a11Ge)g11
alla22--a12a21
(a22Ke-a12Ge)e~-k(2a22KeWa12Ge)g~
(9b)
alla22--a12a21
where
(10a)
(10b)
(10c)
a22 = -- Gm + [ - f + (1 -f)(283311
--
81111
--
When the aspect ratio, c/a, of the ellipsoidal inclusion approaches zero, the inclusion becomes a disc with
radius a and thickness c and a > > c. The representative volume element of the composite is a disc-shaped
inclusion sandwiched by two discs of fnatrix (Fig. 1
(a)). In the X 3 direction, there is no constraint and the
residual thermal stresses are zero in both the matrix
and the inclusion (i.e., 033 = 0 ) . In the X 1 and the X"2
directions, continuity of the displacement between the
inclusion and the matrix is required, such that
81122)]
x (Ge-- am)
(lOd)
Em
(1 1)
25
C.-H. Hsueh, P.F. Becher / Materials Science and Engineering A212 (1996) 22 28
(15)
Em
,f0-11 + (1 -J)0-]l(,.)= 0
f(1
--+
Ee
(17)
Vm)
(1 - f ) E m
When the aspect ratio, c/a, of the ellipsoidal inclusion is equal to one, the inclusion becomes a sphere
with radius a. The representative volume element of the
composite is a composite sphere (Fig. 1 (b)). This
problem has been analyzed when the CTE in the inclusion, ~, is isotropic. In this case, the residual thermal
stress in the spherical inclusion is hydrostatic such that
[14]
~e)AT
(,Z m --
3K:
4(l'-f)Gm
(18)
3(I-j')K m
When Eq. (18) is compared with the solution obtained from the modified Eshelby model for the case of
c/a = 1, ~e = (20~1 -~ ~3)/3 is assumed in this study.
3.3. The fiber-shaped inclusion
When the aspect ratio, c/a, of the ellipsoidal inclusion is much greater than one, the inclusion becomes an
infinitely long fiber with a radius a. The representative
volume element of the composite is a composite cylinder (Fig. 1 (c)). The residual thermal stress in the fiber
has been analyzed, such that [15]
'1
+ ~
2
352
407
:~ ( x l 0
0.21
0.23
4.45
8.34
6 of)
(l-f)eo, J (~m--~3) AT
-500
Disc-Shaped
Spherical
Fiber-Shaped
-1000
(19a)
~+(l__f)Emj(~gm-~l)
[-l--v e 1 + f + ( 1 - - f ) V m ] ,
+L-V
+
(19b)
-1500
W
~ -20OO
. . . .
i
5
where A is given by
A=
+ (1 --~)Em
0-11=0-22=A
0-33~.--=--A
fl-SiC
~-A1203
(GPa)
4. Results
(C~m-- ~,)AT
1 - - v~
(16)
Table 1.
Material properties of SiC whisker-reinforced AI203 composites
. . . .
10
i
15
. . . .
20
ASPECT RATIO, c / a
(l+Ve)(1--2Ve) + f(2-ve
E~2
-+ f(1 + vm)(1 + f - - 2fVm)]
( ] --f)2Em2
. . . .
Vm 4VeVm)+ 1 + Vm
(1 --f)EeEm
-
(2O)
C.-H. Hsueh, P.F. Becher Materials Science and Engineering A212 (1996) 22-28
26
o
E (GPa)
cq ( X 10 - 6 C)
63
385
70
0.2
0.35
25
236
0
236
( x 10 - 6
C)
-500
Graphite
AI
t/)
/)
w
rr
Table 2
Material properties of graphite fiber-reinforced AI composites
-1000
w
~ -1500
-2000
02
0,4
0.6
0.8
VOLUME FRACTION, .t
Fig. 3. The calculated asymptotic values (i.e., for the cases of c/a >
10) of 0"~,, 0"33, and # in ellipsoidal inclusions for SiC/AI20 3 composites. The measured # is also shown
_o
u)
[-
_z
_z 3
I
LU
n"
Ju)
Spherical
Fiber-Shaped
l []
Finite
Element
.oll..
ll
LU
T
I--
~-~
, i , , . i . . , i . . . i , , ,1
0.2
0.4
0.6
0.8
1.
c/a
rr
-1
20
40
60
80
ASPECT
RATIO,
100
c/a
C.-H. Hsueh, P.F. Beeher / Materials Science and Engineering A212 (1996) 22 28
0.5
'
(3
0.0
cd
I E] SquaroArray
LU
ffl
-0.5
Army]
O Hexagonal
.~ -1.0
O
LU
re
-1.5
-2.0
0.2
0.4
0.6
0.8
5. Conclusions
Using a modified Eshelby model, closed-form analytical solutions are derived for residual thermal stresses in
27
Acknowledgements
The authors thank Drs. E.Y. Sun and K.J. Kozaczek
for reviewing the manuscript. Research sponsored by
the US Department of Energy, Division of Materials
Sciences, Office of Basic Energy Sciences, under contract DE-AC05-84OR21400 with Lockheed Martin Energy Systems.
Appendix A
The Eshelby tensor for ellipsoidal inclusions
28
C.-H. Hsueh, P.F. Becher / Materials Science and Engineering A212 (1996) 22-28
given by
83333 =
References
(A1)
Qc2/Cc + R/C
- RIa
(A2)
(A3)
(A4)
(A5)
83311 = 53322 =
Qa2/ca - R/C
-- RIa
(A6)
1 -2%
(A7)
8re(1 - Yr.)
[c(c
I a (c2_a2)3/2
\~-
1"~1/2
,]
(c)]
-cosh-'
(A8)
(l_CZ'~I/2l
\
a2] ]
(A9)
For the above two cases (i.e., c/a ~ 1), the remaining
coefficients can be related to Ia by
/C = 4zr - 2Ia
(A10)
Ia-L
/ca =
3(c 2 _ a 2)
(A11)
4rr
/ c c - 3c 2
2~ca
(A12)
rc
lab = 3a 2
/ca
4
(A13)
/cb --
Iaa = 3Iab
(AI4)
(c/a =
1)
4rr
/ =/C = -3-
(A15)
4z
Iaa =/co = 3/Ca = 3/cb = 3/ab = 5a 2
(A16)