CHEMCAD

6.2.0

Page

Job name:

Debutanizer2Date:

1
10/3/2012 Time:

17:08:19

HEATING CURVES SUMMARY

Eqp #

1 Unit type :

HTXR

Unit name:

Del H
MJ/h

Vapor
kg/h

Stream 4
NP

Temp
C
1
2
3
4
5
6
7
8
9
10
11

Pres
bar
40
55.1
69.7
83.8
97.5
110.9
123.8
136.4
148.7
160.6
171.8

5.5
5.5
5.5
5.5
5.4
5.4
5.4
5.4
5.4
5.4
5.3

0
2.79E+03
5.59E+03
8.38E+03
1.12E+04
1.40E+04
1.68E+04
1.95E+04
2.23E+04
2.51E+04
2.79E+04

Liquid
kg/h
1
0
0
0
0
0
0
0
39
171
629

92325
92326
92327
92327
92327
92327
92327
92327
92287
92155
91698

Vap mole
Vap mass
frac.
frac.
0.0003
0
0.0001
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0009
0.0004
0.0032
0.0019
0.0097
0.0068

Stream 3
NP

Temp
C
1
2
3
4
5
6
7
8
9
10
11

Eqp #
Condenser

Pres
bar
191.9
180.6
169
157.1
144.9
132.4
119.5
106.3
92.8
78.8
64.4

5.3
5.3
5.2
5.2
5.1
5
5
4.9
4.8
4.8
4.7

3 Unit type :

Del H
Vapor
MJ/h
kg/h
2.79E+04
2.51E+04
2.23E+04
1.95E+04
1.68E+04
1.40E+04
1.12E+04
8.38E+03
5.59E+03
2.79E+03
0

TOWR

Unit name:

Liquid
kg/h
0
0
0
0
0
0
0
0
0
0
0

Vap mole
frac.
91798
91798
91798
91798
91798
91798
91798
91798
91798
91798
91798

Vap mass
frac.
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0

NP

Temp
C
1
2
3
4
5
6
7
8
9
10
11

Pres
bar
70.8
73
71.6
70.1
68.3
66.3
63.9
60.8
56.7
50.9
42.1

5.3
5.3
5.3
5.3
5.3
5.3
5.3
5.3
5.3
5.3
5.3

Del H
Vapor
Liquid
Vap mole
Vap mass
MJ/h
kg/h
kg/h
frac.
frac.
5.11E+03
13797
0
1
1
4.60E+03
11950
1847
0.8765
0.8661
4.09E+03
10420
3377
0.7731
0.7552
3.58E+03
8910
4887
0.67
0.6458
3.07E+03
7432
6366
0.568
0.5386
2.55E+03
5995
7802
0.4675
0.4345
2.04E+03
4616
9182
0.3694
0.3345
1.53E+03
3318
10479
0.2751
0.2405
1.02E+03
2144
11653
0.1874
0.1554
511
1174
12623
0.112
0.0851
0
527
13270
0.0591
0.0382

Reboiler
NP

Temp
C
1
2
3
4
5
6
7
8
9
10
11

Pres
bar
185.7
186.4
187.1
187.7
188.4
189
189.6
190.2
190.8
191.3
191.9

Del H
MJ/h
5.3
5.3
5.3
5.3
5.3
5.3
5.3
5.3
5.3
5.3
5.3

0
980
1.96E+03
2.94E+03
3.92E+03
4.90E+03
5.88E+03
6.86E+03
7.84E+03
8.82E+03
9.80E+03

Vapor
kg/h
0
2702
5441
8214
11017
13846
16700
19576
22472
25387
28319

Liquid
Vap mole
Vap mass
kg/h
frac.
frac.
120141
0
0
117438
0.0243
0.0225
114699
0.0488
0.0453
111926
0.0734
0.0684
109124
0.0982
0.0917
106295
0.1231
0.1152
103441
0.148
0.139
100565
0.1731
0.1629
97669
0.1982
0.187
94754
0.2234
0.2113
91822
0.2486
0.2357

Dew

Bub

CHEMCAD

6.2.0

Page

Job name:

Debutanizer2Date:

Unit type : TOWR Unit name:

Temp
C

Stg
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26

1
10/3/2012 Time:

Eqp # 3

Pres
bar
42.2
70.8
78.7
83.2
87.3
92.8
101.9
117.5
139.9
173.6
175.9
176.6
177.1
177.5
177.9
178.3
178.7
179.2
179.8
180.4
181.1
181.9
182.9
184.1
185.7
191.9

17:08:19

5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35
5.35

* Net Flows *
Liquid
Vapor
Feeds
Product
Duties
kmol/h
kmol/h
kmol/h
kmol/h
MJ/h
202.13
12.72
-5108
226.44
214.85
228.38
239.16
225.83
241.1
218.73
238.55
205.63
231.45
186.03
218.35
164.86
198.75
142.32
177.58
1052.17
155.03
861.14
1075.1
203.75
1082.23
226.68
1086.06
233.81
1089.3
237.64
1091.79
240.88
1094.41
243.37
1097.36
245.99
1100.78
248.94
1104.27
252.36
1108.36
255.85
1112.83
259.94
1117.92
264.41
1123.55
269.5
1129.94
275.13
1129.38
281.52
280.96
848.42
9797

Mole Reflux ratio 15.891

Total liquid entering stage
10 at

167.367 C

991.281 kmol/h.

CHEMCAD

6.2.0

Page

Job name:

Debutanizer2Date:

1
10/3/2012 Time:

17:08:18

CHEMCAD

6.2.0

Job name:

Debutanizer2Date:

FLOW SUMMARIES:
Stream No.
Stream Name
Temp C
Pres bar
Enth MJ/h
Vapor mass frac.
Total kmol/h
Total kg/h
Total std L m3/h
Total std V m3/h
Flowrates in kg/h
Hydrogen
Methane
Ethane
Propane
Isobutane
N-Butane
Isopentane
N-Pentane
N-Hexane
N-Heptane
N-Octane
N-Nonane
N-Decane
Benzene
Toluene
O-Xylene
Cyclohexane
Cycloheptane
Methylcyclohexan
1-1-Dimethylcycl
1-3-5-Trimethylb
P-Cymene
1-trans-3-5-Trim
1-2-3-4-Tetramet

Page

1
171.7746
5.3494
-75242
0
861.1404
92326.5582
117.8308
19301.3
5.6075
4.2316
50.348
111.6402
70.8815
86.666
705.912
0
2638.035
9948.7735
14517.1591
13517
2064.1536
2855.2889
10944.5256
18901.9737
13.8578
0
44.3727
73.5964
14182.6029
1523.4179
59.9816
6.5448

1
10/3/2012 Time:

17:08:18

2
3
4
5
Distillate
Bottom
Feed
42.1608
191.8796
40
64.3776
5.3494
5.3494
5.5
4.7064
-1186.7
-69366 -1.03E+05
-97292
1
0
0
0
12.7197
848.421
861.1404
848.4206
528.6769 91797.9034 92326.5582 91797.8892
1.0493
116.7815
117.8308
116.7815
285.09
19016.21
19301.3
19016.2
5.6075
4.2316
50.348
111.6394
70.7688
85.8229
199.3785
0
0.5471
0.0324
0.0022
0.0002
0
0.2807
0.0157
0.0009
0.0006
0
0.0001
0
0.0001
0
0
0

0
0
0
0.0008
0.1127
0.8435
506.5334
0
2637.4879
9948.7416
14517.1582
13517.0012
2064.154
2855.0087
10944.5124
18901.9754
13.8571
0
44.3726
73.5964
14182.6046
1523.418
59.9816
6.5448

5.6075
4.2316
50.348
111.6402
70.8815
86.666
705.912
0
2638.035
9948.7735
14517.1591
13517
2064.1536
2855.2889
10944.5256
18901.9737
13.8578
0
44.3727
73.5964
14182.6029
1523.4179
59.9816
6.5448

0
0
0
0.0008
0.1048
0.7954
506.5458
0
2637.5041
9948.7451
14517.1627
13517
2064.154
2855.0149
10944.5124
18901.9808
13.8572
0
44.3726
73.5964
14182.6082
1523.4181
59.9816
6.5448

CHEMCAD

6.2.0

Job name:

Debutanizer2Date:

STREAM PROPERTIES
Stream No.
Name
- - Overall - Molar flow kmol/h
Mass flow kg/h
Temp C
Pres bar
Vapor mole fraction
Enth MJ/h
Tc C
Pc bar
Std. sp gr. wtr = 1
Std. sp gr. air = 1
Degree API
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
- - Vapor only - Molar flow kmol/h
Mass flow kg/h
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
Cp J/kmol-K
Z factor
Visc Pa-sec
Th cond W/m-K
- - Liquid only - Molar flow kmol/h
Mass flow kg/h
Average mol wt
Actual dens kg/m3
Actual vol m3/h
Std liq m3/h
Std vap 0 C m3/h
Cp J/kmol-K
Z factor

Page

1
10/3/2012 Time:

2
Distillate

861.1405
92326.5582
171.7746
5.3494
0.009709
-75242
318.3667
33.13
0.784
3.702
49.0877
107.2143
464.3622
198.8244
117.8308
19301.2989

Feed

12.7197
848.421
861.1405
848.4206
528.6769 91797.9034 92326.5582 91797.8892
42.1608
191.8796
40
64.3776
5.3494
5.3494
5.5
4.7064
1
0 0.0002979
0
-1186.7
-69366 -1.03E+05
-97292
108.071
319.8486
318.3667
319.8486
79.3094
32.0236
33.13
32.0235
0.504
0.786
0.784
0.786
1.435
3.736
3.702
3.736
149.3454
48.5103
49.0877
48.5103
41.5638
108.1985
107.2143
108.1986
9.0215
608.7095
753.9585
744.2783
58.6017
150.8074
122.4558
123.3381
1.0493
116.7815
117.8308
116.7815
285.094 19016.2084 19301.2989 19016.1996

8.3612
12.7197
628.5113
528.6769
75.1704
41.5638
11.7242
9.0215
53.6081
58.6017
0.896
1.0493
187.4039
285.094
163566.636 81381.5723
0.9273
0.9402
1.00E-05
8.84E-06
0.0351
0.0303
852.7793
91698.0563
107.5285
631.4582
145.2163
116.9348
19113.8945
280755.604
0.0282

3
Bottom

17:08:17

0.2565
1.149
4.4789
0.9441
1.217
0.0082
5.7498
31709.5199
1.0023
9.86E-06
0.1525
848.421
860.8839
848.4206
91797.9034
92325.41 91797.8892
108.1985
107.2449
108.1986
608.7095
761.5175
744.2783
150.8074
121.2387
123.3381
116.7815
117.8226
116.7815
19016.2084 19295.5488 19016.1996
294787.438 211380.998 224718.41
0.0283
0.0343
0.0281

Visc Pa-sec
Th cond W/m-K
Surf. tens. N/m

0.000169
0.0897
0.0094

0.0001534
0.0844
0.0078

0.0004787
0.1252
0.0223

0.0003825
0.1192
0.0203

CHEMCAD

6.2.0

Page

Job name:

Debutanizer2Date:

1
10/3/2012 Time:

EQUIPMENT SUMMARIES
Heat Exchanger Summary
Equip. No.
Name
1st Stream dp bar
2nd Stream dp bar
U W/m2-K
Area/shell m2
No. of SS Passes
No. of TS Passes
Calc Ht Duty MJ/h
LMTD (End points) C
LMTD Corr Factor
Calc U W/m2-K
Calc Area m2
1st Stream Pout bar
2nd Stream Pout bar

1
0.1506
0.643
698.6333
500.7961
1
1
27926.2051
22.1727
1
698.6333
500.7961
5.3494
4.7064

Towr Rigorous Distillation Summary

*** Equip. 3 ***

Cant converge with original specs. Alternative optimal solution is found.
Equip. No.
Name
No. of stages
1st feed stage
Condenser type
Condenser mode
Condenser spec.
Reboiler mode
Reboiler spec.
Initial flag
Calc cond duty MJ/h
Calc rebr duty MJ/h
Est. Dist. rate
(kmol/h)
Est. Reflux rate

3
26
10
1
11
528
11
91798
1
-5108.4482
9797.0342
12.7204
202.1368

17:08:17

(kmol/h)
Est. T top C
Est. T bottom C
Tray type
Column diameter m
Tray space m
Thickness (top) m
Thickness (bot) m
No of sections
Top efficiency
Bottom efficiency
Calc Reflux ratio
Calc Reflux mole
(kmol/h)
Calc Reflux mass kg/h
No of passes (S1)
Weir side width m
Weir height m
System factor
Optimization flag

88.4455
191.8824
3
1.9812
0.6096
0.0063
0.0079
1
0.67
0.5
15.8915
202.1339
13268.708
1
0.3683
0.0508
1
1

CHEMCAD

6.2.0

Job name:

Debutanizer2Date:

COMPONENTS
ID #
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24

Page

1
2
3
4
5
6
7
8
10
11
12
13
14
40
41
42
38
356
39
87
77
382
609
2022

1
10/3/2012 Time:

17:08:17

Name
Formula
Hydrogen
H2
Methane
CH4
Ethane
C2H6
Propane
C3H8
Isobutane C4H10
N-Butane
C4H10
Isopentane C5H12
N-Pentane C5H12
N-Hexane C6H14
N-Heptane C7H16
N-Octane
C8H18
N-Nonane C9H20
N-Decane C10H22
Benzene
C6H6
Toluene
C7H8
O-Xylene
C8H10
Cyclohexane C6H12
CycloheptaneC7H14
Methylcyclohexan
C7H14
1-1-Dimethylcycl
C8H16
1-3-5-Trimethylb
C9H12
P-Cymene C10H14
1-trans-3-5-Trim
C9H18
1-2-3-4-Tetramet
C10H20

THERMODYNAMICS
K-value model : SRK
Enthalpy model : Mixed Model
Liquid densityLibrary
:
Std vapor rate reference temperature is 0 C.
Atmospheric pressure
1.0132
is bar.
SRK Parameters:
Bip A + B * T + C * T * T T Temperature in degree K
I

J
1
1

A
2
3

B
-0.009
-0.014

C
0
0

0
0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6

4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
10

0.07996
0.12164
0.14455
0.20031
0.21667
0.28828
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
0.32358
-0.0004

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

CHEMCAD

6.2.0

Page

Job name:

Debutanizer2Date:

1
10/3/2012 Time:

Overall Mass Balance

kmol/h
kg/h
Input
Output
Input
Output
Hydrogen
2.782
2.782
5.608
5.608
Methane
0.264
0.264
4.232
4.232
Ethane
1.674
1.674
50.348
50.348
Propane
2.532
2.532
111.64
111.64
Isobutane
1.22
1.219
70.881
70.874
N-Butane
1.491
1.49
86.666
86.618
Isopentane
9.784
9.784
705.912
705.924
N-Pentane
0
0
0
0
N-Hexane
30.612
30.612
2638.035
2638.051
N-Heptane
99.285
99.285
9948.773
9948.778
N-Octane
127.086
127.086 14517.159 14517.164
N-Nonane
105.389
105.389
13517
13517
N-Decane
14.507
14.507
2064.154
2064.154
Benzene
36.553
36.553
2855.289
2855.296
Toluene
118.78
118.78 10944.526 10944.527
O-Xylene
178.04
178.04 18901.973
18902
Cyclohexane
0.165
0.165
13.858
13.858
Cycloheptane
0
0
0
0
Methylcyclohexan 0.452
0.452
44.373
44.373
1-1-Dimethylcycl 0.656
0.656
73.596
73.596
1-3-5-Trimethylb 117.998
117.998 14182.603 14182.608
P-Cymene
11.35
11.35
1523.418
1523.418
1-trans-3-5-Trim
0.475
0.475
59.982
59.982
1-2-3-4-Tetramet 0.047
0.047
6.545
6.545
Total

861.14

861.14

Overall EnergyMJ/h
Balance
Input
Output
Feed Streams
-103168
Product Streams
-98479.1
Total Heating
9797.03
Total Cooling
-5108.45
Power Added
0
Power Generated
0
Total

-98479.4

-98479.1

92326.558

92326.572

17:08:16

CHEMCAD

6.2.0

Page

Job name:

Debutanizer2Date:

1
10/3/2012 Time:

17:08:16

Calculation mode : Sequential

Flash algorithm : Normal
Equipment Calculation Sequence
1
3
Equipment Recycle Sequence
1
3

Recycle Cut Streams

3

Recycle Convergence Method: Direct Substitution

Max. loop iterations

40

Recycle Convergence Tolerance

Flow rate
Temperature
Pressure
Enthalpy
Vapor frac.

1.00E-03
1.00E-03
1.00E-03
1.00E-03
1.00E-03

Recycle calculation has converged.

Run Time Error and Warning Messages:

*** Equip. 3 ***
Cant converge with original specs. Alternative optimal solution is found.

CHEMCAD

6.2.0

Page

Job name:

Debutanizer2Date:

1
10/3/2012 Time:

17:08:14

FLOWSHEET SUMMARY
Uop ID

Type

Label

Stream Numbers

1 HTXR
3 TOWR

4
1

Stream Connections
Stream

Equipment
From
1
2
3
4
5

To
1
3
3
1

3
1
1

3
-2

-1
-3

-5