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Matrix Treatment Design

PRESENTATION SUMMARY

Preamble

Matrix design methodology

Equipments expected on
location

Assess profitability

Evaluation of the job

Matrix treatment design key


points

Candidate selection
Nature and location of damage

Fluid and additives

Placement strategy

Practical considerations

EP Matrix Treatment Design

PreambleFormation damage

Definition
DEFINITION

Formation damage
is any impairment
of reservoir permeability
around the wellbore
It is a consequence of the
drilling, completion, work
over, production, injection or
stimulation operations
Productivity or Injectivity are
adversely affected

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ONLY TWO TYPES!!!


Although there are a number
of damage mechanisms,
there are only two ways in
which near wellbore
permeability can be reduced:
1)Physical reduction in
pore/pore throat size
2)Relative permeability
reduction

Types of damages

Invasion of Fluids and/or Solids

Deposits

Scales: organic, inorganic


Corrosion
Bacterial slime
Unfiltered solids (injection wells)

Fluid Problems

EP Matrix Treatment Design

Drilling Mud
Cement, frac fluids, acid treatments
Plugged Perforations
Perforation Compaction
Fines Migration

Emulsions
Water Production
Clay swelling
Wettability changes

Origins of formation damage


PROCESS TYPE
FLUID-ROCK
INTERACTION

PHYSICAL PORE SIZE


REDUCTION
Fines migration

RELATIVE PERMEABILITY
REDUCTION
Wettability change due to
surfactant adsorption

Clay swelling Solids

invasion
Adsorption / precipitation of
large molecules (polymers)
FLUID-FLUID
INTERACTION

Scale

Fluid saturation change

Emulsion

Fluid blocking
(water block, gas block)

mud(sludge)
PRESSURE /
TEMPERATURE
REDUCTION

Gas breakthrough
Condensate banking
Water coning

MECHANICAL PROCESS
(stress induced)

Permeability reduction
Perforation plugging

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Types of Mineral SCALES


Production Tubing Scale

Reservoir Scale

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Scale:
Adhering mass of solid formed on a surface in
contact with water hard and impermeable.
Carbonate scale: CaCO3, FeCO3 / Sulfate scale:
CaSO4, BaSO4, SrSO4 /Chloride scale: NaCl,...

Sludge:
Mass of loose precipitated solids that can form in a
location and settle downstream where the flow
velocity is less.

Darcys lawoil wellvertical

= Oil flow rate, stb/d

K H Pe Pwf

re
141 .2 o B 0 ln
rw

K= Permeability, md

= Reservoir thickness, ft

Pe

= Reservoir pressure, psi

Pwf

= Bottom hole flowing pressure, psi

= Oil viscosity, cp

Bo
= Formation volume factor, res
bbls/stb

re

= Reservoir drainage radius, ft

rw

= Wellbore radius, ft

rs

= Damaged zone radius

= Skin factor

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re
rS
rw
ks
Damaged
Zone

kf
Bulk
Formation

Skin definition

S total skin is a dimensionless term


To take into account the additional pressure drop in the
wellbore area
Result from formation damage and other factors
Skin effect is positive if an additional pressure drop is present
Skin effect is negative if the actual Pwf is higher than the ideal
Pwf

EP Matrix Treatment Design

Skin damage equation: permeability reduction


Skin effect is intended to describe
alterations in the near wellbore zone
Nature of radial flow is that pressure
difference increases with logarithm of
distance: the same pressure is consumed
within the 1st foot as within the next ten
,hundred,therefore conceivable that largest
portion of total pressure gradient may be
consumed within the near well bore zone.

rw
rs
re

ks

Ideal:

kf

Q=Kf*H*(PsPwfideal)/141.2*B* *ln(rs/rw)
If damaged:

Q=Ks*H*(PsPwreal)/141.2*B* *ln(rs/rw)
Pwfideal Pwfreal=Q*B* *S/(2*pi*H*K)

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Skin damage equation: permeability reduction

S=
rw

ks
rs

re

kf

Kf Ks

Ks

(ln (rs/rw))

For Rs = 4 ft
Rw = 6 inches (0.5 ft)
Kf = 100 md

If

Ks = 10 md

S = ?

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Skin damage equation: permeability improvement

re

S=

rS
rw

Ks

(ln (rs/rw))

For Rs = 4 ft
Rw = 6 inches (0.5 ft)
Kf = 100 md
ks
Damaged
Zone

EP Matrix Treatment Design

Kf Ks

kf
Bulk
Formation

If

Ks = 1000 md

S = ?

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Skin effect on vertical wells

Completion Efficiency

PI with skin

PI S 0

CE = ln(re/rw) / (ln(re/rw) + S). As ln(re/rw) often ranges between 7 and 9.

+ 100%
50%

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Skin
The

total Skin (ST) is the combination of formation damage and pseudoskins. It is


the total skin value that is obtained directly from a welltest analysis.

Formation Damage:
S>0
Damaged Formation
S=0
Neither damaged nor stimulated
Mathematically defined as an infinitely thin zone that creates a steadystate
pressure drop at the sand face.
S<0
Stimulated formation

Pseudo Skin:
Includes situations such as fractures, partial penetration, turbulence, and
fissures.

The Formation Damage is the only type that can be removed by stimulation.

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Near well bore damage


0

Near well bore damage has


the greatest impact

Completion efficiency

0
1
100%

Retained permeability

0
9
0

8
80%
w
o
lf
la
n
ig
ir
o
f
o
tn
ce
r
e
P

0
7

0
6
60%
0
5

Ks/Kf =
0.50

50%

Ks/Kf =
0.30

30%

Ks/Kf =
0.20
Ks/Kf =
0.10

4
40%
0
3

0
20%
2

20%

Severe but shallow damage


can have the same effect as
lesser deeper damage

How can we tell which type of


damage we have if the
resultant production loss is the
same ?

We can not, we can only look


at the well records and
hypothesis

10%

0
1
0

1 2 3

Radial extent of damaged zone (ft)


With :

EP Matrix Treatment Design

Ke = 50md
Re = 1000ft
Rw = 0.354ft (8 1/2'' OH)

10

15

Skin in horizontal well

S vertical

K 1 ln rdamage

K damage
rw

Rw
Rd
Kd

EP Matrix Treatment Design

S horizontal

kh
kv

S vertical
Lp

Lp: productive length


of the horizontal drain

S horiz < S vertical


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Skin in horizontal well

Stimulation has generally more impact


on vertical wells

Completion Efficiency

200%

Horizontal well

125%
100%

Vertical well
-4

10

15

20

Skin

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Areas of damage
Tubing

Formation
Perforations

Gravel Pack

Tubing

Gravel Pack

Perforations

Formation

Scales
Organic deposits
Silicates, Aluminosilicates
Emulsion

no

Water block

no

no

no

Wettability change

no

no

no

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Sources of formation damage

Drilling & Completion


Cementing
Perforating
Stimulation

Gravel packing

Workover

Production

Injection operations

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I MATRIX DESIGN METHODOLY

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Matrix treatment design methodology


A typical design for a stimulation job should involve the following major
steps
Candidate Selection

Establish Nature and Location of Damage

Treating fluid / Additive Selection

Determine Pressure / Injection Rate

Establish Fluid Volume

Determine Placement strategy

Define Shutin / Cleanup Stages

Assess Profitability through Productivity Improvement

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II CANDIDATE SELECTION

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Candidate selection

Why stimulate
the well ?
Other
issues
Scales

Improve
Production

Drill mud
invasion

What caused
the problem ?
Cement
losses
Perforation
damage

EP Matrix Treatment Design

Bad
stimulation
fluids

Formation
collapse

Incompatible
completion
fluid

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Candidate selection
Other times it may not be very obvious such as when:

Water cut has increased

The formation pressure has declined to the point the reservoir cannot
sustain production

the tubular size is inappropriate

Main possible damage causes to check:

on a new well due to mud losses or cement losses

From perforating debris on a new or existing well

in an old well possibly due to fluid incompatibility and scale formation

Large pressure draw downs that might have caused formation collapse
(sand control)

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III NATURE AND LOCATION


OF DAMAGE

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25

Matrix treatment design methodology

DIAGNOSIS to establish Nature and Location of damage


Tubing Gravel
pack

Perforations

Formation

Scales

possible

possible

possible

possible

Organic
deposits

possible

possible

possible

possible

possible

possible

possible

possible

posible

possible

Silicates
Aluminosili
cates
Emulsion
Waterblock

possible

Wettability
change

possible

EP Matrix Treatment Design

KEY POINTS

well data/history
laboratory test

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Well Candidate Selection Process

Does data
suggest stimulation
will improve PI?

No

No Treatment

Yes

EP Matrix Treatment Design

Matrix acid

Frac acid

candidate?

candidate?

K>10md
oil well

K<10md
oil well

K>1md
gas well

K<1md
gas well

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IV FLUID AND ADDITIVES

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Matrix treatment design methodology

Establish fluid volume and acid (HCl) strength

Calcite

Depend

on the selected
treatment and not on the
formation characteristics

Acid Wash: 10 20 gal/ft

Stimulation: 5070 gal/ft (1 1.5m

/ perforated meter (HCl)

Limestone

EP Matrix Treatment Design

Acid

strength: 15% in all cases


except Low temperature ...

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Matrix treatment design methodology

Treating fluid / Additive Selection


1.Inhibitors
2.Surfactants
3.Diverters
4.Mutual solvents
5.Iron control

6.Clay control
7.Non emulsifying agents

Select the proper


formulation of treating fluid
that will remove the damage
without damaging the rock through
formation of secondary precipitates,
sludge...

This may require laboratory tests.

8.Antisludge agents
9.Scale control

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Matrix treatment design methodology

Corrosion Inhibitor
A

chemical added to acid to reduce


the corrosion of tubulars
A

corrosion inhibitor forms a barrier


at a cathodic or anodic surface which
interferes with electrochemical
reactions
Inhibitor

effectiveness is a function
of its ability to form and maintain a
film on the steel surface.

Acceptable metal loss:


0.02lb/ft with t up to 250F
0.05lb/ft with t up to 250F

Inhibitor Effectiveness
Temperature

and Pressure

Flow Velocity

Volume/Area Ratio

Concentration and

Type of other

Additives

Concentration of inhibitor

Concentration and Type of acid

Metal type

Laboratory evaluations
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Matrix treatment design methodology

Surfactant
Chemicals containing both an oil soluble and water soluble
groups with the ability to alter liquidliquid or gasliquid interfacial
properties. They thus make it possible to solubilize two immiscible
phases.

water wet

oil wet

Hydrophilic

M+

X-

Hydrophobic (Lipophillic)

Anionic

Cationic

Anionic types tend

to waterwet sand.

Cationic types tend to oilwet sand.

Anionic types tend to oilwet carbonate.

Cationic types tend to waterwet carb.

Anionic

types tend to emulsify oilinwater


and break waterinoil emulsions
Cationic

types tend to emulsify waterinoil


and break oilinwater emulsions.
Non-Ionic
Anionic

types tend to disperse clays in

water.
(pH)

+-

Amphoteric

The wrong type of surfactant or the wrong


concentration , may cause formation
damage.
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Cationic

types tend to flocculate clays in


water and disperse them in oil.
Anionic

and cationic types


compatible with each other.

are

not
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Matrix treatment design methodology

Mutual solvent
This

term means the chemical is


soluble in both oil and water

Reduces

Type

EGMBE (Ethylene Glycol


Butyl Ether)

Use mainly in oil bearing sands

Mono

pore water saturation

Reduces interfacial tension

Solubilises

or removes oil and oil


wetting chemicals from mineral surfaces
that tend to be naturally water wet
Enhances

chemicals

the action of water wetting

Reduces

the absorption of chemicals


and oil on mineral surfaces

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Emulsion preventing
Allows more rapid cleanup

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1
0

IFP
Training

33

Matrix treatment design methodology

Iron control
Chemical

which prevents iron


hydroxide precipitate

Avoid

emulsions with oil


(asphaltenes)..

Avoid very strong precipitates

Iron(Fe)

dissolved during an acidizing


treatment can exist in either the Fe3+ or
Fe2+ oxidation state. Upon spending of
the acid, Fe3+ will start to precipitate at a
Ph of 2.2. At 3.2 all the dissolved Fe3+ will
be precipitated. Fe2+ hydroxide will not
precipitate below a Ph value of of 7.7
Must always be used in acid

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1
0

IFP
Training

34

Matrix treatment design methodology

Iron control

20
1
0

IFP
Training

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Matrix treatment design methodology

Clay control agent

Foaming agent

Formation

Used as a mechanism to divert

Boost the flow back

Improved matrix leak off control


(return production of spent acid by
reducing fluid gravity and surface
tension of the fluids injected)

damage can result from


the dispersion , migration or swelling
of clay particles.
Clays

stabilizers eliminate
problem in most cores.

Laboratory test

this

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Matrix treatment design methodology


Nonemulsifying anti sludge agents
Avoid

emulsion problems between


acid, used acid and oil in place

Emulsifying agents include:


Asphaltenes
Formation fines

Laboratory test
Action of friction reducers
(at a given flow rate)

Friction reducer
Use

to lower the friction pressure of


ungelled fluids in high rate job
Used

during matrix acidizing through CT

Suppress

turbulence of the fluid

Increasing flow rate


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V PLACEMENT STRATEGY

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Matrix treatment design methodology

Determine placement strategy


A successful stimulation is to get
uniform penetration of the treating
fluid througout the entire perforated
height

packers
ball sealer

Chemical Diverter
VDA (viscoelastic diverting acid)
benzoic acid, rock salt.....
oil soluble resins, foam

Diversion is essential to ensure that


the treating fluid is continously
removing damage rather than simply
being injected into a thief zone

EP Matrix Treatment Design

Mechanical Placement technique

Coiled tubing vs Bullheading


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Matrix treatment design methodology

Define shutin/cleanup stage


a bad cleanup can increase the damage near the
wellbore
precipitates
emulsion
scales
fines

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VI PRACTICAL CONSIDERATIONS

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Matrix treatment design methodology


Determine pumping hydraulic parameters
Maximum Injection Rate
4.917 x10 6 kh FGxd dPs p
Q max
Rs

B Ln
S
Rw

KEY POINTS
Qmax should not be exceeded
during the treatment.

q = injection rate (bpm)


k = undamaged permeability (md)
h = net height of the formation (ft)
= viscosity of the injected fluid (cp)

p = pore pressure (psi)


Rs = drainage radius (ft)
Rw = wellbore radius (ft)
B = formation volume factor
dPs = safety pressure (200 500 psi)
D:DEPTH VERTICAL FT
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What is the expected rate?

Injectivity index can be calculated based on Darcy s Law


Rule of thumb

Skin prior acid : + 20


Skin after acid : 4
Pressure of the treatment depends on Friction in the tubing / on Frac

pressure / on reservoir pressure


Rate will be maximised if possible.

EP Matrix Treatment Design

4 .917 x10 6 kh FGxd dPs p


Q max

Rs

S
B Ln

Rw

43

Matrix treatment design methodology

Determine pumping hydraulic parameters below frac


pressure
Maximum Surface Pressure

Ps = FG x d Ph + Pf dPs

If the frac gradient is not known,

Ps = surface pressure (psi)

it can be estimated by adding 0.25psi/ft

FG = fracturing gradient (psi/ft)


d = vertical depth (ft)

to the BHSP gradient.

Ph = hydrostatic Pressure (psi)


Pf = friction pressure (psi)
dPs= safety pressure (200500psi)

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VII EQUIPMENTS EXPECTED


ON LOCATION

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Expected equipment on location

CT required to spot the acid ?

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Pretreatment check list...

What should you do on location prior a treatment

EP Matrix Treatment Design

Safety issues (Escape line, shower, PPE, fire hose)


Contengency plan ready (what if there is a leak ?)
Review of treatment parameters
Review of equipment calibration
QAQC of fluid mixed on location
Review of pumping program

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Required Equipment

Pumps: 8 x HT 400, 4800 HP

Storage: 76,000 gal

Pressure: Maxi 5000psi (Wellhead)

Blending: Max Rate @ 60 bpm

Monitoring
BHP w: Down Hole Gauge, real time
Pumping Rate
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Expected Equipment on location

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Required Rig up

to M V 220

Cem en t Un it

C h ristm as tree o n p la te fo rm

Ac id L ine
Rig P u m p s

8
Ac id L ine

P1

P2
5

1
2

F lo w line

4
6

F lo w line

An nu lu s M o n ito ring
Rig P u m p s

S D P 3 p la te form

T o c em ent un it/R ig
p um p

P1

T ubing pressu re 1 and 2

M a ste r V alve
Swab v alve
W ing V a lv e / E S D / F low Line V alve

3" w he el v alve
2" or 1 " b all va lv e

K ill Line V alve / Inlet W in g V alve

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E m erg en cy B lee d O ff line.


O n ly to b e u sed if a cid in th e
lin e

C hec k v alve

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VIII ASSESS PROFITABILITY

EP Matrix Treatment Design

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Matrix treatment design methodology

Assess profitability of treatment by estimating


increases in productivity or injectivity vs.
the cost of the treatment itself.

$$$

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IX EVALUATION OF THE JOB

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The pressure response during main acid treatment

How to analyze a pressure response during an acid

treatment ?
Ensure the calculated bottom hole pressure is correctly

calculated (Good friction estimate)


Calculate the injectivity index
II = Rate (bpm) / (BHP BHPi)

Ensure that the quality of the fluid pumped is what was


required

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Data recorded during an acidizing job


Tubing Pressure (at W H)

Data : W HP / BHP versus tim e and BPM

Overdisplace with
SW

Cum ul Job Volum e

3000

2500

2000

Pressure (psi) - Job Volume (bbls)

3500

22

Down Hole Pressure


Pum ping Rate

20

Stages at perf
18
16
14

Squeeze SW

12
10

1500

8
1000

6
4

500

2
0

18:00

18:14

18:28

18:43

18:57

19:12

19:26

19:40

19:55

20:09

20:24

20:38

20:52

21:07

21:21

21:36

Tim e (8th Dec 2001)

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Injectivity index Analysis

200

2500

II (b/d/psi) = Q (bpm) x 24 x 60 / (BHP Pres)


180

160

BPM - Injectivity Index (bbl/d/psi)

Pressure (psi)

3000

2000

1500

Tubing Pressure (at W H)


Pum ping Rate
1000

Stages at perf
Injectivity Index

140

120

100

80

60

40
500

20

0
0

500

1000

1500

2000

2500

3000

3500

Cum ulative Job Volum e (bbls)

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Guidelines for selection / Evaluation


Keep a critical eye on recordings !

BHP(gauge)
WHP

Data: W HP / BHP versus tim e and BPM


2700

(real time)

22
20

2500

18
16

2300

14

250psi

12

2100
10
8

1900

From surface
readings, Job
appears to be a
school case !
Looking at BHP only
250psi are lost in
2800bbls...

6
4

1700

Time (8th Dec 2001)


1500
19:12

EP Matrix Treatment Design

19:26

19:40

19:55

20:09

=> check for possible


other causes
(density, leak)

20:24

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Treatment data analysis


200
Pressure (psi)

3000

180

160
BPM - Injectivity Index (bbl/d/psi)

2500

2000

1500

Tubing Pressure (at W H)


Pum ping Rate
Stages at perf
Injectivity Index

1000

140

120

100

Perform

the analysis
downhole data if possible

on

80

60

40
500

20

0
0

500

1000

1500

2000

Cumulative Job Volume (bbls)

2500

3000

3500

Calculate

the variation of the


Injectivity Index during the
treatment
II(bpd/psi)= Qinject x 24 x 60 /
(BHP Pi)

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On site quality control

Bad

Good

Check on site the quality of the fluids to be pumped


Stability of fluids
Efficiency of diverters
Compatibilities

1000

20

pH
2

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X MATRIX TREATMENT DESIGN


KEY POINTS

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60

Matrix treatment design : Key Points

Candidate selection

Good estimation of the damage (nature and origin)

Selection of the fluids (additives, lab tests)

Fluids placement and entire zonal coverage

Choice of the appropriate equipments

Assess profitability

EP Matrix Treatment Design

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