Aramid
Glass
Glass
Olefin
Polyester
Rayon
Saran
Spandex
Vinal
_-
Wet Spinning
TvDical Wet SDun Fibers
Viscose
Acrilan
Creslan
Disadvantages
Slow (70 - 150 yddmin)
0'
Advantages
Large tows can be handled
Dry Spinning
TvDical Dry SRun Fibers
Acetate
(acetone solvent)
Triacetate
(methylene chloride)
Disadvantages
Flammable solvent hazards
0'
Solvent recovery
Slow (?)
Advantages
Yarn does not require purification
_-
3-4
Melt Spinning
TvDical Melt Spun Fibers
Nylons
0
Polyester
Polypropylene
Disadvantages
Separate drawing step (unless spin draw)
Advantages
High speed (275 to 1500 yddmin); (4000 yddmin spin draw)
Nosolvents
No purification problems
B. Dry Spinning
Polymer
Solution
Air Outlet
Heating
Jacket
--
Filament
Winding -
C. Melt SRinning
Storage
Hopper
- ,-
Roll
Finish
%jp
.I
dfI-
Filament
Winding
Prima- ProDerties
Length; length-width ratio
Tenacity (strength)
Flexibility (pliability)
Acceptable extensibility for processing
Cohesion
Uniformity of properties
Secondary ProDerties
0
-0
Dyeability
Resistance to solvents, corrosive chemicals, micro-organisms, and
environmental conditions
Flammability
Luster
10
15
20
2 5 3 0
35
SMnPercent
4 0 4 5
50
Modulus
Elasticity and recovery from strain
Tensile strength
Density
Moisture absorption
Dyeability
comfort
_-
&
1
,>?$
...
...
... ,,.+
...
.:.:..
........
....
..:.:.:.,.
:::'
I.'#=
-*-
Oval to round,
Overlapping scales
Medulla
Wool
Triangular, Round
edges, Uniform in
man-mades
Silk, Nylon
Type 90 Dacron
Type 62
Cicular, Uniform in
diameter
Nylon, Dacron
Cuprammonium Rayon
Dog-Bone
Orlon, Verel,
Lycra
Lobular
Lengthwise
Striations
Acetate
,y'
...
Y-Shaped
Ribbon-Shaped
Dyne1
Celacbud
Type 20
Acetate
Cumulofi Nylon
2'.........2EE=
$&&.
Trilobal
Antron
Nylon
Circular, Serrated,
Lengthwise
Striations
Viscose Rayon
Densits ( d c c )
Natural Fibers
Cotton
Flax
Silk
Wool
1.52
1.52
1.25
1.32
Man-made Fibers
Acetate
Acrylic
Aramid
Flurocarbon
Glass
Modacrylic
Nylon
Nylon Qiana
Olefin
Polyester
Rayon
Spandex
1.32
1.17 - 1.18
1.38 - 1.44
2.2
2.49 - 2.73
1.30 - 1.37
1.14
1.03
0.91
1.22 or 1.38
1.50 - 1.52
1.20 - 1.22
_-
Absorbency
Fiber
Moisture Regain*
Natural Fibers
Cotton
Flax
Silk
Wool
7-11
12
11
13 - 18
Man-made Fibers
Acetate
Arne1 triacetate
Acrylic
&amid
Flurocarbon
Glass
Modacrylic
Nylon
Nylon Qiana
Olefin
Polyester
Rayon
Rayon HWM
Spandex
6.0
3.2
1.3 - 2.5
4.5
0
0 0.3
0.4 4.0
4.0 4.5
2.5
0.01 - 0.1
0.4 - 0.8
15
11.5 - 13
0.75 - 1.3
_-
Fiber
Melting Point
OF
Safe Ironing
Temperature*
OF
OC
Softening
Sticking Point
OF
OC
OC
Natural Fben
Cotton
Wool
Acetate
I
I
I
I
I
I
I
I
I
I
425
2 18
Nonmelting
450
232
Nonmelting
300
149
Nonmelting
300
149
446
230
364
184
350
177
575
302
482
250
464
240
400-490
204-254
300-350
149-176
Acrylic
Aramid
Glass
Modacrylic
200-250
93-121
Nonmelting
Novoloid
Nylon6
414
2 12
340
171
300
149
Nylon66
482
250
445
229
350
177
Olefin
275
135
Polyester PET
480
249
460
238
325
163
Polyester PCDT
550
311
490
254
350
177
375
191
-saran
Spandex
Vinyon
1
I
1400-3033
;--~
Nonmelting
260
127
Nonmelting
350
177
300
149
446
230
347
175
140
200
93
285
150
(lowest possible)
Do not iron
300
149
Do not iron
Modacrylic
Polyester
Rayon
Acetate
Triacetate
Similar to acetate
Nylon 66
Olefin
Very resistant
Glass
Cotton
Similar to rayon
Wool
--
3-17
Modacrylic
Resistant to alkalies
Polyester
Rayon
Acetate
Triacetate
Nylon 66
Little or no effect
Olefin
Very resistant
Glass
Cotton
Wool
Unaffected
Modacrylic
Polyester
Rayon
Unaffected
Acetate
Triacetate
Nylon 66
Olefin
Glass
Unaffected
Cotton
Resistant
Wool
Generally resistant
Little or no effect
Modacrylic
Polyester
Rayon
Acetate
Triacetate
Nylon 66
Olefin
Glass
None
Cotton
Wool
Rayon
(A Cellulosic Man-Made Fiber)
ComDosition
Regenerated cellulose
Physical ProDerties
0
Microscopic Appearance
- Striations seen in viscose and high-strength rayon
- If delustered, scattered specks of pigment can be seen.
0
Length
-Filament and staple
Color
-Transparent unless dulled by pigments
Luster
-High unless delustering pigment added
Strength
- Fair to excellent
-Regular rayon has fair strength
-High tenacity types have good to excellent strength
Elasticity
-Regular rayon is low
High strength rayon is good
-0
Resiliency
-High wet-strength rayon is better
Man Made Fibers And Their Properties 3-21
Moisture Absorption
- Higher than natural cellulose
- Fibers swell in water
- Weaker when wet
Heat
- Loses strength above 300' F
- Decomposes between 350 and 400' F
Flammability
-Burns rapidly unless treated
Electrical Conductivity
- Fair - static charge can be reduced with special finishes
Specific Gravity
- 1.52 (similar to cotton)
Chemical ProDerties (similar to cotton)
Easily damaged by strong acids
Resistant to alkalies, reduction in strength if concentrated
Lengthy exposure to sunlight weakens the fabric
Greater f i n i t y for dyes than cotton
Acrylic
(A Wool-Like Fiber)
ComDosi t ion
Acrylonitrile and small amounts of other monomers
Physical Properties
Microscopic appearance
- Uniform and smooth surface
- Irregular spaced striations
Length
- Mainly a staple fiber
Color
- White to off-white
Luster
-Bright, semidull, or dull
Strength
-Fair to good strength
Elasticity
- Good
--
Resilience
- Good
Water Absorption
-1-3%
Man Made flbers And Their Properties 3-23
Heat
-Yellowing may occur above 300' F
- Softening o r sticking about 450' F
Flammability
- Burns with yellow flame
Electrical Conductivity
- Fair to good
Specific Gravity
- 1.14 to 1.19
- Good bulk and covering power
Chemical ProDerties
Damaged only by strong concentrated acids
Not normally affected by alkalies
Very resistant to ultraviolet light
Nylon
(A Polyamide Fiber)
ComD osit ion
Phvsical Proverties
Microscopic Appearance
-Very smooth and even
Length
, - Filament and staple
Color
- Off-white
Luster
- High natural luster can be controlled
Strength
- Exceptionally high (60,000 - 108,000)pounds per square inch
Elasticity
- Exceptionally high
Resiliency
-Very good
--
Moisture Absorption
- 3.8%
Man Made Fibers And Thelr Properties 3-25
Heat
- High resistance, melts at 482' F
Flammability
- Melts slowly
- Does not support combustion
Electrical Conductivity
- Low, generates static
Specific Gravity
'1.14 (low density)
Chemical ProDerties
Weakened by concentrated strong acids
High resistance to alkalies
Loses strength in prolonged exposure to sunlight - bright yam more
resistant than dull yam
Polyester
(Most Versatile Fiber)
ComDosition
Combination of Terephthalic Acid or Dimethylterephthalate and
Ethylene Glycol
Phvsical ProDerties
Microscopic Appearance
- Smooth, even, rodlike, different cross-sectionalshapes
Length
- Filament and staple
Color
-White
Luster
- Bright or dull
Strength
- Good to excellent
Elasticity
-Fair to good
- Greater than cotton or rayon
_-
Resilience
-Excellent
Moisture Absorption
- Less than 1%
Man Mode Fibers And Thelr Properties 3-27
Heat
- Softening o r sticking temperature is above 400' F (thermoplastic)
Flammability
- B u m slowly
Electrical Conductivity
-Accumulates static changes
Specific Gravity
-Typically 1.38
Chemical Pronerties
Good resistance to most acids
--
Drying
r-l
1 Drawing Tow
Drawing
2 Crimping
3
3 Drying/Heat Setting
4 Cutting
Filament Yam
Staple Fiber
--
Acetate
(A Cellulosic Man-Made Fiber)
ComDosition
Acetate Ester of Cellulose
Phvsical ProDerties
Microscopic Appearance
- Striations farther apart than viscose rayon
- Lobed cross-section
Length
-Filament and staple
Color
-Transparent unless dulled by pigments
Luster
- Bright, semibright, or dull
Strength
-Moderate
- Less than rayon when wet
Elasticity
-Not very high
- Similar to rayon
--
Resilience
-Poor
Moisture Absorption
- 6%, little strength loss when wet
Heat
- Ironing temperatures of 275' F are satisfactory
Flammability
- Slowly combustible
Electrical Conductivity
- Good
Specific Gravity
- 1.32
Chemical ProDerties
Concentrated strong acids will decompose it
Strong alkalies will damage it
Long exposures to sunlight produce a weakening effect
--
Polypropylene
(An Olefin Fiber)
ComDosition
Propylene
Physical ProDerties
Microscopic Appearance
- Smooth and rodlike
Length
- Filament and staple
Color
- Translucent
Luster
- Dull, semidull, bright
Strength
-Excellent strength (depends on degree of polymerization)
Elasticity
- Good
Resilience
- Good resistance to crushing
0
Moisture Absorption
-None
Heat
-Melts at about 330' F
- Progressive shrinkage can occur at 140' F to 212' F
Flammability
- Slow burning
Electrical Conductivity
-Excellent
Specific Gravity
- 0.90 to 0.91
Chemical ProDerties
Very resistant to most acids
Very resistant to alkalies
Dye pigments usually added to the liquid before fibers are extruded
Loses strength in sunlight, degrades upon long exposure
--
Polyethylene
(An Olefin Fiber)
Composit ion
Ethylene
Phvsical ProDerties
Microscopic Appearance
- Smooth and rodlike
Length
- Filament and staple
Color
-Translucent
Luster
- Dull, semidull, bright
Strength
- Fair to good (depends on degree of polymerization)
Elasticity
- Good
Resilience
- Good resistance to crushing
6 - Moisture Absorption
-None
Heat
-Very heat-sensitive
- Melts at about 260' F
Flammability
- Slow burning
Electrical Conductivity
- Excellent
Specific Gravity
- 0.90 to 0.91
Chemical ProDerties
Very resistant to most acids
Very resistafit to alkalies
Dye pigments usually added t o the liquid before fibers are extruded
Loses strength in sunlight, degrades upon long exposure
_-
1.5 - 1.55
3.3 - 6.4
3.0 - 4.9
7-8
NONE
3-7
I
Acetate
1.32
1.3 - 1.5
1.2 - 1.4
23 - 24
(sM00-445'F
(m)500F
Acrylic
1.16 - 1.18
2.0 - 3.6
1.6 - 2.9
1.5 - 2.5
35 - 39
(sM20'F
Glass
2.50 - 2.55
9.6 - 19.9
6.7 - 19.9
NONE
3.1 - 5.3
~~
~~
(s)135O-156O0
Nylon 66
1.14
3.0 - 7.2
2.6 6.1
4.2 - 4.5
l6
(sM5OF
(mM80-500'F
Polyester
1.38
2.2 - 6.6
2.2 - 6.6
0.4 - 0.8
12-67
(sM5'F
(mM82'F
I
R.LIYOI1,
HT
Wool
13
9 - 26
DNM
Decomposes
350400F
1 1.5
16
30 40
DNM
Decomposes
310-350'F
3-5
11
25
DNM
350-4509
1.50 1.53
3.0 - 5.7
1.3 1
1.9 - 4.3
Moisture absorbency: 2 - 5%
Dyeable
Low flammability
to 100'
0
Ease of care
Industrial Reauirements
Tenacity: 7 - 8 graddenier
--
Absorbency or
Moisture Regain
The percentage of moisture
a bone-dry fiber Will absorb
from the air under
standard conditions of
.temperature and moisture
Is Due To
Contn'buter To Fabric
ProDertv
Durability
Abrasion resistance
Resistance to splitting
Fiber toughness
Flexible molecular chains
Hydroxyl groups
Amorphous areas
Chemical structure
Storing of fabrics
Care required in
cleaning/bleaching, ability to
take acid or alkali finishes
Crimp or twists
Resistance to ravel
Warmth in fabric
Aging Resistance
Chemical Reactivity
The effect of acids, alkali,
oxidizing agents, solvents
Cohesiveness
The ability of fibers to cling
together during spinning,
not important in
continuous filament
Cover
The ability to occupy
space for concealment
or protection
Creep
Delayed elasticity;
Recovers gradually
-- &om strain
Density
see Specific Gravity
Dyeability
The fibers receptivity to
coloration by dyes
Elastic Recovery
The ability of fibers to
recover from strain
Processability of fabrics
Resiliency
Elasticity
The ability of a stretched
material to retum
immediately to its
original size
Electric Conductivity
The ability to transfer
electrical charges
Chemical structure:
polar groups
Elongation
The ability to be strztched,
extended, or lengthened;
varies at different temperatures and when wet or dry
Fiber crimp
Molecular structure: molecular crimp orientation
Feltability
The ability of fibers to
mat together
Flammability
The ability to ignite
and burn
Chemical composition
Fabrics bum
Cross-sectional shape,
crimp, diameter, length
Hand of fabric
Crimp
Cross-sectional shape
Warmth
Hand
The way a fiber feels: silky,
harsh, soft, crisp, dry
Heat Conductivity
Heat Sensitivity
The ability to soften, melt,
or shrink when subjected
t o heat
Smoothness
Fiber length
Flat or lobal shape
Luster
Hydrophilic or
Hygroscopic
Bee Absorbency
Luster
The light reflected from
a surface; more subdued
than shine; light rays are
broken up
Luster
Loft or Compressional
Resiliency
The ability to spring back
t o original thickness after
being compressed
--
Shine
Fiber crimp
Stiffness
Mildew Resistance
Low absorption
Moth Resistance
Pilling
The bailing up of fiber
ends on the surface
of fabrics
Fiber strength
High molecular weight
Pilling
Unsightly appearance
Molecular weight
Stiffness or Rigidity
The opposite of flexibility;
the resistance t o bending
o r creasing
Body of fabric
Resistance to insertion of
yam twist
Molecular structure:
orientation, crystallinity,
degree of polymerization
Chemical composition
Strength
The ability to resist stress;
expressed as tensile
strength (pounds per
square inch) or a s tenacity
(grams per denier)
Sunlight Resistance
The ability to withstand
degradation from
direct sunlight
Toughness
Wicking
The ability of a fiber to
transfer moisture along
its surface
3-41
3-42