True strain is the elongation per unit length calculated using the
Ceramics
High
crystalline
materials
made
from
amorphous
Five types: White Iron - relatively hard and brittle, increased wear
4 Thermoplastic States
glasses;;
Heat
treatment
after
forming
and
added
oxides
allow
for
and corrosion resistance, used for rolling mills, grinding plates,
Liquid: Thermoplastics above melting temperature. Bonds between
cement mixers, extrusion dies. Gray Iron - most common, graphite crystallization; Offers good mechanical strength, toughness, high
chains are weak; chains move easily; no strength and elasticity:
temperature
corrosion
resistance,
with
a
low
coefficient
of
thermal
flakes form, low solidification rate, high machinability and wear
Rubbery: Thermoplastics just below melting temperature just below
resistance, good oil retention and dampening. Ductile Iron - similar expansion;
melting temperature; chains move easily resulting in plastic
Chapter
16;
Polymer
properties to gray irons except stronger and tougher. Malleable Iron deformation (state used for forming); Leathery: At lower
Polymer is a long chain of molecules made from many monomers
formed by annealing white iron (contain irregular graphite nodules
temperature(Just above glass transition temp); Bonds between chains
bonded
together;
Typically
polymers
consist
of
a
carbon
backbone
called mallebalization). Compacted Graphite Iron - properties
which is covalently bonded to other atoms such as hydrogen oxygen orstrengthen making thermoplastic stronger and more rigid.
between gray and ductile irons, good for high-temperature
Rigid State: thermoplastic polymer is just below its glass transition
nitrogen
applications
temperature. Polymer is glass-like making it strong and stiff yet
3 Types of Polymers
Chapter 14: Non-Ferrous Alloys
Thermoplastics; Atoms within the chains are covalently bonded with brittle
Non-ferrous alloys dont contain iron
the chains themselves bonded by van der Waals bonds; Are generally Crystallinity in Polymers: Thermoplastics may partially crystallize
Aluminum Alloys: Low density; low stiffness, high electrical /
at temperatures blow melting point; Chains become closely aligned
ductile; May be amorphous or crystalline depending on the
thermal conductivity; good corrosion resistance; good strength /
temperature; Soften when heated which allows for shaping and easy folding over themselves creating plates (lamella)
recycling
ductility; poor fatigue resistance. Wrought Alloys Use a 4 digit
system where first digit indicates principle alloying elements, suffix Thermosetting Also long chain molecules; Strongly cross-linked
c
a
forming rigid 3D structures; Stronger but more brittle than
% Crystalline =
, p is the
after digits indicates how alloy is heat treated. Copper Alloys
thermoplastics; Do not melt simply decompose; Recycling difficult
Excellent electrical and thermal conductors; Good corrosion & wear
Elastomers Capable of elastic deformation greater than 200%; May be
c
a
resistance; Good strength, high ductility, cold workability Common both a thermoplastic or thermosetting; Contain coil-like molecules that
measure of density of the polymer, pa is the density of amorphous
Copper Alloys Brass (Cu + Zn) Good strength, ductility, corrosion stretch
polymer, Pc is the density of completely crystallized polymer
resistance; Bronze (Cu + Sn) Good strength and wear resistance; Cu Types of Polymerization (2 types)
Mechanical Properties of Polymers
Addition Polymerization (Chain Growth)
+ Be alloys Highest strength of Cu alloys age hardenable
Molecular weight, Amount of branching, Degree of branching,
Additive
polymerization
is
a
process
to
make
long
chain
polymers
by
Magnesium Alloys Low density, melting temp, and modulus of
Degree of cross-linking, Degree of crystallinity (folding of chains),
elasticity; Good specific strength, corrosion resistance (except marine combining several monomers together.
Tacticity, Temperature, Strain rate
Condensation Polymerization (Step-Growth)
environments); Poor fatigue, creep, and wear resistance Nickel Alloys
Condensation polymerization forms polymer chains by reacting two Geometric Isomers: Monomers with the same composition but
Have good strength, particularly at high temp; Good corrosion
or more molecules together to produce a polymer and a small moleculedifferent structures (ie rubber)
Cross-linking: Bonding between polymer chains to prevent viscous
resistance; Used for heat exchangers, gas turbines Titanium Alloys by-product.
plastic deformation (Low cross-linking - soft, flexible (i.e. rubber
High strength, low density; Excellent corrosion resistance; Good high Degree of Polymerization
bands, rubber gloves)
Average length of a linear polymer chain is given by degree of
temperature properties; Used in chemical processing equipment,
High cross-linking - hard rigid (i.e. hockey pucks))
polymerization
biomedical implants, jet engines
Vulcanization: Technique for cross-linking elastomer chains by
Degree
of
Polymerization
=
Chapter 15: Ceramics
adding sulphur atom chains which displace hydrogen atoms (non
Ceramics: solid compounds that comprise at least one metal and one
referable, cant recycle)
non-metallic element or a combination of at least two non-metallic
Tensile Testing of Elastomers: All deformation is elastic (nonelement solids.
linear); Initially the polymer chains uncoil; Chains then stretch with
Properties of Ceramics Hard and wear resistant, brittle, prone to
further deformation; Eventually the bonds break
thermal shock, refractory (high melting point), generally electrically
Tempered glass is produced by quenching the surface of the glass withThermoplastic Elastomers Dont rely on cross linking for plastic
insulating, generally thermally insulating, generally non-magnetic,
deformation - instead one chain crystallizes to prevent the sliding of
air resulting in residual compressive stresses which increases the
chemically stable and oxidation-resistant
chains
strength of the glass.
Processing of ceramics: 1. Synthesis of ceramic powders 2. Blending
Thermosetting Polymers
Annealed glass is glass with the residual stresses removed
and spray drying using additives 3. Shaping into useful shapes called
Highly cross linked; Limited chain movement due to 3D structure;
Laminated Glass Consists of two annealed glass pieces laminated
green ceramics 4. Consolidation into a dense object using sintering or
with a polymer (polyvinyl butyral) in b/w; Used to make windshields; Good strength stiffness and hardness, but brittle; Begin as linear
firing 5. Secondary processing such as cutting or polishing 6.Final
chains-mixed with resins and heat to from cross-linking
Bulletproof glass is made with polycarbonate layers instead
sintered ceramic product.
Glass Ceramics High crystalline materials made from amorphous Common Thermosets Phenolics - adhesives, brake pads; Amines
A
A
of the mould pressing the plastic into the mould; Often used for bottles
Thermoset Place solid materials in the mould then heating causes cross
linking to form the final product; Compression moulding - high pressure
and temperature causes the plastic to melt and it fills the mould as it
cools
Compression moulding - high pressure & temperature causes the plastic
to melt & it fills the mould as it cools
of properties, strength, toughness, electrical conductivity Metal matrix
composites (MMCs) Polymer-matrix composites (PMCs) ceramic
matrix composites (CMCs) Abrasives i.e. grinding cutting tools
Chapter 17: Composites
Rule of Mixtures
Fibre-reinforced Composites stronger, fatigue resistance, elasticity,
stiff, brittle, metal, glass, or polymers, carbon, boron
matrix is softer, more ductile, examples Kevlar, tennis rackets
Rule of mixtures predicts density (above) & modulus of elasticity for
loads || to fibres Ec= ffEf +fmEm Load perpen to fibres (stress same,
strain different)1/Ec =fm/Em+ff/Ef
Fibre Length determines load carrying ability, large aspect ratio =
stronger, smaller d=less flaws, longer fivers stronger b/c end dont
support load, fibre volume = strong too
Whiskers simple crystal fibres - strong
Matrixes support fibers and keep them in proper positions, prevent
damage of fibers and cracks in material controls electrical, chemical &
thermal properties of composites
Polymer & Metal Matrix good bonding, allow transfer of load to fibres,
coefficients of thermal expansion similar throughout
Ceramic weak bond between fibres and matrix, deflect cracks make less
brittle
Bonding & Failure Good bonding between matrix & fibres helps
transfer of stress coating improves bonding
Fibre Production Metallic, glass & most composites fibres formed from
the drawing process. carbon, Boron, & ceramics produced through
chemical vapor deposition Fibres, twisted to form yarn or bundled to
form tows
Composite production Short fibre, casting or injection moulding,
continuous handlayup
Metal Matrix Composites Strengthened by metal or ceramic fibres,
good high temp properties i.e. Aluminum
Ceramic Matrix Composites Ceramic fibres in a ceramic matrix,
strong, fracture resistance,poor bonding between fibres and matrices
Carbon Carbon Composite Super strong
Laminar Composites coatings which improve corrosion & wear
resistance
Chapter 3: Atomic and Ionic Arrangements
No Order no orderly arrangement, atoms are not connected and
occupy space randomly Short Range Order Arrangement of atoms
extend only to nearest neighbours, molecules occupy space randomly
Long Range Order Crystalline structures with extended atomic
arrangements forming regular repetitive 3D patterns, molecules occupy
well defined positions
Number of Atoms per Unit Cell Corners = 1/8 atom, Face-Centres =
atom, Body-Cetnres = 1 atom. Simple Cubic Structure (SC) = 1 atom.
Body Centered Cubic Structure (BCC) = 2 atoms. Face Centered Cubic
Structure = 4 atoms. All have 8 corner atoms. The stacking of the atoms
within the crystal structure determines the size of the unit cell.
Coordination Number Higher number indicates more efficiently
packed atom; number of nearest neighbors to an atom in its atomic
arrangement.
Atomic Packing Factor =
W W
x 100
W W
W =W eight of ceramic after submergingwater ;
W =Dry weight of ceramic ;
W =Weight of ceramic when suspended water
pB
x 100 ;
p
p=theoretical density of the ceramic ; B isthe measured
density of the ceramic
Q
RT
P (PP )
P( P P )