Vidyamandir Classes

Solutions to Booster Test [JEE-2016]

CHEMISTRY
26.(C) First ionisation enthalpies : F N C Be B
27.(D) Ionic radius increases with addition of e and decreases with removal of e .
28.(C)

A(Z 1)

Halogen

B (Z)
C (Z + 1)
D (Z + 2)

Noble gas
Alkali metal
Alkaline earth metal

29.(C)
31.(B)

30.(B)
r H

1
2
1
2

NNN

diss H Eg H Hyd H
(240) 349 381 610

32.(A) For smaller ions, lattice energy is greater.

33C)

SF2 , SF4 and SF6 have sp3 , sp3d and sp3d 2 respectively.

34.(A) XeF6 :

Oxidation state +6
Hybridisation : sp3d3
Shape : distorted octahedral

35.(D) NH3 bond angle 107

PH3 bond angle 93.5
BCl3 bond angle 120C

36.(A) SF4

Lone pair = 1

CF4

Lone pair = 0

XeF4

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37.(D)

3
H 2O, N H 4 , SO 42 and CrO4 are sp .

38.(D)

I 3 has 3 lone pairs of e

CrO3 has 1 lone pair
XeF4 has 2 lone pairs
SF4 has 1 lone pairs

39.(C) Ice has a cage-structured network whereas.

H2O has sheet like network.
Due to this, ice has some voids in its structure leading to lesser density.
40.(B)

Temperature, viscosity and surface tension are intensive.

41.(A)

N 2 3H 2 2NH3

H 93.6 kJ / mol

Since the reaction is exothermic, so on lowering the temperature, concentration of NH3 increases.
Also by taking excess N2 or H2, NH3 increases.
42.(C) Initially P = 1 atm
n 1mole
V

4
3

(radius) 2

Q Diameter 1m

Radius 0.5 m 5dm

(5 dm)3

dm 2
3
Finally P 4atm
n ??
500

(radius)3

(20 dm)3
3
32000

dm3
3
Now, since T is constant, so
P1V1 P2 V2

n1
n2

1 500
1

(Q Diameter is given proportional to pressure)

4 32000

n2

n 2 256 moles

255 moles are added.

43.(A) Check Z vs P graph for van der waals equation.

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44.

1
O 2 g
2
p
mL
2

CO g
p mL

CO 2 O2

CO 2 g
p mL
X

20 p mL

Volume contraction = 20 X 16 X
VR VP 4
p
p=8
p p 4
2

In 20 mL sample:

CO will be 8 mL and CO2 will be 12 mL

In 30 mL sample:

CO will be 12 mL and CO2 will be 18 mL

On reaction with NaOH, CO2 will be lost.

Residual volume = 12 mL

45.(C) As we add He at constant P, reaction moves forward direction and moles of CO increase.
46.(ABD)
Water freezer when it loses heat,

exothermic.
Neutralisation is always exothermic
U defined as heat at constant volume.
47.(ABCD)

Reaction II is balanced but H2O2 cannot act as reducing agent as well as disproportionate at the same time.
n-factor of K 2Cr2O7 6
n-factor of H 2O 2 1

48.(ABCD)

As we increase the value of n, energy levels become closer to each other.

49.(ABD)

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50.(ACD)

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PHYSICS
51.(D) Vsep = eVapp
V1 v = 2v
V1 = 3v
Hence height w.r.t point of collision
9v 2
2g

H max

52.(D) Question is cancelled.

3t 2
t2

t2
t2

a
V2

V0

dv (t 2)dt
V4

V2

From

a = 3t 2

V0 = 4m/s

dv (3t 2)dt

Hence = 24 m/s
53.(A) F + mg = kx
1 2
kx
2

mgx

F mg k

2mg
k

2mg
k

F m

2
2g

M
54.(B)

Net force = m acm

acm = 1m/s2

55.(D) Loss in GPE = Gain in K.E.

2
N mg cos mv
r
5
cos
6

56.(C) ac = krt2

v2 = krt2

v = krt

dv
at kr
dt
Power = (Fv) = k2r2t
Power = r2t
Hence

3R
i
13

57.(C)

58.(B)

Work done

m
y m
y
g g
4
4 2
2
ml

16

5g

59.(D) acm till 2nd sec = 0

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Hence distance Vcm 2 1 2 2m
After 2nd sec to 4th sec distance by A = 2m
Hence COM = 1m
Hence = 3m
60.(B)
61.(A)

mgh

1
1
2 1
2
(vgl ) 2 m u m u
2m
2
2

m 2 gl 2mu

As l 4m

Hence 1m
62.(C)

V 2 gt 2 10 1 2 5m / s

Displacement of A w.r.t C

V 2 42 2 10 s

O 2 5

(Relative C)

2 10 S

20
1m
20
Hence = 100cm

63.(B)

l v l l


v 2

64.(A) Relative velocity along x-axis

5 3m / s

tan 30
1

5 3t
h

5 3t

h = 5t

1
t 10t 2
2
2
2

10 5t
5t 15t 5t
t = 2sec

5t 10 5

65.(B)

tan 37

20
V = 15m

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20

3
4

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66.(A)

Vcos60 = ucos45

1
2

1
5

V 2u

67.(C) Loss in GPE = Gain in K.E

Hence
68.(B)

V 2 gR 1

Max speed at F = kx

Fx
V
th

1
kx 2 mv 2
2
2

1 F2 1 2
F k 2 mv
x 2 k
2
F

F
mx

69.(A) Velocity of n ball =

5gr (To just complete the circle)

70.(A) Force applied

M

g y Av 2
l
71.(BC)

72.(ABCD)

M
l

gy

M
l

gv02

Velocity of block will be = V/5 and acceleration of block will be = a/5

73.(CD)

T ma cos mg sin

mv 2 sin 2
L

74.(ABC)

Acceleration of both the blocks should be same for no slipping. Reaction between M & m vector sum of f and N
75.(AB)

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