TUTORIAL CHM270
CHAPTER 3: CHEMICAL KINETICS
The reaction is first order in both reactants. The rate constant is 3.0
-4
-1 -1
+
x10 M s at 25C. Calculate the rate of reaction if [NH4 ] =0.85 M and
-5
-1
[NO2 ] =0.20 M.
(5.1x10 Ms )
2.
4.
[O2]0 M
0.020
0.040
6.0 x 10
-4
0.040
0.040
2.4 x 10
-3
0.040
0.080
4.8 x 10
-3
Determine the rate law and the rate constant based on data above.
2
5.
Nitrogen and water are formed when ammonium ion reacts with nitrite
ion.
+
-1
The reaction order in N2O2 is zero order. The order with respect to Br2
is second order.
a)
b)
c)
d)
-1
[NO]0 M
3.
-1
[ClO2]0 M
[OH ]0 M
0.012
0.012
2.07 x 10
-4
0.024
0.012
8.28 x 10
-4
0.012
0.024
4.14 x 10
-4
0.024
0.024
1.66 x 10
-3
a) Determine the order of reaction and write the rate law for the
reaction
b) Calculate the value of rate constant, k for the reaction.
UiTMPHG/NFMR
6.
-4 -1
-2
0.500 M.
(3.12x10 M)
c) How many hours will it take for the [H2O2] to decrease to 25% of its
initial concentration?
C3H6 to 0.015 M.
b) Calculate the [C3H6] after 1 hour.
(3.85x10 s)
10.
(21.4 hours)
allowed to react. The rate constant for the reaction is 2.2 x10 s .
7.
constant, k=0.56M s .
2NO2 2NO + O2
(8.75 hours)
(0.0394 M)
c) How many hours will it take for the [SO2Cl2] to decrease to 6.25%?
(36 hours)
-1 -1
11.
-5 -1
Rate constant for the decomposition of N2O5 at 25C and 45C are
-4 -1
-3
(5.5x10 M)
reaction.
(95.4 s)
12.
The rate constant for the dissociation of N2O5 are measured at two
different temperatures, 45C and 55C. The rate constant at 45C is
Half-Lives of Reactions
-4 -1
-3 -1
9.
a)
b)
-3 -1
(5.2x10 s )
UiTMPHG/NFMR
16.
Molecularity and Reaction Mechanism
the proposed mechanism, derive the rate law that agrees with the
experimental rate law.
13.
N2O5
(slow)
NO2 + NO3
(fast)
(slow)
NO3 + NO 2NO2
(fast)
(slow)
HI + ICI I2 + HCI
(fast)
(fast)
UiTMPHG/NFMR
SEPT 2013
MAC 2013
UiTMPHG/NFMR
OCT 2012
UiTMPHG/NFMR
SEPT 2011
UiTMPHG/NFMR
MAC 2011