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acid+rain.jpg
Copyright: http://uksovannara.blogspot.co.uk/2012/07/harmful-effects-of-acid-rai
n.html
Today s lecture
Sources of acidifying pollutants in air.
Acid deposition and stages of
acidification
Effects of acid rain and their controls
Terrestrial ecosystems
Aquatic ecosystems
UK Acid Water Monitoring Network
(AWMN): Status, Recovery and
Future ..
forest-acid-rain-bg
What do we mean by
Acid rain ?
pH of unpolluted rain?
Dissolution of CO2:
Oxidation of N and S compounds in the
atmosphere to form nitric and sulphuric acid:
Other natural sources of acidity in rain.
Thus rain with acids dissolved in it.
Dynamic equilibrium of carbonic acid with CO2 at pH 5.65
Fertilizer
O2 + heat O + O
N2 + O NO + N
N + O2 NO + O
J. Galloway, 2008.
A global increase in atmospheric reactive N deposition (Oxidized and reduced for
ms).
History of
acid rain
research
acid rain
acid rain
colonsay-rain
imageEUG
pine_needle_ice
Occult deposition
Spatial trends .
Regional rather than global problem.
Sulphur compounds in the atmosphere have a residence
time of a few days, therefore, they are not well mixed
and have regional effects
Areas with high rainfall amounts may have higher acid
loading even though less acidic precipitation.
Rate and distance of movement also associated with
height of pollutant emissions i.e. tall stacks enhance
long-distance transfer
Atmospheric circulation patterns also important
acid rain
Acid
precipitation in
Europe
Elsom, 1992, p85
Sweden more acidity
from wet deposition
further from source general circulation
Stages of acidification
3 stages of
acidification
3 stages of acidification
acid rain
Effects: Terrestrial ecosystems
See: Vrba, J. et al (2003) Long term studies (1871-2000) on acidification and rec
overy of lakes
in the Bohemian Forest (central Europe). Science of the Total Environment, 310,
73-85.
The effects of acid rain on a
spruce forest in the Czech
Republic.
Suggested relationship to forest
decline (although possibly other
effects e.g. O3 in air).
Direct acid deposition on leaves
of plant can cause lesions, only
where pH 3.4 or below
Leaches Ca, Mg, K from leaves
and needles
Depletion of Ca in needles affects
susceptibility to freezing
acid conifers
-Conifers are
efficient
scavengers of
cloud
droplets
Geological sensitivity
granite-xpl_pm18-23
sandstone2_pm13-19
Sandstone: grains of quartz, cemented
together by calcium carbonate.
Granite: feldspars, quartz, mica,
tourmaline.
limestone-xpl_pm14-09
Limestone: fossils, and calcite crystals
http://www.earth.ox.ac.uk/~oesis/micro/index.html
The type of underlying bedrock
will control the catchment s
susceptibility to acidification as
HCO
3
concentrations influenced
by catchment geology
The type of underlying bedrock
will control the catchment s
susceptibility to acidification as
HCO3- concentrations influenced
by catchment geology
decomposition and
generation
decomposition and
generation
acid rain
Gypsum highly soluble and occupies large volume (mechanical stress)
Gypsum highly soluble and occupies large volume (mechanical stress)
Effects: Calcareous building stone
1908
1969
Summary of effects
Harm to terrestrial ecosystems (plants and soils)
Harm to aquatic ecosystems
Mobility of toxic metals (e.g. Al)
Weathering of building material
Effects amplified where:
Trees intercept clouds/fog
High acid deposition (i.e. uplands with high rainfall)
Base poor soils
Solutions?
1.Technological:
I.Desulphurization of flue gases
II.Liming of forests, soils and lakes
2.Prevention (see Schindler et al. 2006)
3.International legislation - management of acid
deposition needs to be done internationally
(i.e. EU, Canada/USA)
So in case of the UK
Significant recovery in chemical and biological
parameters of water bodies observed, but still lags
behind the reference levels in most sites
And (next page)
RECAP
ACID deposition due to air pollution
Impacts on ecosystems and built environment
Significant improvement in water bodies status
in the UK
Atmospheric reactive N deposition may drive
acidity in the current century.
References
Kernan, M., R.W. Battarbee, C. J. Curtis, D. T. Montieth,
and E. M. Shilland. 2010. Recovery of Lakes and
Streams in the UK from the Effects of Acid Rain. UK Acid
Water Monitoring Network 20 Year Interpretative
Report. DEFRA
(http://awmn.defra.gov.uk/resources/interpreports/20yearInterpRpt.pdf).
Monteith, D.T. and Evans, C.D. (2005) The United
Kingdom Acid Waters Monitoring Network: a review of
the first 15 years and introduction to the special issue.
Environmental Pollution, 137, 3-13.
Schindler, D.W., Dillo, P.J. and Schreier, H. (2006) A
review of anthropogenic sources of nitrogen and their
effects on Canadian ecosystems. Biogeochemistry, 79;
25-44.
General References
Arnell, N. (2002) Hydrology and Global
Environmental Change. Pearson.
Elsom, D.M (1992) Atmospheric Pollution a
Global Problem. Blackwell.
Heal, K.V. (2005) Solutes. In: Holden, J. (Ed.)
An Introduction to Physical Geography and the
Environment. Pearson.
Kemp, D.D. (2004) Exploring Environmental
Issues. An integrated approach. Routledge.