CY: Chemistry
Duration: Three Hours
deducted for each wrong answer. In Q.21 to Q.76, Q.78, Q.80, Q.82 and in Q.84, 0.5
mark will be deducted for each wrong answer. However, there is no negative marking in
Q.77, Q.79, Q.81, Q.83 and in Q.85. More than one answer bubbled against a question
will be taken as an incorrect response. Unattempted questions will not carry any marks.
5. Write your registration number, your name and name of the examination centre at the
8. Charts, graph sheets or tables are NOT allowed in the examination hall.
9. Rough work can be done on the question paper itself. Additionally blank pages are given
at the end of the question paper for rough work.
10.
This question paper contains 24 printed pages including pages for rough work. Please
check all pages and report, if there is any discrepancy.
51121 FoodlO6-CY-1A
CY J/24
Physical Constants
(a) Universal gas constant, R = 8.3145 J K- I mol-I = 0.082 L atm K- I mol-'
(b) Planck constant, h = 6.626
10-34 J s
1023 mol-I
108 m 5- 1
2.
Atomic Numbers
8=5
Si = 14
Ti=22
V=23
Cr= 24
Mn=25
Co=27
Ni=28
Xe=54
Eu=63
Dy=66
Yb =70
Lu = 71
Re = 75
Pt= 78
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51121 FoodlO6-CY-1B
Q. l
The rate of sui phonation of benzene can be significantly enhanced by the use of
(A)
(B)
(C)
(D)
Q.2
The reaction
0
"""-""":0....
Uq.
+ 2 Na + 2 C 2H sOH
"H,
0'
'C,H,oN.
is an example of a
Q.3
NBS
---=-=---;.~
H3C
(A)
(X)
(B)
~~-O
H3 C
(C)
Br
(D)
Br
CH 3
Br
H,c
Q.4
Benzene can not be iodinated with 12 directly. However, in presence of oxidants such
as HNO), iodination is possible. The electrophile formed in this case is
(C)
(B)
[ r
(D)
]+
.0
.0
[ 10Hz
ey
3124
]+
.0
-0
[ IOH z
Q.5
Classify the following species as electrophiles (E) and nucleophiles (N) in routine
organic synthesis
SO,
Ci+
CH1NH2
H10+
BHl
CN(A) E = SOl, CI+, BHl
(B) E = CI+, H,O+
N = CH,NH2, H,O+, CNN = SO" CH1NH2, BH1, CNN = SOl, CH1NH2, H10+, CW
N = CH1NH2, CW
The major product obtained upon treatment of compound X with H2S04 at 80C is
HO
(X)
(B)
(A)
(D)
(C)
>0
~
Q.7
BaTi[Si}09J is a class of
(C) lp
Q.9
(Al Zn
Q.IO
(B) Cu
(D)
Fe
The octahedral complex I complex ion which shows both facial and meridianal
isomers is
(A) Triglycinatocobalt(III)
(C) Dichlorodiglycinatocobalt(III)
Q.II
(C) Mn
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Q.12
The difference in the measured and calculated magnetic moment (based on spin-orbit
coupling) is observed for
(A) Pm 3+
Q.13
(A) -708 mY
(C)
-650 mY
(0) -621 mY
Q.14
The dimension of Planck constant is (M, Land T denote mass, length and time
respectively)
Q.15
(C)
(0)
Q.16
1Ig of
1Iu
lowest energy
oflowest energy
(C)
Q. I 7
~v
= +1 and
~J
The S2 operation on a molecule with the axis of rotation as the z axis, moves a
nucleus at (x, y, z) to
(A) (-x, -y , z)
Q.18
(B) ~v = +1 and 6J = +1
(0) Ilv = - 1 and ~J = - I
=-1
The expression which represents the chemical potential of the ith species (fli) in a
mixture (i '" j) is
(A) (aE / an; }s, V, n)
(B)
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Q.19
Q.20
The value of the rate constant for the gas phase reaction
38 dm) mol-I S-I at 300K. The order of the reaction is
(A) 0
2N~
+ F2 --. 2N02F is
(C) 2
(B) I
(0) 3
Q.21
Boric acid in aqueous solution in presence of glycerol behaves as a strong acid due to
the formation of
(A) an anionic metal-chelate
Match the compounds in List I with the corresponding structure / property given in
List II
(a)
(b)
(c)
(d)
(A)
(B)
(C)
(0)
Q.23
List I
(Ph)P)RhCI
LiC6
PtF6
Ni)S.
a- iii
a- iv
a- iii
a- iv
b-i
b-ii
b-ii
b - iii
(i)
(ii)
(iii)
(iv)
d- iv
d- i
d- iv
d- i
c-ii
c- iii
c-i
c-ii
W(CO)6 reacts with MeLi to give an intermediate which upon treatment with CH2N2
gives a compound X. X is represented as
(A) WMe6
(C) (CO),W=C(Me)OMe
Q.24
List II
Spinel
Intercalation
Oxidising agent
Catalyst for alkene hydrogenation
(B) (CO),W-Me
(0) (CO), W "CMe
Considering the quadrupolar nature of M-M bond in [Re2Claf-, the M-M bond order
in [Re2Ci.(PMe2Ph).r and [Re,CI.(PMe2Ph).] respectively are
(A) 3.0 and 3.0
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Q.25
A student recorded a polarogram of 2.0 mM Cd2+ solution and forgot to add KCI
solution. What type of error do you expect 1n his results?
(A)
(B)
(C)
(D)
Q.26
The separation of trivalent lanthanide ions, Lu 3+, Vb 3+, Oy3+, Eu 3+ can be effectively
done by a cation exchange resin using ammonium a-hydroxy isobutyrate as the
eluent. The order in which the ions will be separated is
(A) Lu 3+, Yb3+, Oy3+ , Eu 3+
3+ Yb 3+) L u3+
(8) EU3+, 0 y,
3+ Yb 3+, Eu 3+, Lu 3+
(C) oy,
3
3
3
(D) Yb +, Oy3+, Lu +, Eu +
Q.27
Arrange the following metal complexes in order of their increasing hydration energy
Q.30
Q.29
EtOH. (X)
(A)
(8)
(C)
(D)
X = (Et)2P(S)SH
; Y = (Et)2P(S)CI
X = (EtO)2P(S)SH ; Y = (EtO)2P(S)CI
X = (EtO)2PSH
; Y = (EIO)2PCI
X = (Et)3PO
; Y = (Et)3PCI
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Q.31
(A) i
Q.32
(C) iv
(B) ii
The pair of compounds having the same hybridization for the central atom is
(B) [NiCI 4]'- and [PtCI 4]'(D) [CO(NH')6]'+ and [CO(H,O)6]'+
Q.34
Q.38
(C) HgO
Q.37
Q.36
The Lewis acid character ofBF" BCI, and BBr, follows the order
(A) BF, < BBr, < BC"
(C) BF, < BCI, < BBr,
Q.3S
(D) iii
The catalyst used in the conversion of ethylene to acetaldehyde using Wacker process
is
(A) HCo(CO).
(C) V,O,
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0.39
0.40
(0) 18.0 kJ
(8) 0.0075
(C) 0.075
(0) - 0.075
Given that Eo(Fe J +, Fe)= -0.04 V and Eo(Fe2+, Fe) = -0.44 V, the value of
Eo(F e3., Fe2+) is
(A) 0.76 V
0.42
(C) 9.0 kJ
The specific volume of liquid water is 1.0001 mL g-' and that of ice is 1.0907 mL g-'
at OC. If the heat of fusion of ice at this temperature is 333.88 J g-', the rate of
change of melting point of ice with pressure in deg atm-' will be
(A) - 0.0075
0.41
(8) 13.5 kJ
(8) - 0.40 V
(C) - 0.76 V
(D) 0.40 V
For the reaction P + 0 + R -4 S, experimental data for the measured initial rates is
given below
Expt.
I
2
3
4
Initial conc. P
(M)
0.2
0.4
0.4
0.1
Initial cone. 0
(M)
0.5
0.5
2.0
0.25
Initial conc. R
(M)
0.4
0.4
0.4
1.6
Initial rate
(M s-')
8.0 x 10- 5
3.2x 10-4
1.28 x 10-3
4.0 x 10- 5
0.43
(8) 2, 1,2
(C) 2, I, I
(D) I, 1,2
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S/121 FoodlO6-CY- 2A
Q.44
The reaction
proceeds via the following steps
Q.45
40 millimoles ofNaOH are added to 100 mL ofa 1.2 M HA andY M NaA buffer
resulting in a solution of pH 5.30. Assuming that the volume of the buffer remains
unchanged , the pH of the buffer (KHA = 1.00 x 10-') is
(A) 5.30
Q.46
(D) 10.30
The ionisation potential of hydrogen atom is 13.6 eV. The first ionisation potential of
a sodium atom, assuming that the energy of its outer electron can be represented by a
H-atom like model with an effective nuclear charge of 1.84, is
(A) 46.0 eV
Q.48
(C) 0.30
Q.47
(B) 5.00
(B) I J.S eV
(C) 5.1 eV
(D) 2.9 eV
(A)
(B) P/(2rr)
(C) P/(4rr)
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$/121 Food/06-CY-2B
Q.49
Q.50
Q.54
(B) 1503
(C) 2354
(D) 2987
The J ~ 0 ~I rotational transition for ' H79 Br occurs at 500.72 GHz. Assuming the
molecule to be a rigid rotor, the J ~ 3 ~ 4 transition occurs at
(A) 50.1 cm-'
Q.53
(D) 2/3
(C) 1/2
(B) 3/4
N non interacting molecules are distributed among three non degenerate energy levels
eo~ 0, &, ~ 1.38 X 10- 2 ' J and &2~2.76 x 10- 2 ' J at lOOK. If the average total energy
of the system at this temperature is 1.38 x 10- 18 J, the number o f molecules in the
system is
(A) 1000
Q.52
Assuming H2 and HD molecules having equal bond lengths, the ratio of the rotational
partition functions of these molecules, at temperatures above lOOK is
(A) 3/8
Q.51
(B) only ii
The rate constants of two reactions at temperature Tare k,(T) and k2(T) and the
corresponding activation energies are E, and E2 with E2> E,. When temperature is
raised from T, to T 2, which one of the following relations is correct?
k,(T,)
beT,)
The number of degrees of freedom for a system consisting ofNaCI(s), Na+(aq) and
Cqaq) at equilibrium is
(A) 2
(8) 3
(C) 4
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11/24
(D) 5
Q.55
Match the structures in List I with their correct names given in List II
List I
(a)
List II
dO"'
(b)
C)
(ii) Imidazole
(c)
CA"",
(d)
HO
(e)
Q.56
b-ii
b-ii
c-vi
c-vi
d-iii
e-iv
d-iii
e-v
(8)
(D)
a-vii
a-I
b-ii
b-ii
c-vi
c-vi
d-viii
e-Iv
d-iii
e-iv
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12 /24
Q.57
NIGH,),
H,GO
(X)
NIGH,),
#'
#'
NIGH,),
OGH,
(8) Y <Z<X
NIGH,),
#'
OGH,
(Z)
(V)
Q.58
NIGH,),
OGH,
(D) X<Y<Z
(C) X<Z<Y
In the reaction
H,C
C2
'"II,}-sr
OH- (aq)
C,Hl
if the concentration of both the reactants is doubled, then the rate of the reaction will
(A) remain unchanged
(8) quadruple
(C) reduce to one fourth
(D) double
Q.59
Match the structures in List I with the coupling constant ['H J (Hz)] given in List II
List I
List II
(a)
(i) - I Hz
(b)
(ii) - 10 Hz
(c)
(iii) - 15 Hz
(A) a-i
(C) a-iii
b-ii
b-ii
c-iii
C-I
(8) a-ii
(D) a-iii
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b-iii
b-i
C-I
c-ii
Q.60
(3)
(A)
OH
OH
CH,N(CH 3 ),
#
CH,N(CH 3"
(D)
(C)
CHO
CHO
CH,N(CH 3 ),
CH,N(CH 3"
Q.61
CD
0JYs
l)-NCD '"
\Y
mainl y occurs at
(A) position I
(C) position 3
Q.62
(3) position 2
(D) either position 4 or 5
)I
N'
)
- - - - <....
benzophenone
(Al i:C H,
(3) ':CH,
(C) i: CH,
(D) 3: CH,
CY 14124
(V)
Q.63
()I-I() .. !-I"()
CH,
(A)
H,C
NH,
CH,
(8)
NH,
CH,
(C)
H,C
H,C
NH,
H,N
NH,
(D)
H,C
H,N
and
CH,
H,N
Q.64
Match the observed principal abso rbtions in the visible spectrum shown in List I with
the bond that shows this absorbtion in List II
List II
List I
(a) CI ~ cr(b) n~CI'
(c) n, rr(d) rr, rr(A) a-i
(C) a-ii
b-ii
b-i
(il
(ii)
(iii)
(iv)
c-iii
c-iv
C- C
C-O
C =0
C= C
d-iv
d-iii
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15/24
c-ii
c-iii
d-iv
d-i
Q.65
(8) Q
(D) S
(C) R
o
o
0>
respectively is
(A)
(8)
(e)
(D)
Q.67
is / are
(A) only M
(Ll
ey
(C) only L
16/24
(1\1)
(D) only K
Q.68
The stereochemical descriptors for the atoms labeled H, and Hb in the structures
H.
~Hb
..
~,....
HX~Hb
..' "
"
HO
(Z)
CI
(X)
respectively are
(A)
(B)
(C)
(D)
Q.69
Q.70
__
(X)
(Y) on treatment with alkaline permanganate gives (Z). Y and Z respectively are
(A)
(B)
OH
OH
~
~
and
eOOH
OCH 3
OCH 3
(C)
~
and
eaOH
---:P
(D)
OCH 3
OCH 3
OCH 3
OCH 3
~
and
~
CH 2 COOH
CY 17/24
and
~
eOOH
The number of distinct symmetry operations that can be performed on the molecule is
(A) 2
Q.72
(C) 6
(D) 8
Q.73
(B) 4
(B) 2
(C) 3
(D) 4
When two H atoms of the above molecule are also replaced by F atoms, the point
group of the resultant molecule will be
(A) C i
Q.7S
The compound which on reacting with aniline will NOT form an acetanilide is
(A)
(B)
(C)
(D)
p naphthol
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Q.76
In the reaction
03
W. H20
Compound X is
(A)
(B)
0
c;
H
0
CHO
(C)
(D)
0
H
CHO
H
Q.77
(8)
(COOH
COOH
(C)
(D)
COOH
COOH
COOH
CY 19124
In the reaction
Compound X is
(8) Xanthine
(D) Adenosine
(A) Adenine
(C) 2,6 - diaminopurine
Q.79
(8) Adenine
(C) Hypoxanthine
(D) Guanine
The reaction of ammonium chloride with 8Cl l at 140C followed by treatment with
NaBH., gives the product X. The formula of X is
(D) [BH-NHl n
Q.81
(8) only ii
(0) i and iv
Q.83
h
(8) <Px>=a
h
(C) <Px>=2a
h
(D) <Px>=2,ra
The uncertainty in the momentum (t.px) of the particle in its lowest energy state is
(A) t.px=O
h
(8) t.px =-
h
(C) t.px = 2a
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h
(D) t.px=21/"a
In the mixture obtained by mixing 25.0 mL 1.2 x 10-3 M MnCh and 35.0 mL of
6.0 x 10-4 M KCI solution, the concentrations (M) of Mn2+, K+ and
ions respectively are
cr
Q.85
(C) 3.0
10-4
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