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Part I

Completely Mixed System - Completely Stired Tank Reactor

ODE Modeled Dominated Processes


Lecture 1

(Stated Variables is change

Introduction
The need of surface water quality modeling
Some fundamental aspects
mass, rates, flux
The law of conservation in mass and energy

Lecture 2

Reaction Kinetics
Reaction fundamentals
reaction kinetics
zero, first and second order ODE model
solution of ODE
stochiometry

Lecture 3

Mass Balance
Absolute mass balance
Relative mass balance - Model of mass balance for well mixed lake (CSTR)
storativity, the rate of change of storage, accumulation
loading
outflow
settling
reaction
model of mass balance within CSTR
residence time

Lecture 4

Particular Solution
Analytical solution
treatment of loading

Lecture 5

Feedforward Systems of Reactors


Model of interconnected tanks - feedforward system of reactions
cascade model
non cascade model
Feedforward reactions

Lecture 6

Feedback Systems of Reactors


Model of interconnected tanks - feedback system of reactions
reactions with feedback
hypolimnion or epilimnion lake
interaction between bay and main lake
resuspension of sediment in a lake or settling pond

closed system of reactors


open system of reactors

Lecture 7

Computer Method for Well-Mixed Reactors


Numerical methods

(Equation 6.49 & 6.50)


(Equation 6.62 & 6.63)

Stired Tank Reactor (CSTR)

Stated Variables is changes against TIME only)

ixed lake (CSTR)

or settling pond

Equation 6.49 & 6.50)


Equation 6.62 & 6.63)

Part II

Incompletely Mixed System

PDE Modeled Dominated Processes


Lecture 8

{Stated Variables is cha

Diffusion
The transport of mass
advection - mass transport in fluid due to hydraulic gradient
diffusion - mass transport in fluid due to concentration gradient
dispersion
(diffusive and non diffusive)
conduction - heat transport due to heat gradient
convection - heat transport due to hydraulic gradient
Model of mass transport
diffusion of mass between two volumes
embayment model

Lecture 9

Distributed System - Steady State


Ideal reactors
plug flow reactor (PFR) - advection dominated mass transport
comparison of PFR and CSTR - more resident time in CSTR
Mixed flow reactor (MFR) - mixed advection and diffusion mass transport
Application of PFR to streams
stream modeling
point source
distributed source
Application of MFR to estuaries
estuary modeling
point source
distributed source

Lecture 10

Distributed System - Unsteady State


Plug flow
Spatio-temporal model - PDE
Estuary number

Lecture 11

Control Volume Approach - Steady State


Control volume approach
System dynamics approach
Boundary condition

Lecture 12

Simple Time Variable Solutions - Control Volume Approach - Unste


Spatio-temporal model - PDE
Spatial dynamics approach

Lecture 13

Advance Time Solution

Numerical method

Stated Variables is changes against SPACE only(SS) or SPACE & TIME (US)}

ulic gradient
tration gradient

ass transport
me in CSTR
diffusion mass transport

me Approach - Unsteady State

Part III

Water Quality Environments


Media of Processes

Lecture 14

River and streams


Stream hydrogeometry
Dispersion and mixing
longitudinal dispersion
lateral mixing
Flow, depth and velocity
discharge coefficient
Manning equation
Routing and water quality
routing water quantitative entity (Equation 14.33) - Absolut
routing pollutants - qualitative entity (Equation 14.54)

Lecture 15

Estuaries
Estuary transport
Net estuarine flow
Estuary dispersion coefficient

Lecture 16

Lakes and Impoundments


Standing waters
Lake morphometry
Water balance
Near shore model

Lecture 17

Sediments
Sediment transport overview
Suspendid solids
suspendid solids properties
settling and Stoke's law
Bottom sediments
Simple solids budgets
Bottom sediments as a distributed system
Resuspension

Lecture 18

Modeling Environment

Equation 14.33) - Absolut Quantity


Equation 14.54)

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