Airborne Pollutants
Steel workers may be exposed to a wide range of pollutants depending on the particular process, the materials involved and the
effectiveness of monitoring and control measures. Adverse effects are determined by the physical state and propensities of the pollutant
involved, the intensity and duration of the exposure, the extent of accumulation in the body and the sensitivity of the individual to its effects.
Some effects are immediate while others may take years and even decades to develop. Changes in processes and equipment, along with
improvement of measures to keep exposures below toxic levels, have reduced the risks to the workers. However, these have also
introduced new combinations of pollutants and there is always the danger of accidents, fires and explosions.
Dust and fumes
Emissions of fumes and particulates are a major potential problem for employees working with molten metals, making and handling coke,
and charging and tapping furnaces. They are also troublesome to workers assigned to equipment maintenance, duct cleaning and
refractory wrecking operations. Health effects are related to the size of the particles (i.e., the proportion that are respirable) and the metals
and aerosols that may be adsorbed on their surfaces. There is evidence that exposure to irritant dust and fumes may also make
steelworkers more susceptible to reversible narrowing of the airways (asthma) which, over time, may become permanent (Johnson et al.
1985).
Silica
Exposures to silica, with resultant silicosis, once quite common among workers in such jobs as furnace maintenance in melting shops and
blast furnaces, have been lowered through the use of other materials for furnace linings as well as automation, which has reduced the
number of workers in these processes.
Asbestos
Asbestos, once used extensively for thermal and noise insulation, is now encountered only in maintenance and construction activities when
formerly installed asbestos materials are disturbed and generate airborne fibres. The long term effects of asbestos exposure, described in
detail in other sections of this Encyclopaedia, include asbestosis, mesothelioma and other cancers. A recent cross-sectional study found
pleural pathology in 20 out of 900 steelworkers (2%), much of which was diagnosed as restrictive lung disease characteristic of asbestosis
(Kronenberg et al. 1991).
Heavy metals
Emissions generated in steel making may contain heavy metals (e.g., lead, chromium, zinc, nickel and manganese) in the form of fumes,
particulates, and adsorbates on inert dust particles. They are often present in scrap steel streams and are also introduced in the
manufacture of special types of steel products. Research carried out on workers melting manganese alloys has shown impaired physical
and mental performance and other symptoms of manganism at exposure levels significantly below the limits currently allowable in most
countries (Wennberg et al. 1991). Short-term exposure to high levels of zinc and other vaporized metals may cause metal fume fever,
which is characterized by fever, chills, nausea, respiratory difficulty and fatigue. Details of the other toxic effects produced by heavy metals
are found elsewhere in this Encyclopaedia.
Acid mists
Acid mists from pickling areas can cause skin, eye and respiratory irritation. Exposure to hydrochloric and sulphuric acid mists from pickling
baths have also been associated in one study with a nearly twofold increase in laryngeal cancer (Steenland et al. 1988).
Sulphur compounds
The predominant source of sulphur emissions in steel making is the use of high-sulphur fossil fuels and blast furnace slag. Hydrogen
sulphide has a characteristic unpleasant odour and short-term effects of relatively low-level exposures include dryness and irritation of
nasal passages and the upper respiratory tract, coughing, shortness of breath and pneumonia. Longer exposures to low levels may cause
eye irritation, while permanent eye damage may be produced by higher levels of exposure. At higher levels, there may also be a temporary
loss of smell which can delude workers into believing that they are no longer being exposed.
Oil mists
Oil mists generated in the cold rolling of steel can produce irritation of skin, mucous membranes and upper respiratory tract, nausea,
vomiting and headache. One study reported cases of lipoid pneumonia in rolling mill workers who had longer exposures (Cullen et al.
1981).
Polycyclic aromatic hydrocarbons
PAHs are produced in most combustion processes; in steelworks, coke making is the major source. When coal is partially burnt to produce
coke, a large number of volatile compounds are distilled off as coal tar pitch volatiles, including PAHs. These may be present as vapours,
aerosols or adsorbates on fine particulates. Short-term exposures may cause irritation of the skin and mucous membranes, dizziness,
headache and nausea, while long-term exposure has been associated with carcinogenesis. Studies have shown that coke-oven workers
have a lung cancer mortality rate twice that of the general population. Those most exposed to coal tar pitch volatiles are at the highest risk.
These included workers on the oven topside and workers with the longest period of exposure (IARC 1984; Constantino, Redmond and
Bearden 1995). Engineering controls have reduced the numbers of workers at risk in some countries.
Other chemicals
Over 1,000 chemicals are used or encountered in steel making: as raw materials or as contaminants in scrap and/or in fuels; as additives in
special processes; as refractories; and as hydraulic fluids and solvents used in plant operation and maintenance. Coke making produces
by-products such as tar, benzene and ammonia; others are generated in the different steel-making processes. All may potentially be toxic,
depending on the nature of the chemicals, the type, the level and duration of the exposures, their reactivity with other chemicals and the
susceptibility of the exposed worker. Accidental heavy exposures to fumes containing sulphur dioxide and nitrogen oxides have caused
cases of chemical pneumonitis. Vanadium and other alloy additions may cause chemical pneumonitis. Carbon monoxide, which is released
in all combustion processes, can be hazardous when maintenance of equipment and its controls are substandard. Benzene, along with
toluene and xylene, is present in coke-oven gas and causes respiratory and central nervous system symptoms on acute exposure; longterm exposures may lead to bone marrow damage, aplastic anaemia and leukaemia.
Stress
High levels of work stress are found in the steel industry. Exposures to radiant heat and noise are compounded by the need for constant
vigilance to avoid accidents and potentially hazardous exposures. Since many processes are in continuous operation, shift work is a
necessity; its impact on well-being and on workers essential social support are detailed elsewhere in this Encyclopaedia. Finally, there is
the potent stressor of potential job loss resulting from automation and changes in processes, plant relocation and downsizing of the
workforce.
Preventive Programmes
Protecting steel workers against potential toxicity requires allocation of adequate resources for a continuing, comprehensive and
coordinated programme that should include the following elements:
assessment of all raw materials and fuels and, when possible, substitution of safer products for those known to be hazardous
effective controls for the storage and safe handling of raw materials, products, by-products and wastes
continuous monitoring of workers personal occupational environment and ambient air quality, with biological monitoring when required,
and periodic medical surveillance of workers to detect more subtle health effects and verify fitness for their jobs
engineering systems to control potential exposures (e.g., equipment enclosures and adequate exhaust and ventilation systems)
supplemented by personal protective equipment (e.g., shields, gloves, safety glasses and goggles, hearing protectors, respirators, foot and
body protection, etc.) when engineering controls do not suffice
application of ergonomic principles to design of equipment, machine controls and tools and analysis of job structure and content as a
guide to interventions that may prevent injury and enhance workers well-being
maintenance of readily available, up-to-date information about potential hazards, which must be disseminated among workers and
supervisors as part of an ongoing worker education and training programme
installation and maintenance of systems for the storage and retrieval of the voluminous health and safety data, as well as for the analysis
and reporting of records of inspection findings, accidents and worker injury and disease.