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MOCK TEST - 1
INSTRUCTIONS

Time : 3 hrs.
Chemistry (120 marks)

Question No. 1 to 30 are of 4 marks each.

Physics (120 marks)

Question No. 31 to 60 are of 4 marks each.

Mathematics (120 marks) :

Question No. 61 to 90 are of 4 marks each.

Negative Marking

One fourth () marks will be deducted for indicating incorrect response of each question.
. . . Best of Luck

CHEMISTRY
CH3
1.

IUPAC name of

4.

is

CH2CH3
(a) 1-methyl-3 ethyl cyclohexane
(b) 1-ethyl-3 methyl benzene
(c) 1-ethyl-3 methyl cyclo hexane
(d) Cyclo hexane-1-ethyl-3-methyl
Which of the following resonance structure is lowest in
energy?

: :

B.

6.

(a) sp2, sp3 and sp2 respectively


(b) sp, sp2 and sp3 respectively
(c) sp2, sp and sp3 respectively
(d) sp2, sp3 and sp respectivley
In a compound AOH, electronegativity of A is 2.1, the
compound would be
(a) Acidic
(b) Neutral towards acid & base
(c) Basic
(d) Amphoteric
Which of the following orders is wrong?
(a) Electron affinity N < O < F < Cl
(b) Ist ionisation potential Be < B < N < O
(c) Basic property MgO < CaO < FeO < Fe2O3
Cl
(d) ReactivityBe < Li < K < Cs
The dipole moment of chlorobenzene

is 1.5 D. The

O H

: :

A.

H O Q
||
|
HC C
+
|
O H
B
H
:

H O
||
|
HC C
|
B
H

5.

: :

2.

Max. Marks : 360

H O Q
|
|
HC C
| + O H
B
H
: :

3.

Cl
Cl

: :

C.

dipole moment of

(a) A
(b) B
(c) C
(d) All have same energy
The hybridization of atomic orbitals of nitrogen in
NO +2 , NO -2 and NH +4 are

7.

Cl

Cl

is

(a) 2.86D
(b) 2.25D
(c) 1.5D
(d) 0D
Following substances are in solid state :
(A) Methane
(B) Cesium chloride

8.

9.

(C) Ice
(D) Lithium
Which non-conductive solid when melts converts into
conductive liquid?
(a) C, D
(b) Only C
(c) Only B
(d) A, B and C
On applying pressure to the equilibrium
ice
water, which phenomenon will happen
(a) More ice will be formed
(b) More water will be formed
(c) Equilibrium will not be disturbed
(d) Water will evaporate
The energy levels for

ZA

( + Z-1)

(d) En for A(+Z1) =


10.

1
Z2

(a)

SO 32 - < S 2 O 24 - < S2 O 62 -

(b) S 2O 24- < S2 O62- < SO 32(c)

S 2O 62- < S2 O 24- < SO 32-

(d) S 2O 24- < SO 32- < S2 O 6216.

17.

En for H

The oxidation states of sulphur in the anions


SO 32 - , S2 O 24- and S2 O 62 - follow the order

can be given by

(a) En for A(+Z1) = Z2 En for H


(b) En for A(+Z1) = Z En for H
(c) En for A(+Z1) =

15.

Which of the following statements is not correct?


(a) C Cl bond in vinyl chloride is less polar than in CH3Cl
(b) C Cl bond in vinyl chloride is stronger than in CH3Cl
(c) C Cl bond in vinyl chloride is shorter than in CH3Cl
(d) Vinyle chloride undergo nucleophilic substitution more
readily than CH3Cl.
Which of the following will not be soluble in sodium
carbonate solution?
OH

1
En for H
Z

O2N

(b)

(a)

a
Given, HF + H 2 O K

H 3O + + F ;

b HF + OH .
F + H 2 O

Which relation is correct

11.

12.

13.

14.

COOH

NO2

NO2

1
Kw

(a) Kb = Kw

(b)

Kb =

(c) Ka Kb = Kw

(d)

Ka
= Kw
Kb

In an amino acid, the carboxyl group ionises at pK a1 = 2.34


and ammonium ion at pK a 2 = 9.60. The isoelectric point of
the amino acid is at pH
(a) 5.97
(b) 2.34
(c) 9.60
(d) 6.97
AB, A2 and B2 are diatomic molecules. If the bond enthalpies
of A2, AB and B2 are in the ratio 1:1 :0.5 and enthalpy of
formation of AB from A2 and B2 is 100 kJ mol1 . What is
the bond energy of A2 :
(a) 200 kJ mol1
(b) 100 kJ mol1
1
(c) 300 kJ mol
(d) 400 kJ mol1
Equal volume of 0.1 M urea and 0.1 M glucose are mixed.
The mixture will have
(a) Lower osmotic pressure
(b) Same osmotic pressure
(c) Higher osmotic pressure
(d) None of these
If the following half cells have the E values as

OH
NO2

(c)
18.

19.

20.

21.

Fe +3 + e
Fe +2 ; E = + 0.77V and Fe +2 + 2e -
Fe ;

E = 0.44V. The E of the half cell Fe +3 + 3e


Fe will be
(a) 0.33 V
(b) 1.21 V
(c) 0.04 V
(d) 0.605 V

SO2OH

22.

(d)

Although Al has a high oxidation potential it resists corrosion


because of the formation of a tough, protective coat of
(a) Al(NO3)2
(b) AlN
(c) Al2O3
(d) Al2(CO3)2
A metal which is not affected by conc. H2SO4, HNO3 or
alkalis forms a compound X. This compound X can be used
to give a complex which finds its application for toning in
photography? The metal is
(a) Au
(b) Ag
(c) Hg
(d) Cu
If Cl2 gas is passed into aqueous solution of KI containing
some CCl4 and the mixture is shaken, then.
(a) Upper layer becomes violet
(b) Lower layer becomes violet
(c) Homogenous violet layer is formed
(d) None
In Lassaignes test, the organic compound is fused with a
piece of sodium metal in order to
(a) increase the ionisation of the compound
(b) decrease the melting point of the compound
(c) increase the reactivity of the compound
(d) convert the covalent compound into a mixture of ionic
compounds
An aqueous solution of colourless metal sulphate M gives

3
a white precipitate with NH4OH. This was soluble in excess
of NH4OH. On passing H2S through this solution a white
ppt. is formed. The metal M in the salt is

23.

24.

25.

(a) Ca

(b) Ba

(c) Al

(d) Zn

(b)

A laboratory reagent imparts green colour to the flame. On


heating with solid K2Cr2O7 and conc. H2SO4 it evolves a red
gas. Identify the reagent
(a) CaCl2

(b) BaCl2

(c) CuCl2

(d) None of these

(c)

(d)

Which of the following compound can not used in


preparation of iodoform?
(a) CH3CHO

(b) CH3COCH3

(c) HCHO

(d) 2-propanol

29.

CN

II.

CBr (CH 3 ) 2
(a)

IV. CH 2 - C - OCH 3
(c)

O
||

V.

C-H

30.

(a) II, III, V, I, IV

(b) V, II, I, IV, III

(c) III, IV, I, II, V

(d) II, V, I, IV, III

Identify X in the sequence given :


NH2
CHCl3
KOH

(Y)

HCl
(300 K)

(c)
27.

28.

Cl

Cl

(b) C N

atm - 2

0.5 (1.5)3
atm 2
3 3

(b)

0.5 (1.5) 3 atm 2

(d)

(1.5) 3
atm - 2
0.5

0.5 g mixture of K2Cr2O7 and KMnO4 was treated with excess


of KI in acidic medium. I2 liberated required 100 cm3 of 0.15N.
Na2S2O3 solution for titration. The percentage amount of
K2Cr2O7 in the mixture is
(a) 85.36 %
(b) 14.64 %
(c) 58.63 %
(d) 26.14 %

PHYSI CS
31.

NH2

3 3
0.5 (1.5)3

X + methanoic acid

Cl

(a)

2 NH 3 (g ) .

The K p for the dissociation of NH 3 is

O
||

III. COOH

1 mol of N 2 and 3 mol of H 2 are placed in a closed container


at a pressure of 4 atm. The pressure falls to 3 atm at the same
temperature when the following equilibrium is attained
N 2 (g) + 3H 2 (g )

The correct priorities for the substituents shown below,


according to the E-Z sequence rule is
I.

26.

(a) CH2= CH CH2 CH2 CH2 CH2 CH3

Cl

(d) CH3NH

Cl

32.

Select the rate law that corresponds to the data shown for
the following reaction A + B
C
Expt. No.
(1)
(2)
Initial Rate
1
0.012
0.035
0.10
2
0.024
0.070
0.80
3
0.024
0.035
0.10
4
0.012
0.070
0.80
3
4
(a) Rate = K[B]
(b) Rate = K [B]
(c) Rate = K [A] [B]3
(d) Rate = K [A]2 [B]2
An alkene upon ozonolysis yield
CHO CH2 CH2 CH2 CHO only. The alkene is

A d.c. supply of 120V is connected to a large resistance X. A


voltmeter of resistance 10kW placed in series in the circuit
reads 4V. What is the value of X?
(a) 190 kW

(b) 90 kW

(c) 290 kW

(d) 390 kW

An insect trapped in a circular groove of radius 12 cm. moves


along the groove steadily and completes 7 revolutions in
100 sec. What is the linear speed of the motion
(a) 2.3 cm/sec.

33.

(b) 5.3 cm/sec.

(c) 0.44 cm/sec.


(d) None of these
The period of the satellite of the earth orbiting very near to
the surface of the earth is T0. What is the period of the
geostationary satellite in terms of T0
(a)

T0
7

(c) 7T0

(B)

7T0

(d)

7 7T0

4
34.

35.

36.

37.

38.

In Al and Si. If temperature is changed from normal


temperature to 70 K then
(a) The resistance of Al will increase and that of Si will
decrease
(b) The resistance of Al will decrease and that of Si will
increase
(c) Resistance of both decrease
(d) Resistnance of both increase
For Dopplers effect, which of the following is a correct
statement
(I) During observer motion both frequency and
wavelength will change
(II) During source motion both frequency and wavelength
will change
(III) During source motion only frequency will change
(IV) During observer motion only frequency will change
(a) I, II
(b) I, II
(c) II, III
(d) II, IV
When white light passes through a dispersive medium, it
breaks up into various colours. Which of the following
statements is true?
(a) Velocity of light for violet is greater than the velocity of
light for red colour.
(b) Velocity of light for violet is less than the velocity of
light for red.
(c) Velocity of light is the same for all colours
(d) Velocity of light for differnet colours has nothing to do
with the phenomenon of dispersion
An engine has an efficiency of 1/6. When the temperature
of sink is reduced by 62C, its efficiency is doubled.
Temperatures of source and sink are
(a) 99C, 37C
(b) 124C, 62C
(c) 37C, 99C
(d) 62C, 124C
Two isothermals are shown in figure at temperatures T1 and
T2. Which of the following relations is correct?

40.

41.

42.

43.

44.

45.

(c) find no deflection in the galvanometer


(d) find a maximum deflection in the galvanometer
The radius of curvature of a thin plano-convex lens is 10 cm
(of curved surface) and the refractive index is 1.5. If the
plane surface is silvered, then it behaves like a concave
mirror of focal length
(a) 10 cm
(b) 15 cm
(c) 20 cm
(d) 5 cm
The circular head of a screw gauge is divided into 200
divisions and move 1 mm ahead in one revolution. If the
same instrument has a zero error of 0.05 mm and the reading
on the main scale in measuring diameter of a wire is 6 mm
and that on circular scale is 45. The diameter of the wire is
(a) 6.275 mm
(b) 6.375 mm
(c) 5.75 mm
(d) 5.50 mm
Ammeter and voltmeter readings were recorded as 0.25 A
and 0.5 V during the experiment to determine the resistance
of a given wire using Ohm's law. The correct value of the
resistance is
(a) 0.125 W
(b) 2 W
(c) 0.75 W
(d) 0.25 W
A wheel is rotating at 900 r.p.m. about its axis. When power
is cut off it comes to rest in 1 minute. The angular retardation
in rad/s2 is
(a) p/2
(b) p/4
(c) p/6
(d) p/8
Choose the wrong statement from the following
(a) a metre bridge can be used to determine the emf of a
primary cell
(b) a metre bridge works on the principle of Wheatstone
bridge
(c) a potentiometer is used to compare the emfs of two
primary cells
(d) a multimeter can be used as an ohmmeter
The adjacent figure shows the position graph of one
dimensional motion of a particle of mass 4 kg. The impulse
at t =0 s and t = 4 is given respectively as:

x(m)
T1

T2

(a) T1 > T2

39.

(b) T1 < T2

1
(c) T1 = T2
(d) T1 = T2
2
During the experiment to determine the resistivity of a wire
by a metre bridge, the jockey is moved gently along the wire
from left to right to
(a) find a deflection in the galvanometer towards left
(b) find a deflection in the galvanometer towards right

46.

t(s)

(a) 0,0
(b) 0, 3 kg ms 1
(c) + 3 kg ms1, 0
(d) + 3 kg ms 1, 3 kg. ms1
In case of a p-n junction diode at high value of reverse bias,
the current rises sharply. The value of reverse bias is known
as

47.

48.

49.

50.

(a) cut off voltage


(b) zener voltage
(c) inverse voltage
(d) critical voltage
The following observations were taken while comparing
the e.m.f.s of two primary cells using a potentiometer.
Balance point when E 1 (Leclanche cell) in the circuit
(l1 in cm) = 350
Balance point when E2 (Daniel cell) is the circuit (l2 in cm)
= 275
The ratio (E1/E2) of emfs is approximately
(a) 1.30
(b) 1.17
(c) 1.27
(d) 1.5
A photon materializes into an electron-positron pair. The
kinetic energy of the electron is found to be 0.19 MeV. What
was the energy of the photon?
(a) 0.38 MeV
(b) 0.70 MeV
(c) 1.40 MeV
(d) None
If 10% of a radioactive material decays in 5 days, then the
amount of the original material left after 20 days is
approximately
(a) 60%
(b) 65%
(c) 70%
(d) 75%
Lights of two different frequencies, whose photons have
energies 1 eV and 2.5 eV respectively, successively illuminate
a metal whose work function is 0.5 eV. The ratio of the
maximum speeds of the emitted electrons will be
(a) 1 : 5
(b) 1 : 4
(c) 1 : 2
(d) 1 : 1

DIRECTIONS (Qs. 51 and 52) : Read the following passage


and answer the questions that follows :
A block of mass 15 kg is placed over a frictionless horizontal
surface. Another block of mass 10 kg is placed over it, that is
connected with a light string passing over two pulleys fastened
to the 15 kg block. A force F = 80N is applied horizontally to the
free end of the string. Friction coefficient between two blocks is
0.6. The portion of the string between 10 kg block and the upper
pulley is horizontal. Pulley, string and connecting rods are
massless. (Take g = 10 m/s)

52.

If applied force F = 120 N, then magnitude of acceleration of


15 kg block will be
(a) 8 m/s
(b) 4 m/s
(c) 3.2 m/s

ASSERTION & REASON


DIRECTIONS (Qs. 53 and 54) : Each of these questions
contains two statements: Statement-1(Assertion) and
Statement-2 (Reason). Choose the correct answer (ONLY
ONE option is correct) from the following (a) Statement-1 is false, Statement-2 is true.
(b) Statement-1 is true, Statement-2 is true; Statement-2
is a correct explanation for Statement-1.
(c) Statement-1 is true, Statement-2 is true; Statement-2
is not a correct explanation for Statement-1.
(d) Statement-1 is true, Statement-2 is false.
53.

54.

55.

Statement-1 : When two semiconductor of p and n type are


brought in contact, they form p-n junction which act like a
rectifier.
Statement-2 : A rectifier is used to convert alternating current
into direct current.
Statement 1 : A nucleus at rest splits into two nuclear parts
having radii in the ratio 1 : 2. Their velocities will be in the
ratio 8 : 1.
Statement 2 : The radius of a nucleus is proportional to the
cube root of its mass number.
A plate of mass (M) is placed on a horizontal frictionless
surface and a body of mass (m) is placed on this plate. The
coefficient of dynamic friction between this body and the
plate is m. If a force 3mmg is applied to the body of mass (m)
along the horizontal, the acceleration of the plate will be
(a)

56.

(c)

15 kg

51.

The magnitude of acceleration of the 10 kg block is


(a) 3.2 m/s
(b) 2.0 m/s
(c) 1.6 m/s

(d) 0.8 m/s

(b)

mmg
M+m

3mmg
2mmg
(d)
M
M+m
Two rods of length d1 and d2 and coefficients of thermal
conductivities K1 and K2 are kept touching each other. Both
have the same area of cross-section the equivalent of thermal
conductivity is
(a) K1 + K2
(b) K1d1 + K2d2

=0.6

Smooth

mm
g
M

(c)

10kg

F = 80N

(d) 4.8 m/s

57.

d1K1 + d 2 K 2
d1 + d 2

(d)

d1 + d 2
(d1 / K1 + d 2 / K 2 )

Two masses A and B of 10 kg and 5 kg respectively are


connected with a string passing over a frictionless pulley
fixed at the corner of a table (as shown in figure). The
coefficient of friction between the table and the block is 0.2.
The minimum mass of C that may be placed on A to prevent
it from moving is equal to

6
63.

(a) p

(a) 15 kg
(b) 10 kg
(c) 5 kg
(d) 0 kg
A particle starts S.H.M. from the mean position. Its amplitude
is a and total energy E. At one instant5 its kinetic energy is
3 E/4, its displacement at this instant is
(a)

(c)
59.

(b)

(c)

a
2

(d)

3/ 2

3m 0
2p

(b)

3m 0
2p

(d)

(c)

1
pf (2 pfL - R )
1
pf (2 pfL + R )

(b)
(d)

(a)

(c)

1

10

66.

9
10 5

(d)

67.

m0
2p

1
2 pf (2 pfL - R )
1
2 pf (2 pfL + R )

1
5

(b)

1
4

(c)

7
12

(d)

5
12

The value of

r n Cr -r 1 =

14

(b) 5 (n 2)
(d) 5 (2n 9)

C7 +

17-i C6 =
i =1

m0
p

9
(b)
10

1
9

(a) 5 (n 3)
(c) 5n

68.

69.

(a)

16

C7

(b)

17

C7

(c)

17

C8

(d)

16

C8

If y = A sin wt then

d5y
dt 5

(a)

Aw5 cos wt -
2

(b)

Aw5 sin wt -
2

(c)

Aw5 cos wt +
2

(d)

Aw5 sin wt +
2

x -1 y - 2 z - 3
=
=
l for which x - 2 = y - 4 = z - 8 and
l
-3
6
-3
7
l
are perpendicular equals
(a) 5
(b) 6
(c) 7
(d) 8

The angle between the two lines

x +1 y + 3 z - 4
=
=
&
2
2
-1

x - 4 y + 4 z +1
=
=
is
1
2
2

Area of triangle formed by the vertices (0, 0), (6, 0), (4, 3) is
(a) 6
(b) 9
(c) 18
(d) 24
In a box containing 100 bulbs, 10 are faulty. The probability
that from a sample of 5 bulbs none are defective.
5

(a)

r =1

y= a

MATHEMATICS

62.

p
2

p
(d) None
4
The probability of getting the sum more than 7 when a pair
of dice is tossed is

In a circuit L, C and R are connected in series with an


alternating voltage source of frequency f. The current leads
the voltage by 45. The value of C is
(a)

61.

64.

65.

y=

y=

Two long parallel wires P and Q are both perpendicular to


the plane of the paper with distance of 5 m between them. If
P and Q carry current of 2.5 amp and 5 amp respectively in
the same direction, then the magnetic field at a point halfway between the wires is
(a)

60.

y=

(b)

(c)

58.

If 2 sec 2a = tan b + cot b then one of the values of (a + b) =

70.

(a)

4
cos -1
9

(b)

3
cos -1
9

(c)

2
cos -1
9

(d)

1
cos -1
9

The contrapositive of (p q) r is
(a)

r (p q)

(b)

~ r (p q)

(c)

~r~p~q

(d)

p (q r)

7
71.

72.

73.

74.

75.

76.

If (2, 3, 5) are ends of the diameter of a sphere


x2 + y2 + z2 6x 12y 2z + 20 = 0. Then coordinates of the
other end are
(a) (4, 9, 3)
(b) (4, 3, 5)
(c) (4, 3, 3)
(d) (4, 3, 9)
Three persons A, B, C throw a die in succession. The one
getting 'six' wins. If A starts then the probability of B winning
is
(a)

36
91

(c)

41
91

(b)

25
91

(d)

30
91

2
5

(b)

3
5

(c)

4
5

(d)

1
5

79.

If f(x) = | x 2| and g(x) = f (f(x)) then for x > 10, g'(x) equal
(a) 1
(b) 0
(c) 1
(d) 2x 4
If a, b, c are in A.P., b, c, d are in G.P. and c, d, e are in H.P. then
a, c, e are in
(a) A.P.
(b) G.P.
(c) H.P.
(d) None

The coefficient of x10 in the expansion of 3x 2

77.

(a)
(c)

(b)

15! 35
10! 5!

(d)

DIRECTIONS (Qs. 80 - 84) : Each of these questions


contains two statements: Statement-1(Assertion) and
Statement-2 (Reason). Choose the correct answer
(ONLY ONE option is correct) from the following (a) Statement-1 is false, Statement-2 is true.
(b) Statement-1 is true, Statement-2 is true; Statement-2
is a correct explanation for Statement-1.
(c) Statement-1 is true, Statement-2 is true; Statement-2
is not a correct explanation for Statement-1.
(d) Statement-1 is true, Statement-2 is false.
e

80.

81.

15

x2

is

15! 10
3
10! 5!

15! 8
3
7! 8!

(a)

i=1

(b)

(c)

i=1

(d)

S y if i

(x - b)

S fi

(a)

dx

(x - a)(b - x )

2
a-b

x-a
+c
b-x

is

is zero.

Statement-2 : The value of a determinant is zero if the entries


in any two rows (or columns) of the determinant are
correspondingly proportional.
Statement-1 : Slope of tangents drawn from (4, 10) to
parabola y2 = 9x are

i =1
n

i =1

78.

83.

S y if i

4 - x 2 is [0, 2]
Statement2 : f(x) is increasing for 0 x 2 and decreasing
for 2 x 0.
Let x, y, z are three integers lying between 1 and 9 such that
x 51, y 41 and z 31 are three digit numbers.
Statement-1 : The value of the determinant

i =1
n

Si

dx, n N

x51 y41 z31

S yi
i=1

Statement1 : Range of f(x) =

( lnx )

Let In =

Statement-1 : I1, I2, I3 . . . is an increasing sequence.


Statement-2 : ln x is an increasing function.

The mean of discrete observations y1, y2, y3,...,yn is given


by
S yi

The spheres x 2 + y 2 + z 2 + x + y + z - 1 = 0 and


x 2 + y2 + z2 + x + y + z - 5 = 0
(a) intersect in a plane
(b) intersect in five points
(c) do not intersect
(d) None of these

82.
15! 10
3
10! 5!

a-b
( x - a) b - x (d) none of these.
2

ASSERTION & REASON

The eccentricity of the ellipse represented by


25x2 + 16y2 150x 175 = 0 is
(a)

(c)

84.

1 9
,
4 4

Statement-2 : Every parabola is symmetric about its directrix


Statement-1 : If x 2 + x + 1 = 0 then the value of
2

27
1 2 1
1

x + + x + 2 + .... + x + 27 is 54.
x

x
x

(b)

2
( x - a) (b - x ) + c
a -b

Statement-2 : w, w2 are the roots of given equation and

x+
85.

1
1
1
= -1, x 2 + 2 = -1, x 3 + 3 = 2
x
x
x

88.

If AB = 0, then for the matrices

cos q sin q and


A = cos q

sin 2 q
cos q sin q
2

cos 2 f
cos f sin f
B=
, q f is
sin 2 f
cos f sin f
(a) an odd number of

89.

87.

(c)

1
6

9
cm 3 / min .
4p

(b)

1
cm 3 / min .
4p

(c)

1
cm 3 / min .
9p

(d)

4
cm 3 / min .
9p

The equation of tangent to 4x 2 9y2 = 36 which are


perpendicular to straight line 5x + 2y 10 = 0 are

p
(c) an even multiple of
2
(d) 0
If f'(x) = (x 1) (x 2) (x 3) then f(x) in monotonically
increasing in
(a) x < 1
(b) x > 3, x < 1
(c) x > 3, 1 < x < 2
(d) x < 1, 2 < x < 3
The area enclosed by the curve y = x5, the x-axis and the
ordinates x = 1, x = 1 is

(a) 0

(a)

117
(a) 5 (y3) = 2 x

p
2

(b) an odd multiple of p

86.

An inverted cone is 10 cm in diameter and 10 cm deep. Water


is poured into it at the rate of 4cm3/min. When the depth of
water level is 6 cm, then it is rising at the rate

(b)

1
3

(d) None

(b) 2y 5x + 10 2 18 = 0
(c) 2y 5x 10 2 18 = 0
(d) None of these
90.

log p

log

p2

1
e 2 x sec 2 e 2 x dx is equal to :

(a)

(b)

(c)

3 3
2

(d)

1
3
1
2 3

HINTS AND EXPLANATIONS


1
2
3
4
5
6
7
8
9
10
11
12
13
14
15

1.

(d)

(d)
(a)
(b)
(b)
(b)
(c)
(c)
(b)
(a)
(c)
(a)
(d)
(b)
(c)
(d)

16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

31
32
33
34
35
36
37
38
39
40
41
42
43
44
45

(d)
(c)
(c)
(a)
(b)
(d)
(d)
(b)
(c)
(a)
(a)
(a)
(b)
(b)
(b)

ANSWER KEY
46
(c)
47
(b)
48
(d)
49
(b)
50
(d)
51
(b)
52
(a)
53
(a)
54
(c)
55
(c)
56
(a)
57
(b)
58
(a)
59
(a)
60
(d)

CH3
3
2
1 CH CH Ethyl group comes first in alphab2
3

6.

3.

(a) The order of stability of resonating structures carrying


no charge > carrying minimum charge and each atom
having octet complete.
(b)

NO +2 =

1
[5 + 0 + 0 1] = 2 sp;
2

4.
5.

1
= [5 + 4 + 0 1] = 4 sp3
2

(b) In A O H, if EN of A is 2.1 then it will be neutral,


as XA X0 = X0 XH. (where X is EN)
(b) Correct order is B < Be < O < N.

(b)
(d)
(a)
(c)
(a)
(d)
(d)
(d)
(b)
(a)
(c)
(b)
(d)
(d)
(a)

120
2
3

Cl

Dipole moments of 2Cl and 5Cl

Cl

It is due 1 Cl and 3 Cl m 2
2
2
= m1 + m 2 + 2m1 m 2 cos q

= (1.5) 2 + (1.5) 2 + 2 1.5 1.5 cos 120 \ m = 1.5 D


7.
8.

9.

(c) CsCl is ionic solid.


(b) Volume of ice > volume of water & thus increase in
pressure favours forward reaction showing decrease
in volume.
(a) EHe+ = EH 22; ELi2+ = EH 32 ..... up to Z
[HF][OH ]
[H 3 O + ][F ]
K
=
.
and b
Ka =
[HF][H 2 O]
[F ][H 2 O]

10.

(c)

11.

Therefore, Ka Kb = [H3O+] [OH] = Kw.


(a) Isoelectric point (pH)

1
NO 2 = [5 + 0 + 1 0]= 3 sp2;
2

NH +4

76
77
78
79
80
81
82
83
84
85
86
87
88
89
90

(b)
(b)
(c)
(d)
(b)
(b)
(d)
(c)
(a)
(c)
(a)
(d)
(b)
(c)
(b)

are vectorically cancelled.

4-ethyl-1-methyl cyclohexane. It follows lowest sum


rule
(i.e., lowest set of locant is preferred.)
2.

Cl
1

Cl 5 4

2 Br , 2-bromo1
CH3

Lowest sum of locant is = 1 + 2+ 3 = 6

(c)

C2H5
3

atical order but IUPAC name of

61
62
63
64
65
66
67
68
69
70
71
72
73
74
75

(b)
(d)
(c)
(b)
(c)
(a)
(b)
(c)
(a)
(a)
(d)
(a)
(b)
(a)
(d)

=
12.

pKa1 + pK a 2
2

2.34 + 9.60
= 5.97
2

(d) Let bond energy of A2 be x then bond energy of AB is


also x and bond energy of B2 is x/2.
Enthalpy of formation of AB is 100 KJ/mole:

10
1
1
A 2 + B2 AB; D = - 100KJ
2
2
2x + x - 4x
x x
or - 100 = + - x \- 100 =
\ x = 400 KJ
2 4
4

23.

A 2 + B2 2 AB;

13.

(b)

M total

(b) The reagent is BaCl2 which imparts green colour to


flame. BaCl2 forms chromyl chloride (which is red in
colour), when treated with K2Cr2O7 and conc. H2SO4.
2BaCl2 + K 2Cr2O7 + 3H 2SO4

K 2SO 4 + 2BaSO 4 + 2CrO 2Cl 2 + 3H 2O

(n + n 2 )
= 1
st ,
v1 + v 2

Chromyl chloride
(red gas)

24.

(c) Formaldehyde can not produce iodoform, as only those

n1 = n2 = 0.1, V1 = V2 = 1litre M total = 0.1 M


14.

(c)

compound which contains either CH3 - CH - group


|

0.77 - 0.88
0.11
0.77 + 2( -0.44)
=
=E =
3
3
3

OH

or CH3 -CH - group on reaction with potassium


||

- 0.04
15.

(d) The chemical bond method gives the O.N.


O O

O O

S = O: O S S O :
O +4
+3

16.

(d)

d+
d
CH2 = CH Cl

18.
19.

OS SO

+5 O O

25.

CH2 CH = Cl

Vinyl chloride

17.

O
iodide and sod. hypochlorite yield iodoform.

(c) o-Nitrophenol is not sufficiently strong acid so as to


react with NaHCO3.
(c) Because the layer of Al2O3 (oxide) is inert, insoluble
and impervious.
(a) Au, the gold is not attacked by acids and alkalis. It
forms AuCl3.AuCl3 further reacts with HCl to form
H[Au(Cl)4] which is used in photography.

O-C
|
|
C
O
(v)
|
H

Arrange (NNN), (BrCC), (OOO), (CHH), (OOH) in


increasing atomic number. The order is ii, iii, v, i, iv.

Complex

(b)

H O-C
|
|
(iv) - C - C - OCH 3 ,
|
|
H O

OH
|
(iii) - C - O ,
|
|
O C

AuCl3 + HCl
H[Au(Cl)4 ]
20.

CH 3
|
(ii) - C - CH 3 ,
|
Br

N C
|
|
(a) (i) - C - N ,
|
|
N C

2KI + Cl 2 2KCl + I 2

I 2 + CCl 4 Violet Colour

26.

(a)

CHCl3

Cl

KOH

Note: The excess of Cl2 should be avoided. The layer


may become colorless due to conversion of
NC [Y]

Cl

I 2 to HIO 3

HCl
300 K

I 2 + 5Cl 2 + 6H 2 O 2HIO 3 + 10HCl


In case of Br 2 :
21.

22.

(d) To convert covalent compounds into ionic compounds


such as NaCN, Na2S, NaX, etc.
(d)

Zn

2+

+ 2NH 4 OH
Zn(OH) 2 + 2NH 4+
White ppt.

Zn(OH)2 + 2NH 4 OH
(NH 4 ) 2 ZnO 2 + 2H 2 O
Soluble

(NH 4 )2 ZnO2 + H 2S
ZnS + 2NH 4 OH
White ppt.

+ HCOOH

Cl

Br2 + 2H 2 O + Cl 2 2HBrO + 2HCl

[X]
27.

(a) Let the rate law be r = [A]x[B]y


Divide (3) by (1)

0.10 [0.024]x [0.035] y


=
0.10 [0.012]x [0.035] y

\ 1 = [2]x, x = 0
Divide (2) by (3)

0.80 [0.024]x [0.070] y


=
0.10 [0.024]x [0.035]y

\ 8 = (2)y , y = 3
Hence rate equation, R = K[A]0[B]3 =K[B]3

11
CH2 C H
O

28.

(b) CH2

33.
CH2 CH

Ozonolysis

(b)

CH2 CH

34.

N 2 (g) + 3H 2 (g)

2 NH 3(g)

2 0 .5 3

p N2 p H2

(Si)

36.

(d) (Source) motion l, n both change, (Observer) motion


only n change.
(b) As mv > mr therefore, vv < vr.

37.

(a) From h = 1 -

35.

p 2 NH 3

In 2nd case :

T2 T2
1 5
,
= 1 - h = 1 - = ...(i)
6 6
T1 T1

T2 - 62
2 2
= 1 - h' = 1 - = .....(ii)
T1
6 3

Using (i), T2 62 =

2
2 6
4
T1 = T2 = T2
3
3 5
5

or 1 T2 = 62, T2 = 310 K = 310 273 = 37C


5

= 0.5 (1.5) 3 atm 2


30.

T (300K to 70K )

(Al)

1 - 0 .5
3 - 3 0 .5
3

3
3
3

(b)

= 7 3 ; Ts = 7 7 T0

T R metal R semi - conductor

1x
3 3x 2x at equilibrium
Total moles,
1 x + 3 3x + 2x = 4 2x = 3 (given)
(Since, 4 moles = 4 atm given)
\ x = 0.5

K p for dissociation of NH 3 =

2
3
2
3
T 2 r 3 law; T0 R & Ts (> 7R) ;

Ts

T
0

CH2

CH2 C H

29.

(d)

6
6
T2 = 310 = 372 K = 372 - 273 = 99C
5
5
(a) As isothermal at T1 is farther from the origin than the
isothermal at T2, therefore, T1 > T2
(c) The jockey is moved so as to get the null point (i.e., no
deflection in the galvanometer).
(c) The silvered plano convex lens behaves as a concave
mirror; whose focal length is given by
1 2
1
= +
F f1 f m
T1 =

(b) Let the amount of the K 2Cr2 O 7 in the mixture be x g,


then amount of KMnO4 will be (0.5 x) g

38.
39.

x 0.5 - x 100 0.15


+
=
\
31.6
1000
49

40.

where 49 is Eq. wt. of K 2Cr2 O 7 and 31.6 is Eq. wt. of


KMnO4 .
On solving, we get x = 0.073 g
% age of K 2Cr2 O 7 =
31.

0.0732 100
= 14.64%
0.5

(c) Given (10 kW) I = 4V OR 10 kW .

120V
= 4 V OR 300
X + 10kW

kW = X + 10 kW;
X = 290 kW.
120V

32.

If plane surface is silvered


X

2p
7
= 2 pn = 2p
= 0.44 rad / sec . ;
T
100

V = Rw = 0.44 12 = 5.3 cm/sec.

R2
= =
2
2

1
1
1
1 1 m 1
= (m 1)

= (m 1) =
R
f1
R
R1 R 2

1 2(m 1) 1 2(m 1)
R
=
+ =
F =

F
R
R
2(m 1)

10kW

(b) This of example of uniform circular motion.


w=

fm =

Here R = 20 cm, m = 1.5


\ F=

20
= 20cm
2(1.5 1)

12
41.

(a) Pitch = 1 mm
Number of divisions on circular scale = 200

50.

(c) Einstein equation KEmax = E Work function;


1
mv 2 = E - W
2

Pitch

L.C =

Number of divisions on circular scale


1 mm
=
= 0.005 mm = 0.0005 cm
200

Using this concept,

Diameter of the wire = (Main scale reading + Circular


scale reading L.C.) zero error
= 6 mm + 45 0.005 ( 0.05)
= 6 mm + 0.225 mm + 0.05 mm = 6.275 mm
42.
43.

V 0.5
(b) R = =
= 2 W.
I 0.25
(a) Angular retardation,

1
mV12 max
1 - .5
1
V max 1
2
=
= or 1
=
1 2
2.5 - .5 4
V
2
2 max
V2 max
2

51.

(a) First, let us check upto what value of F, both blocks


move together. Till friction becomes limiting, they will
be moving together. Using the FBDs

44.
45.

(a) A metre bridge is used to determine the resistance of a


given wire and not to determine the emf of a cell.

a2
10 kg block will not slip over the 15 kg block till
acceleration of 15 kg block becomes maximum as it is
created only by friction force exerted by 10 kg block on
it.

3
Little before 4 second v = m / s, little after 4 second,
4
velocity becomes zero
Therefore, Impulse

46.

= m(vf - vi ) = 4 0 - = -3kg ms -1

4
(b) In reverse bias on p-n junction when high voltage is
applied, electric break down of junction takes place,
resulting large increase in reverse current. This high
voltage applied is called zener voltage.

47.

(d)

48.

= 2.7 106 Hz = 2.7 MHz


(c) Conservation of Energy,

F-f
f
=
for limiting condition as f maximum is 60N.
10
15
F = 100 N
Therefore, for F = 80N, both will move together.
Their combined acceleration, by applying NLM using
both as system, F = 25a

52.

Photon e + + e - + energy
re -

80
= 3.2 m / s 2
25
(b) If F = 120N, then there will be slipping, so using FBDs
of both (friction will be 60 N)
For 10 kg block, 120 60 = 10a a = 6 m/s.
For 15 kg block, 60 = 50a a = 4 m/s.
(c) Study of junction diode characteristics shows that the
junction diode offers a low resistance path, when
forward biased and high resistance path when reverse
biased. This feature of the junction diode enables it to
be used as a rectifier.
a=

+ K.E. of both e - + e +
+

49.

a1 > a 2(max)

f c = 9 N m = 9 9 1010

+E

3
\ Impulse = m (vf vi) = 4 - 0
4
1
= 3 kg ms

re +

F
F

15 kg

3
(d) t < 0, vi = 0 and t > 0, vf = m / s
4

EP = E

a1

w - w1 2p(n 2 - n1 ) 2p(0 - 900 / 60) p


a= 2
=
=
= rad / s 2 .
t
t
60
2

We know that rest mass energy of e + e


Hence E P = .5 + .5 + .19 2 = 1.40MeV
(b) Let initial amount be 100 gm.
disintegrated
100 10
5 days
100 gm
10
100
90 10
Next 5 days
90
9
100
8110
Next 5 days
8.1
81
100
73 10
Next 5 days
73
7.3
100

53.
is .5 MeV

Left
90

54.

(a)

l = 3,

d = 6 ,

l
a
d
d = ? ; d l a = 1

81

6 d l

73
65

l =

3
6

1
=1
3

1
2

; ld = 2

13
If C be the critical angle, then

1
1
Sin C = =

5 Amp

C = 45. As angle of incidence < 45, it will not be


internally reflected. So statement 1 is false statement 2
is true.
55.

5m

mmg
(a) a =
M

Magnetic field at half way due to Q wire

Body
m

BQ =

3mmg

fr

M plate

57.

B = BP + BQ =

(d) When two rods are connected in series


Q=

A(T1 - T2 )t A(T1 - T2 ) t
=
d1 d 2
(d 1 + d 2 ) / K
+
K1 K1

d1 + d 2 d1 d 2
;
=
+
K
K1 K 2

\K =

60.

m 0 m 0 3m 0
(downward
+
=
p 2p
2p

3m 0
2p

(d) From figure,

(d 1 + d 2 )
d1 d 2
+
K1 K 2

(a) Let T be the tension in the string; f = frictional force


between block A and table; m = minimum mass of C.
For the just motion of block A on table

For the just motion of block B, T = 5g


From (i) and (ii), 5g = 0.2 (10 + m)g
or 5 = 2 + 0.2m or m =

1
- wL
w
tan 45 = C
R

....(ii)

5-2
= 15kg
0.2

1
2 2
(b) Total energy, E = mw a ;
2

K.E. =
So,
59.

Hence net magnetic field at midpoint =

T = f = mR = m(m + m ' )g = 0.2(10 + m' )g ....(i)

58.

m0I 2 m0
=
[upward
5 2p
2p
2

[where I 2 = 2.5Amp. ]
Net magnetic field at half way

fr

fr = mmg = Ma

56.

2.5 Amp

3E 1
= mw 2 (a 2 - y 2 ) .
4
2

61.

(a) When current flow in both wire in same direction then


magnetic field at half way due to P wire.
(where I1= 5Amp)

The direction of Bp is downward

62.

1
1
= R + wL
- wL = R
wC
wC

C=

1
1
=
w(R + w)
2 pf ( R + 2 pfL)

(b)

3 a2 - y2
a
a2
2
=
=
y
or
or y = .
2
4
2
4
a

uur
m I
m I
m
BP = 0 1 = 0 1 = 0
5
p .5
p
2p
2

(b)

(4, 3)

(6, 0)

(0, 0)

(4, 0)

Area =

1
1
b h = 6 3 = 9 mt 2
2
2

p=

1
10

q=

9
10

9
\ Probability that none are defective =
10

14
63.

64.

(c)

tan 2 b + 1
2
1
=
=
cos 2a
tan b
sin b cos b

(a) Let the co-ordiante of other ends are (x, y, z).


The centre of sphere is C(3, 6, 1)
Therefore,

p
sin2b = cos2a = sin (90-2a) a + b =
4
(d) Sum of 7 can be obtained when (2,6), (3,5) (3, 6), (4, 4),
(4,5), (4, 6)(5, 3)(5, 4) (5, 5)(5, 6)(6, 2)(6, 3)(6, 4)(6,5)(6, 6)

\ Probability of sum > 7 =


n

65.

71.

(b)

15
5
=
36 12

y+3
z+5
= 6 y = 9 and
= 1 z = -3
2
2

72.

(d)

r. n
r - 1. n - r + 1 n - r + 1
=
.
=
n
r. n - r
n
n-r
Cr -1
Cr

n - r +1
= n - r +1
n -r

73.

= 5n - 10 = 5(n - 2)

(b)

14

67.

C7 +

15

C 6 +16 C 6 = 16 C 7 +16 C 6 =17 C 7

dx 2
3

d y
dx3
d4 y
dx
\

3
30
5 5
1 + ...... =
36 6
91

( x - 3) 2 y 2
+
=1
25
16

16
3
=1- e2 e = .
25
5

75.

(b) a, b, c in A.P. a + c = 2b;

b, c, d in G.P..

c, d, e in H.P. d =

bd = c2;

= - Aw 2 sin wt

2ce
c+e

a + c 2ce

= c2 (a + c)e = (c + e)c c2 = ae.


2
c+e

Therefore, in G.P.

= -Aw3 cos wt

15

76.

(b)

2 1

3x x2

= + Aw 4 sin wt

d5y
dx

1
Tr +1 =15 C r (3x 2 )15-r x2
=15 C r 315-r (-1) r x 30- 2 r - 2 r

= A w 5 cos w t = A w 5 sin w t +

(c) For perpendicularity 3l 21 + 6l = 0 l = 7.


(a) a1 = 2, b1 = 2,c1 = 1 and a2 = 1, b2 = 2, c2 = 2
cos q =

Therefore, T6 = -15 C 5 310 =

a12 + b12 + c12 a 22 + b 22 + c2 2

4
=
= .
9
4 + 4 +1 1+ 4 + 4
(c) Contrapositive of p q is ~ q ~ p
\ contrapositive of (p q) r is
~ r ~ (p q) i.e. ~ r (~ p ~ q)

Therefore, 30 4r = 10 r = 5.

a1a 2 + b1b2 + c1c 2

2+ 4- 2

70.

(c) For x > 10, f (x) = x 2.


Therefore, g(x) = x 2 2 = x 4
\ g(x) = 1.

dy
= Aw cos wt
(d) y = A sinwt. \
dx

d2 y

68.
69.

C7 +

5 1 5
1 5 1
+
+
...
6 6 6
6 6 6

74.

17-i C 6 =14 C 7 +14 C 6 +15 C 6 +16 C 6


i =1
15

r =1

66.

P(E E) + P(E E E E E )

(b) The ellipse

= n + (n - 1) + (n - 2) + (n - 3) + (n - 4)
3

x+2
= 3 x = 4
2

77.

(d) Lf '(0) = Lt h 0

-15! 10
3 .
10! 5!

f ( 0 + h ) - f (0 )
- h2 -0
= Lt
=0
h
h
h 0-

f ( 0 + h ) - f (0 )
+h2
= Lt
=0
h
h 0+
h 0+ h

& Rf ' (0) = Lt

\ Lf (0) = Rf (0) ,
Hence, f(x) is differentiable at x = 0

15
78.

(a) I =

dx

(x - b)

5 4 3

( x - a )(b - x )

=1 1 1
x

Put x = a sin 2 q + b cos 2 q

which is zero provided x, y, z are in A.P.

[see the standard substitutions]


dx = 2(a - b) sin q cos q dq

83.

(d)

Also, ( x - a) = (b - a ) cos 2 q
2

( x - b) = ( a - b) sin q

\I =

2( a - b) sin q cos q dq

(a - b) sin 2 q (b - a) sin q cos q

2
2
(- cot q) + C =
cot q + C
b-a
a -b

y = mx +

10 = 4m - 1

9/ 4
16m 2 - 40m + 9 = 0
m

m1 + m 2 =

9
40 5
= ; m1m2 =
16
16 2

1
9
, m2 =
4
4
every parabola is symmetric about its axis only
Statement 1 is true.

84.

Now , x = a sin 2 q + b cos 2 q

(b)

x+

1
1
= -1, x 2 +
= -1,
x
x2

x3 +

1
1
1
= 2, x 4 +
=x+ ,
3
4
x
x
x

x5 +

1
1
= -1, x 6 +
= 2 , etc.
x5
x6

x cos ec 2 q = a + b cot 2 q
2

x (1 + cot q) = a + b cot q

\cot q =
79.

80.

1
> 0 (as x > 0, so that f (x) is defined)
x

Statement I isnot trueas0 < ln x < 1, " x (1, e) and


hence (ln x)n decreases as n is

a decreasing sequence.

increasing. So that I n is

-x

(d) f (x) =

4 - x2

\ f (x) is increasing for 2 x 0 and decreasing for


0 x 2.
5

82.

(d)

D = x51 y41 z31


x

y
5

2
2
3 9
1
1
1

+ x 6 + 6 + x 7 + 7 +........+ ( x ) + 3 9
x
x
(x )

85.

= (1 + 1 + 4) + (1 + 1 + 4) + (1 + 1 + 4) + ......... 9 times
= 6 9 = 54.
(a) We have,
cos 2 q
cos q sin q cos 2 f
cos f sin f
AB =

2
sin 2 f
sin q cos f sin f
cos q sin q

cos 2 q cos 2 f + cos q cos f sin q sin f


=
2
2
cos q sin q cos f + sin q cos f sin f
cos 2 q cos f sin f + cos q sin q sin 2 f

cos q cos f sin q sin f + sin 2 q sin 2 f


cos q cos f cos q sin f
= cos( q - f)

sin q cos f sin q sin f

= 100x + 51 100y + 41 100z + 31


x

1
1

+x4 + 4 +x5 + 5
x
x

(c) As the given spheres both have same cenre and


different radii therefore they are concentric and they
do not have any point in common. Hence they do not
intersect.
(a) Statement II is true, as if f (x) = ln x, then
f (x) =

81.

1
1
1

x + +x 2 + 2 +x3 + 3
x
x
x

x -a
+C
b- x

2
x-a
; \I=
a-b
b-x

a
m

m1 =

2
dq
2
=
=
cos ec 2 q dq
b - a sin 2 q b - a
=

[R2 R2 100R3 10R1]

y z

Since, AB = 0, \ cos( q - f) = 0

\ q - f is an odd multiple of

p
2

16
86.
87.

(c) When x > 3, f '(x) > 0; when 2 < x < 3, f '(x) < 0; when 1 <
x < 2, f '(x) > 0; when x < 1, f '(x) < 0.
(b) Required area
1

We have to find out the rate of increase of water-level

= | y | dx = | x 5 | dx = 2 | x 5 | dx
-1
1

-1

i.e.

dV p
dy
p
dy
dy
16
= .3y 2 . ; \ 4 = y 2 . ; \
=
.
dt 12
dt
4
dt
dt py 2

(d) Let y be the level of water at time t and x the radius of


the surface and V, the volume of water.
We know that the volume of cone
=

1
p (radius)2 height
3

When y = 6 cm,

89.

5cm

dy
16
4
=
=
cub.cm. / min .
2
dt p6
9p

(d) Slope of the equations 4x2 9y2 = 36


8x - 18y

dy
.
dt

Differentiating (1) with respect to t, we get

x6
2 1
= 2 x 5 dx = 2 = =
6 0 6 3
0

88.

dV
. = 4 cub.cm./min.
dt

4x
dy
dy 4x
or m1 =
=0
=
9y
dx
dx 9 y

Slope of the straight line, 5x + 2y 10 = 0 is m 2 = Therefore, for the perpendicularity, m1m2 = 1

10 cm

Now,

10 x
in 4 x 2 - 9 y 2 = 36 gives imaginary
9
roots resulting in no tangents.

1
\ V = px 2 y. Let BAD = a
3

90.

MR x
1 x
y
= ; = ; \x = .
AR y
2 y
2

p 2
1
1 y
p.x 2 y = p. .y =
y
3
3 2
12

I=

log p
log p 2

1
e 2 x sec 2 e 2 x dx

When x = log p 2 , t = e 2 log

p2

=p

When x = log p , t = e 2 log

\V =

(a)

Put e 2 x = t 2 e 2 x dx = dt

BD 5 1
=
= .
AD 10 2

Again, from right angled DAMR, we have


tan a =

4 x -5
10x
.

= -1 y =
9y 2
9

Putting y =

tan a =

5
2

......(1).

\I =

By question, the rate of change of volume


=

3
2

p1
1
sec 2 t
p2
3
2

log p 2
=
=e

t
1 1
dt = . 1 tan .
3 p
2

1
p
p 3

=
tan 3 - tan 6 = 2 3 3

p
2

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