of
LIMERICK
OLLSCOIL LUIMNIGH
CG5082
Module Title:
Lecturer(s):
External Examiners:
Semester:
Spring 2013
Duration of Exam:
2.5 h
Instructions to Candidates:
1. Any non-programmable calculator may be used provided it has been cleaned of any
information that would subvert the purpose of the examination
2. Calculations must be shown in sufficient detail to illustrate your understanding of the
procedure
3. Please write clearly and readably.
4. The corresponding marks allocated to each answer are shown in the text below.
5. Marks will be deducted for the inclusion of irrelevant material in these answers, down
to a minimum of 40% of the marks available for the question.
___________________________________________________________________
Page 1 of 11
Part 1
20 marks
Problem 1.1.
Problem 1.2.
Problem 1.3.
A waste stream of alcohol vapour in air from a process was adsorbed by zeolites particles in a
packed bed having a diameter of 5 cm and length of 20 cm containing 200 g of zeolite. The
inlet gas stream having a concentration of 900 ppm and density of 0.001 g/cm 3 entered the
bed at a flow rate of 500 cm3/s. Data in Table give the concentration of the breakthrough
curve. The break-point concentration is set at c/c 0 = 0.1. Determine the break-point time, the
fraction of total capacity used up to the break point, and the length of the unused bed, and the
saturation loading capacity of the zeolite.
Time
h
0
5
6
7
8
9
10
11
12
13
14
15
Problem 1.4.
c/c0
0
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
30 marks
Absorption of carbon dioxide from a carbon dioxideair mixture in a solution containing 100
kg/m3 of caustic soda, using a 250 mm diameter tower packed to a height of 2 m with 19 mm
Raschig rings. The results obtained at atmospheric pressure 1013hPa, and gas rate is 0.4
kg/m2s, and liquid rate is 5.0 kg/m2s. The carbon dioxide in the inlet gas was 850 parts per
million and the carbon dioxide in the exit gas was 65 parts per million. The equilibrium can
be described by the relation y1e =1.6x1.
What is the value of the overall gas transfer coefficient KGa in kmol/m3skPa? Calculate
height and number of transfer units.
Page 2 of 11
Part 2
Problem 2.1.
30 marks
A slurry is filtered in a plate and frame press containing 18 frames, each 0.35 m square and
25 mm thick. During the first 280 s the pressure difference for filtration is slowly raised to the
final value of 400 kN/m2 and, during this period, the rate of filtration is maintained constant.
After the initial period, filtration is carried out at constant pressure and the cakes are
completely formed in a further 1200 s. What is the volume of filtrate collected per cycle?
A sample of the slurry had previously been tested with a leaf filter of 0.07 m2 filtering surface
using a vacuum giving a pressure difference of 60 kN/m2. The volume of filtrate collected in
the first 500 s, was 350 cm3 and, after a further 400 s, an additional 225 cm 3 was collected. It
may be assumed that the cake is incompressible and that the cloth resistance is the same in
the leaf as in the filter press.
Problem 2.2.
20 marks
Problem 2.3.
25 marks
The mass-transfer coefficient from a free water surface to an adjacent moving air stream has
been found to be 0.02 kg m-2 s-1. Estimate the rate of evaporation from a surface of 1 m2 at a
temperature of 30C into an air stream with a dry-bulb temperature of 50C and relative
humidity of 30% and the consequent necessary rate of supply of heat energy to effect this
evaporation.
Problem 2.4.
25 marks
A salt solution weighting 50 tonnes with 60wt% MgCl 2 is cooled to 290 K. The salt
crystallizes as the hexahydrate. What will be the yield of MgCl 2 6H2O crystals if the
solubility is 56 kg anhydrous /100 kg of total water? Assume that 10% of the total weight of
the solute is lost by evaporation of water in cooling. Molecular mass (M): M MgCl2 = 95.2
g/mol; M MgCl2 6H2O = 203.3 g/mol; M.
Page 3 of 11
Appendix 1.
Page 4 of 11
Page 5 of 11
Dp > 2.5mm
Dp =0.6~2.5mm
Adsorption
Langmuir isotherm
KA = K0/RT
or
Page 7 of 11
BET isotherm
Freundlich isotherm
for dilute
concentrations
Gm = moles of inert
gas/(unit time) (unit
cross-section of
tower),
Lm = moles of solutefree liquor/(unit time)
(unit cross-section of
tower),
NOG = overall gas
transfer units,
HOG = height of the
overall gas transfer
unit,
HOL = height of the
overall liquid transfer
unit,
CT = is the mean
molar density of the
liquid.
Column capacity
HT is the total bed
length,
HB is the length of
bed used up to the
Page 8 of 11
Membrane separation
J is the membrane flux, expressed
as volumetric rate per unit area,
|P| is the pressure difference
applied across the membrane, the
transmembrane pressure,
|| is the difference in osmotic
pressure across the membrane,
Page 9 of 11
Boiling
Page 10 of 11
Drying
humid volume
Page 11 of 11