com
Proceedings
ScienceDirect
of the
Combustion
Institute
www.elsevier.com/locate/proci
Abstract
Combustion experiments on cylindrical bio-coke (BIC), a highly densied biomass briquette, have been
conducted to observe whether quasi-one-dimensional steady combustion can be attained in room temperature air ow. In the experiments, the air ow velocity was the main test condition and the fuel consumption rate when the bottom surface of the BIC sample burned was evaluated as the regression rate of the
combustion zone at the bottom surface. In addition, one-dimensional calculations based on an energy
equation at the combustion zone were conducted to understand the mechanism that results in steady combustion and predict the eect of water and volatile matter content in BIC on the extinction limit. The
results showed that steady combustion of the BIC sample could be attained in 4.67 m/s or more, and,
in contrast, extinction was observed in 3.82 m/s or less. The critical regression rate explained by the combustion zone temperature was shown, and the reason combustion becomes unsteady could be explained by
the energy balance at the combustion zone. Though the main reason for extinction was radiation heat loss,
the heat loss by water and volatile matter was not negligible. Therefore, the eect of water and volatile matter content on steady combustion must be considered.
2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
Keywords: Biomass briquette; Solid combustion; Surface combustion; Steady ame propagation; Extinction limit
1. Introduction
Presently, biomass fuels are an increasingly
attractive primary energy source because of their
intrinsically renewable nature and potentially limited generation of pollutants. Biomass usually
contains negligible sulfur and low concentrations
Corresponding author. Tel.+81 11 706 6385, fax:
http://dx.doi.org/10.1016/j.proci.2014.08.013
1540-7489/ 2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
2416
Nomenclature
A
A0
cp
D
dn
E
k
L
Nud
Q
R
SB
T
td
frequency factor
theoretical amount of air
specic heat
diusion coecient
nozzle diameter
activation energy
reaction rate constant
latent heat
Nusselt number for substance
diusion
caloric value
universal gas constant
regression rate
temperature
thickness of diusion layer
e
k
m
q
r
emissivity
excess air factor
stoichiometric coecient
density
StefanBoltzmann constant
Subscripts
a
ambient
char
char
CO2
carbon dioxide
i
carbon dioxide, nitrogen, oxygen
O2
oxygen
s
surface
v
volatile matter
w
water
Greek symbols
b
substance diusion rate
2. Experimental method
2417
Pulley
Air
0.2
1300
17.9
Elemental analysis
(dry basis)
C [wt%]
H [wt%]
O [wt%]
N [wt%]
47.72
5.95
32.75
0.47
Industrial analysis
(as received basis)
Char [wt%]
Volatile matter [wt%]
Water [wt%]
Ash [wt%]
13
70
10
7
Data
logger
Inner tube
PC
Mechanical
scale
Bio-coke sample
Counter
weight
Thermocouples
Window
DV camera
Combustion zone
Outer tube
Stage
Electric heater
IR camera
Germanium glass window
Flow meter
Blower
2418
S B qv Qv qw Lw erT 4s T 4a
1
S B qchar Qchar :
In Eq. (1), the energy balance among the absorption of heat is considered, which consists of sensible heat, decomposition heat of the volatile
matter, latent heat of vaporization, and radiation
heat, and the amount of generated heat from carbon combustion(carbon in the char).
The rst term that appears in the left-hand side
of Eq. (1) represents the sensible heat increasing
from the original temperature to the combustion
zone temperature of nitrogen and excess oxidizer
by air ow, pyrolysis gas, water vapor, and CO2
generated by char oxidation inside the control volume. The ratio of composition of pyrolysis gas is
CO:CO2:CH4 = 2:2:1 [11,12]. The second term in
the left-hand side of Eq. (1) is the latent heat of
water vaporization and heat for the pyrolysis reaction based on results of dierential thermal analysis inside the control volume. The radiation heat
in Eq. (1) is thought to approximate the combustion zone gray body in which emissivity is 0.8.
This approximation is based on experimental data
and calibrating temperatures measured by IR
camera and thermocouple. The right-hand term
in Eq. (1) is the char oxidative reaction inside
the control volume. The chemical reaction formula with nitrogen and excess oxidizer in the supplied air is expressed by Eq. (2).
C 0:23kA0 O2 0:77kA0 N2 ! mCO2 CO2
0:23k 1A0 O2 0:77kA0 N2 :
BIC sample
Air
Fig. 2. Direct image of end-face combustion.
60
1100
50mm
20mm
40mm
1000
Temperature [K]
2419
10mm
900
30mm
800
700
600
500
400
300
200
50
40
30
20
2.97m/s
3.82m/s
5.52m/s
6.37m/s
4.67m/s
10
0
10
20
30
40
50
60
70
20
40
60
80
100
120
140
Temperature [K]
900
800
700
Regression length: 20mm
600
500
400
Regression length: 40mm
300
200
0
10
2420
3.00
Solid line : Calculation
Dots : Experiment
2.50
2.00
1.50
1.00
0.50
0.00
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
1200
1100
2.97m/s
900
5.52m/s
800
700
600
3.82m/s
500
400
300
8.00
0.00
0.50
1.00
1200
1100
1000
900
800
700
600
Solid line : Calculation
Dots : Experiment
400
300
1.00
2.00
3.00
4.00
5.00
2.00
2.50
3.00
6.00
7.00
8.00
70.0
60.0
0.00
1.50
500
6.37m/s
4.67m/s
1000
Radiation
50.0
Sensible heat
40.0
30.0
20.0
10.0
0.0
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
8.00
6.37m/s
5.52m/s
2.50
4.67m/s
2.00
3.82m/s
2.97m/s
1.50
Unsteady region
1.00
0
10
15
20
25
3.50
2421
6.37m/s
5.52m/s
3.00
4.67m/s
3.82m/s
2.50
2.97m/s
2.00
1.50
Unsteady region
1.00
60
65
70
75
80
Fig. 11. Eect of volatile matter content on the regression rate and extinction limit.
Experiments with BIC, a highly densied biomass briquette, were conducted by burning the
BIC quasi-one-dimensionally to observe whether
the combustion reaches a steady state in room
temperature air ow. In addition, one-dimensional calculations were done to help understand
the mechanism that allows for steady combustion
and predict the eect of water and volatile matter
content in BIC. The results thus obtained may be
summarized as follows:
(1) It was conrmed that quasi-one-dimensional
combustion of BIC is attained in room
temperature air ow. The combustion
reaches a steady state in high air ow
velocity (4.67 m/s or larger), but extinction
is observed in low air ow velocity (3.82 m/
s or lower).
(2) According to the one-dimensional analysis,
there is a critical regression rate to sustain a
steady state. The existence of the critical
regression rate is explained by the bottom
surface temperature change, which is given
by the ratio of heat loss to heat released
by char combustion.
(3) The heat loss caused by water and volatile
matter content included in the BIC is not
negligible, but the main reason for extinction in low air ow velocity is radiation heat
loss. Moreover, the extinction limits shifts
to a higher regression rate as water and volatile matter content increase. Therefore, the
eects of water and volatile matter content
on steady combustion are important.
Acknowledgements
This research was supported by Grants-Aid for
Scientic Research (Houga, Subject #22656050)
from MEXT Japan in 20102011 and was partially supported by Grants-Aid for Scientic
Research (Kiban (C), Subject #26420160) from
MEXT Japan in 2014.
2422
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