SOLUTION CHEMISTRY FOR XII C2, XII G2, , XII C, XII G

1.

2.

3.

The flame colours of metal ions are due to

(a) Frenkel defect
(b) Schottky defect
(c) Metal deficiency defect
(d) Metal excess defect
A metal crystallizes in two cubic phases, face centred cubic (fcc) and body centred
cubic (bcc) whose unit cell length are 3.5 and 3.0 respectively. Calculate the
ratio of density of fcc and bcc.
(a) 2.123
(b) 1.259
(c) 5.124
(d) 3.134
Which of the following figures represents the cross-section of an octahedral site ?

(a)

4.

5.

(b)

(d)

Choose the correct matching sequence from the possibilities given

(a) Crystal defect

(1) AB AB AB.....type crystal

(b) hcp

(2) Covalent crystal

(c) CsCl

(3) Frenkel

(d) Diamond

(4) Face centered in cube

(e) NaCl

(5) Body centered in cube

(a)

a-3, b-1, c-2, d-5, e-4

(b)

a-3, b-1, c-5, d-2, e-4

(c)

a-3, b-5, c-2, d-2, e-4

(d)

a-5, b-3, c-4, d-2, e-1

A solid has a bcc structure. If the distance of closest approach between the two
atoms is 1.73 . The edge length of the cell is :
(a) 200pm

6.

(c)

(b)

3 / 2 pm

(c) 142.2 pm

(d) None of these

Choose the incorrect statements

(a) Vacancy defects lower the density of the substance
(b) Interstitial defects increase the density of the substance
(c) Schottky defects, preserve the electrical neutrality of the crystal.
(d) Frenkel defects affect the density of the crystal.

7.

Pick up the correct statements

(a) The ionic crystal of AgCl has Schottky defect
(b) The unit cell having crystal parameters, a = b = c, a = b = 90, b = 120 hexagonal
(c) In ionic compounds having Frenkel defect, the ratio r+/r is high
(d) The coordination number of Na+ ion in NaCl is 4

8.

Select the correct statement (s)

(a) In NaCl crystal, each ion has an tetrahedral coordination.
(b) The C.N. of an atom in hcp structure is 12.
(c) Diamagnetic materials are attracted by the magnetic fields.
(d) An octahedral hole is smaller than a tetrahedral hole.

9.

As we proceed from NH3 to BiH3, which of the following statements is not correct(a) The hydrides become more basic
(b) The reducing power of the hydrides increases
(c) Their stability decreases
(d) The ease of replacing hydrogen of the hydrides by other group increases

10. The ionic character of H X is highest in

(a) HBr

(b) HI

(c) HF

(d) HCl

(c) Bi

(d) P

11. Which of the following does not form pentoxide

(a) As

(b) Sb

12. The molecule having the smallest bond angle is

(a) H2O
(b) H2S
(c) H2Te
13. Among the trihalides of nitrogen ,the one which is least basic is

(d) H2Se

(a) NF3
(b) NCI3
(c) NBr3
(d) NI3
14. Indicate for the CIF3 molecule, the shape and the type of hybridization (of the Clatom)

(a) F

(c)

sp2

(b)

sp3d

(d)

sp3d

15. In the nitrogen family the H M H bond angle in the hydrides MH3 gradually
becomes closer to 90 on going from N to Sb. This shows that gradually
(a) The basic strength of hydrides increases
(b) Almost pure p-orbitals are used for M H bonding
(c) The bond energies of M H bond increases
(d) The bond pairs of electrons becomes nearer to the central atom
16. In the following reaction
H 2O

x CH 3CHO What is X ?
C2H2
HgSO4 / H 2 SO4 ,600 C

(a) CH3CH 2OH

(b) CH3-O-CH3
(c) CH 3CH2CHO (d)
H2C=CHOH
17. The presence of OH groups on adjacent carbon atoms can be detected by
the reaction of the compound with
(a) Concentrated H 2SO4
(b)
Concentration
HNO 3
(c) HIO4
(d) Acid KMnO4
18. Ethylene glycol is treated with HI then product formed is
(a) ICH 2 CH 2 I
(b) CH 2 CH 2
(c) OHCH 2 CH 2 I
(
d
)

CH 2 CHI
19. Ethylene glycol on oxidation by HIO4 product formed is
(a) acetaldehyde
(b) acetone
(c) formaldehyde

(d)

acrolein

20. Alkaline hydrolysis of oil or fat is known as

(a) decarboxylation
(b) fermentation
(c) decomposition
(d) saponification
21. When glycerol is treated with excess HI the product formed is
(a) acrolein
(b) allyl iodide
(c) isopropyl iodide
(d) allyl alcohol
22. Ethylidene chloride on treatment with aq. KOH gives
(a) CH3CHO
(b) CH2OH.CH2OH
(c) HCHO
(d) CHO. CHO
23. Benzene reacts with CH3COCl in the presence of AlCl3 to give
(a) C6H5COCl
(b) C6H5Cl
(c) C6H5CH3
(d) C6H5COCH3
24. Aldehydes can be prepared from acid chlorides by
(a) Clemmensen reduction
(b) Wolff-kishner reduction
(c) Rosenmund's reduction
(d) LiAlH4 reduction.
25. A dihaloalkane on alkaline hydrolysis produces a ketone with formula C3H6O. The
dihaloalkane can be
(a) 2,2-Dichloropropane
(b) 1,1-Dichloropropane
(c) 1,2-Dichloropropane
(d) 1,3-Dichloropropane
26. Ozonolysis of an alkene X produce acetaldehyde and acetone then X is
(a) 2-butene
(b) 2-methyl-2- butene
(c) 1-butene
(d) 2,3-dimethyl-2-butene
27. When phenol is treated with CHCl3 and NaOH, the product formed is :
(a) Benzaldehyde
(b) Salicylaldehyde
(c) Salicylic acid
(d) Benzoic
acid
CH3
|

28. IUPAC name of CH3 CH2 C H C H CH2 CH3

|

CHO

(a) 4-methyl hexanal-3

(b) 3-ethyl-2-methyl pentanal
(c) 2-ethyl-3-methyl pentanal
(d) 4-methyl heptonal
29. When propyne is treated with aqueous sulphuric acid in presence of
Mercuric sulphate, the major product is
(a) Proponal
(b) Propyl Hydrogen Sulphate
(c) Propanol
(d) Propanone
0
30. Iso propyl alcohol in presence of Cu at 300 c gives the following
(a) Acetaldehyde
(b) Acetone
(c) Formaldehyde
(d) Benzaldehyde
SOLUTION
1.

(d)

2.

(b). =

n Mm

NA a3
For fcc centred cubic cell n = 4, a = 3.5
4 Mm
r(fcc) = N (3.5)3
A

For bcc lattice

n = 2, a = 3.0

................. (i)

r(bcc) =

2 mm

................. (ii)

N A (3.0)3

From equations (i) and (ii)

(fcc)

(bcc)

33
4333
4
=

=
= 1.259
2 3.5 3.5 3.5
(3.5)3
2

3.
4.
5.
6.
7.
8.
9.
10.

(d)
(b). Crystal defects are refferred as Frenkel and Schottsky defects.
(a)
(b)
(b)
(b)
(a)
(b). The ionic character is expected to increase as the electronegativity of the halogen increases. Thus due
to the highest electronegativity difference in H and F, the H F bond should be most ionic. But H I bond
being the weakest gives the hydrogen readily. HI is also the strongest acid because of its least bond
dissociation energy. The ionic character thus follows the order HI > HBr > HCl > HF

11.

(c). The stability of the highest oxidation states decrease down the group and Bi does not form a pentoxide.
Moreover higher oxidation states are more acidic than lower oxidation states.
(c). Bond angle decreases in the
H2O > H2S > H2Se > H2Te.
(a)
(c). Distorted T-shape; sp3d hybridization
(b). The hybrids have a pyramidal or tetrahedral shape with a lone pair of electrons in one of the orbitals. The
H M H bond angle is less than the original 10928' tetrahedral bond angle (H N H in NH3 is 10645')
because of greater repulsion between lone pair and a bond pair than between two bond pairs of electrons.
Because electronegativity of M decreases from N to Bi, the bond pair lie farther away from the central atom,
and the lone pair causes greater distortion of bond angle.
Thus H P H bond in PH3 is 94, while in AsH3 and SbH3 it is about 91.8 and 91.3 respectively (closer
to 90). This suggests that orbtials used for bonding are closer to pure p-orbitals.
(d)

12.
13.
14.
15.

16.

H O

2
CH 2 CHOH CH 3CHO
C2H2
HgSO4 / H 2 SO4 ,600 C

17.
18.
19.
20.
21.

(c)
(b)
(c)
(d)
(c)

22.

(a)

CH3CH

aq. KOH

CH3CH

H O

CH3CHO

23.
24.

(d) Electrophilic substitution (Friedel Craft acylation reaction).

(c)

25.

Cl
OH
O
|
|
||

H2O
OH / H2O
(a) CH3 C CH3
CH3 C CH3

CH3 C CH3
|
|
Cl
OH

26. (b)
27. (b)
28. (c)
29. (d)
30. (b)