17860
ST'BJECTCODE
.E
20r4Gr)
CIIEMICAL SCIENCES
TEST BOOKLET
MXI,BT
CODE
tr
Maximw
INSTRUCTIONS
t.
you have opted-for English as medium of Questbn Paper. This Test Booklet contaim
one hundred ard
4.
Questions
3.
.d'-and
ffiooklet
ts
Ii6ii-the
Answer Sheet. failins which. the comnuter shall not be able to decipher
6.
and
'B'
8.
9.
rough
- - -g-- work'
'j -- --Use of calculator is NOT Permiued.
7.
10.
ll.
Rou
ffipart,A'
ffir
the
sheet
No....l.l.9.t6.t
Nu-".$oo1n,l; Stgsto*r(.
oMR,A,nswer Sheet No..l.\.69.(.1..
s/ss csl/l4-1AE-IA
-"{"*:.":"il/*
srfrfiqg{dfii{dia
gilqraatii.=arr
wia'fr{diq.
gdEraat*t'tr
fWrraAznat+.
r6retEFItrr
m
h
IeV
amu
Ry
rrf,{rr rdldrdl6
N6
3ilffi:dc?Tr
9.954 v 1g-t2p^-t
4T x 10-7 Hm-a
ata{ihTf{diq'
x Lo-23J /t(
3.0 x 108m/sec
1.38
x1g-trY*z1rn-z
6.67
x 10-3a/ sec
1.6 x 10-1ec
6.63
1.6 x 1o-1eJ
L.67 ;< 10-z7kg
lto
9.11x 10-31kg.
1.097
6.023
x L07m-7
LAz3moIe-7
8.3L4JK-lmole-L
Mass of elecffon
Planck's constant
Charge of electron
Boltzmann constant
Velocity of Light
1.6 x L0-1e;
L.67 x L0-27kg
6.67 x 1g-tt7i1*z1rn-z
Rydberg constant
Avogadro's number
9.954 719-t2p*-t
Fo
m
h
IeV
amu
&
Ne
9.11x 10-31kg
6.63x10-3*J sec
1.6 x 10-1eC
1,.38 x fi-23J /K
3.0
x!08m/sec
x1:}7m-t
6.A22 x !023mole-l
L.097
B.314JK-lmole-L
'
El.nlcnt
Symbol Atomic
Aluminium
Amcricium
Antimony
Argon
Arsrnic
Ast.tinc
Errium
Bcrkrllum
Be ryllium
Bismuth
Eoron
Brominc
Cadmium
Calcium
californium
carbon
cerium
cesium
chlorinc
Al
A rn
Sb
Ar
As
At
Ba
Bk
Be
Bi
B
Br
Cd
Ca
cf
c
ce
cs
cl
chromium cr
::n:,
curium ::
cm
oysprorium Dy
Einstrinium
Erbium
Europium
Fermium
Fluorinc
Francium
Gedotinium
Gallium
Gcrmrnium
Gotd
Hrfnium
Hctium
Hotmium
Hydrogen
tndium
todine
tridium
lron
Krypton
Lanthrnum
Lrwrencium
Lead
Lithium
Lutetium
Magncsium
Manganese
Es
Er
Eu
Fm
F
Fr
cd
Gr
Gc
Au
Hf
Ho
Ho
H
ln
I
lr
Fc
Kr
Lr
Lr
pb
Li
Lu
Mg
Mn
Mendelevium Md
'Brtcd on mils of Cir at
t3
95
gt
i8
33
85
56
9z
4
83'
S
35
48
20
98
6
58
55
17
24
Atomic Element
ii
26.9g
(211)
1Z1.tS
39.948
74.92
(2iO)
132.34
(2491
0.012
208.98
10.8.t
29.909
112.10
40.08
(2s1)
n.011
110.12
112.91
r:fl
Symbol Atomic
Molybdcnum Mo
Neodymlum Nd
lleon
Ne
Neptunium Np
ilickel
Ni
Nlobium
Nb
Nltrogon
N
Nobetium
no
osmium
os
Oxygen
O
p"ttiAirm
pd
phosphorur p
pfatinum
pt
plutonium
pu
poioniurn
po
potassium K
pra""oayrniurn pr
prorn"t iuln
pm
pa
,.Joo,","rn
:1gg n"l-iu_
Ra
Rn
',i
illl
r;;:
e6
ff
,::,1
66
,:-r:r: xil::il
il;il,n
Rb
99
68
63
1oo
9
g7
64
31
32
79
7A
2
67
t
49
53
7t
26
36
57
lO3
gZ
3
71
12
25
101
{2S.t} _-:'-"
Rurhentum
,iird
i51.96 samarium
{2s31 scand'um
ie.od solonium
tzzs,l sllicon
Sitvor
riz.zi Sodlum
69.22
?2.s9 strontium
196.97 sulfur
lZO.49 Tantalum
it.003 Technetium
164.93 Tellurium
t.oo80 Terblum
11a.82 Thallium
ii6.90 Thorium
192.2 Thutium
55.85 Tin
g3.80 Titanium
13g.91 Tungsten
(2S7) Uranlum
207.19 Vanrdium
6.939 Xenon
174.97 Ytterbtum
24.912 Yttrium
54.94 Zinc
(2561 Zirconium
Ru
Sm
sc
Se
si
Ag
t{a
sr
s
Ta
Tc
Te
Tb
Tl
Th
Tm
sn
Ti
W
U
V
Xo
yb
Y
Zn
Zr
42
60
10
93
2E
41
7
102
76
8
46
15
tB
94
84
t9
59
6t
sl
so
86
i:tt
44
62
21
34
14
q
11
38
t6
73
43
52
65
B,l
90
69
50
22
71
92
23
5.1
IO
39
30
40
Atomic
95.94
141.2a
20.18t
dt
{2311
S8.zt
1t
92.9i
(r
,anO,
(2531
tgo.z
15.9994
106.a
30.974
i9S.09
12121
(2rol
19.102
t40.91
(1a71
(2311
(2201
dzzr
lll.3l
2.
05..7
,toi.t
150.35
'l't.96
78.96
2E.09
t0t.E?0
22.9098
87.62
32.064
180.95
(ee I
127.!0
ras.g2
20a.37
232.0a
i68.9t
llE.69
42.90
l8l.85
218.03
50,9{
i31.30
173.0{
88.91
65.3?
91.22
. The ratio of these weights of those on lhe order chemical scale (in which oxygen of
naturll isotopic composition was assignod a mass of 16.0000...) ls 1.000050. (Values ir1 parentheses represent
the mosr
stabls known isotopes.) F
'12.000:..
L'
1.
3.
g-.
5
rmic
4.
!fl!!
0.59
5.9a
a.2a'
1.
183
r37l
1.71
1.9!
c07
53)
0.2
r94
6.a
t71
CN!
f,'K
GI
(d) He
r?l
0l
takes
meals
02
a total of 14 NON.VEG
What is z?
L 18
3. 20
rl
r)
3
1
2.
I
I
5
i
I
I
person sells two objects at Rs.1035/each. On the first object he suffers a lgss
of t0% while on the second he gains
l5%. What
loss/gain
2.24
4. 38
is his net
percentage?
Ja'9
3.
"
6.
3.
50km
35 km
2.
4.
45 km
10
Yi"iik" ffiw
'4
< l%
loss
tbg(
V-o
4. no ross, no gain
WJ.:
A bank offers a scheme *nf,*'ffi,,
made for 1600 days are doubled in value,
the interest being compounded daily. The
interest accrued on a deposit of Rs.l000/over the first 400 days would be Rs.
1.
3.
2.a
v.o
91
7'l
1l
1. L
3.N
days
09
1.
3.
km
2.
4.
250
148
183
190
2.
3.
4.
shell
y9
7.
1.
2.
3.
4.
t%,"
v
,.#, v :fu
FF
6
B.
of the following
portion becomes
sequence?
2&&1,.9
l.
3.
9.
11.,8, 15,
13
t9
"o*r[.,
l. min
3. Z:6min
13.
1. 32
2.
4.
3. 25
10.
17.
10...
2.
4.
t2
t7
f;. n
64
100
2.
4.
2 min
4 min
18.
1. l:i
3. l:3
It.
2.
4.
I:2
l:4
1.
2.
-3.
4.
14.
1.2n2.n
3. t
(250r
300
751
?50
(1s0r
';og
150
5or
(10or
100
sot
15.
4.
20
n2+n
3J-4Lry&,4t,-,-,-
50
12.
400
l.
19.
(l +rf
150
3.
apambola
of a circle
a shaight line
a hlperbola
the arc
20a0
2002
l.
3.
2.
4.
2001
2003
16.
2.
4.
59,77,100
43,47,53
64,91, 100
55,99, 113
l.
3.
2.
4.
936
t872
4
I
1148
2574
::
i;
.t
;t
t
t
,.r\
ry
,71
.&
,/
flt
The
tare_
18.
The
weights (in'kg)
below:
of
13 persons are
given -L l;*}fi;;
4.
Mg2*and 02-
92,94
conjugation in
(a) heme" (b)
macrocyclic rings of
kg
coenzyme Brz and (c) chlorophyll
average
follows the order
by
2. (a) > (b) > (c)
(c) > (b)
2. I ke
-{<^l>
3. (c) > (a) > (b) 4' (b) * (a) > (c)
4. 1.8 kg
l. 0 ke
3. 1.6 kg
19.
I
n
if
n(n+t)Q*2)(n+3)(n+4){n+5)(n+6)
is divisible by
3 butnotT
3 and7
Tbutnot3
neither 3 nor 7
l.
2.
3.
4.
2.
4.
l. 3000
3. 55s0
25.
27.
HrSbFr + ZFz
HSbFz+3Fz
5bS9
{ L}(T
2.
4.
Hgtt
Oz
l.
2
3.
4.
3. SbF3+ll2+2F2
,-t 4. tsbF6l- [HzF]*
'
r. ngt
3 Clz
--1
PART '81
1.
f-c
lo
?
28. Thc
3.
4.
T-shaped [Rh(HXPPhr)Cl]*
Trigc'nal-planar [Rh(HXPPh3)2]
.E
2. 4and4
4. 6 and2
1. 6rtd6
*y'+*s
?L
In the
35.
tPtcLI2- + Noz-
Ni(coL
+ Fphr
3 ryi1co)3ephil +
3.
4.
ofpropene,
CO and Hz in the presence of Coz(CO)s
as a catalyst is
butanoic acid
oou oo$
1
,",{ \'i'
tlv
?\-/ /
are
tAandl
l.
3. 1 and 0
respcctively,
d'/
3t2 ando
are
33.
34.
l.
2.
-(
D3l and
Da6
41.
8.
l.
*-r3.
B
C
l.
39.
ot
2.
4.
3.
Trigonal-planar [Rh(PPh3)2Cl]2*
aqid-
l. 2,3 and3,3
,y 3,3 and2,3
3. 3,3 and,2,2
4. 2,4 and3,2
and C4
T -shaped [Rh(PPhr)zCl]
histitline amino
of
of
38.
cis-[PtCl2(N Oz)212-
t$ly
\
3.
* ,)A
2. %and} "J"*"
4.
-+ e I3 s
rrans-[PtClz(No)O{Hr)]cis-[PtCl2(NOt(NH3)1frans-[PtClz(NH:)z]
The number
36.
l.
2 butanal 7
3. 2-butanone
4{}.
compound B is
l.
2
CO
depcrds on
-"t
following reaction
\-2.
4.
oh
.rn
antiarornatic is
fi
Upo
ilt
bo":
*@
-ru.
*t\1
'
5\o.
tv
t7
41
v'-
ftofu \
o
2,
4.
1. I
3. III
IV
M*#,1
of the
The increasing order of pKa values
circled hydrogens in the following
compounds is
o
Me
40.
@*\
@*'"*
oA*j
BFi l*
H2N-"\NH2
Me
I
I<II<III
1.
c
41.
N<I<III
J.
d:
d
uAHl >fu_-+.t
>t,,-'L
t're
II
+@
4*,u,
3. 3R,6R
eFi ile
2.
4.
%2%
T<III<II
II<III<I
&)*.&
3.
4.
O
tv
45.
2. NaH/DMF
3. H3O+
reaction is
4.
cH20H
O
45.
CHTOMC
0
cHo
chiral
43. The absolute configurations of the
centres of starting ketone in the following
HO
(,
,,
t-lJ
4.
35,6R
lll
1. I>II>III>IV
2 IV>I>II>III
3: III>II>I>IV
4. IV>III>II>I
3.
35,6L
4.
44
o5
2.
?cH2ocH3
/\
\
HsC- -)
1' soc-BuLi
2.coz >
H3o+
3'
n{o
) hlo
f e.-
F
F
F
F:
I&
E
10
t.
OCH2OCH3
2.
OCH2OCH3
I
?
J.
4.
,.,.A"*,. ,..4
c,ooH
4''"':D
9CH2OCH3
,..dtt"
47.
ocH2ocHs
3.
cooH
0'*^^
48.
51.
cooH
h^^
,,,
53.
it
ia
s
s
l.
2
3.
4.
s
e
F
,i;
!,l
:i
i:
;'
L--o
4 4Yo'
o
Fra-____-- Fz.
CO
w7)
2.
4.
t25.4
2t0.2
l:4:6:4:l
1:3:3:l
l:6:15:20:15:6:l
l:3:6:7:6:3:I
$r:
h
i.ii
l.
2
3.
4.
The cyclic product(s) of the following
2. 01
-------+
l. t4t.2
3. 4s.0
52.
49.
-O
l=>o
1M*,ZZZ1
t.*@r,'
reaction is
V-s',-
.f
/-o
Diethylphthalate
a)^
i./
..
*s:
'50.
l.
3.
only2,6dimethylcyclohexanol
a:.
itli
onlycis-1,2_dimethylcyclopentane
only trans-I,2-dimethylcyclopentane
a mixture of cis- andirais-L,Zdimethylcyclop entanes
shikimic acid
mevalonic acid
chorismic acid
cinnamic acid
r*l$\3*
,+-
nt' -D
xla
s
&4
t,n
-. llg
g9
*s
11
54.
:ane
58,
..cooH
lH
nrN\N
anula
in IR
rd 22
lrrect
"- cooMe
\pn
Speed
l.
2.
l.
2.
3.
4.
'.31
4.
55.
IC
)o
2.
3.
4.
59.
spectroscopy.
Sna+(aq)
Snz+ (aq)
nonzero,
spectrurn
the
is
will show
.{ n2 /(BmLz)
3. h2 /(32mLz)
A,A %L
2.
4.
/(BmLz)
h2 /(ZmLz)
h2
2e + Snz+(aq), Eo = *0.15 V
2e -+ Sn(s), Eo = -0.14 V
l.
3.
rotational-vibrational
l. PandRbranchesonly.
2. P and Q branches only.
3. Q and R branches only.'
4. all the P, Q and R branches.
*
*
60.
2.
4.
H2
+__ $
HH
ttl
$-q--
s-
1.
3. pt/?
2.
p2
4.
p'1,
:T 't4
61.
(enJ,
66.
-ih*
momentum
l.
3.
operator
form expliAt].
(tl=#'u)
4 !d*-7ao
yytr
3. ydx - xdy
67.
ofA
r. o,t
i, tf,,+t,t:,...
.(4.
2. dx -zrdl
xdy
Tt
3.
l.
f-T-srt
2 -(#),
3 (#),
z-
, (H,
, JH\
2.
4.
32 eV
52 eV
42eV
62 eY
r. 39
3.r
2.3
4. 87
For an
enzyme-substrate reaction,
4. o,;,:,:,...
between
i *d fr
Z. l1-a Lmol-ls-l
3. 1gz 1^o1-tr-t
4. 19+ 1^o1-tt-t
68.
a plot
fields a slope of 40 s.
l.
2.
4.
A+B+AB
AB*C+D
d({.
\s.t
Fnq
$9
ts
,C,)
If
69.
l.
2.
3.
4.
*K
at8$""b)
$h'
13
l.
70.
r. 7.0
2.
4.
3. 5.6
2.
8.4
9.6
3.
4.
71.
76.
Column
I.
anhydrase
Plso
(f) oxygentransport
The correct answer is
I - (0 ; tl - (c]; ItI
75.
2.
1.54
4.
2.54
2.
4.
rhree
Two
Four
binding
,,-{
$2
3.
f 4.
One
peptidase A
l.
2
3.
4.
,.?.
to HzCOt
IV.Carboxy-
AES) is
argon
carbon dioxide
nitrous oxide
hydrogen
VJ/
l. 1.05
3. 2.05
Column B
t
II. Carbonic c
l. A,BandC
2. B,CandD
3. A,CandD
4. A,BandD
73.
tg
deoxyhemoglobin and
deoxymyoglobin, the binding curve and
its pH dependence, respedively,ary
77.
(d);
Iv-
(a)
1q5-c5H5;Fe(co)2Br and
(rlt- ctgtFe(co)zH
2
ry4-Csutre(Co)28r2 and
(ry4-
3.
4.
crHtFe(co)2HBr
ry'.-'
"4,r::t-s,
rCto
18.
l.
2.
,-{
4.
79.
r-
tMn(cQ)11Krlt-CrHr)Mo(Co)31-
r ")''<"" -)''+'+
ttrq(coxpphr)zl
[(ryt-CrHr)zR.eH]
l.
2
4.
Ph2.
tfr
(Ph:sio).(r
=t,t
or
").,<0i.,(rn'.0
Ph-.- ,ro[
_-Si---oHand (ph2sio)o(n=3,4,oro )
Ph-
,t/
4. ::>''<,, and,>.,<)',<:
3.7.2
80.
-ao..
t^'
are
i.
B.
disallowed
o"rri i""
state {
u;r*;
selection rule
preserice of2T2r.eiorld 5tate
charge transfer transition
The correct answer
A and
nand
C.
D.
51.
,.
adoPts
Stgso -
- structure
nido structure
tf,,rorr
t n{,"
is
84. The final product in the reaction of
2.
C
B
[Cp*zThIi] with CO in an equimolar ratio is
"{3. BandC
CandD
f4.
,
1.
cP*rrh-oa
81. The reaction of phosphorus trichloride
\crr:-rhcp*r
with phenyllithium in 1:3 molar ratio
yields product
2.
cp*2Th-s-
\)-:rtcp'1
respectively, &re
4.
82.
tPPh4lcl,ipfrrp:cnzll,
The reaction
tPh;P(Bu)lLi 4'
betweendiphenyltlichloro-
silaneandwater
inl:Zmolarratiogives
\cH'-Q'-1trsor'
'-'\
"o.rrr(l
/"69
-*1ru51*"'Llt5;y(
l*qY'tt.]I::"
85.
Hindered
r-4l
is an
whereas
reaction,
overall second order
that of [Co(CN)6]3- is of first order' The
rates depend in both cases solely on the
concentiations of the cobalt complex'
2
3.
4.
91.
ico(cN)ul'
B. S*'.u mechanism in the case of
g7.
-Y't
88.
AandB
AandC
92. ComPlexes
AandD
2.
4.
BcHr
BsHs
.-{
2
3.
4.
XeFa,
NNOz
NNOI
2.
3.
4.
I.h
ether
hYdroPhobicitY of crown ether
and FzO
t'lI -)
(o*
Sr
Tt,
fA
HM(CO)5 and
I 8-electron
[(ryt-CrHtM'(CO)3]2 obey ttre
iule. Identify M and M' and their 'H NMR
chemical shifts relative to TMS'
B onlY
to
A borane (X) is reacted with ammoniailB
;il;iloruotonYaride (Y)' The
Nft{n spectrum of Y consists of a triplet
and a quintet. The borane X is
BrHs
l. BzHt
3.
*ot
\)/
2
3.
4.
[CoCl(NH3)5]2* onlY
C. S*t.u mechanism in the case of
lCo(CN)el3- onlY
D. S*t., mechanism in both the complexes
Corrcct exPlanation(s) iVare
l.
2.
3.
4.
7u{'
_
r,t,^r
,o'*'
|N-+rrr{+rl'
. $!hs't
t\hrr
l{
4d+d .
b^und\nl
GEry,*
16
94.
-$\ (9;
^-&S''1
*i o '-fl
:1
f,'F
9r|
Qn.
F6
2.
95.
a'
A.
Lanthanides
B. Alkaline earths
C. Fatty acids
D. Low molecular
weight peptides
The correct answer is
2.
4.
l. AandB
.{cand D
96.
BandC
AandD
toot>^aoot
TrOH (cet)
2. BHS, THF
6tt
3.
1. Me2C(OMe)2,
3. H3O+
OsrO..,
1. q,
o
2.
\}
OH
3.
"\}
HOo*
4"p
HO
17
The major product fonned in the
transformation is
97.
following
reaction is
9o
Jn{
1.guzBOTf, r:PrzNEt
2' PhcHo
*ulY"Ph
oHo
:ilv
Yfi"/Y-Ph
1. HsO*,
*G{"
o
3.
-H
-H
Me
Me
'r.r{
_"'tr:
Ph
ni.r--zMu
, a$* , ab*
Ph
Me
Yi'"\"
Me
il-rrM"
OHOA
,rA4*-<.i
hv ,
2. NaOH
9HP
*'$ry{
,.
r.
Ph
ueu.,)-HH
ai} 4GC
it
-H
98.
sequence is
is
Br2 (1 equiv)
excess Me2NH_>
oil
hexane, rt.
l.
M?rNr..-,
t*FNMez
MezNa-^
2.
',,tNM2
t-
l=rz\-NMez
Q
4.
NMe2
oPh
/
"'**".
o=P{-oPh
N-=
-XU",
HN-'
-t-O--t
99.
'
rur"o^T
-ttz'I
rtr"olf\.
H-zN,
I
cF3co2H >
.Y\
ol-')7t;\o
s/55 CSI/1+-1AE-?A
"'r*, ""o"V ( ,
3. Y"g*"\:-'l'r6f 4.
#-*n
Z\:-r \
ru"oA/J
rr,reo-)'o-'1
.-4
l.
".rioi
2. Meo'v
Meo"'
2.
(ococF3
',,,ro
0 -=
^ffi#'.'; '+#1*
C+"
18
l.A
2,
ry
A:
l--(
\-/
B:
fr^N.ffi
0T
3.A
f-c{r
R.rctl6
T.
1C
PPlr!
B.
oo
q**.aod+ q-.",
:,
FOO$
Aril
4,A
F*
8:O
OH
rue3sl---\^1u't* aortaglaatral
\:.v,O
smt2 >
A THF,
EtO{
ue.fr_O-
/.,v,Cctr{l .
l.
3.
+'
G&lotl
/,r.@/.]',t
2.
4.
B: t*n)
k,
HrtOr
*--v-Y;,+ff:-^ k*I A:
''
*"4,r
I)
Q*"}-i
2.xo
'oH
8,o
,rHr,.)L*,
Up
",^u,.)L*n
oo,c>--\
(-) oo{
Sillca
A:
3 A:
B;
"{Ci'*
"tei''
MesSi
EocHll
J3''"
o \_1
\-/ "oa
-d Eqcl{--llco,Gi
,t
\-/
t,
I' srN'Y)
oy,rn,
fu"-
!_"n,^_.-\
O"" V,rn,
Silte!
4' A:
't
o=1-l^f
rz\-o
b".
rtl"-.-A
[_j
r Q*n
2.
Br--r
cooEt
\-J
/-\
NC 'H
3. H2O, OH'
4.H*
s/55
CSU14-1AE-28
is
19
ot-
\,u"
'rK\_
l.
tnt-( X
2.
Et
.)
rN
p6s' 11,)-{'t
*sN\--
CI+r
to.u"
G-1t.
6or,r.
A:
ET
\r"
3.
**,ffi--
*JA-_
2.
-N
iorr'lu
iorr,ro
A:
*t)
rsPh
.lv.J rN
rN
3.
*Jti--'-
A:
ET
Coruu
rsft
IH
MsOOc
r\NCcN
/t. A:
tnt)
ffi>"
lll Nc cN
\"L,)--
rn
reaction is
\2
\__//
n+rsPh
\Z^-N
ryF'Et
//
Pns^N1o>-\_1
["vt'
Y
EIO2C
heat
NMe2
reaction sequence is
,. MezN{rPctr
2.
NMe2
Mezl'l
1. ErCOCl, Et3N
2. LDA, THF,.78
OH
3.A
rd-aoMoM
\cj
CN
4. H3O'
5. CH2N2
""^sf*
ocoEt
A
IY
NC
NC
oc, TMSct
fi-y/-oMoM
tus^o
CNCN
)L(cH
a,)
\a-ouou
4. rvrezN{_r[
xooc-rAd
ro{
(-\J
,t.
r-OMOM
ueOOc-Acii
I
Me
Me
and B in the
following
V-nh"**
3q* '
t.TBAF.Mccil,5dc
o o
,r.Ao\t
"'lD
HGd
OH
-+
tl
/.t
io.
PPh3
imkJazole
12,
-+
AcN-
Y- '8,
20
l. A-P;B-R;C-P
2 A-R;B-Q;C-P
3. A-R;B-P;C-Q
4. A-Q;B-R;C-S.
/\
1. Boc-N\_J)-t
CN
.,-4\nf\-o'
*< \_J
3 *flo'
'rI=CF"'
4. "*)ot
NC
Me
etooc.-Jo-,Br
aq. NaoH
------------'-
""Ao\
A
1. Hooc- -cooH
Me
I
Me
2.
1{
Me
PPh3
3. LiAtH4
**A*o,
'Me
H
-OH
Me. /^-+-^
3.
l12.
t't"\--l/
H
.r'",rr-r/o-.--\.
Me
"'M"
Me
Me
-nru
4.
1. Free radical
p
value
+ 2.01
ArO-+Etlin
- 0.99
EtOH
ArCO2Et + aq
NaOI{ in EIOH
ArNH2 +
PhCOClin
B
C
benzene
3.
4.
(n-Bu3sn)2
Y-l
O
BF3'OEt2, hv
and 4-iodomethyloxepan-2-
one
Free radical and 5-iodooxacan-2-one
Carbene and 3-oxabicyclo[S. 1.0]octane2-one
115.
-2.69
+ 0.78
2. DIBAL-H, -
78 to - 40 oC
.14
zt
XlE. The
I
2 eueofS
1xo
following
Me
1.Zn,AcOH
2. PhSeNa
3. n'-CPBA, heat
tVte
ta\
\l//'..
itle
'
2' nuAoAo
Mu\
1. lrie*\gAO
f-\
n*fJ,-n
u rde'{sAc
o ur.--^-\Aor,,,
Hz),6'8 (1H,
J:
8 Hz) PPm;
s), 6.90 {1H, d,
'3cNhrlR, a 146.5, 144.0,131.0, 130.5,
123.0, 119.0, i14.0, 108.0,55.0, 18"0
ppm.
The structure of the eompound is
.z1,Cl'lO
V*"v
1.
2.
leat
Ts
,r\*,\.Me
lt'l
1.
HONY
,r^\r-\
2. ^oP
OMe
lri
l'l.lN-r\
sequence, the
N
I
vx
FOrpt'
.\-1,
ir
i'ule.
. oH
x
,.s.-l
li Y)o
bo
,-_r'\^n-y'
HO.Y
o6trtu
4.
OMe
Ts
Forpt
ffi"oo',
o
1,
2.
3.
4.
r:-V-i
lll
N"
,'\'-M"
ot
'lr--l
t{
,i'lr,.l ,t-C
OMe
ri:-"
-f
3.
il",'le.
ot"
4.
o(yi'
lll\,
1. MeMgBr, Et2O
'.LDA,rHF
Oet
2. |CH2CH2CH2C|
A
2. H3O*
22
o
&:"
'^^&*, 8: ot*
o
2.
_4
A.
hv/k
QYt
4.
l.
2.
3.
J.
r^o
d*
A:
lAlrn/k_
\\^'
B:
limits of
"l-\\*
A:
- lAluz 4.
3.
k_
e-o/r
and,
f,e-en
,_0/zr utd
f,e-elzr
e-elzr {d lue-elT
,-0/2r
und 9 r-e1zr
T
oEr
l.
3.
'
Ttlz
2. T-Llz
T-s(z
4.
T-712
122. Species A
undergoes a unimolecular
reaction as follows:
kr
A+A _
A*{rp
kr.
A++A
lAluz.
when pressure of
^4 is
2.
4.
L/2
[Hint:
2.
4.
e2
e-21e
t'1
3.
constant becomes
l. e
3. L- e-2
2/L
are defined by
Sr=SrtfSy,
c^
gk
commutator [Sr,S*] is
c.
o
6'
{o *"/'
ii
z.
4.
hs_
-h.s_
23
1.
2.
{l]:
A
l3l.
l.
ter.m
3. repulsive term is equal
to the attractive
term
4. the system is independent of both the
;=l-llt'
128. Given
xtdlq*
x2d.1tr=g
(A)
and
x$V1*
x2dV, =
g,
(B)
1.
2. relation A is conec! but B is not.
3. relation B is correct, but A is not.
4. both the relations are incorrect,
except for very dilute solutions.
n29.
rlf
2.
3.
4.
.
2.
3.
4.
EPR spectrum
of a free radical
1. Amr=0, A*r=0
2. Am, = +1, Amr = g
3. Am, = f1, Ams - +1
4. Am, = 0, Am; = +1
t
Do(H)
Do(Hl)
r(H) + r(H2)
to
A2
o
I
cru
Cz
4,,
B1
I
I
I
B"
-I -1
A"
-L
o!.
z,x2,y2,z
Rr, Xll
x,Ru,xz
Rr,lZ
'1 ,
l.
2
7AL+lBL+BB2
gAL+4BL+782
3.7A1+3P|-+782
\-A/ sh + 3h + BBz
134. Thc product o'v.S"+ (.Sf is the four fold
improper axis of rotation around the z axis,
and oxt is the reflection in the xy plane) is
2.
4.
ci.i.
cf
;{a"
24
l.
3.
atoms
2.
4.
6.023 x t027
6.02 x t}2t
of
clean
in
1cm3
3.45 x 1023
3.8 x 1021
3.
4.
function
co4rc(s)
*torfu)
-> 4co2(fi
l.
3.
'/
of
2.
4.
A
't'
1.
2
l4l.
2.
4.
1+krklo
. llsoc(l) 1s6a(1)l
ke[^A]o
rl4l,
L+ktlAlo
ttH;
tDro,tDro.tDro
are
T2
r+kt[Ala
tDro,tDro
EosE <Er
l1s"a(1) 1s6p(1)l
ltsoa(Z) Ls6Be)l
1+t
o<E<Eo
microstates that.
'"
E<
of
144
lLsoc(L) lsop(1)l
ftsoa(Z) ts"Fe)l
a
J'
2.
4.
F>o
E>Er
,r'
r.
will satisfr
l.t6
3.8
tDo
sHzO(r)
1.
3.
(3
N2
energy E, it
electical energy
If
'Dr,'D,tDr,
143.
3D3,3D2,3D1
lLs"u(2) 1s6c(z)l
llsoa(l) lsep(l)l
^" llsoa(l)
1s6p(z)l
oflevelj:gr.)
l. I
3. \i
si
2. So
4. ll|,i
9i
tr
2_J
Il n
/1++84++P
is measured in two different
iln rpj
W
aqueous
and
ionic strengfts 0.01
of
0:04 M. If ,logko-
solutions
l. 1
on B is closest'to
2.2
4.6
3.3
pressrue
2. lrn
3. I
4.2
1. L/2
Rough
\
\\ ts))"\s"L
.\
ors)r
Itfy
(cr\t'' \nt
\- o*\
\ itr"
\
E\/
N\
'o,i
-!f
.*"n
(o
n-4nfn
tt
i\t'Mlr' {:"?7*'^)t^
-\\
s/55CSVI4-|AE-3
,5 /l
rJ$v{r/
I\
]lri)lL,ot
4
n\
^$q
/l
v.r$"