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Alcohol, Phenol and Ethers

No

Questions

Which one is primary alcohol

( )

Butaon-1-ol

( )

Buten-2-ol

( )

2,3-dimethylhexane-4-ol

( )

Propan-2-ol

Ethyl alcohol is industrially prepared from ethylene by


( )

Permanganate oxidation

( )

Absorbing in H2SO4 followed by


hydrolysis

( )

Fermentation

( )

Catalytic reduction

Which of the following cannot be produced by acidic dehydration of


alcohols?
( )

Aldehydes

( )

Alkyl hydrogen sulphate

( )

Ethers

( )

Alkene

Dehydration of glycerol gives


( )

Acrolein

( )

Propene

( )

Propane

( )

Benzene

Maximum number of active hydrogens are present in


( )

Methanol

( )

Methane

( )

Acetic acid

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11

Glycerol

Salol is prepared from


( )

Salicylic acid and phenol

( )

Salicylic acid and methyl alcohol

( )

Both

( )

None

Phenol is heated with CCl4 and alkaline KOH when salicylic acid is
produced. The reaction is known as
( )

Sommelet reaction

( )

Friedel-Craft reaction

( )

Rosenmund's reaction

( )

Reimer-Tiemann's reaction

Ethanol containing one methanol is called


( )

Power alcohol

( )

Rectified spirit

( )

Methylated spirit

( )

Absolute spirit

Mild oxidation of glycerol with H2O2/FeSO4 gives


( )

Glyceraldehyde

( )

Dohyroxy acetone

( )

Glycerose

( )

None

Hydrolytic conversion of sucrose into glucose and fructose is known


as
( )

Insertion

( )

Inhibition

( )

Induction

( )

Inversion

Alcohols of low molecular weight are

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( )

Insoluble in water

( )

Soluble in water

( )

Soluble in water on heating

( )

Insoluble in all solvents

Alcohols react with Grignard's reagent to form


( )

Alkynes

( )

All these

( )

Alkanes

( )

Alkenes

Alcohol fermentation is brought about by the action of


( )

Invertase

( )

O2

( )

Yeast

( )

CO2

Primary and secondary alcohols on action of red hot copper give


( )

Only ketones

( )

Only aldehydes

( )

Aldehydes and ketones respectively

( )

Ketones and aldehydes respectively

Ethyl alcohol on oxidation with K2Cr2O7 gives


( )

Acetic acid

( )

Acetaldehyde

( )

Formic acid

( )

Formaldehyde

The strongest acid among the following aromatic compound is


( )

O-nitrophenol

( )

P-nitrophenol

( )

P-chlorophenol

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M-nitrophenol

Which of the following groups will increase the acidity of phenol?


( )

-NO2

( )

-CN

( )

-X(halogen)

( )

All

Which is used as an antifreeze?


( )

Methanol

( )

Water

( )

Ethyl alcohol

( )

Glycol

Which one of the following compounds gives characteristic deep


colour with FeCl3 solution?
( )

Ethanol

( )

Phenol

( )

Acetone

( )

Acetic acid

C2H5OH can be differentiated from CH3OH by


( )

Reaction with HCl

( )

Iodoform test

( )

Solubility in water

( )

Reaction with NH3

Scientific study of fermentation was first made by


( )

Biot

( )

Pasteur

( )

Buchner

( )

Liebig

Phenol is more readily soluble in


( )

Dil.HCl

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( )

NaOH sol

( )

Both NaOH and HCl

( )

Sodium bicarbonate solution

On heating glycerol with conc.H2SO4, a compound with unpleasant


odour is obtained. The compound is
( )

Glycerol sulphate

( )

Methyl alcohol

( )

Formic acid

( )

Prop-2-enal

Grignard reagent on reaction with ketone forms


( )

Carboxylic acid

( )

Tertiary alcohol

( )

Primary alcohol

( )

Secondary alcohol

Sodium phenoxide reacts with CO2 at 400 K and 4.7 atm pressure to
give
( )

Benzoic acid

( )

Sodium salicylate

( )

Salicyl aldehyde

( )

Catechol

The order of reactivity of halogen acids for reaction with C2H5OH is


( )

HBr>HCl>HI

( )

HI>HBr>HCl

( )

HCl>HBr>HI

( )

HBr>HI>HCl

Which of the following statements is correct?


( )

Phenol is more acidic than ethanol

( )

Phenol is more acidic than CH3COOH

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( )

Phenol is more acidic than carbonic


acid

( )

Phenol is less acidic than ethyl alcohol

Isopropyl alcohol on oxidation gives


( )

Acetaldehyde

( )

Acetone

( )

Ether

( )

Ethylene

Which of the following statements is incorrect?


( )

Alcohol with less number of carbon


atoms is more soluble in water than
alcohol with more number of carbon
atoms

( )

Alcohol produces H2 by reaction with


sodium metal

( )

Ethyl alcohol is heavier than water

( )

Ethyl alcohol evaporates more quickly

Which of the following process is employed to convert alkyl halide


into alcohol?
( )

Dehydrohalogenation

( )

Substitution

( )

Molecular rearrangement

( )

Addition

The boiling point of glycerol is more than propanal beacuse of


( )

Hybridisation

( )

H-bonding

( )

Resonance

( )

All these factors

Zn powder + Ph-OH---------->X. In this reaction the product X will be


( )

Anisole

( )

Phenyl acetate

( )

Benzene

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Benzaldehyde

An organic compound 'X' on treatment with acidified K2Cr2O7 gives a


compound 'Y' which reacts with I2 and sodium carbonate to form
triodomethane. The compound 'X' is
( )

CH3COCH3

( )

CH3CHO

( )

CH3CH(OH)CH3

( )

CH3OH

1-Phenylathanol can be prepared by reaction of benzaldehyde with


( )

Mrthyl iodide and magnesium

( )

C2H5I and Mg

( )

Methyl bromide and AlBr3

( )

Methyl bromide

The reaction of aromatic acyl chloride and phenol in the presence of a


base NaOH or pyridine is called
( )

Kolbe's reaction

( )

Sandmeyer's reaction

( )

Schotten Baumann reaction

( )

Perkin's reaction

Which of the following compound is known as oil of winter green?


( )

Phenyl acetate

( )

Methyl salicylate

( )

Phenyl salicylate

( )

Phenyl benzoate

Ethylene reacts with 1% cold alkaline KMnO4 to give


( )

Oxalic acid

( )

Acetone

( )

Ethylene glycol

( )

Formaldehyde

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38

Phenol gives _________ colour with neutral FeCl3 solution.

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41

42

Which of the following will not give iodoform test?


( )

Ethanal

( )

Benzyl alcohol

( )

Isopropyl alcohol

( )

Ethanol

Which of the following is the most suitable method for removing the
traces of water from ethanol?
( )

Reacting with Mg

( )

Distilling it

( )

Reacting with Na metal

( )

Passing dry HCl through it

Na reacts with phenol to produce


( )

CO gas

( )

Benzene

( )

H2 gas

( )

CO2 gas

2,4,6-trinitrophenol is known as

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Propanone is the product obtained by dehydrogenation of


( )

Propanethoil

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48

( )

1-propanol

( )

2-propanol

( )

Isobutyl alcohol

When ethylene glycol is heated with acidified potassium


permanganate, the main organic compound obtained is
( )

Formic acid

( )

Oxalic acid

( )

Glyoxal

( )

Ethanol

Which of the following compound is obtained on passing ethanol


vapours on heated Al2O3?
( )

Ethylether

( )

Acetone

( )

Ethanol

( )

Ethane

Which of the following is correct?


( )

Sucrose on reaction with NaCl gives


invert sugar

( )

Reaction of vegetable oil with H2SO4


gives glycerine

( )

Reduction of any aldehyde gives


secondary alcohol

( )

Alcoholic iodine with NaOH gives


iodoform

A compound of formula C4H10O reacts with sodium and undergoes


oxidation to give a carbonyl compound wich does not reduce Tollen's
reagent, the original compound is
( )

Diethyl ether

( )

N-butyl alcohol

( )

Sec-butyl alcohol

( )

Isobutyl alcohol

A compound is soluble in conc.H2SO4, it does not decolourise


bromine in carbon tetrachloride but is oxidized by chromic anhydride
in aqueous sulphuric acid within two seconds, turning orange solution

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to blue, green and then opaque. The orignal compound is

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( )

Primary alcohol

( )

Tertiary alcohol

( )

Alkene

( )

Ether

3 moles of ethanol react with one mole of phosphorus tribromide to


form 3 moles of bromoethane and one mole of X. Which of the
following is X?
( )

H3PO2

( )

HPO3

( )

H3PO3

( )

H3PO4

An organic compound A reacts with methyl magnesium iodide to form


an addition product which on hydrolysis forms the compound B.
Compound B gives blue colour salt in Victor Meyer's test. The
compound A and B are respectively
( )

Acetaldehyde, ethyl alcohol

( )

Acetone, isopropyl alcohol

( )

Acetaldehyde, tertiary butyl alcohol

( )

Acetaldehyde, isopropyl alcohol

Organic acid without a carboxylic acid group is


( )

Ascorbic acid

( )

Picric acid

( )

Oxalic acid

( )

Vinegar

During dehydration of alcohols to alkenes by heating with


conc.H2SO4, the initial step is
( )

Protonation of alcohol molecule

( )

Elimination of water

( )

Formation of carbocation

( )

Formation of an ester

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Which is more acidic?


( )

P-nitrophenol

( )

Phenol

( )

M-cresol

( )

O-cresol

The only alcohol that can be prepared by indirect hydration of alkene


is
( )

Isobutyl alcohol

( )

Propyl alcohol

( )

Ethyl alcohol

( )

Methyl alcohol

When alcohol reacts with conc.H2SO4 intermediate compound formed


is
( )

Carbonium ion

( )

Alkoxy ion

( )

Alkyl hydrogen sulphate

( )

None of these

Carbolic acid is

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57

Williamson's synthesis is used to prepare

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58

When phenol is distilled with zinc dust, it is reduced to


( )

Benzaldehyde

( )

Hexanol

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63

( )

Toluene

( )

Benzene

Which one is used as a fuel for internal combustion engines in many


european countries?
( )

CH3COOH

( )

C2H2

( )

CH3OH

( )

C2H5OH

Which one of the following immediately reacts with conc.HCl in the


presence of ZnCl2?
( )

Ether

( )

Secondary alcohol

( )

Tertiary alcohol

( )

Primary alcohol

The reaction of sodium with ethanol gives


( )

H2

( )

H2O

( )

CH3OH

( )

NaH

Which of the following is an isomer of ethanol?


( )

CH3OH

( )

CH3OCH3

( )

C2H5OC2H5

( )

C2H5OH

Industrial alcohol may be denatured by the addition of


( )

Any of these

( )

Pyridine

( )

Acetone

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Methyl alcohol

Rectified spirit contains alcohol about


( )

85%

( )

95%

( )

80%

( )

90%

Ethanol can be converted into ethanoic acid by


( )

Hydration

( )

Fermentation

( )

Hydrogenation

( )

Oxidation

Which compound is more soluble in water?


( )

N-hexanol

( )

C2H5OH

( )

C6H5OH

( )

CH3OCH3

Which compound shows H-bonding?


( )

C2H6

( )

C2H5OH

( )

C2H5Cl

( )

CH3-O-CH3

Which of the following is produced when an aqueous solution of


butan-2-ol is refluxed with dil acidified KMnO4?
( )

Butanone

( )

Butanoic acid

( )

Butanol

( )

Butane

Which of the following will not react with sodium metal to release
hydrogen?

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( )

C6H5OH

( )

C6H5CH2OH

( )

CH3CH2OH

( )

CH3CH2CH3

Which one of the following correctly describe the acid properties of


phenol?
( )

Stronger than carboxylic acid

( )

Stronger than HCl

( )

An acid stronger than carbonic acid

( )

Weaker than carboxylic acid

Which of the following is weakly acidic in nature?


( )

Alcohol

( )

Phenol

( )

Amide

( )

Aldehyde

Dow's process is used for preparation of

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73

Oxidation of 2-propanol gives

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74

Ethyl alcohol may be identified by


( )

Ring test

( )

Iodoform test

( )

Bazeyer's test

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75

Tollen's test

Glucose in presence of zymase is converted into

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76

The malt-sugar in presence of yeast or invertase gives

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77

Oxidation of methyl alcohol gives

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79

80

Methyl alcohol possesses


( )

Burning taste

( )

Poisonous

( )

Causing blindness

( )

All these

Which of the following is known as wood spirit?


( )

Propyl alcohol

( )

Ethyl alcohol

( )

Butyl alcohol

( )

Methyl alcohol

Which of the following is used as anesthetics?


( )

Alcohol

( )

Diethyl ether

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82

( )

Phenol

( )

Dimethyl ether

Nitration of phenol gives


( )

O-nitrophenol

( )

P-nitrophenol

( )

M-nitrophenol

( )

Both o and p-nitrophenol

Alcohol reacts with halogen acid to produce

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85

86

When phenol is reduced in Zn dust, we get


( )

Cyclohexane

( )

Benzyne

( )

Benzene

( )

Cyclohexene

According to lewis concept, ethers behave as


( )

Acid

( )

Base

( )

Acid as well as a base

( )

None

Methyl alcohol is not used


( )

For denaturing of ethyl alcohol

( )

As an anti-freezing agent

( )

As a solvent

( )

As a substitute for petrol

Which compound is called universal solvent?


( )

H2O

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91

( )

C2H5OH

( )

CH3-O-CH3

( )

CH3OH

Which enzyme is not involved in fermentation of starch?


( )

Zymase

( )

Urease

( )

Invertase

( )

Diastase

Ethanol can be converted into ethanoic acid by


( )

Fermentation

( )

Hydration

( )

Hydrogenation

( )

Oxidation

Which compound will not dissolve in water?


( )

C2H5OH

( )

CH3CH2CH2OH

( )

CH3OH

( )

C6H6

Which compound is more soluble in water?


( )

CH3OCH3

( )

C2H5OH

( )

Benzene

( )

Hexane

Which compound does not show hydrogen bonding with water?


( )

C6H5OH

( )

CH3OH

( )

C2H5OH

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93

94

CH3-O-CH3

Which compound shows hydrogen bonding?


( )

CH3-O-CH3

( )

C2H6

( )

C2H5Cl

( )

C2H5OH

Diethyl ether is obtained by Williamson's synthesis using


( )

Ethanol + Na + C2H5Br

( )

Methanol + Mg + CH3Br

( )

Methanol + Na + CH3Br

( )

Ethanol + Mg + C2H5Br

IUPAC name of diethyl ether is

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96

97

Methanol and ethanol can be distinguished by


( )

Lucas test

( )

Dichromate/H2SO4 oxidation test

( )

Flame test

( )

Iodoform test

The test used for the detection of ethanol in the mouth of a drunk
driver is that the drunk driver is asked to blow air into a solution of
K2Cr2O7 and H2SO4. The colour changes, if the driver is drunk
( )

From orange to green

( )

From pink to green

( )

From pink to colourless

( )

From orange to colourless

When sodium metal reacts with alcohols


( )

Hydrogen gas is evolved

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100

101

102

( )

Alcohol is reduced

( )

Sodium hydroxide is obtained

( )

Alcohol is polymerized

The boiling points of alcohols are higher than corresponding alkanes.


This is because
( )

Alkanes are dipolar compounds

( )

Alcohols are sweet in taste

( )

Alcohols are soluble in water

( )

Of H-bonding in between molecules of


alcohol

Which is not the common name of an isomeric alcohol with formula


C4H10O
( )

1-butanol

( )

Ter-butyl alcohol

( )

Sec-butyl alcohol

( )

Isobutyl alcohol

Alcohols, phenol and ethers may be considered as derivatives of


( )

Benzene

( )

Hydrocarbons

( )

Water

( )

Carboxylic acids

Formula of secondary alcohol is


( )

R-OH

( )

R3COH

( )

R2CHOH

( )

R-CH2OH

Methyl alcohol on oxidation with acidified K2Cr2O7 gives


( )

CH3CHO

( )

CH3COCH3

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104

105

( )

CH3COOH

( )

HCOOH

An alcohol produced in the manufacture od soap is


( )

Ethylene glycol

( )

Ethanol

( )

Butanol

( )

Glycerol

Haloform reaction is used to prepare


( )

CHCl3

( )

CCl4

( )

Halogens

( )

Halides

Ethylidene chloride (CH2CCl2) on hydrolysis with NaOH gives

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107

108

Action of nitrous acid on ethyl amine gives


( )

C2H6

( )

C2H5OH

( )

NH3

( )

Nitromethane

Iodoform can not be prepared from


( )

CH3COCH3

( )

CH3OH

( )

CH3CHO

( )

C2H5OH

When glycerol is heated with KHSO4, the compound formed is


( )

Gluconic acid

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110

111

112

113

( )

Dihydroxy acetone

( )

Glyceraldehyde

( )

Acrolein

Which one of the following is not a phenol?


( )

M-cresol

( )

O-cresol

( )

Benzyl alcohol

( )

P-cresol

Which of the following does not give effervescence with Na2CO3?


( )

Picric acid

( )

Benzoic acid

( )

Benzene sulphonic acid

( )

Phenol

Which one of the following is more acidic?


( )

H2O

( )

CH3CH2CH2OH

( )

C2H5OH

( )

CH3OH

Phenol can be distinguished from ethyl alcohol by all reagent except


( )

FeCl3

( )

Na

( )

Br2/H2O

( )

NaOH

Which one of the following is not soluble in H2SO4?


( )

C4H10

( )

H2O

( )

Ether

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114

C2H5OH

Bond angle in ether is

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116

117

118

119

Ether have boiling point higher than alkanes but lower than alcohol
because
( )

Ethers possess H-bonds and are polar

( )

Neither they have H-bonds nor are


polar

( )

Ethers do not possess H-bonds and


are non polar

( )

Ethers are polar but do not have Hbonds

Water gas in presence of excess of H2 at 450C, 200 atm pressure


and in the presence of ZnO + Cr2O3 catalyst gives
( )

Methanal

( )

Carbonic acid

( )

Methanol

( )

Ethanol

Alcohol of 50 "proof" is
( )

100% pure

( )

70% pure

( )

50% pure

( )

80% pure

Which one of the following undergoes dehydration with ease?


( )

CH3-OH

( )

C2H5OH

( )

Ter.butyl alcohol

( )

Isopropyl alcohol

Which of the following is more reactive towards sodium metal?

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122

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124

( )

Primary alcohol

( )

Tertiary alcohol

( )

Ether

( )

Secondary alcohol

Which one of the following is more soluble in water?


( )

Butanol

( )

Heptanol

( )

Methanol

( )

Hexanol

Which of the following undergoes estrification with ease?


( )

Ter.butyl alcohol

( )

C2H5OH

( )

Isopropyl alcohol

( )

Ter.pentyl alcohol

The reagent used to distinguish primary, secondary and tertiary


alcohols is
( )

Nessseler's reagent

( )

Baeyer's reagent

( )

Tollen's reagent

( )

Lucas reagent

Which one of the following compounds does not liberate CO2 in


reaction with Na2CO3?
( )

H2SO4

( )

Phenol

( )

HNO3(dil)

( )

HCl (dil)

The most acidic among the following is


( )

Methanol

( )

Ether

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125

126

127

128

129

130

( )

Acetylene

( )

Phenol

The alcohol which resists oxidation is


( )

Methanol

( )

Ethanol

( )

Isopropyl alcohol

( )

Ter.butyl alcohol

The least reactive compound among the following is


( )

H-CO-H

( )

CH3-O-CH3

( )

CH3COOH

( )

CH3OH

Detol is a very effective antiseptic. It is a derivate of


( )

Ether

( )

Alcohol

( )

Ketone

( )

Phenol

The compound which does not form iodoform


( )

Acetone

( )

Methyl alcohol

( )

Ethyl alcohol

( )

Acetaldehyde

In estrification, which bond of alcohol undergoes cleavage?


( )

C-H

( )

C-O

( )

O-H

( )

C-C

Which of the following does not undergo dehydration reaction?

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131

( )

Propanol

( )

Ethanol

( )

Butanol

( )

Methanol

Methylated spirit is ethyl alcohol to which _____% methanol has been


added.
( )

50

( )

10

( )

20

( )

70

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