Semiconductors
Pure semiconductors are relatively good insulators as
compared with metals, though not nearly as good as a true
insulator like glass. To be useful in semiconductor applications,
the intrinsic semiconductor (pure undoped semiconductor) must
have no more than one impurity atom in 10 billion semiconductor
atoms.
Figure 4(a) shows four electrons in the valence shell of a
semiconductor forming covalent bonds to four other atoms. All
electrons of an atom are tied up in four covalent bonds, pairs of
shared electrons. Electrons are not free to move about the crystal
lattice. Thus, intrinsic, pure, semiconductors are relatively good
insulators as compared to metals.
Thermal energy may occasionally free an electron from the
crystal lattice as in Figure 4(b). This electron is free for conduction
about the crystal lattice. When the electron was freed, it left an
remains constant because all the electrons of the donor level are
now in the conduction band. This is called donor exhaustion
zone. Beyond this zone, increase in conductivity with rise in
temperature occurs entirely due to intrinsic conductivity.
p-type Semiconductor: As temperature increases, the
number of electrons jumping from the valence band to the
acceptor level increases and thus the conductivity increases, this
rise in conductivity with temperature takes place only up to a
particular level till all the acceptor atoms receive electrons from
the valence band and reach the acceptor saturation zone. In this
temperature zone, the conductivity remains constant since the
accepter level is now completely filled or maximum numbers of
holes have already been formed in the valence band. This is
called acceptor exhaustion zone. Thereafter, the intrinsic
conductivity becomes predominant on further rise in temperature.
Figure 5 indicates the basic idea. The solid black lines show a
specific trajectory of a charge carrier in the absence of any
external force. It proceeds with some constant velocity in some
direction until it experiences a thermal collision. The red dashed
lines indicate how each of these trajectories would be influenced
by a constant external force F: The particle now accelerates in the
direction of F consistent with its initial conditions dictated by the
last collision. When these paths are assembled, we see that F has
caused a net displacement x after the four collisions; the particle
has begun to drift in the direction of F.
For macroscopic quantities, only averages over all particles
are of interest. With the above assumptions, one can obtain an
equation of motion for the average momentum P, given by
dP P
+ =F
dt
J=
q n
E E
m
or E= J
m
q2 n
Fig. 6: Hall Effect geometry again; the strip has a thickness , length l,
and height h.
q
(JB)
m
With the setup shown in Fig. 6 steady current can only flow
in the x direction J=J x^ , while B=B z^ . Performing the cross
product and resolving into components gives
Ex =J
and
Ey =
q
JB
m
Along with Ohms law describing current flow along the strip,
we now have a component to the electric field in the transverse
direction proportional to J and B. The Hall Coefficient (or
Constant) RH is officially defined as this proportionality constant:
Ey = R H JB
1
nq
RH
IB
Hall Effect
Experiment
Procedure:
1. Switch 'ON' the Hall Effect set-up and adjustment current (say
few mA).
Record:
Sample : p-type Germanium
Residual magnetic field =90 gauss
Set magnetic field =3090 gauss
Probe current = 4 mA
Room Temp = 17C
Observation Table :
Graph: