1

Professor Manfred Bochmann Publications 1976 - 2000

Sterically Hindered Iminophosphorane Complexes of Vanadium, Iron, Cobalt and Nickel: A
Synthetic, Structural and Catalytic Study.
S. Al-Benna, M. J. Sarsfield, M. Thornton-Pett, D. L. Ormsby, P. J. Maddox, P. Brs, and M.
Bochmann, J. Chem. Soc., Dalton Trans. 2000, 4247 4257.
Synthetic, Reactivity and Structural Studies on Borylcyclopentadienyl Complexes of Titanium: New
CpB Titanocene Complexes with C-B-Cl, C-B-O and C-B-N bridges [CpB = 5-C5H4B(C6F5)2].
S. J. Lancaster, S. Al-Benna, M. Thornton-Pett and M. Bochmann, Organometallics 2000, 19, 1599
1608.
Borate, Boryl and Borole Compounds and Their Role in Olefin Polymerisation Catalysis.
M. Bochmann, S.J. Lancaster, G. Jimnez Pindado, D.A. Walker, S. Al-Benna and M. ThorntonPett, in: Contemporary Boron Chemistry, M.G. Davidson, A.K. Hughes, T.B. Marder and K. Wade
(eds.), Royal Society of Chemistry, London, 2000, p. 10 - 19.
Synthesis and reactivity of sterically hindered iminopyrrolato complexes of zirconium, iron, cobalt
and nickel.
D.M. Dawson, D.A. Walker, M. Thornton-Pett and M. Bochmann, J. Chem. Soc., Dalton Trans.
2000, 459-466.
Synthesis, Fluxionality and Propene Insertion Reactions of Zirconium Boryldiene Complexes with
Sterically Undemanding Cp Ligands.
M.M. Corradi, G. Jimenez Pindado, M.J. Sarsfield, M. Thornton-Pett and M. Bochmann,
Organometallics 2000, 19, 1150 - 1159.
F.A. Cotton, G. Wilkinson, C. Murillo and M. Bochmann, Advanced Inorganic Chemistry, 6th
edition. J. Wiley & Sons, New York, 1999.
Half-sandwich complexes of titanium and zirconium with pendant phenyl substituents. The
influence of ansa-aryl coordination on the polymerisation activity of half-sandwich catalysts.
J. Samannshausen, A.K. Powell, C.E. Anson, S. Wocadlo and M. Bochmann, J. Organomet.
Chem.1999, 592, 84 - 94.
Facile Formation of a Titanium-Carbon Bond from TiCl4 by HCl Elimination: The Synthesis and
Structure of TiCl3[Me3SiNP(Ph)2CHCH2P(Ph)2NSiMe3].
M.J. Sarsfield, M. Thornton-Pett and M. Bochmann, J. Chem. Soc., Dalton Trans. 1999, 3329 3330.
New Weakly Coordinating Counteranions for High Activity Polymerisation Catalysts: [(C6F5)3BCN-B(C6F5)3] and [Ni{CNB(C6F5)3}4]2-.
S.J. Lancaster, D.A. Walker, M. Thornton-Pett and M. Bochmann, Chem. Commun. 1999, 1533
1534.
New Ligands for Transition Metal Complexes. M. Bochmann, GB Appl. No.9902697.3 (with BP
Chemicals Ltd., 9.2.1999). (P=N ligands)
WO 00 47 592 (17. 8. 00, filing date 22.12.99, priority date 9.2.99).
EP 1 150 989 B1 (filed 22.12.1999, published 5.2.2003).

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Reaction of B(C6F5)3 with zirconium and hafnium half-sandwich benzyl complexes. The crystal
and molecular structures of CpZr(C6F5){4CH2CMeCHCHB(C6F5)2} and [CpHf(2,3Me2C4H4)(OEt2)][PhCH2B(C6F5)3][Cp = 1,3-C5H3(SiMe3)2]
G. Jimnez Pindado, M. Thornton-Pett, M. B. Hursthouse, S. J. Coles and M. Bochmann, J. Chem.
Soc., Dalton Trans. 1999, 1663 1668.
Cationic Zirconocene Hydrides: A New Type of Highly Effective Initiators for carbocationic
Polymerizations.
A.G. Carr, D.M. Dawson, M. Thornton-Pett and M. Bochmann, Organometallics 1999, 18, 2933
2935.
Process for the Preparation of Polyisoolefins via New Initiator Systems of the Metallocene Type.
G. Langstein, M. Bochmann, D. Dawson, A.G. Carr and R. Commander, DE 19836663.9 (13.8.98)
(German Patent appl.).
Heterogenised MAO-free Metallocene Catalysts
S.J. Lancaster, S. OHara and M. Bochmann, in: Metalorganic Catalysts for Synthesis and
Polymerization, ed. W. Kaminsky, Springer Verlag, Berlin 1999, p. 413 425.
The Versatile Chemistry of Metallocene Polymerisation Catalysts: New Developments in HalfSandwich Complexes and Catalyst Heterogenisation.
M. Bochmann, G. Jimnez Pindado and S.J. Lancaster, J. Mol. Catal. A, 1999, 146, 181 192
(conference proceedings).
Cationic Zirconocene Complexes with Benzyl and -Si(SiMe3)3 Substituted Cyclopentadienyl
Ligands.
M. Bochmann, M.L.H. Green, A.K. Powell, J. Samannshausen and M.U. Triller, J. Chem. Soc.,
Dalton Trans. 1999, 43 - 49.
Highly Electrophilic Metallocenes and Their Role in Alkene Polymerizations.
M. Bochmann, Topics in Catalysis 1999, 7, 9 - 22 (invited review).
New Horizons in Olefin Polymerisation Catalysis.
M. Bochmann, International Plastics 1998, issue 1, p. 23 - 26 (Editorial).
The Reaction of AlR3 with [CPh3][B(C6F5)4]: Facile Degradation of [B(C6F5)4] by Transient
"[AlR2]+".
M. Bochmann and M.J. Sarsfield, Organometallics 1998, 17, 5908 5912.
Borato-Cyclopentadienyl Half-Sandwich Complexes. The Crystal Structures of
[NEt4][C5H5B(C6F5)3]CH2Cl2 and [NEt4]2[{C5H4B(C6F5)3}Zr(-Cl)Cl2]2
S. J. Lancaster, M. Thornton-Pett, D. M. Dawson and M. Bochmann, Organometallics 1998, 31,
3829 - 3831.
Construction of a Borole Ligand from Coordinated Diene and B(C6F5)3 via Successive CH
Activation Steps: A Case of Catalyst Self-Activation. G. Jimnez Pindado, S. J. Lancaster, M.
Thornton-Pett and M. Bochmann, J. Am. Chem. Soc. 1998, 120, 6816 - 6817.

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Transition Metal Complexes. M. Bochmann, GB Appl. No. 9805549.4 (with BP Chemicals Ltd.,
March 1998). (Borole complexes)
Determination of Plateau Moduli and Entanglement Molecular Weights of Isotactic, Syndiotactic
and Atactic Polypropylenes Synthesized with Metallocene Catalysts
A. Eckstein, J. Suhm, C. Friedrich, R.D. Maier, J. Samannshausen, M. Bochmann and R.
Mlhaupt, Macromolecules 1998, 31, 1335 - 1340.
Synthesis and Structure of Bis[2,2'-methylenebis(2,4-di-t-butylphenoxo)]niobium chloride.
L. Higham, M. Thornton-Pett and M. Bochmann, Polyhedron 1998, 17-18, 3047 - 3051.
Synthesis, Structure and Reactivity of Synthesis, Structure and Reactivity of (C5H4SiMe3)2Y{(FC6F4)(-Me)B(C6F5)2: Tight Ion Pairing in a Cationic Lanthanide Complex
X. Song, M. Thornton-Pett and M. Bochmann, Organometallics 1998, 17, 1004 - 1006.
Zirconocenes as Initiators for Carbocationic Isobutene Homo- and Co-Polymerizations.
A. G. Carr, D.M. Dawson, and M. Bochmann, Macromolecules 1998, 31, 2035 - 2040.
The [Zr{N(SiMe3)2}3]+ Cation as a Novel Initiator for Carbocationic Isobutene Homo- and
Isobutene/Isoprene Co-Polymerisations.
A.G. Carr, D.M. Dawson and M. Bochmann, Macromol. Rapid Commun. 1998, 19, 205 - 207.
Aspects of Transition Metal Mediated Polymerisations.
M. Bochmann, Current Opinion in Solid State and Materials Science, 1997, 2, 639 - 646. (Invited
review).
New Mono-Cp Complexes of Group 4 and 5 Metals with Chelating Nitrogen Ligands. The Crystal
and Molecular Structures of [Zr(3-C3H5)(4-Ph2N2C2Me2-2,3)Cp] and [TaCl2{4-1,2C6H4(NSiMe3)2}Cp] {Cp = 1,3-C5H3(SiMe3)2}
G. Jimnez Pindado, M. Thornton-Pett and M. Bochmann, J. Chem. Soc., Dalton Trans. 1998, 393 400.
Preparation of (Cp*){C5H4CH2B()(C6F5)3}Zr(+)Ph, a Novel Zwitterionic Single-Component
Polymerisation Catalyst.
X. Song and M. Bochmann, J. Organomet. Chem. 1997, 545-546, 597 - 600.
Dinuclear Cationic Zirconium Complexes with the Fulvalene Ligand. Synthesis and Reactivity.
T. Cuenca, M. Galakhov, G. Jimnez, E. Royo, P. Royo and M. Bochmann, J. Organomet. Chem.
1997, 543, 209 - 215.
Synthesis of Cyclopentadienyl-, Indenyl-, and Fluorenyl-bis(pentafluorophenyl)boranes as Ligands
in Titanium and Zirconium Half-Sandwich Complexes. The Crystal Structures of
[C13H9B(C6F5)2t-BuNH2], [C13H8SiMe3B(C6F5)2] and {5-C5H4B(C6F5)2}TiCl3.
R. Duchateau, Simon J. Lancaster, Mark Thornton-Pett and Manfred Bochmann, Organometallics
1997, 16, 4995 - 5005.

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Zirconium and Hafnium Diene and Dienyl Half-Sandwich Complexes: Synthesis, Polymerisation
Catalysis and Deactivation Pathways. The Molecular Structures of [Zr(3-C3H5)(2,3Me2C4H4)Cp"] and [Hf(3-C3H5)(3-CH2CMeCMeCH2B(C6F5)3}Cp"].
G. Jimnez Pindado, M. Thornton-Pett and M. Bochmann, J. Chem. Soc., Dalton Trans., 1997,
3115 - 3127.
Zwitterionic Bis(allyl)zirconium Complexes: Synthesis, Structure, Polymerisation Activity and
Deactivation Pathways.
G. Jimnez Pindado, M. Thornton-Pett, M. Bouwkamp, A. Meetsma, B. Hessen and M. Bochmann,
Angew. Chem. 1997, 109, 2457 - 2460.
Synthesis of Phosphinochalcogenoic Amidato Complexes of Divalent Transition Metals and Their
Thermolysis to Metal Selenide and Telluride Phases.
X. Song and M. Bochmann, J. Chem. Soc., Dalton Trans. 1997, 2689 - 2692.
Synthesis and Structure of Zirconium(IV) Alkyl Complexes with Bi-, Tri-, Tetra- and Pentadentate
Amido Ligands.
N.A.H. Male, M. Thornton-Pett and M. Bochmann, J. Chem. Soc., Dalton Trans.,1997, 2487 2494.
Titanium-Catalysed Formation of High Molecular Weight Elastomeric Polypropene: Evidence for
Living Propene Polymerisation.
J. Samannshausen, M. Bochmann, J. Rsch and D. Lilge, J. Organomet. Chem. 1997, 548, 23 - 28.
Facile -C-H Activation in 14-Electron Zirconium Half-Sandwich Compounds: Evidence for a New
Catalyst Deactivation Pathway.
G. Jimenz Pindado, M. Thornton-Pett and M. Bochmann, Chem. Commun. 1997, 609 - 610.
Synthesis and Reactivity of [Al(C5H5)2]+: A Highly Efficient Initiator for the Cationic
Polymerisation of Isobutene.
M. Bochmann and D.M. Dawson, Angew. Chem. 1996, 108, 2371 - 2373; Angew. Chem. Int. Ed.
Engl. 1996, 35, 2226 - 2228.
Process for the Preparation of Polyisoolefins via New Initiator Systems of the Metallocene-Type.
G. Langstein, M. Bochmann and D. Dawson, DE 1961003331 (30.1.96) (German Patent Appl.);
Eur. Pat. Appl. 0787748;
US 5703182 (AlCp2+).
Synthesis of Ferrocene-Based Redox-Active Polymers via Palladium Catalyzed Coupling Reactions.
M. Bochmann, J.J. Lu and R.D. Cannon, J. Organomet. Chem. 1996, 518, 97 - 103.
Cationic Group IV Metallocene Complexes and Their Role in Polymerisation Catalysis: The
Chemistry of Well-defined Ziegler Catalysts.
M. Bochmann, J. Chem. Soc., Dalton Trans., 1996, 255 - 270.
Metal Chalcogenolato Complexes as "Single-Source" Precursors to Chalcogenide Materials.
M. Bochmann, Chem Vap. Deposition 1996, 2, 85 - 96.
Novel Group IVB Metal Complexes

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M. Bochmann, Brit. Pat. Applic. GB 2,303,367 (7.7.95)
Anionic and Zwitterionic Metallocene Complexes Derived from Novel Boratocyclopentadienyl
Ligands
M. Bochmann, S.J. Lancaster and O.B. Robinson J. Chem. Soc., Chem. Commun., 1995, 2081 2082.
Phosphinochalcogenoic Amidato Complexes of Zinc and Cadmium as Novel Single-Source
Precursors for the Deposition of Metal Selenide and Telluride Films
G.C. Bwembya, X. Song and M. Bochmann, Chem. Vapor Deposition 1995, 1, 78.
Synthesis of Phosphinochalcogenoic Amide Complexes of Zinc and Cadmium. The Crystal and
Molecular Structure of [Zn{But2P(Se)NPri}2].
M. Bochmann, G.C. Bwembya, M.B. Hursthouse and S.J. Coles, J. Chem. Soc., Dalton Trans.
1995, 2813 - 2817.
Zinc(II) Arene Tellurolato Complexes as Precursors to Zinc Telluride. The Crystal and Molecular
Structure of [Zn(TeC6H2Me3-2,4,6)2(pyridine)2.
M. Bochmann, G.C. Bwembya, A.K. Powell and X. Song, Polyhedron. 1995, 14, 3495 - 3500.
Titanium Complexes: Introduction and Complexes in the Oxidation State +4.
M. Bochmann in : E.W. Abel, F.G.A. Stone and G. Wilkinson (Eds.), Comprehensive
Organometallic Chemistry II. Pergamon Press 1995, vol. 4, p. 273 - 431.
Titanium Complexes in the Oxidation States +2 and +3.
M. Bochmann in : E.W. Abel, F.G.A. Stone and G. Wilkinson (Eds.), Comprehensive
Organometallic Chemistry II. Pergamon Press 1995, vol. 4, p. 221 - 271.
Trends in Organometallic Chemistry.
M. Bochmann, Nachr. Chem. Techn. Lab. 1995, 43, 132 - 137.
Synthesis and Reactivity of New Mono(cyclopentadienyl) Zirconium and Hafnium Alkyl
Complexes. The Crystal and Molecular Structure of [{C5H3(SiMe3)2}HfMe2(6toluene)][BMe(C6F5)3].
M. Bochmann, O.B. Robinson, S.J. Lancaster, M.B. Hursthouse and S.J. Coles, Organometallics,
1995, 14, 2456 - 2462.
Synthesis of Phosphinoselenoic and Phosphinotelluroic Amides and Amidato Complexes. The
Crystal and Molecular Structures of But2P(Te)NHCy, [TiCpCl2{But2P(Se)NPri}] and
[TiCl2{But2P(Se)NCy}2].
M. Bochmann, G.C. Bwembya, N. Whilton, X. Song, M.B. Hursthouse, S.J. Coles and A. Karaulov,
J. Chem. Soc., Dalton Trans. 1995, 1887 - 1892.
Ziegler-Natta Catalysis. Cationic Group 4 Metal Alkyl Complexes and Their Role in Olefin
Polymerization Catalysis.
M. Bochmann in: The Polymeric Materials Encyclopedia. J.C. Salamone (ed.), CRC Press, Boca
Raton 1995.
The Preparation of rac-Ethylene-1,2-bis(1-indenyl)zirconium Dichloride and Dibenzyl Complexes.

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M. Bochmann and S.J. Lancaster in: J.D. Woollins (ed.), Inorganic Experiments, VCH, Weinheim
1994, p. 206 - 210.
Organometallic Molybdenum Compounds.
M. Bochmann and P. Hammerton in: J.D. Woollins (ed.), Inorganic Experiments, VCH, Weinheim
1994, p. 202 - 206.
Preparation and Complexation of Tris(3,5-dimethylpyrazolyl)hydroborate.
M. Bochmann in: J.D. Woollins (ed.), Inorganic Experiments, VCH, Weinheim 1994, p. 28 - 30.
Analysis of an Iron(III) Oxalate Complex.
R.D. Cannon and M. Bochmann in: J.D. Woollins (ed.), Inorganic Experiments, VCH, Weinheim
1994, p. 14 - 17.
Gravimetric Analysis of Hexammine Nickel(II) Tetafluoroborate, [Ni(NH3)6](BF4)2.
R.D. Cannon and M. Bochmann in: J.D. Woollins (ed.), Inorganic Experiments, VCH, Weinheim
1994, p. 10 - 13.
Preparation and Investigation of Some Coordination Compounds.
R.D. Cannon and M. Bochmann in: J.D. Woollins (ed.), Inorganic Experiments, VCH, Weinheim
1994, p. 7 - 9.
Cationic Group IV Metal Alkyl Complexes and Their Role as Olefin Polymerization Catalysts. The
Formation of Ethyl-Bridged Dinuclear and Heterodinuclear Zirconium and Hafnium Complexes.
M. Bochmann and S. J. Lancaster, J. Organomet. Chem. 1995, 497, 55 - 59.
Chalcogenolato Complexes of Bismuth and Antimony. Syntheses, Thermolysis Reactions, and the
X-Ray Crystal Structure of Sb(SC6H2Pri3-2,4,6)3.
M. Bochmann, X. Song, M.B. Hursthouse and A. Karaulov, J. Chem. Soc., Dalton Trans. 1995,
1649 - 1652.
Synthesis and Characterisation of Manganese(II) Chalcogenolato Complexes. The Crystal and
Molecular Structure of [Mn(-SeC6H2Me3-2,4,6)2].
M. Bochmann, A.K. Powell and X. Song, J. Chem. Soc., Dalton Trans. 1995, 1645 - 1648.
Monomer-Dimer Equilibria in Homo- and Heterodinuclear Cationic Alkylzirconium Complexes
and Their Role in Polymerization Catalysis.
M. Bochmann and S.J. Lancaster, Angew. Chem. 1994, 106, 1715 - 1718; Angew. Chem. Int. Ed.
Engl. 1994, 33, 1634 - 1637.
Facile -H Elimination in Cationic Zirconium Alkyl Complexes: Formation of -CH2 Complexes
as a Possible Deactivation Pathway in Polymerisation Catalysis.
M. Bochmann, T. Cuenca and D.T. Hardy, J. Organomet. Chem. 1994, 484, C10-C12.
Synthesis of Base-Free Cationic Zirconium Methyl and Benzyl Complexes. The Crystal and
Molecular Structure of {C5H3(SiMe3)2}2ZrMe(-Me)B(C6F5)3.
M. Bochmann, S.J. Lancaster, M.B. Hursthouse and K.M.A. Malik, Organometallics 1994, 13,
2235 - 2243.

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Synthesis of Low-Coordinate Chalcogenolato Complexes of Zinc with O, N, S, and P Donor
Ligands. Molecular and Crystal Structures of Zn(S-t-Bu3C6H2-2,4,6)2(L) (L = NC5H3Me2-2,6,
PMePh2), Zn(Se-t-Bu3C6H2-2,4,6)2(OSC4H8) and Zn(S-t-Bu3C6H2-2,4,6)2(N-methylimidazole)2.
M. Bochmann, G.C. Bwembya, R. Grinter, A.K. Powell, K.J. Webb, M.B. Hursthouse, K.M.A.
Malik and M. Mazid, Inorg. Chem. 1994, 33, 2290 - 2296.
Organometallics 2: Complexes with Transition MetalCarbon -Bonds.
M. Bochmann, Oxford University Press, Oxford 1994. ISBN 0-19-855813-9.
Organometallics 1: Complexes with Transition MetalCarbon -Bonds.
M. Bochmann, Oxford University Press, Oxford 1994. ISBN 0-19-855750-7.
Synthesis of Poly(biphenylene Ketone)s via Palladium Catalysed Cross-Coupling Reactions with
Ketone Diacetals.
M. Bochmann and J.J. Lu, J. Polym. Sci., Part A: Polym. Chem., 1994, 32, 2493 - 2500.
Syndiotactic Propene Polymerisation with Cationic Benzyl Zirconium Catalysts.
M. Bochmann and S.J. Lancaster, Makromol. Chem. Rapid Commun. 1993, 14, 807 - 811.
Synthesis and Structure of [Me2C(C5H4)(Flu)Zr(-H)Cl]2: An 3:5-Bonded ansa-Metallocene.
M. Bochmann, S.J. Lancaster, M.B. Hursthouse and M. Mazid, Organometallics 1993, 12, 4718 4720.
Low-Coordinate Chalcogenolato Complexes of Zinc, Cadmium and Mercury.
M. Bochmann, G.C. Bwembya, K.J. Webb and R. Grinter, The Chemistry of the Copper and Zinc
Triads, A.J. Welch and S.K. Chapman (eds.), Royal Society of Chemistry 1993, p. 133 - 136.
New Sterically Hindered Manganese Selenolato Complexes. Isolation and Structural
Characterisation of a Reaction Intermediate, [Mn{N(SiMe3)2}(-SeC6H2Pri3-2,4,6)2(THF)]2.
M. Bochmann, A.K. Powell and X. Song, Inorg. Chem., 1994, 33, 400 - 401.
Synthesis of Isocyanide Complexes of Zinc. The Molecular and Crystal Structure of
Zn(SeC6H2But3-2,4,6)2(CNBut)2.
M. Bochmann, G.C. Bwembya, and A.K. Powell, Polyhedron 1993, 24, 2929 - 2932.
Cationic Alkyl Complexes as Catalysts in Olefin Polymerisations.
M. Bochmann, Nachr. Chem., Techn. Lab. 1993, 41, 1220 - 1228.
Base-free cationic alkyl complexes of titanium, Zirconium and Hafnium: A New Generation of
Highly Active Polymerisation Catalysts.
M. Bochmann, GIT Fachzeitschrift fr das Laboratorium, 1994, 38, 117 - 118.
Base-free Cationic Zirconium Benzyl Complexes as Highly Active Polymerisation Catalysts.
M. Bochmann and S.J. Lancaster, Organometallics 1993, 12, 633 - 640.
Non-coordinating anions: underestimated ligands.
M. Bochmann, Angew. Chem. 1992, 104, 1206 - 1207; Angew. Chem. Int. Ed. Engl. 1992, 31, 1181
- 1182.

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Three-coordinate Thiolato Complexes of Zinc: Solution and Solid-state Structures and EHMO
Analysis of the Bonding Pattern of [Zn(S-t-Bu3C6H2-2,4,6)2]2.
M. Bochmann, G. Bwembya, R. Grinter, J. Lu, K. J. Webb, D. J. Williamson, M. B. Hursthouse and
M. Mazid, Inorg. Chem., 1993, 32, 532 - 537..
Base-free Cationic 14-electron Alkyls of Ti, Zr and Hf as Polymerisation Catalysts: A Comparison.
M. Bochmann and S.J. Lancaster, J. Organomet. Chem. 1992, 434, C1 - C5.
Arene Thiolato, Selenolato and Tellurolato Complexes of Mercury.
M. Bochmann and K.J. Webb, Inorganic Syntheses, vol. 31, 24 - 28 (1997).
Arene Chalcogenolato Complexes of Zinc and Cadmium.
M. Bochmann, G. Bwembya and K.J. Webb, Inorganic Syntheses, vol. 31, 19 - 24 (1997).
Sterically Hindered Arene Chalcogenols.
M. Bochmann and K.J. Webb, Inorganic Syntheses, vol. 31, 158 - 162 (1997).
Volatile Cadmium Chalcogenolato Complexes as Single-source Precursors for the MOCVD Growth
of II-VI Films.
M. Bochmann, K.J. Webb, J.E. Hails and D. Wolverson, Eur. J. Solid State Inorg. Chem. 1992, 29,
155 - 166.
The Infrared Spectra of the Dimethyl Complexes of Zinc, Cadmium and Mercury.
M. Bochmann, M.A. Chesters, A.P. Coleman, R. Grinter and D.L. Linder,
Spectrochim. Acta, 1992, 48A, 1173 - 1178.
Homogeneous Catalysis of Organic Reactions by Transition Metal Complexes.
M. Bochmann in: M.V. Twigg (Ed.), Mechanisms of Inorganic and Organometallic Reactions, Vol.
8 (Plenum Press 1994), p. 363 - 396.
Cationic Titanium Alkyls as Alkene Polymerisation Catalysts: Solvent and Anion Dependence.
M. Bochmann and A.J. Jaggar, J. Organomet. Chem., 1992, 424, C5 - C7.
Synthesis of the First Stable Aldehyde and Ketone Complexes of Zinc. The Structure of
[Zn(SeC6H2But3)2(p-OCHC6H4OMe)]2.
M. Bochmann, K.J. Webb, M.B. Hursthouse and M. Mazid, J. Chem. Soc., Chem. Commun. 1991,
1735.
Synthesis and Structure of Hg(SC6H2But3)2(py): A T-shaped Complex of Mercury.
M. Bochmann, K.J. Webb and A.K. Powell, Polyhedron 1992, 11, 513 - 516.
Synthesis of some Alkyl Metal Selenolato Complexes of Zinc, Cadmium and Mercury. X-Ray
Crystal Structure of MeHgSe(2,4,6-Pri3C6H2).
M. Bochmann, A.P. Coleman and A.K. Powell, Polyhedron 1992, 11, 507 - 512.
Synthesis of Aromatic Polymers via Palladium-catalysed Cross-coupling Reactions with
Magnesium, Zinc and Tin Reagents: A Comparison.
M. Bochmann, K. Kelly and J. Lu, J. Polym. Sci, Part A: Polym.Chem. 1992, 30, 2511 - 2519.

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Synthesis of Poly(arylene ethyne)s via Palladium-catalysed Cross-coupling Reactions with Cu and
Sn Reagents.
M. Bochmann and K. Kelly, J. Polym. Sci, Part A: Polym.Chem. 1992, 30, 2503 - 2510.
FT-Raman Spectroscopic Studies on Sterically Hindered Aryl Dichalcogenides.
M. Bochmann and K.J. Webb, Spectrochim. Acta 1991, 47A, 1279 - 1282.
Synthesis of Sterically Hindered Tellurophenols. The Structure of [Cd(TeC6H2Me3)2].
M. Bochmann, A.P. Coleman, K.J. Webb, M.B. Hursthouse, M. Mazid, Angew. Chem., 1991, 103,
975 - 976; Angew. Chem Int. Ed. Engl. 1991, 30, 973 - 975.
Sterically Hindered Thiolato, Selenolato and Tellurolato Complexes of Mercury(II).
M. Bochmann and K.J. Webb, J. Chem. Soc., Dalton Trans. 1991, 2325 - 2329.
Sterically Hindered Chalcogenolato Complexes. Monomeric and Dimeric Thiolates and Selenolates
of Zinc and Cadmium, and the Structure of [Cd(SeC6H2But3)2]2, the First Three-coordinate
Cadmium Se Complex.
M. Bochmann, K.J. Webb, M.B. Hursthouse and M. Mazid, J. Chem. Soc., Dalton Trans. 1991,
2317 - 2323.
Homogeneous Catalysis of Organic Reactions by Transition Metal Complexes.
M. Bochmann in: M.V. Twigg (Ed.), Mechanisms of Inorganic and Organometallic Reactions, Vol.
7 (Plenum Press 1991), p. 339 - 367.
Novel Precursors for the Deposition of II-VI Semiconductor Films.
M. Bochmann and K.J. Webb in: L.V. Interrante, K.F. Jensen, L.H. Dubois, M.E. Gross (Eds.),
Material Research Society Symposium Proceedings, Vol. 204: Chemical Perspectives of
Microelectronic Materials II (Material Research Society 1991), p. 149 - 154.
Cationic Catalysts for the Homogeneous Polymerisation of Olefins.
M. Bochmann, Nachr. Chem. Techn. Lab. 1990, 38, 1238-1239.
Homogeneous Catalysis by Transition Metals.
M. Bochmann in: E.W. Abel, F.G.A. Stone (Eds.), Specialist Periodical Reports: Organometallic
Chemistry. Vol. 19, p. 353 - 397 (The Royal Society of Chemistry 1990).
Electron-deficient Group IV Metal Alkyl Cations, and the Synthesis of Zr(CH2Ph)3(6-C6H5BPh3),
a Fluxional Arene -Complex of a do Metal.
M. Bochmann, G. Karger, and A.J. Jaggar, J. Chem. Soc., Chem. Commun. 1990, 1038 - 1039.
Base-free Cationic 14-Electron Titanium and Zirconium Alkyls: In-situ Generation, Solution
Structures, and Olefin Polymerisation Activity.
M. Bochmann, A.J. Jaggar, and J.C. Nicholls, Angew. Chem. 1990, 102, 830 - 832; Angew. Chem.
Int. Ed. Engl. 1990, 29, 780 - 782.
Cationic Bis(cyclopentadienyl)titanium Complexes. The Synthesis and Structure of
[Cp*2Ti(OH)(HN=CPh2)]BPh4Et2O.
M. Bochmann, A.J. Jaggar, M.B. Hursthouse and M. Mazid, Polyhedron 1990, 9, 2097 - 2100.

10
Nickel-catalysed Cross-coupling Reactions of Grignard Reagents with Di-, Tri- and
Polychlorobiphenyls.
M. Bochmann, C.S. Creaser and L. Wallace, J. Mol. Catal. 1990, 60, 343 - 350.
Synthesis, Structure and Gas-phase Decomposition of [Cd(EC6H2But3)2]2 (E = S, Se): First
Examples of Low-coordinate Volatile Cadmium Chalcogenolato Complexes.
M. Bochmann, K.Webb, M. Harman and M.B. Hursthouse, Angew. Chem. 1990, 102, 703 - 704;
Angew. Chem. Int. Ed. Engl. 1990, 29, 638 - 639.
Synthesis of some Cationic 16- and 18-Electron Nickel Alkyl Phosphine Complexes containing
Bidentate Ligands: Ligand-dependent Square-planar, Trigonal-bipyramidal and Square-pyramidal
Co-ordination Geometries, their Reactions with CO and Alkynes, and the Crystal Structure of
[Ni(CH2SiMe3)(PMe3)3]BF4.
M. Bochmann, I. Hawkins, M.B. Hursthouse and R.L. Short, J. Chem. Soc., Dalton Trans. 1990,
1213 - 1219.
Homogeneous Catalysis of Organic Reactions by Transition Metal Complexes.
M. Bochmann in: M.V. Twigg (Ed.), Mechanisms of Inorganic and Organometallic Reactions, Vol.
6, p. 365 - 433 (Plenum Press 1989).
Process for the Preparation of Catalysts and Their Use in the Polymerisation of Olefins.
M. Bochmann, Brit. Pat. Applic. 89 26800.7.
Homogeneous Catalysis by Transition Metals.
M. Bochmann in: E.W. Abel, F.G.A. Stone (Eds.), Specialist Periodical Reports: Organometallic
Chemistry. Vol. 18, p. 349 - 400 (The Royal Society of Chemistry 1989).
Synthesis of Cationic Alkylbis(cyclopentadienyl)titanium Complexes by One-Electron Oxidation of
Titanium(III) Alkyls. The Structure of [Cp*2TiMe(THF)]BPh4 and [Cp*2Ti(OH)(OH2)]BPh42
THF.
M. Bochmann, A.J. Jaggar, L.M. Wilson, M.B. Hursthouse and M. Motevalli, Polyhedron 1989, 8,
1838 - 1843.
Synthesis and Electrochemical Oxidation of Tetranuclear Nickel Carbonyl Phosphine Clusters. The
Structure of Ni4(CO)6(PMe3)4.
M. Bochmann, I. Hawkins, L.J. Yellowlees, M.B. Hursthouse and R.L. Short, Polyhedron 1989, 8,
1351 - 1355.
Palladium Catalysed Cross-Coupling Reactions with Difunctional Tin Reagents: A General Route
to Aromatic Polymers.
M. Bochmann and K. Kelly, J. Chem. Soc., Chem. Commun. 1989, 532 - 534.
Homogeneous Catalysis by Transition Metals.
M. Bochmann in: E.W. Abel, F.G.A. Stone (Eds.), Specialist Periodical Reports: Organometallic
Chemistry. Vol. 17, p. 362 - 405 (The Royal Society of Chemistry 1989).
Progress in Catalytic C-H Activation.
M. Bochmann, Nachr. Chem. Techn. Lab. 1988, 36, 17.

11
Thermal Deposition of TiS Films from Volatile Ti(SBut)4.
M. Bochmann, I. Hawkins and L.M. Wilson, J. Chem. Soc., Chem. Commun. 1988, 344 - 345.
The Insertion Reactions of Nitriles in Cationic Alkylbis(cyclopentadienyl)titanium Complexes: The
Facile Synthesis of Azaalkenylidene Titanium Complexes, and the Crystal and Molecular Structure
of [(Indenyl)2Ti(NCMePh)(NCPh)]BPh4.
M. Bochmann, L.M. Wilson, M.B. Hursthouse and M. Motevalli, Organometallics 1988, 7, 1148 1154.
Cationic Alkylbis(cyclopentadienyl)titanium Complexes. Synthesis, Reactions with CO and tBuNC, and the Structure of [Cp2Ti{2-C(Me)NBut}(CNBut)]BPh4MeCN.
M. Bochmann, L.M. Wilson, M. B. Hursthouse and R.L. Short, Organometallics 1987, 6, 2556 2563.
Homogeneous Catalysis by Transition Metals.
M. Bochmann in: E.W. Abel, F.G.A. Stone (Eds.), Specialist Periodical Reports: Organometallic
Chemistry. Vol. 16, p. 385 - 426 (The Royal Society of Chemistry 1987).
The Reactions of Alkyltrimethylphosphinenickel Complexes with Isocyanides and Alkynes.
M. Bochmann, I. Hawkins, and M.P. Sloan, J. Organomet. Chem. 1987, 332, 371 - 378.
The Acetyltris(trimethylphosphine)nickel Cation: Synthesis, Carbonylation Reactions, and the
Crystal and Molecular Structure of [{Ni(PMe3)4}BF4Ni4(CO)6(PMe3)4].
M. Bochmann, I. Hawkins, M.B. Hursthouse and R.L. Short, J. Organomet. Chem. 1987, 332, 361 370.
Synthesis and Molecular and Crystal Structure of the Octanuclear Palladium Cluster Pd8( 3CO)2( 2-CO)6(PMe3)7.
M. Bochmann, I. Hawkins, M.B. Hursthouse and R.L. Short, Polyhedron 1987, 6, 1987 - 1991.
Homogeneous Catalysis by Transition Metals.
M. Bochmann in: E.W. Abel, F.G.A. Stone (Eds.), Specialist Periodical Reports: Organometallic
Chemistry. Vol. 15, p. 382 - 421 (The Royal Society of Chemistry 1987).
Synthesis and Insertion Reactions of Cationic Alkylbis(cyclopentadienyl)titanium Complexes.
M. Bochmann and L.M. Wilson, J. Chem. Soc., Chem. Commun. 1986, 1610 - 1611.
Binuclear Halide-bridged Ruthenium(II) Complexes Containing Alkene, Alkyne and Dinitrogen
Ligands.
T. Easton, G.A. Heath, T.A. Stephenson and M. Bochmann, J. Chem. Soc., Chem. Commun. 1985,
154.
Synthesis of a Tricarbonyl (5-2,3-dihydro-1H-1,3-diborolyl)cobalt Complex.
M. Bochmann, K. Geilich and W. Siebert, Chem Ber. 1985, 118, 401.
Promoter Effects in Homogeneous Catalysis: Catalyst Activation and Deactivation in the Codimerisation of Butadiene with 2,7-Octadienes.
M. Bochmann and M. Thomas, J. Mol. Catal. 1984, 26, 79 - 88.

12
Organic Halides as Promoters in the Rhodium Catalysed Synthesis of Dodecatrienyl Carboxylates.
M. Bochmann and M. Thomas, J. Mol. Catal. 1984, 22, 363 - 365.
Tripledecker Sandwiches. Synthesis, Reactivity, Electrochemistry and X-Ray Crystal and Electronic
Structures of Bis(cyclopentadienyl)--1,3-diborolenyl Complexes with 29 - 34 Valence Electrons.
J. Edwin, M. Bochmann, M.C. Bhm, D.E. Brennan, W.E. Geiger, C. Krger, J. Pebler, H.
Pritzkow, W. Siebert, W. Swiridoff, H. Wadepohl, J. Weiss and U. Zennek, J. Am. Chem. Soc.
1983, 105, 2582 - 2598.
Preparation of Unsaturated Compounds Having at least 13 Carbon Atoms by Reacting a 1,3-Diene
with a 1-Hydoxyalkoxy-2,7-octadiene or Derivative thereof in the Presence of a Rhodium
Compound.
M. Bochmann, Brit. Pat. 2,107,701 (to ICI PLC).
Preparation of Unsaturated Compounds Having at least 12 Carbon Atoms by Reacting a 1,3-Diene
with a 1-Substituted 2,7-Octadiene in the Presence of a Rhodium Compound and a Chromium
Halide.
M. Bochmann, Brit. Pat. 2,107,700 (to ICI PLC).
Preparation of Unsaturated esters by Reacting a 1,3-Diene with a 1-Acetoxy-2,7-octadiene in the
presence of a Rhodium or Iridium Compound and an Alkenyl, Aralkyl, Acyl or Alkoxymethyl
Chloride or Bromide.
M. Bochmann, Brit. Pat. 2,108,104 (to ICI PLC).
Organometallic Chemistry - Part (i): The Transition Elements.
M. Bochmann, R.A. Head and M.D. Johnson in: Royal Society of Chemistry Annual Reports B:
Organic Chemistry, vol. 80, p. 273 - 291 (Royal Society of Chemistry, 1983).
Organometallic Chemistry - Part (i): The Transition Elements.
M. Bochmann, R.A. Head and M.D. Johnson in: Royal Society of Chemistry Annual Reports B:
Organic Chemistry, vol. 79, p. 239 - 256 (Royal Society of Chemistry, 1982)..
Organometallic Chemistry - Part (i): The Transition Elements.
M. Bochmann, R.A. Head and M.D. Johnson in: Royal Society of Chemistry Annual Reports B:
Organic Chemistry, vol. 78, p. 255 - 279 (Royal Society of Chemistry, 1981)..
Preparation and Properties of 1-Adamantylmethyl and Adamantyl Complexes of Transition Metals.
M. Bochmann, G. Wilkinson and G.B. Young, J. Chem. Soc., Dalton Trans. 1980, 1879 - 1887.
Synthesis and Properties of Bis(tert.-butyl)methoxides of CrIII, CrIV, MnII, FeIII, CoII and CuI. The
Crystal and Molecular Structures of Lithium Tetrakis[bis(t-butyl)methoxo]chromate(III) Tetrahydrofuran (1/1), Tetrakis[bis(t-butyl)methoxo]chromium(IV), and Lithium Tetrakis[bis(tbutyl)methoxo]ferrate(III) - bis(t-butyl)methanol (1/1).
M. Bochmann, G. Wilkinson, G.B. Young, M.B. Hursthouse and K.M.A. Malik, J. Chem. Soc.,
Dalton Trans. 1980, 1863 - 1871.
Synthesis and Crystal and Molecular Structure of Bis(trimethylsilylmethylidyne)tetrakis(trimethylsilylmethyl)dirhenium (Re-Re).
M. Bochmann, G. Wilkinson, A.M.R. Galas, M.B. Hursthouse and K.M.A.Malik, J. Chem. Soc.,
Dalton Trans. 1980, 1797 - 1799.

13
Preparation and Properties of 1-Adamantoxides, 2-Adamantoxides and 1-Adamantylmethoxides of
TiIV, VIV, NbIV, NbV, CrIII, CrIV, MoIV, MnII, FeIII, and CoII. The Crystal and Molecular Sructure
of Tetrakis(1-adamantoxo)dimethylaminemolybdenum(IV).
M. Bochmann, G. Wilkinson, G.B. Young, M.B. Hursthouse and K.M.A. Malik, J. Chem. Soc.,
Dalton Trans. 1980, 901 - 910.
Preparation, Properties and Structure of a Cyclopentadienyl(1,3-diborolenyl)nickel Sandwich
Complex.
W. Siebert, M. Bochmann, J. Edwin, C. Krger and Y.H. Tsay, Zeitschr. f. Naturforsch. 1978, 33B,
1410 - 1416.
Paramagnetic Tripledecker Sandwich Complexes.
W. Siebert, J. Edwin and M. Bochmann, Angew. Chem. 1978, 90, 917 918; Angew. Chem. Int. Ed.
Engl. 1978, 17, 868 - 869.
(-Cyclopentadienyl)cobalt--(-diborolenyl)-(-cyclopentadienyl)iron - a Tripledecker Sandwich
Complex with Two Different Metals.
W. Siebert and M. Bochmann, Angew. Chem. 1977, 89, 895; Angew. Chem. Int. Ed. Engl. 1977, 16,
468.
-Cyclopentadienyl(-diborolenyl)nickel - a Diamagnetic Nickelocene Analogue.
W. Siebert and M. Bochmann, Angew. Chem. 1977, 89, 483; Angew. Chem. Int. Ed. Engl. 1977, 16,
857 - 858.
-Thiadiborolene-bis-(-cyclopentadienyliron) - Preparation and Structure of a new Tripledecker
Sandwich Complex..
W. Siebert, T. Renk, K. Kinberger, M. Bochmann and C. Krger, Angew. Chem. 1976, 88, 850
851; Angew. Chem. Int. Ed. Engl. 1976, 15, 779.
Cycloheptatrienylmolybdenum Complexes I. Formation and Oxidation of Mixed-Valence
Dimolybdenum Complexes.
M. Bochmann, M. Green, H.P. Kirsch and F.G.A. Stone, J. Chem. Soc., Dalton Trans. 1977, 714 718.
New Routes to 7-Cycloheptatrienylmolybdenum Complexes: Crystal and Molecular Structure of
[Mo(acac)(H2O)(7-C7H7)]BF4 and Mo(NCS)(acac)(7-C7H7).
M. Bochmann, M. Cook, M. Green, H.P.Kirsch, F.G.A. Stone and A.J. Welch, J. Chem. Soc.,
Chem. Commun. 1976, 381 - 383.