B. D. Sharma
California State University, Los Angeles, Los Angeles, CA 90032 and Los Angeles Pierce College, Woodland Hills, CA 91371
Tricllnlc System
The symmetry of a triclinic system is either just onefold
rotation axis or just center of symmetw. These svmmetrv
elements place no restrictionson~either<heinteraxial angles
or axial lengths. 'l'hus, the unit cell for a triclinic system can
have any value of interaxial angles and any ratio of axial
lengths, as long as a parallelepiped is defined. This, obviously,
includes a unit cell with a = b = c and a = 0= y = 90,which
defines a cube. Just because we have defined a cube does not
mean that we have a cubic system. In general, though, the unit
cell of real crystals belonging to triclinic system is such that
there is no specific relationship between axial lengths and
between interaxial angles, a consequence of the nature of the
chemical motif packed in the three-dimensional array exhibiting either just onefold rotation axis or just center of
symmetry.
Monocllnlc Svstem
This system requires either just one mirror plane or just
a single twofold rotation axis. Either of these svmmetrv ronditions demand one axis normal to the otheitwo, thus restricting two interaxial angles to a value of exactly 90.
However, there is no restriction as to the ratio of axial lengths.
Once again a unit cell with a = b = c and a = 0= y = 90 is
fully compatible with a monoclinic system.
Orlhorhombic System
Any packing of a chemical motif in a three-dimensional
array that exhibits just three mutually perpendicular twofold
rotation axes as a minimum symmetry belongs to the orthorhombic system. By the very befinitidn of th6 orthorhomhic
systrm it is clear that the three interaxial angles of the unit
parallelepiped must he exactly 90,hut there is no restriction
upon the axial length ratios. Therefore, aunit cell with a = b
= c and a = 0= y = 90" is an acceptable example of an orthorhombic system as long as the symmetry of the packing
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Crystal
System
Interaxial Angles*
a:b:y
Triclinic
Monoclinic
Onhorhombic
Tetragonal
a = b = y = 90'
a=b=r=goa
Rhombohedra1
Hexagonal
a = 8=y
y=120:a=8=900
Cubic
a=b=r=goO
Axial
Lenglhs
a:b:c
No Restrictions
No Restrictions
NOResnictions
a = b:
c any value
a=b=c
a= b
cany value
a=b=c
Cubic System
The minimum symmetry requirements are four body diagonals of the parallelepiped intersecting each other at angles
of 70' 32' and 109' 28' and have the characteristics of threefold rotation. These automaticallv lead to three mutually
perpendicular rwufold rotation axes which in turn intersect
the threefold rutution axes a t an nnrlc uiSJ0 44'. This leads
to a unit cell with a = b = e and a =-p = r = 90. It is worth
emphasizing that a unit cell defining a cube does not necessarily belong to the cubic system even though a crystal belonging to the cubic system has a unit cell that is a cube, which
may or may not have fourfold rotation axes as a part of the
symmetry required for a cubic system.
Therefore, we wish to emphasize that axial ratios and interaxial angles of unit cells for crystal systems are the conse-
19R9,ValI.
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