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Page 1 of 5

MATERIAL SAFETY DATA SHEET

Sika Canada Inc.

SECTION I: PRODUCT INFORMATION


PRODUCT:

SikaFix PU

USAGE:

INDUSTRIAL COATING

PART A

REVISION DATE: April 5, 2012

MANUFACTURER/SUPPLIER: SIKA CANADA INC.


601, avenue Delmar
Pointe Claire, QC
H9R 4A9
EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666
TDG CLASSIFICATION:
UN NUMBER:
Packaging Group:

Not regulated
Not applicable
Not applicable

WHMIS Classification: B3, D2B


Class:
Not applicable

SECTION II: HAZARDOUS INGREDIENTS


%

T.L.V.

# CAS

LD50
(species, route)

LC50
(species, route)

60 - 100

NOT AVAILABLE

NOT AVAILABLE

NOT AVAILABLE

NOT AVAILABLE

POLYSILOXANE

5 - 10

NOT AVAILABLE

NOT AVAILABLE

NOT AVAILABLE

NOT AVAILABLE

TERTIARY AMINE

0-5

NOT AVAILABLE

NOT AVAILABLE

NOT AVAILABLE

NOT AVAILABLE

Hazardous ingredients
POLYETHER
POLYOL

SECTION III: PHYSICAL CHARACTERISTICS


Physical State:
Liquid
Appearance and Odor: Light straw, mild
Odor Threshold:
Evaporation Rate:
Vapor Density:
Vapor Pressure:

Not available
Not available
Not available
Not available

Boiling Point:
Freezing Point:
Density:
Water Solubility:
pH:
% volatility by volume:
Water/Oil Distribution:

Not available
Not available
1.02 g/ml
Not available
Not available
0
Moderate

Page 2 of 5

MATERIAL SAFETY DATA SHEET

Sika Canada Inc.

PRODUCT:

SikaFix PU

PART A

SECTION IV: FIRE AND EXPLOSION HAZARDS


Flammability:

Combustible liquid

If Yes, under what conditions:

Avoid sparks, flame and


ignition sources.

Extinguishing methods:

Water fog, CO2, dry


chemical, foam

Special Methods:

Fire-fighters must wear


complete protective
clothing with respiratory
equipment

TDG Flammability Class:


Flammable upper limits (% vol.):
Flammable lower limits (% vol.):
Flash Point (setaflash closed cup):
Auto-ignition temperature:
Dangerous Combustion Products

Not applicable
Not applicable
Not applicable
86C
Not applicable
Carbon oxides,
nitrogen oxides

Protect from mechanical impact:

No

Protect from static discharge:

Yes

SECTION V: REACTIVITY DATA


Chemical stability:

Stable

Dangerous decomposition products:

Carbon oxides,
nitrogen oxides

Not known

Polymerization Risks:

No

If not, under what conditions:

Incompatibility with other material:


If Yes, which ones:

Page 3 of 5

MATERIAL SAFETY DATA SHEET

Sika Canada Inc.

PRODUCT:

SikaFix PU

PART A

SECTION VI: TOXICOLOGICAL PROPERTIES


ROUTE OF ENTRY / CONTACT

Eyes:

Will result in eye irritation

Carcinogenicity

Not available

Skin:

Will result in skin irritation

Toxic effects
on reproduction:

Not available

Teratogenicity:

Not available

Mutagenicity:

Not available

Product with synergistic


Effects:

None known

Inhalation:

Ingestion:

Will result in respiratory tract irritation

May cause abdominal pain, vomiting


and diarrhea

An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems.

Page 4 of 5
Sika Canada Inc.

PRODUCT:

MATERIAL SAFETY DATA SHEET

SikaFix PU

PART A
SECTION VII: PREVENTIVE MEASURES

PERSONAL PROTECTIVE EQUIPMENT

OTHERS

Gloves:

Ventilation:

Impervious gloves

Respiratory equipment: If respiratory respiration is


required, use an approved air
purifying respirator
Eyes:

Chemical goggles and full face


shield

Shoes:

Security shoes

Clothing:

Long sleeved, body covering and


protective clothing

Procedure in case
of leaks:

Handling and
Equipment methods:

Other:

Warehouse
Requirements:

Special Shipping
Instructions:

Waste Disposal:

Use adequate ventilation

Remove all sources of ignition


(flames, sparks, etc.). Provide
adequate ventilation. Avoid
prolonged breathing of vapors.
Remove to a container or absorb
with clay, diatomaceous earth or
other suitable inert absorbent.

Avoid inhalation, skin and eye


contact. Wash repeatedly with
soap and water during the
workday.

Keep all containers closed in a


cool, dry and well ventilated area.
Keep away from ignition sources.
Protect from freezing.

Protect from freezing.

Dispose of residues according to


municipal, provincial or federal
laws for disposal of chemicals. Do
not incinerate closed containers.

Page 5 of 5

MATERIAL SAFETY DATA SHEET

Sika Canada Inc.

PRODUCT:

SikaFix PU

PART A
SECTION VIII: FIRST AID

Skin:

Wash thoroughly with soap and water.


If irritation persists, consult a physician

Eyes:

Rinse eyes immediately with plenty of water for at least 15 minutes.


See a physician immediately.

Inhalation:

Remove the affected person to fresh air.


If breathing is difficult, administer oxygen.
Consult a physician if required.

Ingestion:

Do not induce vomiting, administer large amounts of water or milk if available.


Transport immediately to a medical facility.

SECTION IX: PREPARATION INFORMATION

Prepared By:
Telephone #:
Fax #:

The Laboratory, Research and Development Department of Sika Canada Inc.


(514) 697-2610
(514) 694-2792

Notice To Reader
The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable
as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's
current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section IX of this MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE.
SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL
PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sika.ca or 514-697-2610.
AQ 191 A
Date: 2012/02/01
App: S.G.

Page 1 of 5

MATERIAL SAFETY DATA SHEET

Sika Canada Inc.

SECTION I: PRODUCT INFORMATION


PRODUCT:

SikaFix PU

USAGE:

INDUSTRIAL COATING

PART B

REVISION DATE: April 5, 2012

MANUFACTURER/SUPPLIER: SIKA CANADA INC.


601, avenue Delmar
Pointe Claire, QC
H9R 4A9
EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666
TDG CLASSIFICATION:
UN NUMBER:
Packaging Group:

Not regulated
Not regulated
Not regulated

WHMIS Classification: D1B, D2A


Class:
Not regulated

SECTION II: HAZARDOUS INGREDIENTS


Hazardous ingredients

T.L.V.

# CAS

LD50 (mg/kg)
(species, route)

LC50
(species, route)

4,4DIPHENYLMETHANE
DIISOCYANATE

40 - 70

ACGIH
0.005 ppm (TWA)

101-68-8

31 600(rat, oral)

369 mg/m3/4H
(rat, inh)

SECTION III: PHYSICAL CHARACTERISTICS


Physical State:
Liquid
Appearance and Odor: Brown, mild
Odor Threshold:
Evaporation Rate:
Vapor Density:
Vapor Pressure:

Not available
Not available
9
Not available

Boiling Point:
Freezing Point:
Density:
Water Solubility:
pH:
% volatility by volume:
Water/Oil Distribution:

208C
Not available
1.24 g/ml
Not available
Not available
0
Slight

Page 2 of 5

MATERIAL SAFETY DATA SHEET

Sika Canada Inc.

PRODUCT:

SikaFix PU

PART B

SECTION IV: FIRE AND EXPLOSION HAZARDS


Flammability:

No

If Yes, under what conditions:

Extinguishing methods:

Water fog, CO2, dry


chemical, foam

Special Methods:

Fire-fighters must wear


complete protective
clothing with respiratory
equipment

TDG Flammability Class:


Flammable upper limits (% vol.):
Flammable lower limits (% vol.):
Flash Point (setaflash closed cup):
Auto-ignition temperature:
Dangerous Combustion Products

Not applicable
Not applicable
Not applicable
225C
Not applicable
Carbon oxides,
nitrogen oxides

Protect from mechanical impact:

No

Protect from static discharge:

No

SECTION V: REACTIVITY DATA


Chemical stability:

Stable

Dangerous decomposition products:

Carbon oxides,
nitrogen oxides

Incompatibility with other material:

Yes

Polymerization Risks:

May occur

If Yes, which ones:

Water, moisture

If not, under what conditions:

Page 3 of 5

MATERIAL SAFETY DATA SHEET

Sika Canada Inc.

PRODUCT:

SikaFix PU

PART B

SECTION VI: TOXICOLOGICAL PROPERTIES


ROUTE OF ENTRY / CONTACT

Eyes:

Will result in eye irritation. Contact with


eyes may product to polymerize

Skin:

Will result in skin irritation. Contact with


skin may product to polymerize.
Prolonged and/or repeat skin contact
may cause an allergic
reaction/sensitization.

Inhalation:

Ingestion:

Causes respiratory tract irritation. May


cause an allergic respiratory
reaction/sensitization after prolonged or
repeated contact.

Carcinogenicity

Not available

Toxic effects
on reproduction:

Not available

Teratogenicity:

Not available

Mutagenicity:

Not available

Product with synergistic


Effects:

Not known

Harmful is swallowed. Polymerization of


this product in airway could cause
suffocation. Ingestion of this product is
harmful and maybe fatal.

A person who is sensitized to isocyanate may have a


reaction with a level of isocyanate well below the T.L.V.

An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems.

Page 4 of 5
Sika Canada Inc.

PRODUCT:

MATERIAL SAFETY DATA SHEET

SikaFix PU

PART B
SECTION VII: PREVENTIVE MEASURES

PERSONAL PROTECTIVE EQUIPMENT

OTHERS

Gloves:

Ventilation:

Impervious gloves

Respiratory equipment: If respiratory respiration is


required, use an approved air
purifying respirator
Eyes:

Chemical goggles and full face


shield

Shoes:

Security shoes

Clothing:

Long sleeved, body covering and


protective clothing

Procedure in case
of leaks:

Handling and
Equipment methods:

Other:

Warehouse
Requirements:

Special Shipping
Instructions:

Waste Disposal:

Use adequate ventilation

Remove all sources of ignition


(flames, sparks, etc.). Provide
adequate ventilation. Avoid
prolonged breathing of vapors.
Remove to a container or absorb
with clay, diatomaceous earth or
other suitable inert absorbent.

Avoid inhalation, skin and eye


contact. Wash repeatedly with
soap and water during the
workday.

Keep all containers closed in a


cool, dry and well ventilated area.
Keep away from ignition sources.
Protect from freezing.

Protect from freezing.

Dispose of residues according to


municipal, provincial or federal
laws for disposal of chemicals. Do
not incinerate closed containers.

Page 5 of 5

MATERIAL SAFETY DATA SHEET

Sika Canada Inc.

PRODUCT:

SikaFix PU

PART B
SECTION VIII: FIRST AID

Skin:

Wash thoroughly with soap and water.


If irritation persists, consult a physician

Eyes:

Rinse eyes immediately with plenty of water for at least 15 minutes.


See a physician immediately.

Inhalation:

Remove the affected person to fresh air.


If breathing is difficult, administer oxygen.
Consult a physician if required.

Ingestion:

Do not induce vomiting, administer large amounts of water or milk if available.


Transport immediately to a medical facility.

SECTION IX: PREPARATION INFORMATION

Prepared By:
Telephone #:
Fax #:

The Laboratory, Research and Development Department of Sika Canada Inc.


(514) 697-2610
(514) 694-2792

Notice To Reader
The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable
as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's
current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section IX of this MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE.
SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL
PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sika.ca or 514-697-2610.
AQ 191 A
Date: 2012/02/01
App: S.G.

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