1/T
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3. A first order homogeneous liquid-phase reaction is carried out in an ideal stirred
tank reactor. The concentration of the reactant in the feed is 3.0 kmol/m3 and the
volumetric flow rate is 60 x 10-6 m3/sec. The density and specific heat for the
reaction mixture are constant at 1000 kg/m3 and 4.19 kJ/kg.K, respectively. The
reactor volume is 18 lit. There is no product in the feed stream and reactor
operates adiabatically. The heat and rate of reaction are -2.09 x 108 J/kmol and
rA = - 4.48 x 106 CA exp (- 62,800/RT) kmol/m3/sec
where, activation energy is in SI units. CA is the reactant concentration in
kmol/m3. T is in K and R= 8.314 J/mol/K. If the feed is at 273 K what is the
steady state product temperature and conversion? (Hint: the conversion is beyond
90%).
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4. The rate of isomerization of n-butane on a silica-alumna spherical catalyst
measured at 5 atm and 50oC, in a laboratory reactor with high turbulence in the
gas phase surrounding the catalyst pellet is given below. Turbulence ensures that
the external diffusion resistances are negligible. Kinetic studies indicate that the
rate is first order and irreversible. The effective diffusivity is 0.08 cm2/sec at the
reaction conditions, and the density of the catalyst pellet is 1 g/cm3 regardless of
the size. The measured rates when pure n-butane surrounds the catalyst are as
follows:
Particle
diameter (in)
1/16
1/8
3/8
Rate
mol/sec/g of
catalyst
4.88 x 10-4
4.85 x 10-4
4.01 x 10-4
3.54 x 10-4
1 x 10-5
From the above data, determine the intrinsic first order rate constant in the
absence of intraparticle diffusion. Also predict the rate if the particle size is 1.5
inch. It may be assumed that effectiveness factor () is inverse of Thiele modulus
() (i.e. = 1/) when 0.25.
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5. A reactor of irregular geometry offers following E curve. Calculate the average
residence time. Also determine the conversion in each of the following cases (i
and ii) if complete segregation of feed streams is assumed to take place.
i)
For a first order reaction rA = -0.1 CA (kmols/hr/m3)
ii)
For a second order reaction in problem 1,
Also, what will be the conversion for the first order reaction in case-i for the
maximum mixedness case?
E(t) hr-1
2.0
0.0
0.5
1.0
Time (hr)
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