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Ideal gases

Particles

have no volume.
have elastic collisions.
are in constant, random, straight-line motion.
dont attract or repel each other.
have an avg. KE directly related to Kelvin
temperature

Temperature

At constant tempereture

At constant temperature the volume of a


given mass of a gas varies inversely with
the absolute pressure

At constant temperature the volume of a


given mass of a gas varies inversely with
the absolute pressure

P1V1 = P2V2

P1V1 =P2V2
138 x 10 = 1 x V2
V2 = 1380 l

Effect of increasing temperature

At constant pressure

At constant pressure, volume of a give


mass of gas varies directly with absolut
temperature

At constant pressure volume of a give


mass of gas varies directly with absolut
temperature

At constant volume

If the volume is kept constant, absolute


pressure of a given mass of a gas varies
directly with the absolute temperature

If the volume is kept constant, absolute


pressure of a given mass of a gas
variesvaries directly with the absolute
temperature

In a mixture of gases, pressure exerted b


each gas is the same as that which it woul
exert if it alone occupied the container

P = P1 + P2 + P3 + Pn

Equal volumes of different gases at same


Temperature and Pressure contain equal
number of molecules

At same Temperature and Pressure,


equal number of molecules of
different gases occupy same volume

Pressure = 1 atm (100 kpa)


Temperature = 273.15 K (0 C)
23
No of molecules = 1 mole (6.022 x 10 )

Volume 22.4 L

H2 = 2g
O2 = 32g
N2O = 44g

Volume 22.4 L

44 g of N2O = 22.4 l

2.24/224 = 1%

R = Universal Gas Constant

Assessing the contents in a gas cylinder

RT

Pn

Gas A

Gas B

Critical Temperature
The temperature above which a gas can not be
compressed in to a liquid

(Critical Pressure)

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