John Downs
Cabot Specialty Fluids
www.formatebrines.com
Cesium formate
SG 2.3
Oil-based muds
- Improved ability to maintain wellbore stability in shale
22Cr, 2 months
25Cr, 2 months
Downs et al, Royal Society of Chemistry Chemistry in the Oil Industry Conference
Manchester, UK, 1st November 2005
Free of barite
Free of oil
Free of halides
12
13
1.0 S.G.
8.3 ppg
NaCOOH
1.3 S.G.
10.8 ppg
KCOOH
1.57 S.G.
13.1 ppg
CsCOOH
2.3 S.G.
19.2 ppg
15
Lubricating
Hydrate inhibition
Compatible with Aflas, Kalrez and Chemraz elastomers
Not compatible with elastomers that are sensitive to alkaline fluids
(e.g. Nitrile, Viton)
Cesium formate
SG 2.3
16
18
Function
Concentration
Formate brine
Density
Lubricity
Polymer protection
Biocide
1 bbl
Xanthan
Viscosity
Fluid loss control
1 2 ppb
4 8 ppb
15 20 ppb
K2CO3/KHCO3
Buffer
Acid gas corrosion control
2 8 ppb
Function
Concentration
Formate brine
Density
Lubricity
Polymer protection
Biocide
1 bbl
Synthetic polymer
Viscosity
Fluid loss control
5 15 ppb
Sepiolite
5 8 ppb
10 20 ppb
K2CO3/KHCO3
Buffer
Acid gas corrosion control
2 8 ppb
Formate brines
theoretical drilling benefits
Reduced risk of differential sticking
Formate brines
theoretical drilling benefits
Better hydraulics
Lower Surge and Swab Pressures
- Faster tripping times
- Reduced risk of hole instability
or well control incidents
Lower ECD
- Drill in narrower window between pore
and fracture pressure gradients
- Less chance of fracturing well
and causing lost circulation
Formate brines
theoretical drilling benefits
Improved well control and reduced risk
Barite sag eliminated
Thermal equilibrium reached quickly
- Reduces flow-check time
Solubility (kg/m3)
Diffusion coefficient
(m2/sec x 108)
Diffusion flux
(kg/m2s x 106)
OBM
164
1.15
53.30
WBM
2.92
3.98
Formate brine
0.80
0.25
Validated by first HT drilling trials with potassium formate in 1996 (see SPE 59191 by Mobil)
but . no cesium formate available for HPHT wells requiring > SG 1.57/13.1 ppg
29
Formula
Cesium formate
CsCHO2
2.3
> 235 *
Cesium acetate
CsC2H3O2
2.2
> 300
Cesium carbonate
CsCO3
2.2
> 300
Cesium citrate
CsC6H8O7
2.4
> 200
Cesium tungstate
Cs2WO4
2.9
> 300
Cesium molybdonate
Cs2MO4
2.7
> 300
31
32
Norphlet 863
Block 823
210
Temperature (C)
Mary Ann
Franklin
Erskine
Arun
Embla
160
Puffin
Kotelnevsko
North Ossum
500
600
700
Elf Operator
Malossa
Tenguiz
Eugene Island
800
900
Elgin
Shearwater
Trecate
F15
Lacq
Lille Frigg
110
400
West
Cameron
Thomasville
1000
1100
1200
1300
35
UK North Sea
Worlds largest HPHT field
Gas condensate reservoir
16,000 psi @ 20,000ft
BHST 400oF
140,000 bbl/day of condensate
13 million m3 gas /day
Brine left in wells for up to 24 months (well suspension)
36
Formate brine
Results
- Eliminated formation damage problem
- PI increased up to 900 m3/bar/day
- 300-600% PI improvement
- Best well: 53,000 bbl/day
Bromide brine
Water depth:
108 m
Field concept:
Reservoir type:
5-1/2 DP to surface
7 Liner top
9-5/8 Casing shoe
Flow restrictors
Formate brine
SG 1.94
Xanthan
1 ppb
Modified starch
FL7plus
6 ppb
ULV PAC
6 ppb
Potassium carbonate
5 ppb
Calcium carbonate
solids
30 ppb
Drill-in
Completion/workover
- as a brine and in LSOBM formulations (13.8 ppg)
- stand-by kill pill
- outstanding as HPHT perforating kill pill (Visund, Braemar, Judy, Rhum)
Cesium formate
use segmented by application
Differential sticking
Low potential for differential sticking
No incidence of stuck pipe
SPE Chennai 16 July 2008
Brine costs*
($, 000)
G3
913
G4
830
G5
602
G6
879
G7
807
Conclusions
Cesium formate brine represents the 4th revolutionary
innovation in well construction fluid technology
BrineWise
A Tool for Pricing and Comparing the
Operational Costs, Waste and HSE Risk
of Completion Fluids
HSE costs
Consent &
Transport
Operational
Costs
+
+
+
HSE related
costs
=
=
=
Operational
Costs related
to fluid choice
HSE related
costs related
to fluid
choice
Overall
fluid related
cost for well
Cesium Formate
0
0
0
0
0
0
0
0
0
0
0
0
Zinc Bromide
0
0
0
0
20 000
0
0
0
0
0
0
0
20 000
FOR
THE
COST OF
RISK
ALTERNATIVES
Scenario 1 type incidents (ROAD)
Cesium Formate
20 %
1%
9 600
48 813
2 734
116 950
6 600
34 000
6 600
34 000
6 384
58 441
Zinc Bromide
20 %
1%
269 615
2 583 856
13 930
390 950
309 615
1 827 575
309 615
1 827 575
225 694
1 657 489
Cesium Formate
Zinc Bromide
20 000
US$
Included in
comparison
Yes
Yes
Yes
Yes
COST SUMMARY
Currency
COMPARATIVE
US$
US$NORMAL
US$
OPERATIONAL
US$
US$ COSTS
US$
US$
US$
US$
US$
US$
US$ COST OF
US$RELATED
US$
US$
Currency
US$ COMPARATIVE
US$AVERAGE COST
US$
PER WELL
US$
US$
(taking into
Currency
account HSE risk)
6 384
245 694
US$
58 441
1 677 489
US$
1 861
81 714
US$
6 384
225 694
58 441
1 657 489
HSE
RISK
US$
US$
6 000 000
Cesium Formate
Zinc Bromide
5 000 000
US$
4 000 000
3 000 000
2 000 000
1 000 000
0
Fluid costs only Normal operation
costs
Costs of an
incident w ith
small to average
consequences
Costs of an
incident w ith
larger than
average
consequences