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H$moS> Z.

Series OSR

Code No.

amob Z.

56/1

narjmWu H$moS >H$mo Cma-nwpVH$m Ho$ _wI-n


>na Ad` {bIo &

Roll No.

Candidates must write the Code on the


title page of the answer-book.

H$n`m OmM H$a b| {H$ Bg Z-n _o _w{V n> 15 h &


Z-n _| Xm{hZo hmW H$s Amoa {XE JE H$moS >Z~a H$mo N>m Cma -nwpVH$m Ho$ _wI-n> na
{bI| &
H$n`m OmM H$a b| {H$ Bg Z-n _| >30 Z h &
H$n`m Z H$m Cma {bIZm ew$ H$aZo go nhbo, Z H$m H$_mH$ Ad` {bI| &
Bg Z-n H$mo nT>Zo Ho$ {bE 15 {_ZQ >H$m g_` {X`m J`m h & Z-n H$m {dVaU nydm
_| 10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>m Ho$db Z-n H$mo nT>|Jo
Ama Bg Ad{Y Ho$ XmamZ do Cma-nwpVH$m na H$moB Cma Zht {bI|Jo &
Please check that this question paper contains 15 printed pages.
Code number given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 30 questions.
Please write down the Serial Number of the question before
attempting it.
15 minutes time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.

agm`Z {dkmZ (gmpVH$)


CHEMISTRY (Theory)

{ZYm[aV g_` : 3 KQ>o

A{YH$V_ AH$ : 70

Time allowed : 3 hours


56/1

Maximum Marks : 70
1

P.T.O.

gm_m` {ZX}e :
(i)

g^r Z A{Zdm` h &

(ii)

Z-g`m 1 go 8 VH$ A{V bKw-Cmar` Z h & `oH$ Z Ho$ {bE 1 AH$ h &

(iii)

Z-g`m 9 go 18 VH$ bKw-Cmar` Z h & `oH$ Z Ho$ {bE 2 AH$ h &

(iv)

Z-g`m 19 go 27 VH$ ^r bKw-Cmar` Z h & `oH$ Z Ho$ {bE 3 AH$ h &

(v)

Z-g`m 28 go 30 VH$ XrK-Cmar` Z h & `oH$ Z Ho$ {bE 5 AH$ h &

(vi)

Amd`H$VmZwgma bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V Zht h &

General Instructions :
(i)

All questions are compulsory.

(ii)

Questions number 1 to 8 are very short-answer questions and carry


1 mark each.

(iii)

Questions number 9 to 18 are short-answer questions and carry 2 marks


each.

(iv)

Questions number 19 to 27 are also short-answer questions and carry


3 marks each.

(v)

Questions number 28 to 30 are long-answer questions and carry 5 marks


each.

(vi)

Use Log Tables, if necessary. Use of calculators is not allowed.

1.

amgm`{ZH$ emofU

(chemisorption) na

VmnH$_ H$m `m ^md hmoVm h

What is the effect of temperature on chemisorption ?


2.

{gda Ho$ {ZH$fU _| {OH$ YmVw H$m `m H$m` hmoVm h

What is the role of zinc metal in the extraction of silver ?


3.

H3PO3 H$s

jmaH$Vm (~o{gH$Vm) {H$VZr hmoVr h

What is the basicity of H3PO3 ?


56/1

4.

{ZZ OmoS>o _| {H$aob AUw H$mo nhMm{ZE :

Identify the chiral molecule in the following pair :

5.

{ZZ _| go H$mZ-gm mH${VH$ ~hbH$ h


~yZm-S, moQ>rZ|, PVC

Which of the following is a natural polymer ?


Buna-S, Proteins, PVC
6.

mW{_H$ Eoamo_{Q>H$ Eo_rZm| Ho$ S>mBEOmo{Z`_ bdUm| _| n[adVZ H$mo {H$g Zm_ go OmZm OmVm
h ?

The conversion of primary aromatic amines into diazonium salts is


known as ___________ .
7.

`yH$mog Ho$ Ob-AnKQ>Z (hydrolysis) Ho$ CnmX `m h

What are the products of hydrolysis of sucrose ?


8.

p-_o{Wb~OpS>hmBS>

H$s gaMZm {b{IE &

Write the structure of p-methylbenzaldehyde.


9.

KZd 2.8 g cm3 H$m EH$ Vd \$bH$ Ho$pV KZmH$ma (f.c.c.) H$ma H$m _mH$ gob
~ZmVm h {OgHo$ {H$Zmao H$s b~mB 4 108 cm h & Bg Vd H$m _moba `_mZ
n[aH${bV H$s{OE &
({X`m J`m h : NA = 6.022 1023 _mob 1)

An element with density 2.8 g cm3 forms a f.c.c. unit cell with edge
length 4 108 cm. Calculate the molar mass of the element.
(Given : NA = 6.022 1023 mol 1)
56/1

P.T.O.

10.

(i)

LiCl Ho$ Jwbm~r aJ Ho$ {bE BgH$m {H$g


(non-stoichiometric) Xmof CmaXm`r hmoVm h ?

(ii)

NaCl

H$ma H$m A-agg_rH$aU{_Vr`

{H$g H$ma H$m agg_rH$aU{_Vr` Xmof {XImVm h

AWdm
{ZZ{b{IV nXm| Ho$ OmoS>m| Ho$ ~rM Amn {d^oXZ H$go H$a|Jo
(i)
Q>oQ>mhoS>b VWm AmQ>mhoS>b [a{$`m
(ii)
{H$Q>b OmbH$ VWm _mH$ gob

(i)

What type of non-stoichiometric point defect is responsible for the


pink colour of LiCl ?

(ii)

What type of stoichiometric defect is shown by NaCl ?


OR

How will you distinguish between the following pairs of terms :

11.

(i)

Tetrahedral and octahedral voids

(ii)

Crystal lattice and unit cell

Am`Zm| Ho$ dV nbm`Z g~Yr H$mobamD$e (Kohlrausch) {Z`_ {b{IE & VZwH$aU
na {db`Z H$s MmbH$Vm H$_ `m| hmo OmVr h ?

State Kohlrausch law of independent migration of ions. Why does the


conductivity of a solution decrease with dilution ?
12.

56/1

EH$ amgm`{ZH$ A{^{H$`m, R P Ho$ {bE, g_`


Bg Jm\$ _| {XIm`m J`m h &

(order) gwPmBE

(i)

Bg A{^{H$`m H$s H$mo{Q>

(ii)

dH$ H$s dUVm (T>bmZ) `m hmoJr

&

(t)

Ho$ {V gmVm

(R)

_| n[adVZ H$mo
2

For a chemical reaction R P, the variation in the concentration (R) vs.


time (t) plot is given as

(i)
(ii)
13.

Predict the order of the reaction.


What is the slope of the curve ?

YmVwAm| Ho$ {dwV-AnKQ>Zr n[aH$aU H$m AmYma_yb {gmV g_PmBE & BgH$m EH$
CXmhaU Xr{OE &

Explain the principle of the method of electrolytic refining of metals. Give


one example.
14.

{ZZ g_rH$aUm| H$mo nyam H$s{OE


(i)

P4 + H2O

(ii)

XeF4 + O2F2

Complete the following equations :

15.

(i)

P4 + H2O

(ii)

XeF4 + O2F2

{ZZ H$s gaMZmE ~ZmBE


(i)

XeF2

(ii)

BrF3

Draw the structures of the following :

16.

(i)

XeF2

(ii)

BrF3

{ZZ A{^{H$`mAm| go g~pYV g_rH$aU {b{IE


(i)
amB_a Q>r_Z A{^{H$`m
(ii)
{d{b`_gZ gbofU (synthesis)

Write the equations involved in the following reactions :


(i)
Reimer Tiemann reaction
(ii)
Williamson synthesis
56/1

P.T.O.

17.

{ZZ A{^{H$`m H$s {H$`m{d{Y {b{IE

HBr

CH3CH2OH CH3CH2Br + H2O


Write the mechanism of the following reaction :
HBr

CH3CH2OH CH3CH2Br + H2O


18.

{ZZ ~hbH$m| H$mo m H$aZo Ho$ {bE `w$ EH$bH$m| Ho$ Zm_ {b{IE
(i)

~oHo$bmBQ>

(ii)

{ZAmorZ

Write the name of monomers used for getting the following polymers :

19.

(i)

Bakelite

(ii)

Neoprene

(a)

A{^{H$`m
Mg (s) + Cu2+ (Obr`) Mg2+ (Obr`) + Cu (s)

Ho$ {bE

rG

(a)

n[aH${bV H$s{OE &

o
: E gob = + 2.71 V, 1 F = 96500 C _mob 1

{X`m J`m h
(b)

Anmobmo (Apollo) AV[aj moJm_ Ho$ {bE {dwV e{$ CnbY H$amZo Ho$ {bE
`w$ gob Ho$ H$ma H$m Zm_ {b{IE &
o

Calculate rG for the reaction


Mg (s) + Cu2+ (aq) Mg2+ (aq) + Cu (s)
o

Given : E
(b)

56/1

cell

= + 2.71 V, 1 F = 96500 C mol1

Name the type of cell which was used in Apollo space programme
for providing electrical power.
6

20.

pWa Am`VZ AdWm _| SO2Cl2 Ho$ W_ H$mo{Q> Ho$ Vmnr` {dKQ>Z Ho$ XmamZ {ZZ{b{IV
AmH$S>o m hE :
SO2Cl2 (Jg) SO2 (Jg) + Cl2 (Jg)
`moJ

g_`/s1

gH$b Xm~/dm`w_S>b

0 .4

100

0 .7

doJ {Z`VmH$ n[aH${bV H$s{OE &


({X`m J`m h : log 4 = 0.6021,

3
log 2 = 0.3010)

The following data were obtained during the first order thermal
decomposition of SO2Cl2 at a constant volume :
SO2Cl2 (g) SO2 (g) + Cl2 (g)
Experiment

Time/s1

Total pressure/atm

0 .4

100

0 .7

Calculate the rate constant.


(Given : log 4 = 0.6021, log 2 = 0.3010)
21.

B_eg `m hmoVo h
Xr{OE &

BZHo$ {d{^ H$ma `m h

`oH$ H$ma H$m EH$$ CXmhaU


3

What are emulsions ? What are their different types ? Give one example
of each type.
22.

{ZZ{b{IV Ho$ H$maU Xr{OE


(i)

(CH3)3 P = O Vmo

(ii)

BboQ>mZ m H$aZo H$s G$Um_H$ {M dmbr EWnr H$m _mZ g\$a H$s Anojm
AmgrOZ Ho$ {bE H$_ hmoVm h &
H3PO3 H$s Anojm H3PO2 A{YH$ ~b AnMm`H$ h &

(iii)
56/1

nm`m OmVm h naVw

(CH3)3 N = O Zht

{_bVm &

P.T.O.

Give reasons for the following :

23.

(i)

(CH3)3 P = O exists but (CH3)3 N = O does not.

(ii)

Oxygen has less electron gain enthalpy with negative sign than
sulphur.

(iii)

H3PO2 is a stronger reducing agent than H3PO3.

(i)

gH$a

(ii)

gH$a [Co(en)3]3+ {H$g H$ma H$s g_md`dVm {XImVm h


(en = BWoZ-1,2-S>mBEo_rZ)

(iii)

[NiCl4]2

[Cr(NH3)4 Cl2]Cl H$m IUPAC Zm_

{b{IE &
?

`m| AZwMw~H$s` hmoVm h O~{H$ [Ni(CO)4] {VMw~H$s` hmoVm h


(na_mUw H$_mH$$ : Cr = 24, Co = 27, Ni = 28)

(i)

Write the IUPAC name of the complex [Cr(NH3)4 Cl2]Cl.

(ii)

What type of isomerism is exhibited by the complex [Co(en)3]3+ ?

?
3

(en = ethane-1,2-diamine)

24.

(iii)

Why is [NiCl4]2 paramagnetic but [Ni(CO)4] is diamagnetic ?


(At. nos. : Cr = 24, Co = 27, Ni = 28)

(a)

{ZZ _| go `oH$ A{^{H$`m Ho$ _wI EH$hbmoOZr CnmXm| H$s gaMZmE ~ZmBE :

(b)

{ZZ `w_m| _| go H$mZ-gm hbmoOZr `m{JH$


A{^{H$`m H$aoJm :
(i)
CH3Br AWdm CH3I
(ii)

56/1

(CH3)3 C Cl

AWdm

CH3 Cl
8

SN2

A{^{H$`m _| A{YH$ VrdVm go

25.

(a)

Draw the structures of major monohalo products in each of the


following reactions :

(b)

Which halogen compound in each of the following pairs will react


faster in SN2 reaction :
(i)

CH3Br or CH3I

(ii)

(CH3)3 C Cl or CH3 Cl

{ZZ{b{IV Ho$ H$maU {b{IE

(i)

VVr`H$ Eo_rZm|
hmoVo h &

(R3N) H$s

(ii)

Eo{ZbrZ \$sS>ob

(iii)

Obr` {db`Z _|

VwbZm _| mW{_H$ Eo_rZm|

(R-NH2) Ho$

dWZmH$ CVa

H$mQ>g A{^{H$`m Zht XoVr &


(CH3)3N

H$s VwbZm _|

(CH3)2NH

A{YH$ jmar` hmoVr h &

AWdm
{ZZ A{^{H$`mAm| _|

A, B

Ama

H$s gaMZmE Xr{OE

(i)

Sn HCl
H2O
NaNO2 HCl
C6H5NO2
A B
C
273 K

(ii)

H 2O / H
Br2 KOH
NH3
C
A
CH3CN
B

Account for the following :


(i)

Primary amines (R-NH2) have higher boiling point than tertiary


amines (R3N).

(ii)

Aniline does not undergo Friedel Crafts reaction.

(iii)

(CH3)2NH is more basic than (CH3)3N in an aqueous solution.


OR

56/1

P.T.O.

Give the structures of A, B and C in the following reactions :


(i)

Sn HCl
H2O
NaNO2 HCl
C6H5NO2
C
A B
273 K

(ii)

H 2O / H
Br2 KOH
NH3
CH3CN
C
A
B

26.

moQ>rZm| go g~pYV {ZZ nXm| H$s n[a^mfmE Xr{OE


(i)
noQ>mBS> Am~Y
(ii)
mW{_H$ gaMZm
(iii) {dH$VrH$aU

Define the following terms as related to proteins :

27.

56/1

(i)

Peptide linkage

(ii)

Primary structure

(iii)

Denaturation

{dd dm` {Xdg Ho$ Adga na, S>m. gVnmb Zo nmg Ho$ Jmd _| ahZo dmbo YZhrZ
{H$gmZm| Ho$ {bE EH$ dm` H$n bJm`m & OmM Ho$ ~mX, Cgo `h XoI H$a YH$m bJm
{H$ ~ma-~ma H$sQ>ZmeH$m| Ho$ gnH$ _| AmZo Ho$ H$maU {H$gmZm| _| go A{YH$m| H$mo H$ga H$m
amoJ hmo J`m Wm & CZ_| go ~hVm| H$mo _Yw_oh ^r Wm & Chm|Zo CZ_| YZ_w$ Amf{Y`m ~mQ>t &
S>m. gVnmb Zo Bg ~mV H$s gyMZm VH$mb ZoeZb y_Z amBQ>g H${_eZ (NHRC) H$mo
Xr & NHRC Ho$ gwPmdm| na gaH$ma Zo {ZU` {b`m H$s S>mQ>ar ghm`Vm Ama {dmr`
ghm`Vm bmoJm| H$mo Xr OmE Ama ^maV Ho$ g^r Jmdm| _| KmVH$ amoJm| Ho$ ^md H$mo amoH$Zo Ho$
{bE A`{YH$ gw{dYm dmbo AnVmb Imobo OmE &
(i)

(a)

(ii)

ApV_ H$ga _| nrS>m go ~MmZo Ho$ {bE _w`V`m H$mZ-gr nrS>mZmeH$ Amf{Y`m
`w$ H$s OmVr h ?

(iii)

_Yw_oh Ho$ amo{J`m| Ho$ {bE gwPmE JE H${_ _YwH$mam| _| go {H$gr EH$ H$m CXmhaU
Xr{OE &

S>m. gVnmb Ama

(b) NHRC mam

10

XemB JB _m` ~mV| {b{IE &

On the occasion of World Health Day, Dr. Satpal organized a health camp
for the poor farmers living in a nearby village. After check-up, he was
shocked to see that most of the farmers suffered from cancer due to regular
exposure to pesticides and many were diabetic. They distributed free
medicines to them. Dr. Satpal immediately reported the matter to the
National Human Rights Commission (NHRC). On the suggestions of
NHRC, the government decided to provide medical care, financial
assistance, setting up of super-speciality hospitals for treatment and
prevention of the deadly disease in the affected villages all over India.
(i)

28.

Write the values shown by


(a)

Dr. Satpal

(b)

NHRC.

(ii)

What type of analgesics are chiefly used for the relief of pains of
terminal cancer ?

(iii)

Give an example of artificial sweetener that could have been


recommended to diabetic patients.

(a)

{ZZ nXm| H$s n[a^mfm Xr{OE

(b)

(i)

_mobaVm

(ii)

_mobb C`Z pWamH$

(Kb)

EH$ Obr` {db`Z _| {V {bQ>a {db`Z _| 15 g `y[a`m (_moba `_mZ =


60 g _mob 1) Kw{bV h & Bg {db`Z H$m namgaU Xm~ Ob _| byH$moO (_moba
`_mZ = 180 g _mob 1) Ho$ EH$ {db`Z Ho$ g_mZ (g_namgar) h & EH$ {bQ>a
{db`Z _| CnpWV byH$moO H$m `_mZ n[aH${bV H$s{OE &

2, 3

AWdm
56/1

11

P.T.O.

(a)

EWoZmb Ama EogrQ>moZ H$m {_lU {H$g H$ma H$m {dMbZ {XImVm h
Xr{OE &

(b)

Ob _| byH$moO (_moba `_mZ = 180 g _mob 1) Ho$ EH$ {db`Z na bo~b bJm
h, 10% (`_mZ AZwgma) & Bg {db`Z H$s _mobbVm Ama _mobaVm `m hm|Jo ?
({db`Z H$m KZd = 1.2 g mL1)

(a)

(b)

H$maU

Define the following terms :


(i)

Molarity

(ii)

Molal elevation constant (Kb)

A solution containing 15 g urea (molar mass = 60 g mol1) per litre


of solution in water has the same osmotic pressure (isotonic) as a
solution of glucose (molar mass = 180 g mol1) in water. Calculate
the mass of glucose present in one litre of its solution.
OR

(a)

What type of deviation is shown by a mixture of ethanol and


acetone ? Give reason.

(b)

A solution of glucose (molar mass = 180 g mol1) in water is


labelled as 10% (by mass). What would be the molality and
molarity of the solution ?
(Density of solution = 1.2 g mL1)

29.

56/1

(a)

{ZZ g_rH$aUm| H$mo nyam H$s{OE

(i)

Cr2O72 + 2OH

(ii)

MnO4 + 4H+ + 3e

12

2, 3

(b)

{ZZ Ho$ H$maU {b{IE

(i)

Zn

(ii)

gH$_U YmVw ~hV go gH$a ~ZmVo h &

(iii)

Mn3+/Mn2+ `w_, Cr3+/Cr2+ `w_

H$mo gH$_U Vd Zht _mZm OmVm &


go H$ht A{YH$ Eo _mZ aIVm h &

2, 3

AWdm
(i)

gaMZm n[adVZerbVm Ama amgm`{ZH$ A{^{H$`merbVm Ho$ gX^ _| bWoZmBS>m|


Ama EopQ>Zm`S>m| Ho$ ~rM ^oX {b{IE &

(ii)

bWoZmBS> mIbm Ho$ Cg gX` H$m Zm_ {b{IE, Omo


{XImZo Ho$ {bE {g h &

(iii)

{ZZ g_rH$aU H$mo nyam H$s{OE

+4

AmgrH$aU AdWm

MnO4 + 8H+ + 5e
(iv)

Mn3+ Ama Cr3+

(na_mUw H$_mH$
(a)

(b)

_| go H$mZ A{YH$ AZwMw~H$s` h Ama `m|

: Mn = 25, Cr = 24)

Complete the following equations :

(i)

Cr2O72 + 2OH

(ii)

MnO4 + 4H+ + 3e

Account for the following :


(i)

Zn is not considered as a transition element.

(ii)

Transition metals form a large number of complexes.

(iii)

The E value for the Mn3+/Mn2+ couple is much more positive

than that for Cr3+/Cr2+ couple.


OR

56/1

13

P.T.O.

(i)

With reference to structural variability and chemical reactivity,


write the differences between lanthanoids and actinoids.

(ii)

Name a member of the lanthanoid series which is well known to


exhibit +4 oxidation state.

(iii)

Complete the following equation :


MnO4 + 8H+ + 5e

(iv)

Out of Mn3+ and Cr3+, which is more paramagnetic and why ?


(Atomic nos. : Mn = 25, Cr = 24)

30.

(a)

(b)

{ZZ A{^H$maH$m| go
(i)

HCN

(ii)

H2N OH

(iii)

VZw

NaOH

CH3CHO H$s

A{^{H$`m H$aZo na ~Zo CnmXm| H$mo {b{IE :

CH3CHO

H$s CnpW{V _|

{ZZ `m{JH$ `w_m| _| AVa {XImZo Ho$ {bE gab amgm`{ZH$ narjU {b{IE :
(i)

~OmoBH$ Ab Ama \$sZmb

(ii)

monoZb Ama monoZmoZ

3, 2

AWdm
(a)

(b)

(c)

{ZZ Ho$ H$maU {b{IE

(i)

CH3COOH H$s

VwbZm _| Cl CH2COOH A{YH$ ~b Ab h &

(ii)

H$m~m}pg{bH$ Ab H$m~m}{Zb g_yh H$s A{^{H$`mE Zht XoVo &

{ZZ Zm_ Ym[aV A{^{H$`mAm| Ho$ {bE amgm`{ZH$ g_rH$aU {b{IE


(i)

amoOoZ_wS> AnM`Z

(ii)

H${ZOmamo A{^{H$`m

CH3CH2 CO CH2 CH3

H$mZ Am`moS>mo\$m_ narjU XoVm h


56/1

Ama

CH3CH2 CH2 CO CH3

_| go
2, 2, 1

14

(a)

(b)

Write the products formed when CH3CHO reacts with the


following reagents :
(i)

HCN

(ii)

H2N OH

(iii)

CH3CHO in the presence of dilute NaOH

Give simple chemical tests to distinguish between the following


pairs of compounds :
(i)

Benzoic acid and Phenol

(ii)

Propanal and Propanone


OR

(a)

(b)

(c)

Account for the following :


(i)

Cl CH2COOH is a stronger acid than CH3COOH.

(ii)

Carboxylic acids do not give reactions of carbonyl group.

Write the chemical equations to illustrate the following name


reactions :
(i)

Rosenmund reduction

(ii)

Cannizzaros reaction

Out of CH3CH2 CO CH2 CH3 and CH3CH2 CH2 CO CH3,


which gives iodoform test ?

56/1

15

P.T.O.