Nitrogen Foams
Applications & Calculations
Lesson Objectives
In this chapter the student will learn:
Lesson Introduction
Background of Foam in the Oilfield
Foams are being used in a number of petroleum industry
applications that exploit the foams' high viscosity and low liquid
content. Some of the earliest applications for foam dealt with its use
as a displacing agent in porous media and as a drilling fluid.
Following these early applications, foam was introduced as a
wellbore circulating fluid for cleanout and workover applications.
In the mid-1970s, nitrogen-based foams became popular for both
hydraulic fracturing and fracture acidizing stimulation treatments.
In the late 1970s and early 1980s, foamed cementing became a
viable service, as did foamed gravel packing.
The early widespread use of foams as fracturing fluids was to help
low-pressure gas reservoirs in returning the liquid phase of the
Foam Rheology
The viscosity of a fracturing fluid is important because of its
influence in creating fracture geometry and in transporting
proppant. Adding linear polymers or crosslinked polymers to
water increases its viscosity. Viscosity of the fluid mixture is also
increased by adding nitrogen gas to create an internal phase (gas
bubbles), when a stabilizing surfactant (foaming agent) is present.
High-viscosity foam fluids can be prepared using low amounts of
water and gelling agents, thereby minimizing the liquid load
placed on a formation.
Foam viscosity depends on a number of variables, including
quality, viscosity of the external phase, and texture. The most
important parameter is foam qualitythe percent volume occupied
by the internal gas phase. Since gas volume is a function of
temperature and pressure, downhole conditions must be known.
As quality increases, foam viscosity increases. In addition, the yield
point characteristics of foams are an exponential function of
quality.
Higher quality foams have better transport properties, particularly
at very low shear rates, because of high yield points. The viscous
character of the external liquid phase is also a major parameter.
Flow of high-quality foam may be visualized as gas bubbles sliding
past one another on thin films of the liquid external phase. If the
liquid film contains a viscosifying agent, then the bubbles will
undergo greater drag forces because of the viscous thin films, and
flow will be more difficult, resulting in higher bulk viscosity.
Texture, or the bubble size distribution, plays an important but
lesser role in determining foam viscosity. Foams exposed to shear
for a sufficient time will equilibrate to a bubble size distribution
that is characteristic of that shear rate. Texture is also influenced by
Terminology
Q - Quality - This term is used mainly when foaming a fluid. This like VLR has no units
due to being a comparison of the total mixture to just one additive (gas) in the mixture. It
differs from VLR in that the mixture is in the bottom part of the equation rather than the
top. Due to this, the Quality will always be less than one. The Tables in section III of the
Nitrogen Data for Oil Well Servicing manual uses Q. It can also be calculated using the
Tables in section VI.
Foamed Acid
As oil and gas wells age, many of them show similar
characteristics. One of the most obvious is, of course, reduced
bottomhole pressure that can contribute to the formation of
paraffins, asphaltenes, and scales. Many old wells have had
repeated acid treatments. Following conventional acid treatments,
large amounts of insoluble fines such as quartz, gypsum, and
feldspars may reduce fracture conductivity. All of these factors
related to old wells can be controlled through foamed acid
stimulation.
Treating wells with characteristics as outlined above with a
conventional nonfoamed acid treatment will probably be
beneficial. However, the high liquid content of conventional fluids
may increase clay problems. Also, low viscosity of the spent acid
may leave a large amount of insoluble fines in the well. In
addition, low bottomhole pressure may require swabbing to clean
up the well.
Nitrogen (nitrogen) is the most widely used material in foam
treatments. Volumetric gas content (foam quality) is generally
between 65 and 85% (comprising 65 to 85% gas and only 15 to 35%
liquid), although qualities as high as 95% have been used. The
liquid phase of the foam may contain 0.5 to 1.0% surfactant and 0.4
to 1.0% inhibitor.
W
(1 Q)
Problem 1
Given:
W= 95 bbl Acid
Q=0.80 (80 Quality)
Find:
Solution:
95
(1 0. 80 )
95
0. 20
Problem 2
Given:
Find:
Problem 3
Given: V = 600 bbl Foam
Q = 0.75 (75 Quality)
Find: Volume of Water Needed
Solution:
Problem 4
Given: V = 1000 bbl Foam
Q = 0.65 (65 Quality)
Find: Volume of Water Needed
=Q
= Rf (in BPM)
= (Rf) x (1 - Q)
Problem 5
Given:
Rf = 24 BPM
Q = 0.75 (75 Quality)
Find:
Rate of Water
Solution:
Rate of Water =
Problem 6
Given:
Rf = 40 BPM
Q = 0.85 (85 Quality)
Find:
Rate of Water
A customer has called in a foamed acid job. He would like to pump 238
bbl of 80 Quality foamed acid into a reservoir with a BHTP of 2800 psi
at 6000 ft.
Find:
Solution:
Problem 8
Given:
A customer has called in a foamed acid job. He would like to pump 900
bbl of foamed acid at 10 bpm foam rate. The BHTP is 3600 psi and the
temperature at the perfs is 100F. Note: Cannot use Pg. 11 in Nitrogen
Data for Oil Well Servicing book due to temperature is not 80F.
Find:
Volume of acid and nitrogen and the pump rates for the acid and
nitrogen.
10
EXAMPLE TABLE
GAS-LIQUID RATIOS FOR FOAMED FLUIDS
Temperature = 80
Quality
60
65
70
75
80
85
90
250
300
350
400
450
149
177
205
233
261
184
219
254
289
323
231
275
319
363
406
297
354
410
466
522
397
472
547
621
696
562
668
774
880
987
892
1061
1230
1398
1567
500
600
700
800
900
289
345
402
458
514
358
428
497
567
636
450
537
625
712
800
578
691
803
916
1028
771
921
1071
1221
1371
1093
1305
1517
1730
1942
1735
2073
2410
2747
3084
1000
1200
1400
1600
1800
570
683
795
899
1005
706
845
984
1113
1244
887
1062
1237
1399
1563
1140
1365
1590
1798
2010
1521
1820
2120
2398
2680
2154
2579
3003
3397
3796
3421
4096
4770
5395
6030
2000
2200
2400
2600
2800
1108
1209
1307
1408
1503
1372
1497
1618
1744
1861
1724
1881
2032
2191
2338
2217
2418
2613
2817
3006
2956
3224
3484
3756
4007
4187
4567
4936
5321
5677
6650
7254
7839
8450
9017
3000
3200
3400
3600
3800
1594
1683
1769
1853
1933
1974
2084
2191
2294
2393
2480
2619
2752
2882
3006
3189
3367
3539
3705
3865
4252
4489
4718
4940
5154
6024
6359
6685
6999
7301
9567
10100
10617
11115
11596
4000
4200
4400
4600
4800
2010
2092
2166
2239
2303
2488
2590
2682
2772
2852
3126
3254
3370
3483
3583
4020
4184
4333
4479
4606
5359
5578
5777
5972
6142
7592
7902
8184
8460
8701
12059
12551
12999
13436
13819
5000
5500
6000
6500
7000
2370
2527
2671
2803
2932
2934
3129
3307
3471
3630
3686
3931
4155
4361
4561
4740
5054
5343
5607
5864
6319
6738
7123
7475
7819
8953
9546
10092
10590
11077
14219
15161
16028
16820
17592
7500
8000
8500
9000
9500
3048
3157
3257
3356
3446
3774
3908
4032
4155
4267
4742
4911
5066
5220
5361
6097
6314
6514
6711
6892
8129
8418
8685
8948
9190
11516
11926
12304
12677
13019
18291
18941
19541
20134
20677
10000
10500
11000
11500
12000
3531
3613
3690
3763
3834
4371
4473
4569
4659
4747
5492
5621
5740
5853
5964
7061
7226
7381
7525
7668
9415
9635
9841
10034
10224
13338
13650
13941
14214
14484
21184
21679
22142
22576
23004
EXAMPLE TABLE
11
GAS-LIQUID RATIOS FOR FOAMED FLUIDS
Temperature = 100
Quality
60
65
70
75
80
85
90
250
300
350
400
450
143
171
198
225
252
178
211
245
278
312
223
265
307
350
392
287
341
395
449
504
382
455
527
599
672
542
644
747
849
951
861
1023
1186
1348
1511
500
600
700
800
900
279
333
387
441
496
345
412
480
547
614
434
518
602
687
771
558
666
775
883
991
744
888
1033
1177
1322
1054
1258
1463
1668
1873
1673
1999
2324
2649
2974
1000
1200
1400
1600
1800
550
658
758
861
962
681
815
939
1066
1191
855
1024
1180
1340
1496
1100
1316
1517
1722
1924
1466
1755
2022
2296
2565
2077
2487
2865
3253
3634
3299
3949
4550
5167
5772
2000
2200
2400
2600
2800
1061
1157
1250
1349
1439
1313
1432
1547
1670
1782
1650
1799
1944
2098
2239
2121
2313
2500
2697
2878
2828
3084
3333
3596
3838
4007
4370
4722
5094
5437
6364
6940
7499
8091
8635
3000
3200
3400
3600
3800
1527
1613
1696
1777
1854
1891
1997
2100
2200
2296
2376
2509
2638
2764
2885
3055
3226
3392
3553
3709
4073
4301
4523
4738
4945
5770
6094
6408
6712
7005
9164
9678
10177
10660
11126
4000
4200
4400
4600
4800
1929
2009
2081
2152
2216
2389
2487
2577
2665
2743
3001
3125
3238
3348
3447
3859
4018
4163
4305
4432
5145
5357
5550
5740
5909
7289
7589
7863
8131
8371
11577
12053
12489
12914
13295
5000
5500
6000
6500
7000
2281
2436
2579
2711
2838
2824
3016
3193
3356
3513
3548
3789
4012
4217
4414
4562
4872
5158
5422
5675
6083
6496
6877
7229
7567
8618
9202
9743
10241
10720
13687
14615
15474
16265
17026
7500
8000
8500
9000
9500
2954
3063
3164
3262
3353
3657
3792
3917
4038
4151
4595
4764
4922
5074
5215
5908
6125
6328
6523
6705
7877
8167
8438
8698
8940
11159
11570
11953
12321
12665
17723
18375
18985
19569
20116
10000
10500
11000
11500
12000
3439
3519
3599
3673
3743
4257
4357
4455
4547
4634
5349
5475
5598
5713
5822
6877
7039
7197
7345
7486
9170
9385
9596
9794
9981
12990
13296
13595
13875
14140
20632
21117
21591
22036
22457
12
Foam Diversion
In most cases, formations will be comprised of zones possessing
different permeabilities or zones that may have sustained differing
degrees of damage during drilling, completion, or workover
operations. When acidizing treatments are performed on such
formations, the treating fluids naturally enter the zones that
present the least resistance to flow. This can result in placing the
acid in zones that require the least stimulation.
Diversion can be used to alter the fluid injection profile of a
treatment. Because fluids will choose the path of least resistance,
diversion is primarily a resistance problem; the goal is to alter
injection rate per unit of area so that all zones accept the proper
proportion of the treatment. Reservoir properties that can vary the
injection rate per unit of area are permeability, differential
pressure, and length; if these properties are not in the correct
proportion, diversion should be considered. This disproportion
can result from the following:
zones having differing permeabilities
zones having differing formation pressures
zones containing fluids with different compressibility
zones containing fluids with different viscosity
zones having natural fractures
A goal of acid treatment is to cause zones of similar permeability to
produce at higher rates by increasing the permeability in the
critical near-wellbore area. Diversion helps reach this goal by
forcing acid into damaged areas to allow the entire zone (assuming
near equal permeability distribution) to be productive.
Diverting Agents
Diverting agents have been used in stimulation treatments for
years to help ensure treatment distribution over the entire
perforated interval. In order to provide uniform placement of the
reacting fluids across the entire perforated interval, diverting
agents such as insoluble sand, benzoic acid flakes, solid organic
acids, deformable solids, mixtures of waxes and oil-soluble
polymers, acid-swellable polymers, and mixtures of inert solids
(silica flour, calcium carbonate, rock salt, oil-soluble resins, etc.) are
frequently used to form temporary filter cakes on the higher
13
14
recovery. Usually, even in low pressure reservoirs, the need for swabbing is
eliminated. And the well will clean up much faster. In fact, cleanup times often
are measured in hours rather than weeks.
Foam Frac design programs are available to optimize results and establish the
treatment parameters.
Foam Fracturing w/ Constant Internal Phase
The addition of a proppant to a foam fluid has a greater effect on viscosity than
conventional frac systems. The proppant, in effect, increases the quality of the
system, which increases both viscosity and friction pressure. In a constant
internal phase foam, the volume of nitrogen gas is decreased by the volume of
proppant added. As a result the slurry stays similar to the pad fluid.
Concept
Fluid A is a conventional foam pad fluid (no proppant) containing a fixed volume
of gas and liquid. Fluid B is a proppant-laden fluid with solid added while gas
and liquid volumes are held constant. During a fracturing treatment, these
volumes are pumped in a given time, so the ratios also relate to pumping rates.
The volume of internal phase (gas plus solid) in Fluid B is greater than that of
fluid A, although the liquid is constant, and would result in higher viscosity and a
higher downstream rate. This condition has often led to excessive friction losses
higher wellhead pressures, and premature job termination. An attempt to reduce
solid, liquid, and gas rates proportionally to make the downstream rate the same
as the pad does not solve the overall problem. Although the ratios in Fluid C are
the same as in Fluid B, the internal phase ratio of Fluid C is higher than that of
Fluid A, so the viscosity of Fluid C is higher that that of Fluid A and will give
15
A solution has been proposed to keep both downstream flow rate and viscosity
constant. When solid proppant is added, a constant liquid rate should be
maintained, but the gas flow rate should decrease sufficiently to equal the
absolute solid flow rate. Application of the constant-internal-phase concept has
allowed much better control of foam fracturing treatments down small tubing.
16
Foam Cement
There have always been areas in which weak zones can support
only a limited height of a normal-density (11 to 18 lb/gal) cement
column without breaking down. Foam cement provides a means of
preparing 4 to 15 lb/gal cementing slurries that develop relatively
high compressive strengths in a minimum period of time, even at
low formation temperatures.
The use of foamed cement offers a low-density slurry that
develops relatively high compressive strengths and low
permeabilities
protects water-sensitive clay, shale, and salt formations
can control high-volume water flow in weak formations, when
mixed as a quick-set formula
enhances protection against annular gas invasion
is economically competitive
can be used from 28 to 600F
Halliburton Foam Cement is a stabilized system consisting of
cement with carefully chosen additives, a foam stabilizer, a gas
(usually nitrogen), and water. Success of foam cement comes from
the ability to maintain cement slurry density below the hydrostatic
breakdown of sensitive formations, which prevents lost circulation
and fallback problems. This density control flexibility allows a
wide latitude in designing the overall job before it is actually run in
the field. Appropriate computer-assisted programs are used for
prejob planning. If necessary, one can choose to change the density
as the pressure and circulation events vary during job execution.
To prepare a stable foam cement, the slurry should be conveyed
through an effective mechanical foam generating device that
imparts sufficient energy and mixing action with pressurized gas
to prepare uniform gas bubbles of the correct size. In nearly all
17
Foam Generators
The success of many foam treatments is dependent on the foam having the properties
that it was designed for. To ensure a stable foam with good texture, a foam generator
is recommended.
Foam Cements.
Oil Based Stimulation Fluids.
Fluids w/ Blends of Alcohol / Methanol / Toluene / Xylene / condensate /
diesel etc.
High Linear Based Gel Systems.
Rapid Crosslinked Gel Systems.
Low Rate Pumping Jobs (Matrix Aciding) & Acid Foam Diversions.
Customer Request.
When in Doubt About Performance of Surfactant.
Pumping Down Large Casing Strings.
Given:
N2 Pump Rate
1,000 scf/min
Expected WHP
5,000 psi
800 psi
18
Solution:
Q
Gas Density
Solve
Q=
D=
V
/V =
P =
Gas Density =
1,000 scf/min =
1,000 scf/min =
.0224 =
.15
=
/V
1,000 scf/min
?
1580 scf/bbl
800 psi
2.7
1.64 (D2)(1580 scf/bbl) 800/2.7
(D2) 44,603
D2
D
19
For 0 to 40-lb water gel and acid foams with 600 psi nitrogen
pressure loss, use Figure 18-2.
For 40 to 80-lb water gel and oil foams with 1,200 psi nitrogen
pressure loss, use Figure 18-3.
20
Fig. 18-2: Nozzle sizes for 0 to 40-lb water gel and acid foams with 600 psi nitrogen pressure
loss.
21
Double valve arrangement close to the wellhead & as close to the ground as
possible. Remote valve recommended.
Stay upwind of well when flowing back.
Use a Perfball Catcher in the line when Perfballs are used.
(Pressure) (Area)
(Force) (Length)
Area Sq.
3.14
7.07
7.07
7.07
12.56
Pressure
5,000
5,000
5,000
10,000
10,000
Force
15,700
35,350
35,350
70,700
125,600
Length
5
5
10
10
10
Fig. 18-2: Nozzle sizes for 40 to 80-lb water gel and acid foams with 1,200 psi nitrogen pressure
loss.
Torque
78,500
176,750
353,500
707,000
1,256,000
22
Computer Programs
Stimulation
StimWin - This is a Windows based program which allows you to plug in a few
numbers and get back results without having to interpolate off charts and graphs. The
program runs on a 386 DX PC with at least 8 mgs of memory. Instructions to get into
the program are: Click the StimWin GUI, click APP, then Nitrogen Calculations. Under
calculate, click Foam Quality & Density.. Fill in the Black & Pink lines & read the
results givin in the Blue lines. Foam schedules for fracturing applications can also be
determined by clicking foam schedules after clicking App.
PROP TPHASE -
Washing
FoamUP -
Simulates a foam cleanout job when washing varies types of debris out
of vertical & horizontal holes.
Cementing
CJOBSIM FMCEM -
---------------------------------------------------------------------------------------
23
b.
--------------------------------------------------------------------------------------
c.
--------------------------------------------------------------------------------------
d.
--------------------------------------------------------------------------------------
e.
-------------------------------------------------------------------------------------
f.
--------------------------------------------------------------------------------------
4.
60 Q, 70 Q, 80 Q. ------
5.
24
Lesson Summary
We initially discussed what foam is and what are the advantages of using
foamed fluids. We found by adding a larger percentage of nitrogen and a
surfactant to the base liquid we could get a fluid which has a low density and a
high viscosity. In doing so we need to make sure enough energy is imparted
into the system by shearing through high velocities or a foam generator.
A fluid once foamed has many added benefits. In stimulating a reservoir it
allows us could fluid loss properties, improved cleanups, and excellent proppant
carrying characteristics. In wells were there is concern about loosing fluids in a
zone downhole, nitrogen foams can be utilized to circulate out debris or in doing
primary or secondary cementing jobs.