TEST
CLASS XII
QA. Complete the reaction
1. Ca3P2 + H2O
2. P4 + SOCl2
3. PCl3 + H2O
4. PCl5 + H2O
5. HgCl2 + PH3
6. CuSO4 + PH3
7. PH4I + KOH
8. C2H5OH + PCl5
9. Al2O3 + NaOH
10. Se2Cl2
11. H3PO3
12. AgNO3 + H2O + H3PO2
13. I + H2O + O3 14. Fe3+ + SO2 + H2O 15. SO2 + MnO4 + H2O 16. Cu + H2SO4 conc.
17. S + H2SO4 conc. 18. CaF2 + H2SO4
19. KMnO4 + HCl
20. MnO2 + HCl
21. C10H16 + Cl2
22. NH3 excess + Cl2
23. NH3 + Cl2 excess
24. NaOH(hot conc.) + Cl2
25. complete hydrolysis of XeF6.
QB. Guess what it could be ?
1. colourless solid compound of Xe(explosive solid) 2. compound of 18th group element used in tracer technique
3. compound formed by the hydrolysis of inter halogen compound
4. it dissolves noble metals
5. a compound on reaction with NH3 gives white fumes
6. poisonous gases (3) formed from bleaching powder
7. prepared by deacons process
8. gas discovered by Scheele
9. an element (non metal) does not from any oxoacid
10. greenish yellow gas soluble in water
QC. Answer in one word / one line ( give reason)
1. halogens are coloured 2. which hydrogen halide does not give any ppt. with AgNO3
3. perchloric acid (HClO4) is more strong acid than H2SO4 . Why ? 4. iso electronic species (neutral) for ClO
5. H2SO4, CaCl2 and P2O5 not used for drying NH3. Why ? 6. compound used as dehydrating agent for NH3
7.where do we use Bosch process and cynamide process 8. allotropes of oxygen
9. I2 soluble in KI but not in water
10. sulphur disappears on boiling with aqueous solution of sodium sulphite
QD. Draw the shapes of
1. XeO3
2. XeOF4
3. SF4
4. IF7
5. ClF3
6. IF5
7. NCl3
8. NO2
9. XeOF2
10. XeO2F2 11. HClO
12. ClO4 13. H2SO4
14. NHO3
15. S6 and S8.
P BLOCK
TEST
CLASS XII
QA. Complete the reaction
1. Ca3P2 + H2O
2. P4 + SOCl2
3. PCl3 + H2O
4. PCl5 + H2O
5. HgCl2 + PH3
6. CuSO4 + PH3
7. PH4I + KOH
8. C2H5OH + PCl5
9. Al2O3 + NaOH
10. Se2Cl2
11. H3PO3
12. AgNO3 + H2O + H3PO2
3+
13. I + H2O + O3 14. Fe + SO2 + H2O 15. SO2 + MnO4 + H2O 16. Cu + H2SO4 conc.
17. S + H2SO4 conc. 18. CaF2 + H2SO4
19. KMnO4 + HCl
20. MnO2 + HCl
21. C10H16 + Cl2
22. NH3 excess + Cl2
23. NH3 + Cl2 excess
24. NaOH(hot conc.) + Cl2
25. complete hydrolysis of XeF6.
QB. Guess what it could be ?
1. colourless solid compound of Xe(explosive solid) 2. compound of 18th group element used in tracer technique
3. compound formed by the hydrolysis of inter halogen compound
4. it dissolves noble metals
5. a compound on reaction with NH3 gives white fumes
6. poisonous gases (3) formed from bleaching powder
7. prepared by deacons process
8. gas discovered by Scheele
9. an element (non metal) does not from any oxoacid
10. greenish yellow gas soluble in water
QC. Answer in one word / one line ( give reason)
1. halogens are coloured 2. which hydrogen halide does not give any ppt. with AgNO3
3. perchloric acid (HClO4) is more strong acid than H2SO4 . Why ? 4. iso electronic species (neutral) for ClO
5. H2SO4, CaCl2 and P2O5 not used for drying NH3. Why ? 6. compound used as dehydrating agent for NH3
7.where do we use Bosch process and cynamide process 8. allotropes of oxygen
9. I2 soluble in KI but not in water
10. sulphur disappears on boiling with aqueous solution of sodium sulphite
QD. Draw the shapes of
1. XeO3
2. XeOF4
3. SF4
4. IF7
5. ClF3
6. IF5
7. NCl3
8. NO2
9. XeOF2
10. XeO2F2 11. HClO
12. ClO4 13. H2SO4
14. NHO3
15. S6 and S8.
NUMERICALS
XII
TEST
Q1.When current of 0.75 A is passed through a CuSO4 solution for 25 min. 0.369 g of copper is deposited at cathode.
Calculate atomic mass of Cu.
Q2. The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500. What is the cell
constant . If the conductivity of 0.001M KCl solution at 298 K is 0.146 x 103 s cm1.
Q3. Heptane and octane form ideal solutions. At 373 K the vapour pressure of the two liquid compounds are
105.2 Kpa and 46.8 Kpa respectively. What will be the vapour pressure , in bar, of a mixture of 25.0g heptane
and 35g of octane.
Q4. The edge length of the unit cell is 408pm . Its density is 10.6g/cc. Predict whether the metal X is body centered
or face centered or simple cube. (molar mass of metal = 107.9 mol1, NA = 6.023 x 1023)
Q5. The vapour pressure of pure water at 373 K is 760mm Hg. While that of a dilute solution of glucose is 750 mm
of Hg at the same temperature. Calculate the mole fraction of solute and molality of the solution.
Q6. The reaction SO2Cl2 === SO2 + Cl2 is first order reaction with K = 2.2 x 105 S1 at 575 K. What percentage of
SO2Cl2 will get decomposed in 80 min. When the reaction is carried out at 575 K.
Q7. The following experiment data was collected for the reaction Cl2 + 2NO 2NOCl
experiment
[Cl]
[NO]
initial rate
1
0.01
0.01
1.2 x 104
2
0.01
0.03
10.8 x 104
3
0.02
0.03
21.6 x 104
Construct the rate law equation.
1
Q8. The molar conductivity of 0.025 mol L methanoic acid is 46.1 S cm2 mol1. Calculate its degree of dissociation
and dissociation constant. Given m (H+) = m(HCOO) = 54.6 S cm2 mol1.
Q9. Calculate E.M.F. of the cell in which the following reaction takes place
Ni(s) + 2Ag+(0.002M) Ni2+(0.15) + 2Ag(s)
E0 cell is 1.05 V.
Q10. Calculate equilibrium constant of the reaction Cu(s) + 2Ag+(aq) Cu2+(aq) + 2Ag(s) E0cell = 0.46 V.
Q11. For the reaction 2A + B + C A2B + C The rate = K[A][B]2 with K = 2.0 x 106M2S2. Calculate the
initial rate of the reaction when [A] = 0.1M, [B] = 0.2M and [C] = 0.8M. If the rate of reverse reaction is
negligible then calculate the rate of reaction after [A] is reduced to 0.06M.
NUMERICALS
XII
TEST
Q1.When current of 0.75 A is passed through a CuSO4 solution for 25 min. 0.369 g of copper is deposited at cathode.
Calculate atomic mass of Cu.
Q2. The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500. What is the cell
constant . If the conductivity of 0.001M KCl solution at 298 K is 0.146 x 103 s cm1.
Q3. Heptane and octane form ideal solutions. At 373 K the vapour pressure of the two liquid compounds are
105.2 Kpa and 46.8 Kpa respectively. What will be the vapour pressure , in bar, of a mixture of 25.0g heptane
and 35g of octane.
Q4. The edge length of the unit cell is 408pm . Its density is 10.6g/cc. Predict whether the metal X is body centered
or face centered or simple cube. (molar mass of metal = 107.9 mol1, NA = 6.023 x 1023)
Q5. The vapour pressure of pure water at 373 K is 760mm Hg. While that of a dilute solution of glucose is 750 mm
of Hg at the same temperature. Calculate the mole fraction of solute and molality of the solution.
Q6. The reaction SO2Cl2 === SO2 + Cl2 is first order reaction with K = 2.2 x 105 S1 at 575 K. What percentage of
SO2Cl2 will get decomposed in 80 min. When the reaction is carried out at 575 K.
Q7. The following experiment data was collected for the reaction Cl2 + 2NO 2NOCl
experiment
[Cl]
[NO]
initial rate
1
0.01
0.01
1.2 x 104
2
0.01
0.03
10.8 x 104
3
0.02
0.03
21.6 x 104
Construct the rate law equation.
1
Q8. The molar conductivity of 0.025 mol L methanoic acid is 46.1 S cm2 mol1. Calculate its degree of dissociation
and dissociation constant. Given m (H+) = m(HCOO) = 54.6 S cm2 mol1.
Q9. Calculate E.M.F. of the cell in which the following reaction takes place
inorganic
1. Ores 2. minerals 3. Gangue 4. metallurgy 5. Flux
6 . Slag 7. Depressant in metallurgy 8. Zeolite
9. Ligand 10. smelting 11. chromatography 12. Enthalpy of atomization
13. Disproportionation reaction
14. Inter halogen compounds 15. Lanthanide contraction 16. Homoleptic complex 17. Hetroleptic complex
CLASS XII
Q1. Convert :- (a) anisol to phenol (b) acetone into ter.butyl alcohol (c) ethylene into propanoic acid
Q2. Write short notes on
(a) Clemmensens reduction (b) Wolf Kishner (c) Rosenmund (d) Reimer Tiemann
(e) coupling
(f) Gattermann
(g) aldol condensation.
Q3. Identify the unknown
P / I2
Mg
(i) HCHO (ii) HO / H+
(a) CH3CH2OH
A
B
C
HI
aq.KOH
I2 / NaOH
(b) CH2=CH2
A
B
C
H2SO4 / 443K
HBr
aq.KOH
(c) CH3CH2CH2OH
A
B
C
NH3
P2O5 /
(d) RCOOH
A
B
C
NH4OH
Br2 / KOH
(e) RCOOH
A
B
C
P / I2
AgNO2
reduction
CH3Cl
(f) CH3OH
A
B
C
D.
Q4. How will you distinguish between
(a) methanol and ethanol
(b) acetaldehyde and acetone
(c) phenol and benzyl alcohol
Q5. Identify the unknown
(a) CH2Cl
CH2NO2
CH2NC
?
Sn /HCl
NaOH / H2O /
O
O
?
O
?
KOH / Br2
?
(b)
NO2
Sn / HCl
O
Br2 excess
?
H3PO2 / H2O
?
KOH / Br2
?
conc. HNO3/conc. H2SO4
(c)
A
Sn / HCl /
CHCl2 + KOH /
H2 / Pt
D
F
NHCOCH3
O
(d)
Cl2 / Fe+++
conc. HNO3/conc.H2SO4
O
(e)
?
[O]
HCHO
Sn / HCl
?
CH3COOH / MnO2 /
+ CH3COOH
NaNO2 + HCl/273K
?
I2 / NaOH
?
Ag powder
?
CuCl + HCl
?
ALL DEFINITIONS
1. Mole 2. molarity
3. molality
4, normality
5. element
6. mixture 7 compound
8. Law of conservation of mass 9. Law of constant composition 10. Law of multiple proportion
11. Law of reciprocal proportion 12. Gay Lussac law of combining volume 13. Daltons law of partial pressure
14. Avogadros law 15. Boyles law 16. Charles law 17. Grahms law of diffusion 18. Empirical formula
19. Molecular formula 20. dipole moment 21. isotopes 22. isobars 23. isotones 24. photoelectric effect
25.
Hunds rule of maximum multiplicity
26. Heisenbergs uncertainty principle 27. Paulis exclusion principle 28.
degenerated orbitals 29. Aufbaus principle 30. Mendeleevs periodic law 31. modern periodic law
32. diagonal relationship 32. Ionization enthalpy
33. Inert pair effect
34. electron affinity
35. isoelectronic species
36. screening effect
37. electronegativity 38. electrovalent bonding
39. covalent bonding
40. valency
41. lattice enthalpy 42. boiling point
43. hydration enthalphy
44. bond dissociation energy 45. dative bond 46. Lewis acid
47. Lewis base 48. bond order
49. hybridization
50. hydrogen bonding 51. enthalpy of neutralization
52. enthalpy of sublimation
53. enthalpy of combustion 54. entropy
55. free energy
56. first law , zeroth, second law and third law of
thermodynamics
57. surface tension 58. viscosity 59. critical temperature 60. vapour pressure
61. Le- Chateliers principle 62. extensive properties
63. state functions
64. isothermal process
65. adiabatic process
66. isobaric system 67. isochoric system 68. internal energy
69. molar heat capacity 70. Hesss law
71. Henrys law 72. Ostwalds dilution law 73. pH
74. buffer solution 75.common ion effect 76. solubility product 77. Disproportionation reaction
78. redox reaction 79. decomposition displacement
80. electrochemical series 81. oxidizing agent
82. reducing agent
83. resonance
84. law of mass action
NUMERICALS
ASSIGNMENT FOR REVISION
CLASS XI
Q1. Calculate the number of significant numbers in 0.0000000420.
[Ans. 3]
Q2. Carbon and oxygen forms two compounds . The first compound contained 42.9 % C. While the other
has 72.7% O. Show that this data is the aggrement with the law of multiple proportion.
[Ans. the ratio of mass of C combining with fixed mass of O is 2:1 which is a simple ratio.]
Q3. Calculate the mass of one atom of hydrogen.
[Ans. 1.66 x 10 24 g.]
Q4. Calculate the number of atoms and volume of 1 gm He gas at NTP.
[Ans. 5.6 litre (NTP)]
Q5. Calculate the total number of electrons in 1.6 gm methane.
[Ans. 6.02 x 1023 electrons]
Q6. What weight of sulphur has as many atoms as in 3 gm of carbon ?
[Ans. 8.0 gm]
Q7. Calculate total number of atoms in 18 gm H2O.
[Ans. 18.06 x 1023 atoms]
Q8. Calculate the number of Cl1 ions in 111 gm anhydrous CaCl2.
[Ans. 12.04 x 1023 Cl]
Q9. Calculate the number of oxalic acid molecules in 100 ml 0.02 N oxalic acid.
[Ans. 6.02 x 1020 mol]
Q10. What is the weight of one molecule of a compound C60H122 ?
[1.4 x 10 21gm]
Q11. The composition of a compound is : Ca = 25.3%, P = 39.2 % and O = 35.5 % . What is the molecular
mass of the compound ?
[ Ans. 216]
Q12. How much chlorine is required to evolve out 1.6 gm of bromine from KBr ?
[Ans. 0.71 gm]
Q13. 24 gm of sodium sulphate was dissolved in water and BaCl2 solution mixed in it. What substance
will be precipitated and what will be its mass ?
[Ans. BaSO4, 39.3 gm]
Q14. Yellow light emitted from a sodium lamp has a wavelength of 580 nm. Calculate the frequency and
wave number of this light.
[Ans. frequency =5.17 x 1014 s 1 wave number = 1.72 x 106 m1]
Q15. The e energy of the ground state of H atom works out to be 1.312 x 106 J mol 1. What change will
occur in the position of the e in this atom if an energy of 9.84 x 105 J mol1 is added to the H atom ?
[Ans. electron transition occurs from n = 1 to n = 2 level]
Q16. Calculate the wavelength and energy of radiation emitted for the electronic transition from infinity ()
temperature.
[Ans. 1 x 1010]
Q39.The solubility product of a salt MX2 in water is 4 x 1012. What is the concentration of M2+ ions in the
aq. solution of the salt ?
[Ans. 1 x 104 M]
Q40. The solubility product of AgCl is 1 x 1010. Calculate the solubility of AgCl in mol/L [Ans. 1 x 105]
Q41. What will be the pH of 0.1 N HCl ?
[Ans. 1]
+
TEST
FULL PHYSICAL 2013
Q1. The normal B.P of methanol is 640C and its standard enthalpy of vaporization is 38KJ/mol . calculate vapS for this liquid.
Q2. What will be the sign of S, (+ve) or (ve) or zero for the following reactions
Cu2+(aq) + 4NH3(aq) [Cu(NH3)4]2+(aq) (b) Ca(OH)2 (s) + CO2(g) CaCO3(s) + H2O(g)
(a)
Q3. Calculate the enthalpy of formation of acetylene from the following information
(a) 2C2H2(g) + 5O2(g) 4CO2(g) + 2H2O(l) H0 = 2600KJ (b) C(s) + O2(g) CO2(g) H0 = 394KJ
(c) 2H2(g) + O2(g) 2H2O(g) H0 = 484 KJ
(d) H2O(l) H2O(g) H = +44KJ.
Q4. Calculate the number of atoms and volume of 1 gm He gas at NTP.
Q5. The volume of a gas at 750 mm pressure is 25 L. If the pressure is increased to 800 mm, what would
be the new volume , temperature remaining constant ?
Q6. How much chlorine is required to evolve out 1.6 gm of bromine from KBr ?
Q7. What type of forces of attraction are present between the pair of compounds given:(a) NH3 and water (b) CF3 and CH4 (c) HCl and HCl (d) NO3- and I2.
Q8. An atomic orbital has n=3. What are the possible values of l.
Q9. States physical significance of 2.
Q10What is disproportionation reaction ?
Q11. Write electronic configuration of Fe+++ and Fe++ . Compare their magnetic property.
Q12. Indicate the number of unpaired electrons in Cr and Kr.
Q13. Which of the following have higher ionization energy (i) Kr , Xe
(ii) I , I .
Q14. Arrange the following in increasing order (a) F,Cl,Br,I (electron affinity) (b) Br+, Br and Br (atomic size).
Q15. Out of NH3 and NF3 which has higher dipole moment and why ?
Q16. H2O and CO2 both are triatomic but CO2 is linear and H2O is bent . Why ?
Q17. Predict the sign of entropy in the following (a) a liquid crystallizes into solid (b) 2NaHCO 3 (s) Na2CO3(s) + CO2 + H2O(g)
Q18. Under what conditions H and U become equal.
Q19. How is G related to (i) equilibrium constant (ii) e.m.f. of a cell.
Q20. What is the effect of temperature on an exothermic reaction for which S is negative
Q21. Prove that heat change measured at constant volume is the measure of initial energy.
Q22. How many and bonds are present in toluene.
Q23. Write position of an element with at. no. = 53 in periodic table.
Q24. Out of NH3 and N2 which one will have higher value of a and b Vander Waals constants.
Q25.What is the effect of temperature on (a) viscosity (b) vapour pressure of a liquid
Q26. Arrange the following in decreasing order of bond energy H 2, H2+ and He2.
Q27. Plot graph between PV against P at constant T.
Q28. Answer in one word / one line
(a) drop of water is spherical . Why ?
(b) the space in an orbit where probability of finding e is zero. (c) all C C bond lengths in benzene are equal. Why ?
TEST
XI
(mole concept , atomic structure, periodic classification , bonding)
Q1. Arrange the following species in increasing order of stability. Li 2, Li+2 and Li 2. Justify with energy level diagram .
Q2. Write differences between (a) and bonds (b) VBT and MOT.
Q3. Isobutane C4H10 undergoes combustion in oxygen according to the reaction
2C4H10(g) + 13O2(g) 8CO2(g) + 10 H2O(l) When 10.0 lit of isobutene is burnt at 270C and 1 bar
pressure. Calculate the volume of CO2 produced at 800C and 1.5 bar pressure.
Q4. Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or
different ? Justify your answer.
Q5. How does dipole moment help to find out geometry of a molecule ?
Q6. Give reasons (a) BF3 is triangular coplanar but NH3 is pyramidal (b) NH3 bottle is cooled before opening the seal?
(c) N2 is inert ? (d) benzene contains 3 double bonds still it is stable and less reactive . Why ?
Q7. What is dipole moment ? Explain its one application with example.
Q8. Why is Be different from other members of the family ?
Q9. Find out the type of hybridization of Xe in XeF4 , P in PO4 3.
Q10. The mass of an electron is 9.1 x 10 31 Kg. If its K.E is 5.0 x 10 25J. Calculate its wavelength.
Q11.Draw the shapes of obitals for which l = 1, l = 2.
Q12. Why is Ne2 not possible. Explain with energy level diagram?
Q13. Write electronic configuration of Mn2+ ions? also comment on its magnetic behaviour
ORGANIC
TEST
CLASS XI
Q1. A compound of carbon, hydrogen and nitrogen contains the elements in the ratio 18:2:7. Calculate its
empirical formula. If the molecular mass is 108, what is its molecular formula.
Q2. Give a brief description of the principles of the following techniques taking an example in each case.
(a) crystallization
(b) distillation
(c) chromatography
Q3. Describe the method , which can be used to separate two compounds with different solubilities in
a solvent X.
Q4. Name a suitable technique of separation of components form a mixture of calcium sulphate and camphor.
Q5. Will CCl4 give white ppt. of AgCl on heating with silver nitrate ? Give reason for your answer.
Q6. Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens ?
Q7. 0.3780 gm of an organic compound gave 0.5740 gm of silver chloride in carius estimation . Calculate
the percentage of chlorine present in the compound.
Q8. An organic compound contains 69% carbon and 4.8% hydrogen , the remainder being oxygen. Calculate
the masses of carbon dioxide and water produced when 0.20 gm of this substance is subjected to
complete combustion.
Q9. During the test for nitrogen in Lassaignes filtrate, sometimes red colouration is obtained when ferric
chloride is added.
Q10. Suggest a method to purify
(i) kerosene oil containing water (ii) a liquid which decomposes at its boiling point
(iii) essential oil.
Q11. In an estimation by Dumas method 0.15 gm of an organic substance produced 22.5 mL of N2 collected
over KOH solution at 220C and 720 mm pressure. Calculate the percentage of nitrogen by mass in the
organic compound. [Aqueous tension at 220C = 20 mm]
Q12. Why is it necessary to use acetic acid and not sulphuric acid for acidification of sodium extract for
testing sulphur by lead acetic test ?
Q13. Why a solution of potassium hydroxide used to absorb carbon dioxide evolved during the estimation of
carbon present in an organic compound ?
ASSIGNMENT
CLASS XI
ORGANIC
Q1. Draw the structures of (a) 2-methyl-3-isopropylheptane (b) dicyclopropylmethane (c) 2-phenyl ethanoic acid .
Q2. Which of the following compound can show geometrical isomerism
(a) (CH3)2=C(CH3)2
(b) CH3CH=CHCH2CH3
(c) C6H5-CH=CHCH3 (draw).
Q3. Give IUPAC names of the products formed by addition of HBr to hex-1-ene (i) in the absence of peroxide and
in the presence of peroxide and (ii) in the presence of peroxide.
Q4. A reproductive ozonolysis of an alkene gave propanone and acetaldehyde. Give structure of alkene with its
IUPAC name.
Q5. How will you distinguish between ethane ethene and ethyne ?
Q6. (CH3)2C=CH2 + HI A. What is A ? Write its IUPAC name.
Q7. How will you convert 2-butyne into (i) cis-2-butene (ii) trans-2-butene.
Q8. Which of the two is stronger acid ethyne or propyne. Why ?
Q9. Give two reasons to show that ethyne is acidic in nature.
Q10. Convert ethyne into (a) ethanal (b) benzene.
Q11. How will you prepare (a) ethane from methane (b) ethyne from ethene (c) butane from ethane