Special Module
Multi-component absorption
S1. Introduction
In multi-component absorption, a gas mixture is contacted with a liquid solvent
to selectively dissolve more components by mass transfer from the gas to the
liquid solvent. The components transferred to the liquid are referred to as
solute or absorbate. The absorption is used to separate gas mixtures, remove
impurities from a gas or recover valuable chemicals. A typical absorption
operation is shown in Figure S1.
The gas containing air (oxygen, nitrogen and argon of 21, 78 and 1%
respectively), water vapor and acetone vapor is fed in a counter-current
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y n K n xn
(S1)
where
y = mole fraction of specified component in the gas phase,
x = mole fraction of specified component in the liquid phase,
K = vaporization equilibrium constant for specified component on plate or
stage n,
n = arbitrary theoretical plate in the absorber.
In terms of total molar flow rates of the gas and liquid, and the flow rates for
the specified component Equation (S1) can be written as
vn
l
Kn n
Vn
Ln
(S2)
Or
ln
Ln
vn
K nVn
(S3)
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An
Ln
K nVn
(S4)
equations
suitable
(S5)
for
predicting
component
distributions
in
X 'n
x n Ln
L0
(S6)
y nVn
V N 1
(S7)
and
Y 'n
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(S8)
Y ' N 1
L0 X ' N
L
Y '1 0 X ' 0
VN 1
VN 1
(S9)
Equation (S9) can be plotted as straight lines and can be used for any
absorption process. The equilibrium relationship between the gas and liquid
on the tray in terms of the new composition parameters can be written as:
Y 'n
X ' n L0 VN 1 X ' n L0 VN 1
Ln K nVn
An
(S10)
Y 'n
Y ' n 1 An 1Y ' n 1
1 An
where An Ln K nVn
(S11)
and An1 Ln1 K n1Vn1 . For a one-plate absorber
Equation (S11) is
Y '1
1 A1
1 A1
(S12)
Y '2
(S13)
By combining Equations (S12) and (S13) the material balance for a two tray
absorber can then be written as
Y1 '
A1 1Y '3 A1 L0 X '0
VN 1
A1 A2 A2 1
(S14)
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The same procedure is followed for an absorber with three plates and finally,
for absorber with N trays
Y 'N
VN 1
(S15)
(S16)
/
X 'N
AN VN 1Y ' N
L0
(S17)
Y 'N
(S18)
Y ' N 1 Y '1
A1 A2 ..... AN A2 A3 ..... AN ..... AN
Y ' N 1
A1 A2 ..... AN A2 A3 ..... AN ..... AN 1
L X ' A2 A3 ..... AN A3 A4 ..... AN ..... AN 1
0 0
V N 1Y ' N 1 A1 A2 ..... AN A2 A3 ..... AN ..... AN 1
(S19)
The Equation (S19) can be used to determine terminal stream flow rates in a
multicomponent absorber. The left side of Equation (S19) is the fractional
absorption for any component if the liquid and gas flow rates for each tray in
the column in addition to the tray is known. If an average value of the
absorption factor is assumed to be valid for each tray as A=A1=A2=..=AN,
the absorption factors in Equation (S19) can be written as
A N 1 A
A N A N 1 ......... A 2 A
A 1
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(S20)
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and
A N 1 1
A N A N 1 ......... A 2 A 1
A 1
(S21)
A N 1 A
A N 1 1
(S22)
Aavg
L0
K avgV N 1
(S23)
where Kavg is the value of the average equilibrium constant for each
component at the average temperature and pressure in the absorber.
Equation (S22) can be solved either analytically or graphically. Any variable
may be determined if the other two are known.
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