Test - 6 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

TEST - 6 (Paper-I)
ANSWERS
PHYSICS

CHEMISTRY

MATHEMATICS

1.

(4)

31.

(1)

61.

(2)

2.

(1)

32.

(3)

62.

(2)

3.

(2)

33.

(2)

63.

(3)

4.

(2)

34.

(4)

64.

(4)

5.

(1)

35.

(3)

65.

(3)

6.

(3)

36.

(2)

66.

(1)

7.

(4)

37.

(3)

67.

(3)

8.

(3)

38.

(3)

68.

(2)

9.

(2)

39.

(3)

69.

(1)

10.

(4)

40.

(1)

70.

(3)

11.

(3)

41.

(2)

71.

(2)

12.

(3)

42.

(4)

72.

(3)

13.

(3)

43.

(1)

73.

(2)

14.

(1)

44.

(3)

74.

(4)

15.

(2)

45.

(2)

75.

(4)

16.

(1)

46.

(3)

76.

(2)

17.

(1)

47.

(4)

77.

(3)

18.

(4)

48.

(4)

78.

(4)

19.

(1)

49.

(3)

79.

(3)

20.

(1)

50.

(2)

80.

(2)

21.

(1)

51.

(3)

81.

(3)

22.

(2)

52.

(2)

82.

(3)

23.

(1)

53.

(1)

83.

(4)

24.

(3)

54.

(4)

84.

(4)

25.

(1)

55.

(2)

85.

(2)

26.

(2)

56.

(2)

86.

(1)

27.

(4)

57.

(4)

87.

(1)

28.

(2)

58.

(3)

88.

(3)

29.

(1)

59.

(4)

89.

(4)

30.

(2)

60.

(3)

90.

(3)

1/11

All India Aakash Test Series for JEE (Main)-2014

Test - 6 (Paper-I) (Answers & Hints)

PART - A (PHYSICS)
1.

Answer (4)

2.

Answer (1)

10. Answer (4)

G JJG
v B.dl = 0i

In both the cases magnetic field at O will be zero.

3.

Answer (2)

B1 =

0
0
(2R )2
iR 2
i
;
B
=
2
2 [(2R )2 + (2R )2 ]3/2
2 [R 2 + R 2 ]3/2

B1 4 / 8
42 2
=
=
= 1: 2
B2 1/ 2 2 8 2 2
3/2

4.

a
B 2 2 = 0

B a =

Answer (2)

5.

B a =

Ba2
2R
Answer (1)

i=

E=

6.

F=

r
,
2

XL =

r
e( i)
2

i = i0 (1 e

t=

Answer (4)

8.

Answer (3)

dr

3
2 0 J0 a
a
24

100
100
,R=
= 10
8
10

L=

1
8

i=

E
100
=
=5 2A
z 10 2

12. Answer (3)

i = a + bsint
<i2> = a2 + b2 <sin2t> + 2ab<sint>

L
ln 2
R

7.

R
i0
= i0 1 e L

a /2

z=
2 40 + (10)2 = 10 2
8

Answer (3)
t /

20 J0
a

11. Answer (3)

At P, E will be along i

r
2rdr
a

0 J 0a
B = 12

E 2 r = r2.

J0

a /2

1
Ba 2
2

e=

20 J0 r 3

=
a
3 0

Emf induced in the disc will be same as that

induced in a rod rotating in a magnetic field.

a /2

2
= a +

b2
2

Irms = a 2 +

b2
2

For an element at a distance x of length dx

13. Answer (3)
3

de = 20 x 2 dx =
1

9.

50
ln3

14. Answer (1)

15. Answer (2)

Answer (2)

e = 2 2 1 = 4 volt, Req = 4

E (3 + 5t)4 6 (5) = 0

i through slider is 1 A

E = 20t + 42

Fm = i BA = 1 2 1 = 2N = Fext

2/11

Test - 6 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

21. Answer (1)

16. Answer (1)

IC

1
= B a2 cos t
2

1
Ba 2 sin t
2

e=

Q=

i=

1
Ba 2c sin t
2
IL

dQ 1

=
Ba 2c2 cos t
dt 2

Drawing phasor diagram

17. Answer (1)

22. Answer (2)

1
qE0 d = mv 2
2

v=

Inet = | IL IC | = 0.2 A

If charge on capacitor at time t is

2qE0 d
m

18. Answer (4)

19. Answer (1)
20. Answer (1)

E=

Q
0 A

E =

i d = 0

Q
A
Q
=
0 A 2 20
d
1 dQ i
= 0

=
dt
20 dt 2

23. Answer (1)

Q
8CV0 + CV0
= 3V0
VC = net =
Ceq
3C

24. Answer (3)

25. Answer (1)

Current will be maximum when L

400
2R
H =ni = 2000 A/m

di
=0
dt

n=

( PD across capacitors will be same)

Using energy conservation

1
1
1
1 2
(2C ) (4V0 )2 + C(V0 )2 = (3C )(3V0 )2 + Limax
2
2
2
2

I
4.8 102
Susceptibility() = =
= 2.4 105
H
2000
26. Answer (2)
27. Answer (4)
28. Answer (2)

Imax = V0

6C
L

29. Answer (1)

30. Answer (2)

PART - B (CHEMISTRY)
31. Answer (1)

32. Answer (3)

p-Nitrochlorobenzene undergoes nucleophilic

aromatic substitution involving carbanion as
intermediate which is stabilished by resonance.

Cl

+ OH
NO2

OH
H3O

NO2
(X)

CH3 CH = CH CH = O
+
CH3 CH CH = CH O

In addition to resonance shown above, the methyl

group shows + I effect and hyperconjugation.

NO2
(Y)

33. Answer (2)

Addition of HOCl to alkenes follows Markownikoff's
rule.

3/11

All India Aakash Test Series for JEE (Main)-2014

Test - 6 (Paper-I) (Answers & Hints)

36. Answer (2)
4-Bromobutan-2-one (Y) more reactive than

Cl

3-bromobutan-2-one (X) because its -hydrogen is

more acidic.

CH3 CH CH2
KOH

CH3 CH = CH2 + HOCl

OH
(A)

37. Answer (3)

CH3 CH CH2
O

18

Lindlar's

Reagent

HOCH2 C C CH2 CH2OH + H2

(B)

18

HOCH2

(SN2)

C=C

CH3 CH CH2

OC2H5

H+/

C2H5O

CH2 CH2OH

C2H5OH

18

OH

18

HO CH2
+

H2O CH2

CH3 CH CH2

CH2

H3O

O CH2

CH2

C=C

OC2H5

(C)

CH2
C=C

38. Answer (3)

34. Answer (4)

1-Methylcyclohexene is oxidised by Baeyer's reagent to

CH3
CH3 C = C CH = CH CH3

(i) O3
(ii) Zn/H2O

CH3

Me

CH3 CH = C CH = C CH3
CH3

Me

Baeyer's

(i) O3

OH

Reagent

(ii) Zn/H2O

(A)

CH3
O

CH3

1-Methylcyclohexane-1, 2-diol(A). The secondary

alcohol part of (A) is oxidised by K2Cr2O7/H+ and at
the same time the tertiary alcohol part of (A) is not
oxidised.

OH

Me

K2Cr2O7
H

OH

39. Answer (3)

C = O + CH3 C CHO + CH3 CHO

CH3

Cl

Cl
2

CH3 CH CH2 CH2 CH CH3 + S

35. Answer (3)
Cyclic secondary amine is more basic than open
chain secondary amine. Pyridine is weaker base
than both of them because it has sp2 hybridised
N-atom which is more electronegative. Aniline is the
weakest base because lone pair of electrons at
N-atom is delocalised with the benzene ring and
hence partially available.

4/11

Cl
CH3 CH CH2 CH2 CH CH3

CH2 CH2
CH3 CH
S

CH CH3

Test - 6 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

40. Answer (1)

43. Answer (1)

HCOOH is most acidic because its conjugate base

is stabilised by resonance.
O

H C OH

H +HCO

HC=O

Benzoic acid is weaker than formic acid because

carbonyl group is partially available.

OH

Allyl halide is more reactive than primary alkyl halide

towards SN2 reaction because its transition state is
stabilised by delocalisation. Vinyl halide is least
reactive towards SN2 because halogen is attached to
sp2 hybridised C-atom.
44. Answer (3)
Squaric acid is most acidic because its conjugate
base is aromatic and stabilised by resonance.

OH

+ 2H

H +

O
C

OH

45. Answer (2)

Acetic acid is the weakest acid because the +I
effect of CH3 group destabilises its conjugate base.

O
CH3 C OH

2, 4, 6-trinitrophenol (Picric acid) and phenol both

give violet colour with FeCl3.
46. Answer (3)

H+ + CH3 C O

CH3 C = O
41. Answer (2)
Specific rotation of (+) mandelic acid = +158
Specific rotation of a solution containing 35% of ()
mandelic acid and 65% of (+) mandelic acid

Aliphatic and aromatic primary amines react with

CHCl3 and KOH to give a foul smelling isocyanides.
47. Answer (4)
Phenol is oxidised by K 2S2O 8 in presence of a
base to quinol.

OH

= 0.35 158 + 0.65 158 = +47.4

+ K2S2O8

42. Answer (4)

PBr 3 and SOBr 2 react with alcohols to give
bromides without rearrangement by SN2 mechanism
whereas HBr reacts with alcohols to give bromides
with the possibility of rearrangement.

OH
OH

H2O
OH

48. Answer (4)

Pesticides are compounds used to kill insects,
weeds and fungi.

5/11

All India Aakash Test Series for JEE (Main)-2014

Test - 6 (Paper-I) (Answers & Hints)

54. Answer (4)

49. Answer (3)

Tropylium chloride gives instant precipitate of AgCl

with aq. AgNO3.

Carbon monoxide is not a greenhouse gas.

50. Answer (2)

Cl

CH3

is a 2 allyl radical, it is stabilised by

resonance as well as hyperconjugation due to two
-hydrogen atoms.
51. Answer (3)

+ aq.AgNO3

+ NO3 + AgCl
Aromatic

Other compounds do not give Cl ions because the

carbocation formed after loosing Cl ion is not stable.
55. Answer (2)

Conjugated product is most stable.

Hence, (3) is the major product.

OH

OH

52. Answer (2)

The given compound has 6 stereoisomers, two of

which are meso and the remaining 4 are optically
active.
CH3

Cl

CH3
Cl

OH

OH

CH3

Cl
C

Cl

CH3
+

(Meso)

(Dextro)
+

H
CH3

Cl

CH3
Cl

CH3

CH3

Cl

Cl

C
CH3

Cl
C

(Dextro)

56. Answer (2)

CH3

(Levo)

53. Answer (1)

+

CH3 O CH2 and CH3 S CH2 are stabilised

+

by resonance whereas CH3 CH CH3 is stabilised

by +I effect of two CH3 groups and hyperconjugation
due to 6 -hydrogen atoms.
+

CH 3 S = CH2 is more stable

CH3 S CH2
+

than CH3 O CH2

CH3 O = CH2 because

the latter has +ve charge on more electronegative

O-atom.

6/11

CH3

C
H

Cl

C
C

(Meso)

Cl

C
H

H
C

Cl

H
(Levo)

CH3

H
C

57. Answer (4)

Dipole moment of CH3 F is lower than that of
CH3 Cl because C F bond length is shorter than
that of C Cl bond even though the polarity of
C F bond is higher.
58. Answer (3)
Butan-2-ol gives positive iodoform test while butan-1ol does not. Acidic strength of alcohols follows the
order CH3OH > 1 ROH > 2 ROH > 3 ROH
59. Answer (4)
If BOD level of water is greater than 5 ppm, it is
highly pure water.
60. Answer (3)
Aromatic compounds containing strongly deactivating
group like nitrobenzene do not undergo Friedel
Craft's reaction.

Test - 6 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

PART - C (MATHEMATICS)
64. Answer (4)

61. Answer (2)

Differentiating w.r.t. x, we get

Let x = 2sec
dx = 2sec.tand
/3

Now, I =

0
/3

3 cos 2 x + sin( y 2 ).2y .

2 tan (2 sec .tan d )

4 sec 2

dy 3 cos 2 x
=
dx
2y .sin( y 2 )

/3

sin2
d =
cos

(sec cos )d

dy
=0
dx

65. Answer (3)

0
/3
0

= {log(sec + tan ) sin }

Equation of tangent at at , is
t

3
= log(2 + 3)
2

a
1
= 2 ( x at )
t
t

x + t2y = 2at

i.e., = 2 + 3, =

3
2

2a
So that A(2at, 0) and B 0,
t

62. Answer (2)

Local maxima at x = 2,

f (2 + h) f (2)
So, hlim
0

a + 14 | 46 | 3 22

Mid point of AB = at , P
t

So, AP : PB = 1 : 1
66. Answer (1)
As,

a + 14 45

dy
2ax
= 2
dx x a2

a 2011

So, length of tangent at (x, y) is

So, greatest value of a may be 2011.

dx
4a 2 x 2 + ( x 2 a 2 )2
y 1+
=y
2ax
dy

63. Answer (3)

log(e x ) log(1 + e x )
f (x) + c =
dx
1+ ex
e
log
x
=
1+ e
1+ e x
x

1+ e

y ( x 2 + a2 )
2ax

Therefore required sum

). e

1
log(1 + e x )
2

x 2 a2
dx
=
y
Length of subtangent = y

dy
2ax

dx

log 1 + e x

y (2.x 2 ) xy
=
2ax
a
67. Answer (3)
=

dx

+c

{taking log (1 + ex) = t}

As, f(x) is a polynomial function, is continuous and

differentiable for all real x.
Also,
f(x) = (x2 2) (2x + 1)
and f ( 2) = 0 = f ( 2)

7/11

All India Aakash Test Series for JEE (Main)-2014

Hence, by Rolle's theorem for at least one

Test - 6 (Paper-I) (Answers & Hints)

70. Answer (3)

,
x [ 2, 2]

Let x = tan

f(x) = 0

dx = sec2d

6x2 + 2x 4 = 0

x=

2
, 1
3

68. Answer (2)

x=

1
6

f(x) = 6x 1 = 0

log x

/2

/2

x 2 + 2 dx = log d + logtan d

1
1
1
log + 0 = log
2

71. Answer (2)

as f(x) = 6

3
B 1,
2

1
and least value of f is
f is minimum at x =
6

1 3 1 25
f =
+
=2
6 36 6 12

1
A 1,
2

Let r be the common ratio

x=1

Given

r2
=2
1 r

r = 3 1

We can write

69. Answer (1)

x 2 5 x + 6, 0 x 2

As, f ( x ) =
12
2
( x 5 x + 6), 2 < x

x 3/2
2

y =x

From graph Required area

1

x 3/2
x 3/2
x
+
dx

x
dx
=

2
2
0
0
1

2 x 5, 0 x < 2

f ( x ) =
12
2x + 5, 2 < x 5

Now, f(x) = 0

dx =

3/2

5 12
x = 0,
2 5

Also, f (2) does not exist.

Therefore x = 2 is the only critical point.
f(x) changes sign from negative to positive

72. Answer (3)

Differentiating w.r.t. x, we get
(x4 + 1)1/3x7

4 4
4

4/3
3
1/3
3
4
= k ( x + 1) .16 x + ( x + 1) .4 x (4 x 3)
3

So, f is minimum at x = 2 and minimum value

= f(2) = 0
12 6
Also, f(0) = 6, f = , hence maximum value = 6
5 5

So, required sum = 0 + 6 = 6.

8/11

2
sq. units
5

16 x 3

x 7 = k 16 x 3 ( x 4 + 1) +
(4 x 4 3)
3

k=

3
112

Test - 6 (Paper-I) (Answers & Hints)

73. Answer (2)

All India Aakash Test Series for JEE (Main)-2014

76. Answer (2)

Put x y = t

a +1

y)2

So that y(x

=x

Let F (a ) =

( x 1)2

dx

a 1

Becomes (x t)t2 = x

F (a ) = e a e (a2)

t3
t 1

For maximum, F(a) = 0

x=

dx =

t (t 2 3)
Also, x 3 y = 2
t 1

dx
t 2 1 t 2 (t 2 3)
=
.
dt
Here
x 3y t (t 2 3) (t 2 1)2

F (1) = 2e 1 2e 1 < 0
So, F is maximum at a = 1
77. Answer (3)
5 /12

tan

tan

2 dx
2

3dx
3

1
1
1
= tan 2 + 2(tan 3 tan 2)
4

+ 3(tan1(2 + 3 ) tan1 3)

74. Answer (4)

2cos x + 1
dx
(2 + cos x )2

Dividing numerator and denominator by sin2x, we get

5
(tan1 2 + tan1 3) + 3
4
12

5 1 3 + 2

tan
+
4 4
1 6

(2cosec x cot x + cosec 2 x )dx

(2cosecx + cot x )2
dt
, where 2 cosecx + cotx = t
t2

1
= +c
t

78. Answer (4)

We have,
F(x) = 4sinx + 3cosx

1
+c
2cosecx + cot x

75. Answer (4)

1 3
= 5 sin x + tan
4

Now,

Put ex 1 = t2, we get

2

tan (2+ 3 )

1
loge {( x y )2 1} + c
2

tan1 3

1dx +

0.dx +

1
loge (t 2 1) + c
2

tan1 2

/4

[tan x ]dx =

I=

Also, F (a ) = 2ae a + 2(a 2)e (a 2)

t
dt
= 2
t 1

I=

a=1

t (t 3)
dt
(t 2 1)2
2

2t 2
4

I= 2
dt = 2 1 2
dt
t +4
0t +4
0

3
x
4
4

3
< x + tan1 <
2
4

Hence F(x) > 0

1 t
= 4 4 tan
2 0

=4

3
So, F is increasing in ,
and F is least at
4 4
x=

.
4

9/11

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79. Answer (3)

Test - 6 (Paper-I) (Answers & Hints)

81. Answer (3)
Y

y=x

A(1, 1)
y = x

X
B(2, 0)

(3, 3)

Solving y = 2x

1/2 1

Required area
=

x2

y = 1/x
X

x x

1/2

and y = x, we get x = 0, 3

dx

x 3

7
= log x
= loge 2
3
24

1/2

Required area
3

{(2x x

) ( x ) dx

So, p =

82. Answer (3)

7
24

(3 x x

) dx

As, f(0) = f(2) = 0 and

2
x 3
3 x

=
3
2

Now, xf ( x )dx = { xf ( x )}0 f ( x )dx

f ( x )dx = 4

9
2

= 2f (2)

3
3
= 0
4
4

80. Answer (2)

=

3
4

83. Answer (4)

2

y = 4a(2a x)
O

r +
n

lim Sn = lim

r =1

1
rn

y = 4ax
n

r
n

lim

=
We have,
if x < a
4ax,
y2 =
4a(2a x ) if x a

1
r n
r =1
+
n
n

dx
2tdt
=
(t = x )
=
t
t + 1)
(
x
+
x
0
0

Therefore required area

a

= 4
0

10/11

16a2
4ax =
3

= 2{log(t + 1)}0
1

= 2loge2

Test - 6 (Paper-I) (Answers & Hints)

87. Answer (1)

84. Answer (4)

Differentiating the given function w.r.t. x, we get
f ( x ) =

1
sin .3 tan2 x.sec 2 x + (sin 1)sec 2 x
3

= sin.tan2x.sec2x + (sin 1)sec2x

Now, f(x) = 0

tan2 x =

All India Aakash Test Series for JEE (Main)-2014

Clearly f(1) = 2, f(1+) < 2, f(1) < 2

Hence x = 1 is the point of local maxima
Hence statement-1 is true
Statement-2 is also clearly true and explains
statement-1
88. Answer (3)
f(0) = 2, but clearly f(0+) < 2, f(0) < 2. Hence x = 0
is the point of local maxima.

1 sin
<0
sin

which is not true. Therefore, f(x) has no critical

points.

Hence statement is true.

Statement-2: Put y = x
f(0) = f(x) + f(x)

85. Answer (2)

Put cosx = t, so that 1 < t < 1.

put x = 0, we get f(0) = 0

f(x) + f(x) = 0

(2 + t )2
, 1< t < 1
Let (t ) =
1 t 2

f(x) is odd

(f ( x ) + f ( x )) = 0

Differentiating, we get

Statement-2 is false.

2(2t + 1)(t + 2)
(t ) =
(1 t 2 )2

89. Answer (4)

Statement-1: The integral can be written as

Since, 1 < t < 1, hence t =

1
only
2

1
Also, (t ) < 0 for t <
2

and (t ) > 0 for t >

f(x) = ex tanx

x + tan x ) ) dx = e x tan x + c

f(0) = 0

Hence statement-1 false

Statement-2: The integral can be written as

1
2

Hence, is minimum at t =

e ( ( x tan x ) + ( x sec

e
1
and least value =
2

2
2

=3.
1
1
4
86. Answer (1)
Statement-1 : f ( x ) = 3 x 2 + 2bx + c > 0
4b2 4 3 c < 0
b2 < 3c
0 b 2 < 3c
Hence statement-1 is true.
Statement-2 is clearly true and statement-2 explains
statement-1.

1
1
1
x
x + + 1 2 dx = e x + + c

x
x
x

f ( x) = x +

1
x

f(1) = 2

Hence statement-2 is true

90. Answer (3)
Statement-1: The integral can be written as

/2

/2

[ sin x ] dx = 0.dx + 0.dx = 0

Hence statement-1 is true
Statement-2: The integral can be written as
20

10

sin x dx = ( 20 10 ) sin x dx = 10 2 = 20
0

Statement-2 is false.

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