Product : R3X5
(Part B)
1.2. Relevant identified uses of the substance or mixture and uses advised against
R3X5 Polymer Composite. Repair damage caused by impact, abrasion, erosion or corrosion, rebuild worn areas, fill
holes and cracks, provide abrasion resistant surfaces.
1.3. Details of the supplier of the safety data sheet
Supplier:
Company:
3X ENGINEERING
9 Av. Albert II
98000 Monaco
Tel. : +377 92 05 79 81
Fax : +377 92 05 72 71
(mon. fri. 8 a.m. 5 p.m.)
E-mail (questions) : 3x@3xeng.com
1.4. Emergency telephone number
2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
2.1.1. Classification according to Directive 1999/45/EC
Corrosive; C; R34
Harmful; Xn; R20/21/22
R43
R52/53
2.1.2. Canadian WHMIS classification
E: Corrosive materials; D2B: Toxic materials causing other effects 2.1.3. Australian classification
Hazardous according to criteria of Safe Work Australia.
2.1.4. Additional information
For full text of R-phrases: see SECTIONS 2.2 and 16.
2.2. Label elements
Labelling according to Directive 1999/45/EC
Danger symbols:
C C - Corrosive
R-phrases:
R34
Causes burns.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R43
May cause sensitisation by skin contact.
R37
Irritating to respiratory system.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S-phrases:
Product : R3X5
(Part B)
S45
S61
Other information:
In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
Avoid release to the environment. Refer to special instructions/safety data sheets.
None
% Wt.
CAS No./
EC No.
REACH
Reg. No.
Classification
(acc. to 1272/2008/EC)
Benzyl Alcohol
35-55
NA
Xn; R20/22
3-Aminomethyl-3,5,5trimethylcyclohexylamine
30-40
100-51-6
202-859-9
2855-13-2
220-666-8
C; R21/22-34-4352/53
15-25
0121195146
87-32
NA
Not classified
Not classified
68609-08-5
Classification
(67/548/EEC)
Remove to fresh air. If not breathing, administer artificial respiration. Contact physician.
Flood area with water while removing contaminated clothing. Wash clothing before reuse. Consult physician.
Flush eyes for at least 30 minutes with large amounts of water. Contact physician.
If conscious, do not induce vomiting; drink milk, water or vinegar. Contact physician immediately.
4.2. Most important symptoms and effects, both acute and delayed
Direct contact will cause burns to skin, eyes and mucous membranes. High vapor concentrations may cause respiratory tract irritation. May
cause allergic skin sensitization.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms.
5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Carbon Dioxide, dry chemical, foam or water fog
5.2. Special hazards arising from the substance or mixture
None
5.3. Advice for firefighters
Cool exposed containers with water. Recommend Firefighters wear self-contained breathing apparatus.
Flammability Classification: not determined
HAZCHEM Emergency Action Code: 2 Z
6. ACCIDENTAL RELEASE MEASURES
Product : R3X5
(Part B)
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Provide adequate ventilation. Utilize exposure controls and personal protection as specified in Section 8. 6.2. Environmental
Precautions
Keep out of sewers, streams and waterways.
6.3. Methods and material for containment and cleaning up
Contain spill to a small area. Pick up with absorbent material (sand, sawdust, clay, etc.) and place in a suitable container for disposal. Flush floor with
dilute (5%) Acetic Acid. Collect rinsate for proper disposal.
6.4. Reference to other sections
Refer to section 13 for disposal advice.
7. HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid all direct contact. Avoid breathing mist or vapor. Utilize exposure controls and personal protection as specified in Section 8. Remove
contaminated clothing immediately. Wash clothing before reuse. Contaminated leather including shoes cannot be decontaminated and should be
discarded.
7.2. Conditions for safe storage, including any incompatibilities
Store in cool, dry area.
7.3. Specific end use(s)
No special precautions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Control parameters
Hazardous Ingredients
ppm
Benzyl Alcohol
3-Aminomethyl-3,5,5trimethylcyclohexylami ne
Modified cycloaliphatic amine
OSHA PEL
mg/m3
ACGIH TLV
ppm
mg/m3
UK WEL
ppm
mg/m3
AUSTRALIA ES
ppm
mg/m3
Not normally needed. If necessary, utilize an approved (amine) organic vapor respirator.
Chemical resistant gloves (e.g., butyl rubber, nitrile)
Safety goggles.
Impervious clothing as necessary to prevent skin contact.
Odour
Odour threshold
Vapour pressure @ 20C
% aromatics by weight
pH
Density
Weight by volume
Coefficient (water/oil)
Vapour density (air=1)
Rate of evaporation (ether =1)
Solubility in water
Oxidising properties
amine
not determined
not determined
not determined
not applicable
1,0 kg/l
8.32 lbs/gal.
<1
>1
<1
slightly soluble
not applicable
Product : R3X5
(Part B)
Direct contact will cause burns to skin, eyes and mucous membranes. High vapor
concentrations may cause respiratory tract irritation.
Substance
Product
Test
LD50 oral, rat
3-Aminomethyl-3,5,5-trimethylcyclohexylamine
Benzyl Alcohol
Benzyl Alcohol
Benzyl Alcohol
Result
>200 - <2000
mg/kg
1030 mg/kg
8.8 mg/l/4 h
2000 mg/kg
1230 mg/kg
Chronic Effects:
Other Information :
Product : R3X5
(Part B)
3-Aminomethyl-3,5,5-trimethylcyclohexylamine: biodegradable. Benzyl Alcohol: readily biodegradable.
12.3. Bioaccumulative potential
not determined
12.4. Mobility in soil
Liquid. Slightly soluble in water. In determining environmental mobility, consider the product's physical and chemical properties
(see Section 9).
12.5. Results of PBT and vPvB assessment
Not available
12.6. Other adverse effects
None known
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Unreacted components are a special waste. Combine resin and curative. The final cured material is considered nonhazardous.
Landfill sealed containers with a properly licensed facility. May be incinerated at an appropriate facility. Check local, state and
national/federal regulations and comply with the most stringent requirement. This product is classified as a hazardous waste according to
91/689/EEC.
European List of Wastes code:
08 04 09
14. TRANSPORT INFORMATION
14.1. UN number
ADR/RID/ADN/IMDG/ICAO:
UN2289
TDG:
UN2289
US DOT:
UN2289
14.2. UN proper shipping name
ADR/RID/ADN/IMDG/ICAO: ISOPHORONEDIAMINE SOLUTION
TDG:
ISOPHORONEDIAMINE SOLUTION
US DOT:
ISOPHORONEDIAMINE SOLUTION
14.3. Transport hazard class(es)
ADR/RID/ADN/IMDG/ICAO:
8
TDG:
8
US DOT:
8
14.4. Packing group
ADR/RID/ADN/IMDG/ICAO:
III
TDG:
III
US DOT:
III
14.5. Environmental hazards
NO ENVIRONMENTAL HAZARDS
14.6. Special precautions for user
NO SPECIAL PRECAUTIONS FOR USER
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
NOT APPLICABLE
14.8. Other information
US DOT: Shipped as Consumer Commodity ORM-D in packaging having a rated capacity gross weight of 66 lb. or less (49
CFR 173.154(c)). ERG NO. 153
IMDG: EmS F-A, S-B
ADR: Classification code C7, Tunnel restriction code (E)
15. REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU regulations
Authorisations under Title VII:
Not applicable
Restrictions under Title VIII:
None
Other EU regulations: Directive 94/33/EC on the protection of young people at work.
15.1.2. National regulations
US EPA SARA TITLE III
Hazardous Materials Identification System (HMIS)
4 = Severe Hazard
312 Hazards :
313 Chemicals :
HEALTH
Product : R3X5
(Part B)
Immediate
Delayed
3 = Serious Hazard
2 = Moderate Hazard
1 = Slight Hazard
0 = Minimal Hazard
* = See Section 8
none
FLAMMABILITY
REACTIVITY
Personal Protection
1
1
*
H302:Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H332:
Harmful if inhaled.
Relevant R-phrases: