MSDS

Date : 05/01/2013

R3X1050S - PARTIE A

3X ENGINEERING

Page: 1/5

selon 91/155/CEE

1.0 Identification of the substance / preparation and society

1.1 Identification of the chemical:

R3X1050S PARTIE A

1.2 Entity responsible for marketing:

3 X ENGINEERING S.A.M
9 avenue Albert II
98000 MONACO
Tl. : +377 92 05 79 81
1.3 Emergency number:

ORFILA : 01.45.42.59.59

2 .0 Composition / Information of components

Description of chemicals :

Liquid epoxy resin.

Informations of hazardous components :

N CAS
25036-25-3

Dsignation
BPA-Epichlorhydrine PM > 700

%
Ident.
>50% Xi, N

Phrases R
R36/38, R43, R51/53

3.0 Hazard identification

Classification
Irritating, Dangerous for the environment
Indications of risk to humans and the environment
Hazards to humans: Irritating to eyes and skin : Irritating to eyes and skin. May cause sensitization by skin
contact.
Physical and chemical hazards: No Not classified as flammable but can burn.
Environmental Effects:Toxic to aquatic organisms. May cause adverse long-term to the aquatic environment.

4. 0 First aid
4.1 If inhaled : No specific measures. Bring to fresh air. If the person does not recover quickly, consult a
doctor or hospital.
4.2 In case of contact with skin : Remove immediately clothing and shoes. Rinse immediately with plenty
of water and soap if possible for at least 10 minutes. If symptoms persist, consult a doctor or hospital.
4.3 In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Consult an ophthalmologist.
4.4 If swallowed : Do not induce vomiting. If swallowed, immediately consult a doctor or hospital.

5.0 Mesures against fire

5.1 Means of non-extinction appropriate :
Water jet.
5.2 Extinguishing media recommended :
Foam, water spray or fog.
5.3 During the fight against fire :
Not classified as flammable but can burn. Clearance
possible carbon monoxide if incomplete combustion. Coll containers nearby with water spray.
5.4 Protective equipment :
Apparel comprehensive protection and breathing apparatus
autonomously.

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6.0 Action accidental release

6.1 Precautions:
Avoid contact with skin, eyes, clothing.
6.2 Precautions for environmental protection :
Prevent any infiltration or runoff into sewers, gutters
or rivers by using sand or soil or other suitable. If the product reaches the sewers, it must be pumped in a
shell not closed. You can call emergency services to assist in the operation.
6.3 Methods of cleaning/recovering : Absorb or retain the liquid with sand, earth or limiting any subject
spraying. Recovering in a container labeled, closed, to proceed to a safe disposal. Scrub contaminated
surfaces with detergent solution Keep washing water as contaminated waste. Place containers prevarication
in a barrel or even an over-labeled
7.0 Storage and handling
7.1 Handling precautions :
Comply with local regulations. Avoid contact with skin, eyes and clothing..
7.2 Criteria storage : Store according to local regulations. Keep container tightly closed and protected
from humidity. Keep away from heat. The pallets will be stacked up to a properly up to 4 high.
7.3 Storage : Ambient.
8.0 Monitoring the exposure of workers, personal protective equipment
8.1 Technical control : Provide eye wash stations and safety showers. Providing natural or mechanical
ventilation (explosion-proof) to stay below the permissible exposure limit.
8.2 Components with limit values that require monitoring at work :
Components with limit
Updated
Term
values that require
Value
Note
regulations
exposure
monitoring at work
BPA-Epichlorhydrine PM
ACGIH
No established value
>700
8.3 Personal protection measure :

Respiratory: Having a self-contained breathing apparatus

ready for use if necessary. In the premises or the product
is pulverized, workers should avoid contact with aerosols
containing the agent treatment with control methods,
such as exhaust ventilation or suitable protective
equipment such as respirators mask full and air supply,
gloves and protective suits. Wear a respirator if
ventilation is inadequate. Hands: nitrile rubber. In an
emergency, wear waterproof gloves with cuffs to prevent
the spread of material to the area above the wrists.
Neoprene gloves. Butyl rubber. Nitrile rubber. The time
Waterproofing gloves chosen must be longer than the
period of use. Eyes: In places or treatment agent may
come into contact with eyes, workers should wear
goggles and a mask projections. People working near the
equipment, within range of potential exposure must also
wear goggles plastic. Workers should not touch their
eyes or skin with contaminated hands by the treatment
agent.
8.4 Special protection measures and hygiene : Discard leather contaminated. Provide eye wash stations
and safety showers. Wash at the end of each work period
and before eating, smoking or using the toilet.
8.5 General protection measures and hygiene: Trying to prevent the penetration of material into sewers
or waterways. Keep out of surface water or sewage
systems. Build a retaining wall to prevent the dispersion
of liquids.

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9.0 Proprits Physico-chimiques

9.1 Physical condition :

Black liquid

9.2 Odor :

ligth

9.3 Typical temperatures :

Flash point :
>150C.
Boiling point :
>200C
Temperature self-flammability :

9.4 Solubility :

Ca. 0.009 kg/m3 at 25C

9.5 Gravity:

1,35 (at 25C)

9.6 Viscosity (mPa.s) :

Thixotropic (at 25C)

9.7 pH :

Ca. 7

>300C.

10.0 Stability of product et reactivity :

10.1 Conditions to avoid :
The caustic products may induce polymerization strong from a temperature
of about 200C.
10.2 Hazardous reactions :
Stable under normal conditions of use. Reacts with strong oxidizing agents.
Polymerize exothermically with amines, mercaptans and Lewis acids at room temperature and higher.
Polymerizes on contact with caustic soda. Exothermically reacts with bases (example : soda caustic)
ammonia, amines and primary secondary alcohols and acids.
10.3 Hazardous decomposition : Not to our knowledge.

11.0 Toxicologic informations

11.1 Acute :

Ingestion : Low toxic, DL50 (rat) > 2000 mg/kg

Contact with skin : Low toxic, DL50 (rabbit) > 2000
mg/kg

11.2 First irritation :

Of the skin : Slightly irritating to the skin. Filed by the

irritant.
Of the eye : Slightly irritating to the eyes. Filed by the
irritant.

11.3 Additional toxicological information :

According to the method of calculating the latest current
version of the general directive of the EEC on the
classification of preparations, the product has the following
hazards: irritant.
12.0 Ecological informations :
Eco toxicologic effects
Aquatic toxicity :

Fish : toxic, 1 >CL/CE/CI 50 >= 10 mg/l

Algae : toxic, 1 >CL/CE/CI 50 >= 10 mg/l
Invertebraties : toxic, 1 >CL/CE/CI 50 >= 10 mg/l

Toxicity to other agencies:

Non available data.

Persistence et degradability :
Mobility
Flow into the water.
Bioaccumulation

In the basement, the product is mobile and can contaminate water and groundwater.
Potentially bioaccumulative.

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13.0 About the possibility of waste disposal :

13.1 Product :

Putting the collection of toxic waste or make to the dump

for hazardous waste

13.2 Packaging non cleaned :

Evacuation accordance with legal requirements.

14 .0 Transport details :

UN: 3082
Class: 9
Classification: M6
PG: III
No. Labeling:
No risk: 90
Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, NOS ( EPOXY
RESIN)
15.0 Regulatory informations
15.1 Labelling to EEC Directives
Symbol of danger :

Xi, Irritating
N, Dangerous for the environment

15.2 Phrases R :

R36/38 Irritating to eyes and skin.

R43 May cause sensibilising after contact with skin.
R51/53 Toxic to aquatic organisms, may cause adverse long term tothe
aquatic environment.

15.3 Phrases S :
2

Keep out of reach of children.

28A

After contact with skin, wash immediately and thoroughly with soap and
water.

37/39

Wear gloves and a protective eye and face.

61

Avoid release into the environment.

Pays

List

Notification

USA

TSCA

Listed

EU

EINECS

Listed

Canada

DSL

Listed

Australia

AICS

Listed

Japan

ENCS

Listed

South Korea

ECL

Listed

China

SEPA

Listed

Philippines

PICCS

Listed

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16.0 Other informations :

Ensure that all national or local regulations are respected.
Risk phrase
R36/38 Irritating to eyes and skin.
R43 May cause sensibilising after contact with skin.
R51/53 Toxic to aquatic organisms, may cause adverse long term tothe aquatic environment.

This Safety Data Sheet has been established according to European Directives in force and shall apply to all
countries that have translated the Directives into national law.
This profile is based on the current state of our knowledge, but does not guarantee about the properties of
the product and does not give rise to a legal contract.