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RDPUCPA

DISTRICT LEVEL PREPARATORY EXAMINATION _2OL4


II PUC. CHEMISTRY

Minutes

Max.Marks:7O

lnstructions:
Question paper has four parts A, B,

and D. All parts arb compulsory.


Write balanced chemical equations and draw labeled diigrams wherever required.

Answ", Or, ot,fr" following

guestions.

Give an example for solid solution in which the solute


Write Van't Hoff equation for osmotic pressure.
What is a secondary cell?

is a gas.

Give reason: Activated charcoal is used in gas mask.

What is meant by effective collision?

ik

What is the roll of depressant in froth floatation process?


Why does PCl3 fume in moisture?

l0X1 = l0

Name the catalyst used in friedel craft's reaction.

Give an example for the organic acid, which give silver mirror test.
- OH groups are present in a molecuJe of glucose?

1.
2.
3.
4.
5.
6.
7.
8.
9.

lo

PART

g.

ib

1.
2.

co

Time:3 Hours 15

10. How many primary

ia

PART- B

It

questions.

5X2=10

11. calculate the efficiency of packing in case of a metal crystal for simple cubic.
12. How much electricity in terms of faraday is required to produce 20gm of Ca from molten CaCl2?

ed

--

Answer any FIVE of the following

13. 'The velocity constant of a first order reaction is 2.2X10'3 min'l calculate the half life of the reaction,

14.

Give reasons:

i.
ii.

.p

Actinoids show variable oxidation states.


Zr and Hf have almost identical radii.
15. How propene is converted into l-propanol by hydroboration

15. Explain the conversion of benzaldehyde in to cinnamaldehyde.


17. Name any two types of synthetic detergents.
18. What are bactericidal and bacterio static antibiotics?

lll

Answer any FIVE of the following

PART.C

questions

5X3=15

Explain the steps involved in extraction of iron. .

19.

bxidation reaction?

20. How ii phosphine prepared in laboratory in pure form? And give its reaction with copper sulphate.
21. Describe the preparation of ozonised oxygen. Give one anomalous behaviour of oxygen.
22. Explain Deacons process for the manufacture of chlorine. How chlorine does reacts with cold and dilute NaoH solution?
23. Name the metal of first row transition series that

i.
ii.
iii.

Has highest value

of M*2/M standard electrode potential.


moment in its +2 oxidation state.
Exhibit maximum number of oxidation states.
24. How do you account for the following?
i' of the da species cr*z is strongly reducing while manganese (lll) is strong oxidizing agent.
ii. Cobalt (ll) is stable in aqueous solution but in the pr.r"i." of \omptexiig r"rg"ni it is easily oxidized.
iii. The dl configuration is very unstable in ions.
Has zero spin only magnetic

_)

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25.

State the posturates of werner's theory of co-ordination


compounds.

[NiClil-2ionWiihtetrahedralgeometryisparamagnetic.

PART- D
Answer any THREE of the following questions.

co

3X5=15

27.

(3+2)

a)

and

25' Explain on the basis of valence bond theory that


[Ni(clv)n]-2 ion with square planar structure is diamagnetic

An element has body centered cube (bcc) structuie


with a ce, edge of 288pm. The density of element
7

b)

n_type

phosphorous 2)silicon doped with indium.

semiconductors.

State Henry's law. Mention:y:_lTl?n?rt apptications


of Hen4/s
What is elevation of boiling point? Giveian expression
for determination of molecular
mass of solute using elevation of boiling poini
of solvent.

a)

Explain electrochemical theory of

1) Germanium doped with

lo

b)

a)

(3+2)

ib

taw.

29.

(3+2)

corrosion.

a)

an expression
?ulr:
Explain the

b)

ik

b) The standard electrode potential-for a paniel cell is


1.1V. calculate the standard Gibb,s free
energy change for
the reaction,
Zn(s) + 'Cu*z7aq1 - ,"*r(ie)-;;;6)"'

30.

forrate consand offirst order

reaction.

(3+2)

effect ofcatalyst on the rate ofa reaction.

31.

a) Explain

SN2

questlons.

4X5=20

ia

Answer any FOUR of the followlng

a) Give three differences be.f,we9n physisorption


chemis"*fiil
-- r --'
b) what is emulsion? Give dilutioniest to idenufyand
emursion.

mechanism with example

(3+2)

ed

b) How do you convert isopropyr chroride in to 1) propane


2) propene.
33.

a)

Give equations for

b)

ii)Reimer Tiemann reaction.


Explain Lucas test to distinguish between primary
secondary and tertiary arcohor.

(3+2)
s5mthesis.

How do you convert benzene in ro benzoic


acid? why is uunro,"

Write equations for


i)
The formation of oxime frorl carbonyl
compounds.

ii)

1,

Reaction between acetone and ettrytene

a)

b)

36.

a)

b)

jlij)roongu.,hrn

acetic acid?

b)

i) Williamson,s ether

.p

a)

35.

is

g.

.2glcm3 . How many atoms are there in 20gg of


the erement?
Classifo each of the following into p_type and

gl;ot.

--(3+2)

Explain following reactions


Gabriel phthalimide reaction
ii)
Benzoylation of aniline
PtD of aniline is more than that of methyl
amine.

i)

prepare grucose from starch? write


Haworth
.fgw ryo{d r9u

,JlHr.

of sucrose.

37.
a)

Distinguish between the terms homopolymer


and

Prepared?
b)

co-porr[i"'], rrvvY
How is
rr low
ruw density
uellslf,Y porythe.e

Discuss main purpose of vulcanization of


rubber.

i
I

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