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GHEMTSTRY
tI

PU 2014-2015

Max. Marks

Board Preparatory - 02

Duration
Date

Instructions

l. write balanced chemical


2.
equations and draw labeled diagrarrs wherwerrequired.
3. Use log tables and the
calculator ifnecessary. (Use of scientifc calculators is not
A

B, C and D. AII parts are compulsory,

PART . A

Answer ALL of the following (answer ach question iuone word or one setrtenee)
Wbat is anisotropy?

2015

[10x]=101

ib

2. Mention the factor responsible for abnormal molar masses


3. state Raoult's law of dilute solutions containing non-volatile
4. Why does conductance decrease with increase in dih*ion?
5. What is peptisation?
6. Why does CaO react with silica to form the slag?
7. Give the equation for thepreparation of xenon tioxide.
8. Mention the condition for a compound to be chiral.

lo

I
I.

houn

g.

The questions papo has four parts:

70

co

Class

BgNtead with Sustalned Excellence

9.

Given,

R-C:N

ia

ik

solutes.

+ 2[H]-&/Ig!-+R-CH-NH ol,,fto ,A. IndentifyA

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ed

10. What is meant by denaturation of proteins?

PART. B
Answer any FIVE of the following (each question carries 2 marks)
[5 x 2 = 10]
11, Niobium crystallizes in a body centered cubic stucture. Its density is
8.55 g em-3. Calculate the atomic
radius of niobium (Atomic mass:93).

II.

12. calculate the ernf of the cell in which the following reaction takes place.
,Ni(s) + 2Ag* (0.002
M + Ni* (0.160 M)+ 2Ag(s)
Standard errf ofthe cell = +1.05 V.
13. What is a zero order reaction? Give an example.
14. What are interstitial compounds? Why transition melals form interstitial
compounds?

15. Explain Williamson's reaction with an example.


16. Explain iodoform reaction with an example.
17. What are (i) analgesics and (ii) broad spectnrn antibiotics?
18. What are artificial sweetening agents? Give two o<amples.

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(ili) apiAc
22- Describe the followjng
with,respect to halogen
family.

following

The enthalpies of atomisation


of hansit.
(ii) Transition metars
(iii) Mn2* compo*r,
,oo..

;,* ilffiffi,*
*.
ouu," ,r,* #

lanthanidt

24. Compare

"i,urr"t*

I3l

I3l

metats are high

::ffiHi:rrrsnetic.

ia

(i)erecnonic#ililfctinidesT#;:.,ffi;I.*.

25' Discuss the narure


of bonding,,

Ji;:,;i:i

ib

rhe oxidation states


of fralogei family.

23. Account for the

(i)

"f,"*.*

;;".

ofpig iron from

ik

(ii) Explain

--

steps invorved in rhe


extracrion
-

20. (a) Give the reaction


of conc. HNOI ana dilute
HNO3

(i) thermal stability (ii)


reducing

marrs)

co

tr'"i'*iL

g.

19' Desctibe briefly


with equation'

PART. G
(each question carries
3

lo

IIL Answer anv Flvx,,.orthe


fo[owing

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i"*;-

r;the

basis of varence

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,iii\_

r.

r""j?":T""t',*

:]

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26.Draw crystal field splitting


13l
of d-orbitals in octahedral
field. How is the magnitude
nature ofligands?
Ao affected by the
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anv rHREE.lr,o" forrowins


Y'
27. (a) Mention the constituent
parficles;'---

1T*"

28. (a)

5 marrrs)

[3x5=15]

;;;;#

3#l;J},*.T]":T*::"::T:i{:i)^morecurar

.,

(ea"ffil,;i..rries

sorids Give one exampre


ror each

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t21

?:r::'x;:#

rv..e shows
rxuw) a oepressron
depression n
in freezrng
freezngpoint equal to
l.62 "C. Calculate the
,r'j'::'":1-: 1^t^:::,1:,zene
of
the
acid
in
solurion
if it exists aq
solution.
ntution.GivenK.^r.r.--:::1'li-:.11sociatio,n
iGiven Kr of benzene ii +.g
as rrimcrc
dimers in
f n U *"i;.
(b) What is reverse osmosis?
How is it usefiit
13l

2e. (a)

}:il::""

determination of srandard
erectrodepotentiar of zinc
erecrode using

(b) The specific conductance


of 0.02 M NaI is 0.235
,0.
Daive the integrated rate

l"l Define

ft)

expression

(i)

threshold en..gy

aod

,", , ,
--l

S cm_l. Calculate

sthndardrr.;1

*lrr"r* Oon*""

"** r*lnoo""'""'

l3l

al
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(ii) temperature coef,ficient


of a reaction.

,, j:]
l*"ll the mechanism
(b) Desoibe

of enzyme catarysis.

the Freundlich adsorptioo

iroti"r*.

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121

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i
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v' Answer any FouR ofthe fortowiug (each question

rl

carries 5 marks)
32' (a) lVrite the organic product
formed in the forowing reactions.

1g4y

acetone
heat

>

(iii) CH3-CH2-CH:CI1 + HBr peroxide_,


chlorobenzene is Iess reactive
than haloarkanes towards

*'

3a' @)

443

K.

*r:m"#fTT*",1,jtr'-Y

ib

I{zSO+ at
(b) Explain Kolbe,s reaction.

121

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33. (a) Give the reaction of ethanol


u,ith.
(i) benzoic acid and conc. H2SOa

(ii)PCC
(iii) Excess conc.

nucreophilic substirution

g.

:::lilrwhv

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co

cH3CrLCHrcl +

+ CH3C}I2-CI ACI'
-

(i)

(ii)

[4x 5=201

romura

"lt*

TJJ
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on hvdrolvsis in acid medium gives


a

ik

;
ffi H[:J'f,,:,*T:l1*,y1]1:,,rd;';;*il'#r""jHHl;ff
rornrs a ketone c with acetvt
ctro.iil;;.;:T,;H;fff;:,;
H"T,trf3;l'::
Identify,\
B and C.
Given

CH, - CHO
Kor{+orhy'm gryor
--IEL:M!--r 1
!b)
, y . What are X and y?
35' (a) Distinguish primary' secondary
and tertiary amines with
Hinsberg reagent- Give equations.
(b) Give the preparation of erhanamine

ia

by Gabrier phtharimide synthesis.

' (a) what

is chain growth porymerization?


Give the synthesis of polyacryronitrile.
(b) What is copoiymerization?
Give an example.

12)

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12)

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**{<

37

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36. (a) Elucidate the open chain


srmcture ofglucose.
(b,) Briefly explainthe
sfucture of DNAiolecule.

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