539

Electrochemistry

1.

The mass of copper deposited from a solution of CuSO4 by

passage of 5 A current for 965 second is
Copper = 63.5)

2.

3.

4.

5.

7.

(Mol. wt. of

Normal aluminium electrode coupled with normal hydrogen

electrode gives an emf of 1.66 volts . So the standard
electrode potential of aluminium is

[AIIMS 2001]

[KCET 1987]

(a) 15.875 g

(b) 1.5875 g

(a) 1.66 V

(b) + 1.66 V

(c) 4825 g

(d) 96500 g

(c) 0.83 V

(d) + 0.83 V

The current in a given wire is 1.8 A. The number of

coulombs that flow in 1.36 minutes will be
[AIIMS 2001]
(a) 100 C

(b) 147 C

(c) 247 C

(d) 347 C

8.

Fe 2 2e Fe(0.44 V )
Ni 2 2e Ni(0.25 V )

A solution of a salt of a metal was electrolysed for 150

minutes with a current of 0.15 amperes. The weight of
metal deposited was 0.783 gm. The equivalent weight of
the metal is
[AFMC 2001]
(a) 55.97 gm

(b) 65.97 gm

(c) 75.97 gm

(d) 85.97 gm

Which one among the following is the strongest reducing

agent

The resistance of 0.01N NaCl solution at 25 o C is 200 .

Cell constant of conductivity cell is 1 cm1. The equivalent
conductance is
[CBSE PMT 1999]

Sn2 2e Sn(0.14V )
Fe 3 e Fe 2 (0.77 V )

9.

[BHU 1998]

(a) Fe

(b) Fe 2

(c)

(d) Sn

The

Ni
cell

Cu(s) | Cu

reaction

(aq) || Hg

of

(aq) | Hg(l )

(a) 5 102 1cm2eq 1

(b) 6 103 1cm2eq 1

(a) Hg Cu 2 Hg 2 Cu

(c) 7 104 1cm2eq 1

(d) 8 105 1cm2eq 1

(b) Hg Cu 2 Cu Hg

Which of the following reaction is possible at anode

(c)

[AIEEE 2002]

(a) 2Cr

7 H2O Cr2O7

14 H

(c)

is

10.

The specific conductivity of N/10 KCl solution at 20o C is

solution at 20o C is 55 ohm. The cell constant is
[AIIMS 1999]

What is the standard cell potential for the cell

(a) 1.166 cm1

Zn / Zn2 (1M)||Cu 2 (1M) / Cu

(b) 2.173 cm1

E o for Zn / Zn2 (1M) 0.76 V & Cu 2 / Cu 0.34 V

(c) 3.324 cm1

(d) 4.616 cm1

[AIIMS 1980]

11.

The oxide which is not reduced by hydrogen is

(b) 0.34 0.76 0.42 V

(c)

0.34 (0.76) 1.10 V

(d) 0.76 (0.34) 1.10 V

[EAMCET 2003]

0.0212 ohm1 cm1 and the resistance of cell containing this

1
O2 2H H 2O
2

(a) 0.76 (0.34) 0.42 V

cell

Cu Hg CuHg

(d) None of these

6.

galvanic

(d) Cu Hg 2 Cu 2 Hg

(b) F2 2F

the

[JIPMER 1999]

(a)

Ag 2O

(b) K 2O

(c)

Fe 2O3

(d) P4 O10

540 Electrochemistry

(SET -12)

1.

(b) Current (I) = 5A and time (t) = 965 sec.

We know that equivalent weight of copper

Molecular weight
63.5
and quantity of electricity

Valancy
2

passed in coulomb = current time = 5 965 =

63.5
4825C. Since 96500 coulombs will deposit
g of
2

5.

(a) Oxidation always occurs at anode.

6.

(c)

E o Ecathode Eanode

E o 0.34 (0.76) ; E o 1.10 volt .

7.

o
o
(a) Ecell
1.66 E H
E oAl 3 / Al

/H
2

O E oAl 3 / Al or E

copper therefore 4825 coulombs will deposit

Al 3 / Al

1.66 V .

63.5 4825
1.5875 g .
96500 2

8.

(a) The reduction potential of Fe is very high, so it is a

strongest reducing agent.

2.

(b) Q I t ; 1.8 1.36 60 147C .

9.

2
(b) Cu(s) | Cu(2Ag
) || Hg( Ag) | Hg(l )

3.

(a) Time (t) = 150 min = 9000 sec

anode oxidation

Current (I) = 0.15 A

Reduction

Weight of metal (w) = 0.783 g.

Cu Hg 2 Cu 2 Hg .

We know Q I t = 0.15 9000 1350 C . Since 1350

C of electricity will deposited 0.783 g of metal, so,
96500 C of electricity will deposited

0.783 96500
55.97 g .
1350
4.

1 l
1
1 10,000
(a) k V V
R a
200

cathode reduction

Oxidation

10.

(a) K

1
cell constant
R

K R 0.0212 55 1.166 cm1 .

11.

(b) On the basis of electrochemical series K 2 O is not

reduced by hydrogen.

5 10 2 1cm2 eq.1

***